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TM

Mastering Molecular Science

for Industrial Processing Solutions

Electronic
Chemicals
Electronic chemicals
Huntsman is a leading supplier of processing chemicals and intermediates. Our solutions are employed in some of the worlds most
important industries helping to improve performance and efficacy in a variety of pre-treatment, production and finishing applications.
Key products
To support the worlds leading
semiconductor and electronics
companies we have created an
extensive range of high purity
amines, surfactants, solvents and
related chemicals.
Solutions include photoresist
strippers and cleaners for
semiconductors and flat panels;
CMP slurries and post-CMP cleaners;
electrolytic and electro-less plating
of semiconductor wafers and circuit
boards; reflow fluids for circuit board
soldering fluxes; and sapphire and
silicon wafer cutting fluids.
As a fully integrated supplier, we
also produce many of the basic raw
materials used to manufacture these
products - making us a logical choice
for electronics companies looking for
a long-term formulations partner.
Alkylene carbonates
JEFFSOL and ULTRAPURE grades of ethylene
carbonate (EC) and propylene carbonate (PC)
have excellent solvency, high flash and boiling
points. These versatile products are used in
battery electrolyte formulations and for cleaning
and photoresist stripping applications
E-GRADE AMINES,
ALKANOLAMINES & GLYCOLS
With multiple uses in the manufacture of electronic
components, these specialty chemicals include
photoresist stripper formulations, cleaners and
other applications requiring high purity and
extremely low metal concentrations.
JEFFOX FUNCTIONAL FLUIDS
These functional fluids are used in electronic
applications that require high purity and
temperature stability. For example, they keep solder
stable at high processing temperatures and meet
the specifications of the high-tech electronics
sector.
POGOL GLYCOLS
Used in wafer cutting slurries these polyethylene
glycols are employed in the manufacture of
semiconductors and solar cells.
SURFONIC SURFACTANTS
Offering a wide variety of physical and chemical
properties these products are used in cleaners
and other processing applications requiring
surfactancy.
JEFFAMINE POLYETHERAMINES
Huntsmans JEFFAMINE polyetheramine products
impart properties such as corrosion inhibition, solvent
/ water solubility, dispersing characteristics and
surfactancy. The broad range of molecular weights
available, combined with diverse amine functionality
and repeating unit type and distribution, delivers
versatility for the design of new compounds with
different performance attributes.
Huntsman is a leading global supplier of non-ionic, anionic, cationic, amphoteric and polymeric surfactant products that add value
at the surfaces where materials meet. With an extensive range of intermediates, additives and blends, our surface-active agents
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DQGHPXOVLFDWLRQ

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production, supply and technical support.

Typical properties1

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Appearance at 25C

Ross Miles Foam3,

Ross Miles Foam3,

Product
Performance attributes

6SHFLFJUDYLW\
name
Pour point, C

Viscosity, cPs

Cloud point

mm, initial
CMC, ppm

PPQDO
HLB

LOW FOAM (LF) SURFACTANTS

The SURFONIC LF surfactants family is made up of ethoxylated, propoxylated linear alcohols. The choice of alcohol and the positioning of
ethylene oxide (EO) and propylene oxide (PO) give the alkoxylated products low foaming and good surface active properties.

Good detergency and wetting

SURFONIC 1.003 51
Clear liquid - -5 59 9.8 - 75 70 properties, low freeze point and pour
JL-80X surfactants (25C) (25C)
point.

SURFONIC 0.998 96 Low foaming and good surface active

Clear liquid - -12 34 4.8 6.6 6 0
LF-17 surfactants (25C) (25C) properties.

1
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2
0.1% solution, 25C
3
0.1% solution, 120F
Only selected products have been showcased above. Please approach Huntsman for a full range of surfactant products.

JEFFAMINE POLYETHERAMINES PRODUCTS OVERVIEW

The core JEFFAMINE polyetheramines family consists of monoamines, diamines and triamines based on the core polyether backbone
structure. More recently, the addition of secondary, hindered, high-conversion and polytetramethylene glycol (PTMEG)-based
polyetheramines has increased the utility of these products. The majority of JEFFAMINE polyetheramines are relatively innocuous and easy
to handle.

Series Description Representative structure

O NH2
Monoamines of a polypropylene glycol (PPG) and polyethylene glycol (PEG) H 3C O
M y
backbone
x
R

H 2N NH2
O
D Diamines of a polypropylene glycol (PPG) backbone. x
CH3 CH3

H 2N
Diamines of a polypropylene glycol (PPG) and predominantly polyethylene glycol O NH2
ED O O z
(PEG) backbone.
x y
CH3 CH3 CH3

O NH2
EDR Diamines with a higher reactivity than the D, ED and T series. H 2N x O x

CH3
O
y NH2
T Triamines of a polypropylene glycol (PPG) backbone. H 2N
CH2
n
NH2
O O z
x
CH3 R CH3

THF Diamines of a poly(tetramethylene glycol) (PTMEG) backbone. O

n

CH3 CH3
Secondary amines of a core JEFFAMINESRO\HWKHUDPLQHV7KH6'VLJQLHVD
SD and ST
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 Typical properties1

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Product

Color, Pt-Co, max

DPLQHK\UGRJHQ
Description
name
Appearance

cSt @ 25C

JP/&
Viscosity

Density,

AHEW

eq)
POLYETHERAMINES

+XQWVPDQV-())$0,1( polyetheramines range is one of the most extensive in the world. These highly versatile products contain
primary amino groups attached to the end of a polyether backbone, normally based on propylene oxide, ethylene oxide or a mixture of
both compounds. JEFFAMINE polyetheramine products typically impart amine properties, corrosion inhibition, solvent / water solubility,
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functionality, repeating unit type and distribution, offers great versatility to design new compounds with different performance attributes.

JEFFAMINE M series polyetheramines

M-600 Colorless to light yellow liquid 75 - 0.979 291

O NH2
H 3C O
M-1000 x y
White waxy solid 75 - 1.066 (38C) 489
R

M-2005 Monoamines of a polypropylene glycol (PPG) and Colorless to light yellow liquid 75 131 (38C) 1.000 1045
polyethylene glycol (PEG) backbone
M-2070 Colorless to light yellow liquid 75 186 (38C) 1.072 1040

JEFFAMINE D series polyetheramines

D-230 Colorless to light yellow liquid 25 9.5 0.948 60

H 2N NH2
D-400 O Colorless to pale yellow liquid 30 22 0.972 115
x
CH3 CH3
D-2000 Colorless to pale yellow liquid 25 248 0.991 514
Diamines of a polypropylene glycol (PPG) backbone
D-4000 Light yellow liquid 75 877 0.994 1000

JEFFAMINE ED series polyetheramines

ED-600 H 2N O NH2 Colorless to light yellow liquid 75 72 (20C) 1.035 132

O O z
x y
CH3 CH3 CH3
ED-900 Colorless to light yellow liquid at 60C 100 119 1.065 (38C) 250
Diamines of a polypropylene glycol (PPG) and
ED-2003 predominantly polyethylene glycol (PEG) backbone White waxy solid 75 134 (50C) 1.068 (50C) 575

JEFFAMINE EDR series polyetheramines

EDR-148 O NH2 Colorless to light yellow liquid 50 8 0.998 37

H 2N x O x

Diamines with a higher reactivity than the D, ED and

EDR-176 T series Clear liquid 50 9 0.980 44

JEFFAMINE T series polyetheramines

CH3
O
y NH2
CH2
T-403 H 2N n
NH2 Colorless pale yellow liquid 50 72 0.978 81
O O z
x
CH3 R CH3
Triamines of a polypropylene glycol (PPG) backbone

JEFFAMINE XTJ series polyetheramines

Blend of amines that contains triethyleneglycoldiamine

XTJ-512 along with partially aminated compounds and higher Colorless to pale yellow liquid 125 35 (cP,20C) 1.040 65
oligomers.

Polyethertriamine of approximately 400 molecular

XTJ-566 Colorless to pale yellow liquid 75 31 0.958 77
weight.

Polyetherdiamine of approximately 219 molecular

XTJ-568 Colorless to pale yellow liquid 75 7 (cP,25C) 0.943 55
weight.

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 Typical properties1 Typical applications

Vapor pressure, mm
Product

Max. color, Pt-Co

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Description

Semiconductor
name

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LCD display
Amine type

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E-GRADE AMINES

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polymer removal applications, these high purity materials have a low metal content and are well suited to use in the electronics industry.

Diglycolamine agent O
DGA agent H2N OH 1 35 9.51 105 <0.01
2-(2-aminoethoxy) ethanol

O
N
APM Aminopropylmorpholine 1 / 3 30 10.04 144 0.6
H2N

CH3
MDEA Methyldiethanolamine N 3 150 8.59 119.1 0.021
HO OH
HO CH3
N
MMEA Monomethylethanolamine 2 50 9.95 75.1 0.7
H

NH2
MEA Monoethanolamine HO 1 15 10.03 61.08 0.2

OH

TEA Triethanolamine HO N 3 75 7.76 149.19 <0.01

OH

NMMO + CH3
N-Methylmorpholine oxide O N 4 - pH:9 117 >10
50% Aq O

ETHYLENEAMINES

Huntsman offers a complete line of ethyleneamine products. These materials are useful in a wide range of applications, primarily as
reactive intermediates used to produce other chemical products.

EDA Ethylenediamine H2N NH2 1 15 10.4 60.1 10

H
DETA Diethylenetriamine H2N
N
NH2 1 / 2 30 - 103.1 0.37
H
TETA Triethylenetetramine H2N
N
N
NH2 1 / 2 50 - 151 <0.1
H
H H
TEPA Tetraethylenepentamine H2N
N
N
N
NH2 1 / 2 - - 200 <0.01
H

H
AEEA Aminoethylethanolamine HO
N
NH2
1 / 2 25 9.63 104.2 <0.01

AEP-HP Aminoethylpiperazine-HP HN N 1 / 2 / 3 50 9.15 128 <0.1

NH2

AMMONIUM HYDROXIDE

Huntsman offers a line of TMAH (tetramethylammonium hydroxide) alternatives. It provides a highly basic quaternary ammonium product that
is not in the same toxicity category as TMAH, which is considered to be safer to use.

XHE112 Choline hydroxide 4 5 pH:14 121 -

XTA825 Alkylammonium hydroxide 4 75 pH:13 181 -

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 Typical properties1 Typical applications

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Product

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Max. color, Pt-Co

Description

Semiconductor
name

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JEFFOX SOLDER REFLOW FLUIDS

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CH3
PPG-400 400 75 0.2 -
O
Polypropylene glycol HO n OH
PPG-2000 CH3 2000 50 0.1 -

WL-660 Oxirane, methyl, polymer and oxibane, butyl ether 1,800 - 0.3 -

WL-5000 Oxirane, methyl, polymer and oxibane, butyl ether 4,365 200 0.3 -

ALKYLENE CARBONATES

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plant in the world.
O
JEFFSOL EC
Ethylene carbonate O 88.06 40 0.1 99.5
solvent O
O
JEFFSOL PC O
Propylene carbonate 102.9 40 0.1 99.7
solvent O
O

Unique functionality of hydroxyl

JEFFSOL GC O O group allows glycerine carbonate
Glycerine carbonate 118 75 0.1 91.0
solvent to build into polymer matrix or as
OH intermediate.

O
ULTRAPURE EC 20
Ethylene carbonate O 88 20 99.99
solvent O
ppm

O
ULTRAPURE PC O 20
Propylene carbonate 102.9 20 99.99
solvent O ppm

E-GRADE GLYCOLS

7KHJXDUDQWHHGORZWUDFHPHWDOVFRQWHQWDQGKLJKVSHFLFUHVLVWDQFHORZFRQGXFWLYLW\RI(*5$'( glycols makes them especially

suitable for electronics applications.
OH
EG Glycol Ethylene glycol HO 62.07 5 0.04 99.9

OH
HO
PG Glycol Propylene glycol 76 10 0.2 99.5
CH3

POLYETHYLENE GLYCOLS

Polyethylene glycols are composed of a number of linked oxyethylene groups terminated by hydroxyl groups. They are essentially non-toxic,
and are versatile solvents, diluents and excipients.

POGOL 200 glycol 200 50 0.5 -

POGOL 300 glycol 300 50 0.5 -

HO OH
PEG 4000 Polyethylene glycol O n
4000 50 - -

PEG 6000 6000 50 - -

PEG 8000 8000 50 - -

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* Different JEFFSOL carbonates grades are available from Huntsman.
 Americas
Huntsman Corporation
10003 Woodloch Forest Drive
The Woodlands, Texas, 77380
USA
Tel : +1-281-719-6000
Fax : +1-281-719-6055

Asia Pacific
Huntsman Performance Products
150 Beach Road
#37-00 Gateway West
Singapore 189720
Tel : +65-6297-3363
Fax : +65-6296-3368

Europe, Middle East and Africa

Huntsman Performance Products
Everslaan 45
B-3078 Everberg
Belgium
Tel : +32-2-758-9544
Fax : +32-2-758-9946

Huntsman Corporation warrants only that its

products meet the specifications stated in the sales
contract. Typical properties, where stated, are to be
considered as representative of current production
and should not be treated as specifications. While
all the information presented in this document is
believed to be reliable and to represent the best
available data on these products, HUNTSMAN
MAKES NO WARRANTY OR GUARANTEE OF
ANY KIND, EXPRESS OR IMPLIED, INCLUDING
BUT NOT LIMITED TO ANY WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE, NON-INFRINGEMENT
OF ANY INTELLECTUAL PROPERTY RIGHT OF
ANY THIRD PARTY, OR WARRANTIES AS TO
QUALITY OR CORRESPONDENCE WITH PRIOR
DESCRIPTION OR SAMPLE, AND ANY USER
OF PRODUCTS DESCRIBED HEREIN SHOULD
CONDUCT A SUFFICIENT INVESTIGATION
TO ESTABLISH THE SUITABILITY OF
ANY PRODUCT FOR ITS INTENDED USE
AND ASSUMES ALL RISK AND LIABILITY
WHATSOEVER RESULTING FROM THE USE OF
SUCH PRODUCT, WHETHER USED SINGLY OR
IN COMBINATION WITH OTHER SUBSTANCES.
Products may be toxic and require special
precautions in handling. For all products described
herein, the user should obtain detailed information
on toxicity, together with proper shipping, handling,
and storage procedures, and should comply
with all applicable safety and environmental
standards. The behavior, hazards and/or toxicity
of the products referred to in this publication in
manufacturing processes and their suitability in any
given end-use environment are dependent upon
various conditions such as chemical compatibility,
temperature, and other variables, which may not
be known to Huntsman. It is the sole responsibility
of the user of such products to evaluate the
manufacturing circumstances and the final
products under actual end-use requirements and to
adequately advise and warn future purchasers and
users thereof.

DGA, E-GRADE, JEFFAMINE, JEFFOX,

JEFFSOL, POGOL, SURFONIC and
ULTRAPURE are registered trademarks of
Huntsman Corporation or an affiliate thereof in one
or more, but not all, countries.

Copyright 2015 Huntsman Corporation or an

affiliate thereof. All rights reserved.

www.huntsman.com/performance_products