PHYSICAL CHEMISTRY

TARGET : JEE (Main) 2017

Course : ABHINAV (EA) NO. 43

This DPP is to be discussed in the week (18-01-2016 to 23-01-2016)

ANSWERE KEY
DPP No. # 43
1. (4) 2. (1) 3. (4) 4. (4) 5. (4) 6. (4) 7. (3)

DPP No. # 43
Total Marks : 21 Max. Time : 14 min.
Single choice Objective ('1' negative marking) Q.1 to Q.7 (3 marks, 2 min.) [21, 14]

1. For which of the following phase transformation G is +ve.

fuEufyf[kr esa ls fdl voLFkk ifjorZu ds fy, G /kukRed (+ve) gS &
(1) H2O (, 1 atm, 373 K) H2O (g, 1 atm, 373K)
(2) H2O (, 0.9 atm, 373 K) H2O (g, 1 atm, 373K)
(3) H2O (s, 1 atm, 273 K) H2O (, 1 atm, 273K)
(4*) H2O (s, 0.9 atm, 273 K) H2O (, 0.9 atm, 273K)
Sol. At pressure less than 1 atm, conversion of ice into water is non spontaneous.
Sol. 1 atm ls U;wu nkc ij, cQZ dk ty esa ifjorZu vLor% ize gSA

2. For a reaction to occur spontaneously-

(1*) (H TS) must be negative (2) (H + TS) must be negative
(3) H must be negative (4) S must be negative
fdlh vfHkf;k ds Lor% pkfyr gksus ds fy;s vko';d] _.k (negative) gksuk pkfg,&
(1*) (H TS) dk (2) (H + TS) dk
(3) H dk (4) S dk

3. The spontaneous nature of a reaction is impossible if :

(1) H is +ve : S is also +ve (2) H is ve; S is also ve
(3) H is ve; S is +ve (4*) H is +ve; S is ve

,d vfHkf;k dh Lor% izd`fr laHko ugha gksxh] ;fn %

(1) H /kukRed : S /kukRed (2) H _.kkRed ; S _.kkRed
(3) H _.kkRed ; S /kukRed (4*) H /kukRed ; S _.kkRed

4. If a chemical reaction is non-spontaneous at high temperatures and spontaneous at low temperatures, then:
(1) H > 0 and S > 0 (2) H > 0 andS < 0 (3) H < 0 and S > 0 (4*) H < 0 and S < 0
;fn ,d jklk;fud vfHkf;k] mPp rki ij vLor% gksrh gS rFkk fuEu rki ij Lor% gksrh gS] rc
(1) H > 0 rFkk S > 0 (2) H > 0 rFkk S < 0 (3) H < 0 rFkk S > 0 (4*) H < 0 rFkk S < 0

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Sol. If H < 0 and S < 0, then reaction is non-spontaneous at high temperatures and spontaneous at low
temperatures.
;fn H < 0 rFkk S < 0, rc] vfHkf;k mPp rki ij] vLor% gksrh gS rFkk fuEu rki ij Lor% gksrh gSA

5. Which of the following reactions is associated with the most negative change in entropy ?
fuEu esa ls dkSulh vfHkf;k ,UVkWih esa lcls _.kkRed ifjorZu j[krh gS %
(1) N2 (g) + 3H2 (g) 2NH3 (g) (2) C2H2 (g) + 2H2 (g) C2H6 (g)
(3) C (s) + O2 CO2(g) (4*) 2NO2 (g) N2O4 (s)
Sol. ng is most ve (ng vf/kd _.kkRed gSA

6. For the process H2O() (1 bar, 373 K) H2O(g) (1 bar, 373 K), the correct set of thermodynamic
parameters is:
ize H2O() (1 bar, 373 K) H2O(g) (1 bar, 373 K), ds fy;s "ekxfrdh iSjkehVj dk lgh leqPp; gS %
(1) G = 0 (2)S > 0 (3) H > 0 (4*) All of these
Sol. H2O(,1bar, 373K) H2O(g, 1bar, 373 K)
S > 0
H > 0
G = 0

7. Which is not true about Gibb's Function (G).

(1) G is a state function .
(2) Decrease in Gibb's energy of reaction is the measure of maximum non PV work obtained.
(3*) If (G)T,P is positive, reaction is spontaneous.
(4) G = G if Keq = 1
fxCl Qyu (G) ds lanHkZ esa fuEu esa ls dkSulk@dkSuls lgh ugha gS@gSa %
(1) G ,d voLFkk Qyu gSA
(2) vfHkf;k dh fxCl tkZ esa deh] izkIr fd;s tk ldus okys vf/kdre PV jfgr dk;Z non PV work) dk eki gSA
(3*) ;fn (G)T,P /kukRed gS] rks vfHkf;k Lor% gksrh gSA
(4) ;fn Keq = 1 gS] rc G = G
Sol. G = G + RT ln Keq, if Keq = 1, G = G

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
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Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029