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Defining the half-life of the reaction, t1/2 , as the time needed for the CA
concentration of reactants to drop to one-half the original value, we obtain In = In (1 XA ) = (k1 + k 2 CC )t = k observed t
CA0
(0.5)1n 1 Autocatalytic Reactions
t1/2 = CA01n A reaction in which one of the products of reaction acts as a catalyst.
k (n 1)
CR
CA0 (C0 CA ) C
Fractional Life Method, R0
In = In = C0 kt = (CA0 + CR0 )kt
CA (C0 CA0 ) CA
C
F1n 1 A0
tf = C 1n
k(n 1) A0 In terms of the initial reactant ratio M = CRdCAO and fractional
conversion of A, this can be written as
M + XA
In = CA0 (M + 1)kt = (CA0 + CR0 )kt
Irreversible Reactions in Parallel M(1 XA )
ek1t ek2t
CR CR0 k1 CR = CA0 k1 ( + )
= k 2 k1 k1 k 2
CS CS0 k 2
k
1 In ( 2k )
1
t max = =
k log mean k 2 k1
INTERPRETATION OF
BATCH REACTOR DATA