Beruflich Dokumente
Kultur Dokumente
Chemistry
Time: 2 hours
Note: Question number 1 to 10 carries 2 marks each and 11 to 20 carries 4 marks each.
2. 100 ml of a liquid contained in an isolated container at a pressure of 1 bar. The pressure is steeply increased
to 100 bar. The volume of the liquid is decreased by 1 ml at this constant pressure. Find the H & U.
3. Draw the shape of XeF4 and OSF4according to VSEPR theory. Show the lone pair of electrons on the
central atom
Sol. F
F F O
Xe
(square planar) F S (Trigonal bipyramidal)
F F (sp3d2) (sp3d)
F
F
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HO H
H OH
H OH
HO
Sol. -
O O
CHO
H OH H OH
HO H +
HO H
Ag( NH3 )2
H OH H OH
HO H HO H
(L glu cos e)
HO HO
5. a) Draw New mann`s projection for the less stable staggered form of butane.
b) Relatively less stability of the staggered form is due to
i) Torsional strain.
ii) Vander Waals strain.
iii) Combination of the above two.
Sol. a) CH3
H CH3
. .
. H
H
H
b) Less stability is due to Vander Waals strain
7. AlF3 is insoluble in anhydrous HF but when little KF is added to the compound it becomes soluble. On
addition of BF3 ,AlF3 is precipitated. Write the balanced chemical equations.
8. The crystal AB (rock salt structure) has molecular weight 6.023 y amu. where y is an arbitrary number in
amu.. If the minimum distance between cation & anion is y1/ 3 nm and the observed density is 20 Kg / m3 .
Find the
a) density in Kg / m3 and
b) type of defect
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4 6.023 y
Sol. a) Density = [Since a = 2y1/3]
6.023 1023 8 y 1027
= 5 103 g / m 3
= 5Kg / m 3
b) Since the (density) calculated < density observed, it means the defect is metal excess defect.
Sol. Br
Ag aq.
Aromatic Ion
(highly stable)
Ag
Br Antiaromatic Ion
(highly unstable)
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3 2
1 1 1
2 r r / a
=0= 2 e 0
4 2 a 0 a0
r r
2 = 0 2 = 2a0 = r
a0 a0
h 6.626 1034
b) = =
mv 100 103 100
= 6.62610-35 m = 6.62610-25 A
c) Yis 84Po206
12. On the basis of ground state electronic configuration arrange the following molecules in increasing O-O
bond length order.
KO2, O2, O2[AsF6].
2p y 2p y
2 1
Sol. O 2 = 1s 2 , 1s 2 , 2s 2 , 2s 2 , 2p 2x
2
1
2p z 2p z
10 6
bond order = =2
2
2P 2 2Py
* 2
O +2
2P 2
= 1s2 , * 1s2 , 2s2 , * 2s2 , 2Px2 2Pzy2 * 2p y1
{ }
in [O2 (AsF6 )]
10 5 5
bond order =
2 2
Bond length order is O+2 < O2 < O2
G reaction = 2G f ( NO 2 ) G f ( N 2 O 4 )
0 = 100 100
G = G + RT lnk
G = RT ln Q
= 2.303 .082 298 log 9.9 = 56.0304 Lit atm. = Positive
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14. a) 1.22 g C6H5 COOH is added into two solvent and data of Tb and Kb are given as:-
i) In 100 g CH3COCH3 Tb= 0.17
Kb = 1.7 Kg Kelvin /mol
ii) In 100 g benzene, Tb = 0.13 and Kb = 2.6 Kg Kelvin/mol
Find out the molecular weight of C6H5COOH in both the cases and interpret the result.
b) 0.1 M of HA is titrated with 0.1 M NaOH, calculate the pH at end point. Given Ka(HA)=510-6 and
<< 1
Sol. a) In first case
i) Tb = Kbm
1.22
0.17 = 1.7 M = 122
M 100 10 3
ii) In second case
Tb = Kbm
1.22
0.13 = 2.6
M 100 103
M = 244
Benzoic acid dimerises in benzene
0.1
b) Since at end point molarity of salt = = M
2
pH of salt of weak acid and strong base
( pK w + pK a + logc ) 1
pH = = [14 + 5.3010 + [-1.3010] pH = 9.
2 2
15. NO2 NO2
in not more than four steps. Also mention the temp and reaction
Convert
to
condition.
OH
Conc.H 2 SO 4
NH 4 HS
NaNO2 / HCl
H2 O
0 C 5 C
NO2 NH2 + OH
N
NCl
Cl
16.
+
KCN
DMF
(A)
C2 H5 ONa / C 2 H 5 OH
C6 H5 CHO /
(B)
H3 O
(C)
SOCl2
CH3 NH 2
(D)
Identify A to D.
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IIT-JEE 2004-M-6
CN
Sol. NC Ph
H
A= B=
O NH
COOH CH3
Ph Ph
C= D=
17. A1 & A2 are two ores of metal M. A1 on calcination gives black precipitate, CO2 & water.
n Black solid + CO2 + H2O
atio
l ci n
Ca
A1 dil HCl
KI I 2 + ppt
A 2
roasting
Metal + gas
K 2 Cr2 O7 + H2SO4
green colour
Sol. A1 = Cu(OH) 2 CuCO3
A 2 = Cu 2S
Cu(OH) 2 CuCO 3
Calcination
2CuO + CO 2 + H 2 O
(A1) (Black Solid)
Ni
C C
N
H3C N CH3
OH O
Oxidation state of nickel is +2 and hybridization is dsp2
s = n(n + 2) B.M
n=0
s = 0
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20. An organic compound P having the molecular formula C5H10O treated with dil H2SO4 gives two
compounds, Q & R both gives positive iodoform test. The reaction of C5H10O with dil H2SO4 gives
reaction 1015 times faster then ethylene. Identify organic compound of Q & R. Give the reason for the extra
stability of P.
Sol. CH3
C5 H10 O is
H2C O CH3
Note: FIITJEE solutions to IITJEE, 2004 Mains Papers created using memory retention of select FIITJEE
students appeared in this test and hence may not exactly be the same as the original paper.
However, every effort has been made to reproduce the original paper in the interest of the aspiring
students.
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