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1. IDENTIFICATION
2. HAZARD(S) IDENTIFICATION
Appearance Liquid
Color Colourless.
Odor Ketonic.
GHS Pictogram
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Report Date : 25/06/2013
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Solvent,Case 4, 1 liter, MEK
Controlled Product Classification
B2 D2A D2B
Inhalation
Vapours may cause headache, fatigue, dizziness and nausea.
Ingestion
May cause nausea, headache, dizziness and intoxication.
Skin Contact
Acts as a defatting agent on skin. May cause cracking of skin, and eczema.
Eye Contact
Irritating to eyes.
Route Of Entry
Ingestion. Skin absorption. Inhalation.
3. COMPOSITION/INFORMATION ON INGREDIENTS
4. FIRST-AID MEASURES
5. FIRE-FIGHTING MEASURES
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Report Date : 25/06/2013
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Solvent,Case 4, 1 liter, MEK
Unusual Fire & Explosion Hazards
Take precautionary measures against static discharges.
Specific Hazards
Fire creates: Toxic gases/vapors/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
Special Fire Fighting Procedures
Keep run-off water out of sewers and water sources. Dike for water control. If risk of water pollution occurs, notify appropriate authorities.
Use water to keep fire exposed containers cool and disperse vapors. Move container from fire area if it can be done without risk.
Personal Precautions
Wear protective clothing as described in Section 8 of this material safety data sheet.
Environmental Precautions
Do not discharge into drains, water courses or onto the ground.
Spill Clean Up Methods
Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate.
Reference to other sections
Wear protective clothing as described in Section 8 of this material safety data sheet. See section 11 for more detailed information on health
effects and symptoms. For waste disposal, see section 13.
Handling
Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapors. Use approved
respirator if air contamination is above accepted level.
Storage
Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a dry, cool and
well-ventilated place.
Storage Class
Flammable liquid storage.
Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
COMPONENT IDLH
Solvent,Case 4, 1 liter, MEK 3000 ppm
Protective Equipment
Process Conditions
Use engineering controls to reduce air contamination to permissible exposure level. Provide eyewash station.
Engineering Measures
Well-ventilated area.
Respiratory Equipment
No specific recommendation made, but respiratory protection must be used if the general level exceeds the Recommended Occupational
Exposure Limit
Hand Protection
Protective gloves should be used if there is a risk of direct contact or splash. Be aware that the liquid may penetrate the gloves. Frequent
change is advisable.
Eye Protection
Wear splash-proof eye goggles to prevent any possibility of eye contact.
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Solvent,Case 4, 1 liter, MEK
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene Measures
DO NOT SMOKE IN WORK AREA! Promptly remove any clothing that becomes wet or contaminated. Wash promptly if skin becomes wet
or contaminated. Use appropriate hand lotion to prevent defatting and cracking of skin. When using do not eat, drink or smoke. Wash
hands at the end of each work shift and before eating, smoking and using the toilet.
Appearance Liquid
Color Colourless.
Odor Ketonic.
Solubility Partially miscible with water
Initial boiling point and boiling range ~75-85C @ 760 mm Hg
Melting point (C) -87C
Flash point ~ -3C CC (Closed cup).
Flammability Limit - Lower(%) 1.8
Flammability Limit - Upper(%) 10.1
Not available.
Reactivity
There are no known reactivity hazards associated with this product.
Stability
Stable under normal temperature conditions.
Not available.
Conditions To Avoid
Avoid contact with strong oxidisers.
Materials To Avoid
Strong oxidizing substances.
Hazardous Decomposition Products
Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
Toxicological information
No information available.
Waste Management
Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority.
Disposal Methods
Dispose of waste and residues in accordance with local authority requirements.
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Solvent,Case 4, 1 liter, MEK
UN No. (IMDG) 1193
DOT Proper Shipping Name ETHYL METHYL KETONE OR METHYL ETHYL KETONE
TDG Proper Shipping Name ETHYL METHYL KETONE OR METHYL ETHYL KETONE
TDG Label(s) 3
IMDG Class 3
ICAO Class 3
Transport Labels
FLAMMABLE
LIQUID
3
Transport in Bulk according to Annex II of MARPOL 73/78 and the IBC Code Notes
Not applicable.
US Federal Regulations
SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities
N/A
CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA)
5, 000 lbs (2270 Kg)
SARA 313 Emission Reporting
1.00 %
CAA Accidental Release Prevention
Not listed.
FDA Essential Chemical
N/K.
FDA Precursor Chemical
N/K.
US State Regulations
California Proposition 65 Carcinogens and Reproductive Toxins
Not listed.
Massachusetts "Right To Know" List
Yes.
Rhode Island "Right To Know" List
Yes.
Minnesota "Right To Know" List
Yes.
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Report Date : 25/06/2013
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Solvent,Case 4, 1 liter, MEK
New Jersey "Right To Know" List
Yes.
Pennsylvania "Right To Know" List
Yes.
International Inventories
EU - EINECS/ELINCS
EINECS
Canada DSL/NDSL
Domestic Substance List
US - TSCA
Yes.
US TSCA 12(b) Export Notification
N/A.
Australia - AICS
Yes.
Japan MITI
Yes.
Korea - KECI
Yes.
China - IECSC
Yes.
Phillippines PICCS
Yes.
HEALTH
2
FLAMMABILITY
3
PHYSICAL
0
PERSONAL PROTECTION B
FIRE
(3)
HEALTH
(1) (0)
N/A INSTABILITY
SPECIAL
Disclaimer
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no
warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the
suitability of such information for his own particular use.
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