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PAPER-1 CODE - 0

Academic Session: 2014-15

ALL INDIA OPEN TEST-1 (AIOT-1)

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR


(JEE ADVANCED PATTERN)
Target : JEE (Main+Advanced) 2015

tc rd ifjos"kd funsZ'k ugha nsa rc rd iz'u i=k dh lhy dks ugha [kksaysA
Date: 22 Feb. 2015 | Duration: 3 Hours | Max. Marks: 216

COURSE : VIJETA (JP), VISHWAAS (JF), VIJAY (JR) & VIVEK (JCC)

Please read the next page & last page of this booklet for the instructions.
(i;k funsZ'kksa ds fy;s bl iqfLrdk ds vxys ,oa vfUre i`"B dks i<+sA)
Resonance Eduventures Pvt. Ltd.
CORPORATE OFFICE : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
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ALL INDIA OPEN TEST-1 (AIOT-1) (JEE ADVANCED PATTERN)
PAPER-1 COURSE : VIJETA (JP), VISHWAAS (JF), VIJAY (JR) & VIVEK (JCC) CODE - 0
IMPORTANT INSTRUCTIONS / egoiw.kZ funsZ'k
A. lkekU; % A. General :
1. This booklet is your Question Paper. Do not break the 1. ;g iqfLrdk vkidk iz'ui=k gSA bldh eqgjsa rc rd u rksMsa
seals of this booklet before being instructed to do so tc rd fujh{kdksa ds }kjk bldk funsZ'k u fn;k tk;sA
by the invigilators.
2. Blank spaces and blank pages are provided in the 2. dPps dke ds fy;s [kkyh i`"B vkSj [kkyh txg bl iqfLrdk esa gh gSA
question paper for your rough work. No additional dPps dke ds fy, dksbZ vfrfjDr dkxt ugha fn;k tk;sxkA
sheets will be provided for rough work.
3. Blank papers, clipboards, log tables, slide rules, 3. dksjs dkxt] fDyi cksMZ (CLIP BOARD)] ykWx rkfydk]
calculators, cameras, cellular phones, pagers and LykbM:y] dSYdqysVj] dSejk] lsyQksu] istj vkSj fdlh izdkj
electronic gadgets are NOT allowed inside the
examination hall.
ds bysDVkfud midj.k ijh{kk de esa vuqefr ugha gSA

4. Write you name and roll number in the space provided 4. bl iqfLrdk ds fiNys i`"B ij fn, x, LFkku esa viuk uke
on the back cover of this booklet. vkSj jksy uEcj fyf[k,A
5. Using a black ball point pen, darken the bubbles 5. ijh ewy i`"B ds cqycqyksa (BUBBLES) dks dkys ckWy IokbaV
on the upper original sheet.
dye ls dkyk djsaA
6. DO NOT TAMPER WITH/MUTILATE THE ORS OR 6. vks-vkj-,l- (ORS) ;k bl iqfLrdk esa gsj&Qsj@fofr u djsaA
THE BOOKLET.
7. On breaking the seals of the booklet check that it 7. bl iqfLrdk dh eqgjsa rksM+us ds i'pkr~ i;k tkp ysa fd blesa
contains all the 54 questions and corresponding
lHkh 54 iz'u vkSj muds mkj fodYi Bhd ls i<+s tk ldrs gSaA
answer choices are legible. Read carefully the
Instructions printed at the beginning of each section.
lHkh [kaMksa ds izkjaHk esa fn;s gq, funsZ'kksa dks /;ku ls i<+saA

B. Filling the ORS vks-vkj-,l (ORS) Hkjuk


B.
Use only Black ball point pen only for filling the ORS. ORS dks Hkjus ds fy, dsoy dkys cky iSu dk mi;ksx dhft,A
8. Write your Roll no. in the boxes given at the top left 8. ORS ds lcls ij cka;s dksus esa fn, x, ckDl esa viuk jksy uEcj
corner of your ORS with black ball point pen. Also, dkys cky ikbUV ls fyf[k, rFkk laxr xksys Hkh dsoy dkys isu ls
darken the corresponding bubbles with Black ball point
Hkfj;sA ORS ds ihNs dh rjQ Hkh viuk jksy uEcj fyf[k, (;fn
pen only. Also fill your roll no on the back side of your ORS
in the space provided (if the ORS is both side printed). ORS nksuksa rjQ Nih gqbZ gSA)
9. Fill your Paper Code as mentioned on the Test Paper 9. ORS ij viuk isij dksM fyf[k, rFkk laxr xksyksa dks dkys
and darken the corresponding bubble with Black ball cky isu ls dkys dhft,A
point pen.
10. If student does not fill his/her roll no. and paper code 10. ;fn fo|kFkhZ viuk jksy uEcj rFkk isij dksM lgh vkSj mfpr
correctly and properly, then his/her marks will not be rjhds ugha Hkjrk gS rc mldk ifj.kke jksd fy;k tkosxk rFkk
displayed and 5 marks will be deducted (paper wise)
from the total.
iz'u&i=k esa izkIrkad ls 5 vad dkV fy, tkosaxsaA

11. Since it is not possible to erase and correct pen filled 11. pawfd isu ls Hkjs x, xksys feVkuk vkSj lq/kkjuk laHko ugha gS
bubble, you are advised to be extremely careful while blfy, vki lko/kkuh iwoZd vius mkj ds xksyksa dks HkjsaA
darken the bubble corresponding to your answer.
12. Neither try to erase / rub / scratch the option nor make the 12. fodYi dks u feVk,a@u Ldzsp djsa vkSj u gh xyr (X) fpUg dks
Cross (X) mark on the option once filled. Do not scribble, HkjsaA ORS dks dkVs u gh QkMs u gh xUnk ugha djsa rFkk dksbZ
smudge, cut, tear, or wrinkle the ORS. Do not put any
stray marks or whitener anywhere on the ORS.
Hkh fu'kku ;k lQsnh ORS ij ugha yxk;sA

13. If there is any discrepancy between the written data 13. ;fn ORS esa fdlh izdkj dh fy[ks x, vkadMksa rFkk xksys fd,
and the bubbled data in your ORS, the bubbled data vkadMksa esa fojks/kkHkkl gS] rks xksys fd, vkadMksa dks gh lgh ekuk
will be taken as final.
tkosxkA
MATHEMATICS
PART- I : MATHEMATICS

MATHEMATICS
SECTION 1 : (Only One option correct Type)
[k.M 1 : (dsoy ,d lgh fodYi dkj)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
bl [k.M esa 8 cgqfodYi 'u gSaA R;sd 'u esa pkj fodYi (A), (B), (C) vkSj (D) gSa] ftuesa ls dsoy ,d lgh gSA
1 1 1 1
1. Let x (sin 1, 1) and t1 = (sin1 x)sin x
, t2 = (sin1 x)cos x
, t3 = (cos 1 x)sin x
and t4= (cos 1 x)cos x
,
then
1 1 1 1
ekuk x (sin 1, 1) vkSj t1 = (sin1 x)sin x , t2 = (sin1 x)cos x , t3 = (cos1 x)sin x
vkSj t4 = (cos1 x)cos x ,
rc
(A) t1 > t2 > t3 > t4 (B) t4 > t3 > t1 > t2 (C) t1 > t2 > t4 > t3 (D) t4 > t3 > t1 > t2
2. If Areas of triangles OAB, OBC, ODC are 1, 3, 6 square units respectively, then the area of
triangle AOD in the figure given below is
;fn OAB, OBC, ODC dk {ks=kQy e'k% 1, 3, 6 oxZ bdkbZ gks] rks fn;s x;s fp=k esa AOD dk {ks=kQy
gksxk -

5 3
(A) (B) (C) 3 (D) 2
2 2

Space for Rough Work / (dPps dk;Z ds fy, LFkku )

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MATHEMATICS
3. If exy f(xy) = ex f(x) + ey f(y), x, y R+ and f (1) = e, then f(x) is

MATHEMATICS
;fn exy f(xy) = ex f(x) + ey f(y), x, y R+ vkSj f (1) = e, rc f(x) gS&
x x 2
x
(A) e nx + 1 (B) e nx (C) e nx (D) e x nx

11
1 log (9x1 7)
1
If ninth term in the expansion of 3 3 1
3
4. is 660, then the value of x is
log3 (3 x1 1)
38
(A) 4 (B) 1 or 2 (C) 0 or 1 (D) 3
11
1 log (9x1 7)
33 3 1
;fn 1 ds foLrkj esa uok in 660 gS] rc x dk eku gS
log3 (3 x1 1)
38

(A) 4 (B) 1 ;k 2 (C) 0 ;k 1 (D) 3


nx
5. Let (k) = x
0
2
kx k 2
dx, (k >0) and k (k) (1) =
3
then value of k is


nx
ekuk (k) = x
0
2
kx k 2
dx (k >0) rFkk k (k) (1) =
3
rc k dk eku gS -

1 3 3/2
(A) (B) 3 (C) e (D) e
3

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MATHEMATICS
a2
6. A hunter's chance of shooting an animal at a distance r is 2 (r > a). He fires when r = 2a if he

MATHEMATICS
r
misses, he reloads and fires again when r = 3a. Further if he misses at r = 3a then he tries again at
r = 4a. This process continuous till r = na. If he misses at a distance na, the animal escape. Find
odd against the event that animal is shot
a2
,d f'kdkjh }kjk r nwjh ij fLFkr tkuoj dks fu'kkuk yxkus dh laHkkouk 2 (r > a) gSA tc r = 2a gS] rc og
r
xksyh nkxrk gS] ;fn mldk fu'kkuk pwdrk gS rks og cUnwd esa xksyh Hkjrk gS rFkk r = 3a ij fQj ls xksyh
nkxrk gSA fQj ls ;fn r = 3a ij og fu'kkuk pwd tkrk gS] rks og r = 4a ij iqu% iz;kl djrk gS ;g izf;k
r = na rd pyrh gSA ;fn na nwjh ij fu'kkuk pwd tkrk gS rks tkuoj Hkkx tkrk gSA "tkuoj ij fu'kkuk
yxrk gS" bl ?kVuk ds foi{k esa la;ksxkuqikr gS&
(A) (n + 1) : 2n (B) (n +1) : (n 1) (C) (n 1) : 2n (D) (n 1) : (n + 1)

7. Let P be a point on the ellipse x2 + 2y2 = 2 with foci S and S'. The locus of incentre of PSS' is a
conic of eccentricity
ekuk fcUnq P nh?kZo`k x2 + 2y2 = 2 ij gS] ftldh ukfHk;k S rFkk S' gSA ;fn PSS' ds vUr%dsUnz dk fcUnqiFk
,d 'kkado gS rks bldh mRdsUnzrk gksxh&
(A) 21 (B) 3 2 2 (C) 2 1 (D) 2( 2 1)

x 1 y 3 z 4
8. Let image of the line in the plane 2x y + z + 3 = 0 be L. A plane
3 5 2
7x + By + Cz + D = 0 is such that it contains the line L and perpendicular to the plane 2x y+ z + 3= 0,
then find the value of B + 3C + D.
x 1 y 3 z 4
ekuk js[kk dk lery 2x y + z + 3 = 0 esa izfrfcEc L gSA ,d lery 7x + By + Cz + D = 0
3 5 2
bl izdkj gS fd blesa js[kk L fLFkr gS rFkk ;g lery] 2x y+ z + 3 = 0 }kjk iznf'kZr lery ds yEcor~ gS]
rc B + 3C + D dk eku gS&
(A) 0 (B) 4 (C) 3 (D) 5

Space for Rough Work / (dPps dk;Z ds fy, LFkku )

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MATHEMATICS

SECTION-2 : (Matrix - Match Type)

MATHEMATICS
[k.M2 : (eSfVDl&lqesy izdkj)
This section contains 2 questions. Each question contains statements
given in two columns, which have to be matched. The statements in
Column-I are labelled A, B, C and D, while the statements in Column-II
are labelled p, q, r, s and t. Any given statement in Column-I can have
correct matching with ONE OR MORE statement(s) in Column-II. The
appropriate bubbles corresponding to the answers to these questions
have to be darkened as illustrated in the following example.
If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s
and t; then the correct darkening of bubbles will look like the following :
bl [k.M esa 2 iz'u gSaA izR;sd iz'u esa nks dkWye esa oO; (statements) fn;s gq,
gSa ftudk lqesy (match) djuk gSA dkWye-I (Column-I) ds oO;ksa dks A, B, C
rFkk D ukfer fd;k x;k gSa tcfd dkWye-II (Column-II) ds oO;ksa dks p, q, r, s
rFkk t ukfer fd;k x;k gSaA dkWye-I (Column-I) esa fn, x, dksbZ ,d oO;
dkWye-II (Column-II) ds ,d ;k ,d ls vf/kd oO; oO;ksa ls lgh lqesy
djrk gSA bu iz'uksa ds mkj fuEufyf[kr mnkgj.k ds vuqlkj mfpr cqYyksa dks
dkyk djds n'kkZuk gSA
;fn lgh leqsy A-p, s vkSj t ; B-q vkSj r; C-p vkSj q; rFkk D-s vkSj t gS; rks lgh
fof/k ls dkys fd, x, cqYys ,sls fn[krs gSa tks fuEufyf[kr gSaA

Space for Rough Work / (dPps dk;Z ds fy, LFkku )

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MATHEMATICS
9. Column- Column-

MATHEMATICS
(A) The number of those tangents to the curve (p) 2
y 2x 4y + 8 = 0 which pass through the point
2 3

(1, 2) is . Then is divisible by


2

sin( cos2 x)
(B) = lim , integral multiple of is (q) 3
x 0 x 2

1 x 2
(C) If greatest value of tan1 , x [0, 1] is , (r) 8
1 x
then is divisible by

(D) If the absolute difference of greatest and least value of (s) 4


1 1 k
cos1 x2, x , , is , then k is less than or equal to
2 2 6

(t) 5

Space for Rough Work / (dPps dk;Z ds fy, LFkku )

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MATHEMATICS
LrEHk- LrEHk -

MATHEMATICS
(A) ;fn o y2 2x3 4y + 8 = 0 dh Li'kZ js[kkvksa dh la[;k tks (p) 2

fcUnq (1, 2) ls xqtjrh gS] gS] rc 2 ftlls HkkT; gS] og gS&

sin( cos2 x)
(B) = lim , rc dk iw.kkd xq.kt gS& (q) 3
x 0 x 2

1 x 2
(C) ;fn tan1 , x [0, 1] dk vf/kdre eku gS , (r) 8
1 x

rc ftlls HkkT; gS] og gS&

1 1
(D) ;fn cos1 x2, x , ds vf/kdre o U;wure ekuksa dk (s) 4
2 2

k
fujis{k vUrj gS] rc k ftl iw.kkd ls de ;k cjkcj gS] og gS&
6
(t) 5

Space for Rough Work / (dPps dk;Z ds fy, LFkku )

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MATHEMATICS
10. Column - I Column - II

MATHEMATICS
y

[tan
1
x]dx
If = lim , + 3 is divisible by
1 2
(A) y
(p) 1
y
1
1 1 x dx
([.] represents greatest integer function) is

1 x2 1
(B) If tan1 : tan1 x = a : 1 (q) 6
x

then 2a is greater than or equal to

3
x 2 .sin(x!)
(C) lim is less than or equal to (r) 3
x (x 1)

(D) The number of real solution of the equation (s) 2

1 cos 2x = 2 sin1 (sin x), x is .

Integral multiple of is
(t) 4

Space for Rough Work / (dPps dk;Z ds fy, LFkku )

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MATHEMATICS
LrEHk- LrEHk -

MATHEMATICS
y

[tan
1
x]dx
(A) ;fn = ylim 1
y
, rc + 3 ftlls
2
HkkT; gS] og gS& (p) 1

1
1 1 x dx
([.]egke iw.kkd Qyu dks O;Dr djrk gS)

1 x2 1
(B) ;fn tan1 : tan1 x = a : 1 (q) 6
x

rc 2a ftlls cMk ;k cjkcj gS] og gS&

3
x 2 .sin(x!)
(C) lim dk eku ftlls NksVk ;k cjkcj gS] og gS& (r) 3
x (x 1)

(D) ;fn lehdj.k 1 cos 2x = 2 sin1 (sin x), x (s) 2

ds okLrfod gyksa dh la[;k gS] rc dk iw.kkd xq.kt gS&

(t) 4

Space for Rough Work / (dPps dk;Z ds fy, LFkku )

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MATHEMATICS

SECTION 3 : (Integer value correct Type)

MATHEMATICS
[k.M 3 : (iw.kkd eku lgh dkj)
This section contains 8 questions. The answer to each question is a Single digit integer, ranging
from 0 to 9 (both inclusive).
bl [k.M esa 8 'u gSaA R;sd 'u dk mkj 0 ls 9 rd nksuksa 'kkfey ds chp dk ,dy vadh; iw.kkd gSA
1 1
x x
11. The value of x(x Q) satisfying 4 x 3 2
= 3 2
22x 1 , is p, then value of 6p is
1 1
x x
lehdj.k 4 x 3 2
= 3 2
22x 1 dks larq"V djus okys x(x Q) dk eku ;fn p gS] rc 6p dk eku gksxk&

12. If a + b = 3 cos 4 and a b = 4 sin 2, then find maximum value of ab.


;fn a + b = 3 cos 4 vkSj a b = 4 sin 2, rc ab dk vf/kdre eku Kkr dhft,A

13. Let a and b be unit vectors that are perpendicular to each other, then box product


a a b

b a b a b is equal to




ekuk a vkSj b nks ijLij yEcor~ bdkbZ lfn'k gS] rc vfn'k f=kd xq.ku a a b b a b a b dk

eku gS&

14. A point D is taken on the side AC of an acute triangle ABC, Such that AD = 1, DC = 2 and BD is an
altitude of ABC. A circle of radius 2, which passes through points A and D, touches the
N2
circumcircle of triangle BDC at point D. If area of ABC is N, then the value of .
15
,d U;wudks.k ABC dh Hkqtk AC ij fcUnq D bl izdkj gS fd AD = 1, DC = 2 rFkk BD, ABC dk ,d
'kh"kZyEc gSA 2 f=kT;k dk ,d o`k gS tks fcUnqvksa A rFkk D ls xqtjrk gS rFkk BDC ds ifjo`k dks fcUnq D ij Li'kZ
N2
djrk gSA ;fn ABC dk {ks=kQy N gS] rc dk eku gS&
15

Space for Rough Work / (dPps dk;Z ds fy, LFkku )

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MATHEMATICS
2 1 1 1 1
15. The sequence { an } is defined by ak + 1 = ak + ak, a1 = and P = .......... .

MATHEMATICS
2 a1 1 a2 1 a100 1
(where [.] the greatest integer function). The value of P + 4 is
1 1 1 1
vuqe { an } tks fd ak + 1 = ak2 + ak, a1= }kjk ifjHkkf"kr gS rFkk P = .......... .
2 a
1 1 a 2 1 a100 1

(tgk [.] egke iw.kkd Qyu dks O;Dr djrk gS). rc P + 4 dk eku gS&

16. Let 22 + 6 + 5 2 = 1, where R. Then maximum value of (22 1) is


ekuk 22 + 6 + 52 = 1, tgk R gS] rc (22 1) dk vf/kdre eku gS&

17. If z1, z2, z3 are the vertices of an equilateral triangle inscribed in the circle |z| = 1 then find square
of area of quadrilateral formed by z1 , z2 , z3 , z2 .

;fn z1, z2, z3 ,d leckgq f=kHkqt ds 'kh"kZ gS tks fd o`k |z| = 1 ds vUrxZr gS] rc z1 , z2 , z3 , z2 ls cuus okys
prqHkqZt ds {ks=kQy ds eku dk oxZ gS&

18. A pair of fair dice is rolled together till a sum of either 5 or 7 is obtained. If P denotes the probability
that 7 comes before 5, find 5P.
fu"i{kikrh ikalks ds ,d ;qXe dks rc rd Qsadk tkrk gS tc rd fd ;ksx 5 ;k 7 ugha vk tkrkA ;fn ;ksx 5 ls igys
7 vkus dh izkf;drk P gS] rc 5P dk eku gS&

Space for Rough Work / (dPps dk;Z ds fy, LFkku )

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PHYSICS
PART - II : PHYSICS

PHYSICS
SECTION-1 : (Only One option correct type)
[k.M1 : (dsoy ,d lgh fodYi dkj)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
bl [k.M esa 8 cgqfodYi 'u gSA R;sd 'u esa pkj fodYi (A), (B), (C) vkSj (D) gS] ftuesa ls dsoy ,d
lgh gSA
19. In the circuit shown in the figure key k1 is open. The charge on capacitor C in steady state is q1.
Now the key is closed and at steady state charge on C is q2. The ratio of charges q1/q2 is
fp=k esa iznf'kZr ifjiFk esa dqath k1 [kqyh gqbZ gSA LFkk;h voLFkk esa la/kkfj=k C ij vkos'k q1 gSA vc dqath cUn
dh tkrh gS] rFkk la/kkfj=k C ij LFkk;h voLFkk ij vkos'k q2 gSA vkos'kksa dk vuqikr q1/q2 gksxkA
R1 = 2 K1

C R2 = 3
E

(A) 5/3 (B) 3/5 (C) 1 (D) 2/3

20. A ray is incident normally on face AC of a right angled prism as shown in the figure. The total
deviation in the path of this ray as it emerges out of the prism is :
,d izdk'k dh fdj.k fp=k esa iznf'kZr ledks.kh; fizTe ds Qyd AC ij vfHkyEcor~ vkifrr gksrh gSA tc ;g
fizTe ls fuxZr gksrh gSA rc bl fdj.k ds iFk esa dqy fopyu gksxkA
A

(dPps
Space for Rough Work / 45 dk;Z ds fy, LFkku)
=2

C B
(A) 120 (B) 0 (C) 180 (D) 150

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS

21. An ac circuit consists of L(XL = 7 ), R = 4 and C(XC = 4 ) in series. The potential difference

PHYSICS
across R and C is V1 and that across L, C and R is V2.The phase angle between V1 and V2 is :
,d izR;korhZ /kkjk ifjiFk Js.khe esa tqM+s L(XL = 7 ), R = 4 rFkk C(XC = 4 ) ls cuk gSA R rFkk C ds
fljksa ij foHkokUrj V1 gS rFkk L,C o R ds fljks ij foHkokUrj V2 gSA V1 rFkk V2 ds e/; dyk dks.k gksxk :
(A) 45 (B) 82 (C) 98 (D) 53

22. In the circuit shown, after sufficiently long time in position 1 of the switch, so that current is steady
in the circuit, the switch is changed over to position 2. the maximum voltage that can be develop
across L.
nf'kZr ifjiFk esa fLop ds fLFkfr 1 esa i;kZIr yEcs le; rd jgus ds i'pkr~] rkfd ifjiFk esa /kkjk LFkk;h gks]
fLop dks fLFkfr 2 esa ifjofrZr fd;k tkrk gSA rc L ds fljksa ij mRiUu vf/kdre oksYVst gks ldrk gSA

(A) 100 V (B) 100 2V (C) 100 5V (D) 200 V

23. Two identical bricks of length L are piled one on top of the other on a table as shown in the figure. The
maximum distance S the top brick can overhang the table with the system still balanced is:
L yEckbZ dh nks ,d leku bZaV est+ ij ,d nwljs ds ij fp=kkuqlkj j[kh gqbZ gSA ijh bZaV ds fy, vf/kdre
nwjh S dk eku D;k gksuk pkfg,] fd lEiw.kZ fudk; est+ ij lkE; voLFkk dh fLFkfr esa jgsA
L
Space for Rough Work / (dPps dk;Z ds fy, LFkku)

S
1 2 3 7
(A) L (B) L (C) L (D) L
2 3 4 8

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS
24. A long plank of mass M is initially at rest on a frictionless surface. A small block with mass m and
initial speed u0 slides on top of the larger plank. The coefficient of friction between the block and

PHYSICS
plank is . Net work done by friction on system if the top block falls off the plank after sliding over its
length L is
Mm M
(A) mgL (B) gL (C) gL (D) MgL
M Mm
u0
m
M
L
M nzO;eku dk ,d yEck xqVdk ?k"kZ.kjghr lrg ij izkjEHk esa fojkekoLFkk esa gSA m nzO;eku dk NksVk CykWd
izkjfEHkd pky u0 ls c<+s xqVds dh ijh lrg ij fQlyrk gSA CykWd rFkk xqVds ds e/; ?k"kZ.k xq.kkad gSA
NksVs CykWd }kjk c<+s xqVds ij L yEckbZ fQlyus ds i'pkr~ fxjus rd ?k"kZ.k cy }kjk fudk; ij fd;k x;k
dqy dk;Z gksxkA
Mm M
(A) mgL (B) gL (C) gL (D) MgL
M Mm

25. A girl throws a ball with an initial velocity v at an angle of 45. The ball strikes a smooth vertical
wall at a horizontal distance d from the girl and after rebound returns to her hands. What is the
2
coefficient of restitution between wall and ball ? (v > dg)
,d yMdh izkjfEHkd osx v ls 45 dks.k ij xsan Qsdrh gSA yMdh ls {kSfrt nwjh d ij fLFkr fpduh /okZ/kj
nhokj ij xsan Vdjkrh gS rFkk okil yMdh ds gkFk esa vk tkrh gSA xsan rFkk nhokj ds chp izR;koLFkrk xq.kakd
D;k gksxkA (v2 > dg)
v 2 gd gd gd v2
(A) (B) (C) (D)
gd v gd
2
v2 gd
26. An ideal organ pipe resonates at successive frequencies of 50 Hz, 150 Hz, 250 Hz, etc.
(speed of sound = 340 m/s) The pipe is
(A) open at both ends and of length 3.4 m
(B) open at both ends and of length 6.8 m
Space for Rough Work / (dPps dk;Z ds fy, LFkku)
(C) closed at one end, open at the other, and of length 1.7 m
(D) closed at one end, open at the other, and of length 3.4 m
,d vkn'kZ vkxZu ikbZi ekxr 50 Hz, 150 Hz, 250 Hz, bR;kfn vko`fr;ksa ds lkFk vuqukfnr gSA (/ofu dh
pky = 340 m/s) ikbZi gksxkA
(A) nksuksa fljksa ls [kqyk rFkk 3.4 m yEckbZ dk
(B) nksuksa fljksa ls [kqyk rFkk 6.8 m yEckbZ dk
(C) ,d fljsa ls [kqyk rFkk nwljs fljs ls cUn rFkk 1.7 m yEckbZ dk
(D) ,d fljsa ls [kqyk rFkk nwljs fljs ls cUn rFkk 3.4 m yEckbZ dk

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS

SECTION-2 : (Matrix - Match Type)

PHYSICS
[k.M2 : (eSfVDl&lqesy izdkj)
This section contains 2 questions. Each question contains statements
given in two columns, which have to be matched. The statements in
Column-I are labelled A, B, C and D, while the statements in Column-II are
labelled p, q, r, s and t. Any given statement in Column-I can have correct
matching with ONE OR MORE statement(s) in Column-II. The appropriate
bubbles corresponding to the answers to these questions have to be darkened as illustrated in the
following example. If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s and t;
then the correct darkening of bubbles will look like the following :
bl [k.M esa 2 iz'u gSaA izR;sd iz'u esa nks dkWye esa oO; (statements) fn;s gq, gSa
ftudk lqesy (match) djuk gSA dkWye-I (Column-I) ds oO;ksa dks A, B, C rFkk D
ukfer fd;k x;k gSa tcfd dkWye-II (Column-II) ds oO;ksa dks p, q, r, s rFkk t
ukfer fd;k x;k gSaA dkWye-I (Column-I) esa fn, x, dksbZ ,d oO; dkWye-II
(Column-II) ds ,d ;k ,d ls vf/kd oO; oO;ksa ls lgh lqesy djrk gSA bu iz'uksa ds mkj fuEufyf[kr
mnkgj.k ds vuqlkj mfpr cqYyksa dks dkyk djds n'kkZuk gSA ;fn lgh leqsy A-p, s vkSj t ; B-q vkSj r; C-p
vkSj q; rFkk D-s vkSj t gS; rks lgh fof/k ls dkys fd, x, cqYys ,sls fn[krs gSa tks fuEufyf[kr gSaA

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS

27. A circular wire lying in the X Y plane has charge density = 0 sin (0 is positive). Points A, B,

PHYSICS
C and D are shown in the figure. Point E lies on Z axis above origin. Match the description in
Column with the points in Column .

Column Column

(A) Direction of electric field is along j (p) A

(B) Direction of electric field is along j (q) B
(C) Potential is zero (taking infinity as reference) (r) C
(D) Potential is positive (taking infinity as reference) (s) D
(t) E
,d o`kh; rkj ftl ij vkos'k ?kuRo = 0 sin (0 /kukRed gS) gS] dks XY ry esa j[kk x;k gSA fp=k esa
A,B, C rFkk D fcUnq n'kkZ;s x;s gSA fcUnq E, Z v{k ij ewy fcUnq ds ij mifLFkr gS rks dkWye esa fn;s x;s
fooj.k dks] dkWye esa fn;s fcUnqvksa ls feyku djsaA

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

dkWye dkWye

(A) fo|qr {ks=k dh fn'kk j ds vuqfn'k gS (p) A

(B) fo|qr {ks=k dh fn'kk j ds vuqfn'k gS (q) B
(C) fo|qr foHko 'kwU; gS (funsZ'k ds :i esa vuUr dks ysrs gq,) (r) C
(D) fo|qr foHko /kukRed gS (funsZ'k ds :i esa vuUr dks ysrs gq,) (s) D
(t) E

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS

28. Entries in column-I describe quantities x and y and certain change in physical situation. Match

PHYSICS
these entries to all possible entries in column-II describing corresponding changes in x and y.
Column-I Column-II
(A) If radius of capillary tube is decreased (p) x increases
x = mass of liquid rising in a capillary tube of sufficient length
y = height of liquid rising in a capillary tube of sufficient length
(B) If the spring is replaced by a smaller piece of same spring to (q) x decreases
keep a block at rest

x = extension of spring supporting the block at rest in equilibrium


y = elastic potential energy stored in the spring
(C) If oscillation amplitude is increased from 1 to 2 (r) x remains unchanged
x = Time period of simple pendulum
y = Oscillation energy of simple pendulum
(D) A sphere is projected vertically downwards with speed more than (s) y increases
terminal speed then as time passes
x = Magnitude of acceleration of the sphere
y = viscous force on the sphere. (t) y decreases
LrEHk-I esa nks jkf'k;kas x rFkk y esa dqN HkkSfrd ifjorZu n'kkZ;k x;k gSA bu lwpukvksa ds vk/kkj ij LrEHk -II dks nh
xbZ lwpukvksa ls lqesfyr dhft,A
LrEHk-I LrEHk -II
(A) ;fn ds'k uyh dh f=kT;k ?kVk;h tk;sA (p) x c<+sxkA
x = ds'k uyh esa fuf'pr pkbZ rd p<s gqbZ nzo dk nzO;eku
y = ds'k uyh esa fuf'pr pkbZ rd p<s gqbZ nzo dh pkbZ
(B) ;fn CykWd dks fojke esa j[kus ds fy, iznf'kZr fLiazx dks (q) x ?kVsxkA
leku fLiazx ds NksVs VqdM+s ls izfrLFkkfir dj fn;k tk;s rks
Space for Rough Work / (dPps dk;Z ds fy, LFkku)

x = lkE; voLFkk esa fojke :i ls yVds gq, CykWd ls tqM+h gqbZ fLiazx esa izlkj gSA
y = fLiazx esa lafpr izR;kLFk fLFkfrt tkZ gSA
(C) ;fn nkSyu dk vk;ke 1 ls c<+dj 2 gks tk;s] rks (r) x vifjofrZr jgsxkA
x = ljy ykSyd dk vkorZdky
y = ljy ykSyd dh nkSyu tkZ
(D) ,d xksys dks m/okZ/kj uhps dh rjQ lhekUr pky ls (s) y c<+sxkA
vf/kd pky }kjk iz{kSfir fd;k tkrk gSS] rks le; xqtjus ds lkFk
x = xksys ds Roj.k dk ifjek.k
y = xksys ij ';ku cy (t) y ?kVsxkA

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS

SECTION-3 : (Integer value correct Type)

PHYSICS
[k.M3 : (iw.kkZad eku lgh dkj)
This section contains 8 questions. The answer to each question is a single digit integer, ranging
from 0 to 9 (both inclusive)
bl [k.M esa 8 'u gSA R;sd 'u dk mkj 0 ls 9 rd nksauks 'kkfey ds chp dk ,dy vadh; iw.kkZad gSA

29. Monochromatic light of wavelength passes through a pair of slits S1 and S2, separated by a
distance equal to fringe width . There is a screen placed at a distance D in which two parallel slits

S1 and S 2 are cut at the positions of 3rd and 4th maxima. Again there is a screen at a distance

D. P is a point at a distance of from the central line of the first pair of slits S1 and S2 ,, while Q
2

is on the central line of the second pair of slits S1 and S 2 . All slits are of same widths. If the
x
intensity of light at the point P is and the intensity at Q is , then find the value of x.
4
rjaxnS/;Z dk ,d o.khZ; izdk'k fat pkSM+kbZ ds cjkcj nwjh ls i`FkDd`r fLyV S1 rFkk S2 ds ;qXe ls xqtjrk
gSA D nwjh ij ,d inkZ j[kk gqvk gS] ftlesa rhljh o pkSFkh vf/kdre fnIr dh fLFkfr;ksa ij nks lekUrj fLyV

S1 rFkk S 2 dV dh tkrh gSA iqu% D nwjh ij ,d inkZ j[krs gSaA P fLyV S1 rFkk S2 ds izFke ;qXe dh

dsfUnz; js[kk ls nwjh ij gS tcfd Q, S1 rFkk S 2 ds f}rh; ;qXe dh dsfUnz; js[kk ij gSA lHkh fLyVsa
2
x
leku pkSM+kbZ dh gSA ;fn fcUnq P ij izdk'k dh rhozrk gS rFkk Q ij rhozrk gS, rc x dk eku Kkr djksA
4

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS
30. A large open tank is filled with water upto a height H. A small hole is made at the base of the tank.

PHYSICS
H
It takes T1 time to decrease the height of water to (n > 1) and it takes T2 time to take out the
n
remaining water. If T1 = T2, then the value of n is :
,d foLr`r [kqyk Vsad H pkbZ rd ikuh ls Hkjk gqvk gSA Vsad ds ryh esa ,d NksVk Nsn fd;k tkrk gSA blesa
H
ikuh dk Lrj (n > 1) rd ?kVus esa T1 le; yxrk gS rFkk ;g 'ks"k ikuh [kkyh djus esa T2 le; ysrk gSA
n
;fn T1 = T2 gS rc n dk eku gS :

31. A 1kg ball is suspended in a uniform electric field with the help of a string fixed to a point. The ball
0
is given a charge 5 coulomb and the string makes an angle 37 with the vertical in equilibrium
position. In the equilibrium position the tension is double the weight of the ball. Find the magnitude
of the electric field in N/C.
1kg nzO;eku dh ,d xsan fdlh fcUnq ij fLFkj tM+or~ Mksjh dh lgk;rk ls ,dleku fo|qr {ks=k esa yVdh gqbZ
gSA xsan dks 5 dwykWe vkos'k fn;k tkrk gS rFkk Mksjh lkE;koLFkk dh fLFkfr esa /okZ/kj ds lkFk 370 dk dks.k
cukrh gSA lkE;koLFkk dh fLFkfr esa ruko xsan ds Hkkj dk nqxquk gSA fo|qr {ks=k dk ifjek.k U;wVu@dwykWe esa Kkr
djksA

32. Uniform magnetic field 5T exists in a circular region of radius 1m. A particle having specific charge
q
enters the region with velocity v0 as shown. v0 is such that the particle passes through the
m
q
center O of the region. If V0 = p , then find the value of p. [Assume = 30]
m
q
5T dk ,dleku pqEcdh; {ks=k 1m f=kT;k ds o`kkdkj {ks=k esa fLFkr gSA fof'k"V vkos'k dk ,d d.k v0 osx
m
ls bl {ks=k esa fp=kkuqlkj izos'k djrs gSaA v0 bl izdkj gS fd d.k {ks=k ds dsUnz O ls xqtjrk gSA ;fn
q = 30]
V0 = p rc p dk Space
eku Kkrfordhft,A
Rough[ekukWork / (dPps dk;Z ds fy, LFkku)
m

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS

33. A sphere P(emissivity =1) of radius 2R and another sphere Q (emissivity =1/2) of radius R are

PHYSICS
placed in vacuum at some distance. There are no other objects. The temperature of the sphere Q
is maintained at 200K by the means of a heater. A fraction 1/32 of the power emitted by the
sphere Q falls on the sphere P. If the equilibrium temperature of the sphere P is 10 T, find the
value of T.
2R f=kT;k dk ,d xksyk P (mRltZdrk =1) rFkk R f=kT;k dk vU; xksyk Q(mRltZdrk =1/2) dqN nwjh ij
fuokZr esa j[ks gq, gSaA ogkW vU; dksbZ oLrq,sa ugha gSA xksys Q dk rki ghVj dh lgk;rk ls 200K ij O;ofLFkr
j[kk tkrk gSA xksys Q }kjk mRlftZr 'kfDr dk 1/32 va'k xksys P ij fxjrk gSA ;fn xksys P dk lkE;rki 10 T
gS, rks T dk eku Kkr djksA

34. A block of mass m is released on a smooth inclined wedge of inclination 30 and mass M. Height
2
of the block (from ground) varies with time as h = 1.5 1.5t . (h in metre and t = time in second).
x 2
The acceleration of M is m/s . Find the value of x :
3
M nzO;eku rFkk 30 dks.k dh fpduh ur lrg okys ost ij m nzO;eku ds CykWd dks NksM+k tkrk gSA CykWd dh
tehu ls pkbZ le; ds lkFk h = 1.5 1.5t2 }kjk nh tkrh gSA (h ehVj esa gS rFkk t = lsd.M esa gSA) ;fn M
x 2
dk Roj.k m/s gks rks x dk eku Kkr djks :
3

Space for Rough Work / (dPps dk;Z ds fy, LFkku)


Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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PHYSICS
35. An ideal gas has adiabatic exponent . In a process its molar heat capacity varies with temperature

PHYSICS
as C = . Work performed by one mole of gas during its heating from T0 to nT0 is given by
T
4RT0
W = n5 then find the value of n.
1

,d vkn'kZ xSl dk :)kS"e xq.kkad gSA bl ize esa bldh eksyj "ek /kkfjrk rkieku ds lkFk C = ds
T
}kjk ifjofrZr gksrh gSA T0 ls nT0 rkieku rd xSl dks xeZ djus ds nkSjku ,d eksy xSl }kjk fd;k x;k dk;Z
4RT0
W = n5 gks rks n dk eku Kkr dhft,A
1

36. A soap bubble of radius R is surrounded by another soap bubble of radius 2R, as shown. Take
surface tension = S. The pressure inside the smaller soap bubble, in excess of the atmospheric
nS
pressure is , then find the value of n.
R

Atmosphere
R f=kT;k dk ,d lkcqu dk cqycqyk fp=kkuqlkj 2R f=kT;k ds vU; lkcqu ds cqycys ls f?kjk gqvk gSA i`"B
nS
ruko = S gSA NksVs lkcqu ds cqycqys esa nkc ok;qe.Myh; nkc dh rqyuk esa vf/kd gks rks n dk eku Kkr
R
dhft,A

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

ok;qe.My

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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CHEMISTRY
PART III : CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,

CHEMISTRY
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION 1 : (Only One option correct Type)


[k.M 1 : (dsoy ,d lgh fodYi dkj)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
bl [k.M esa 8 cgqfodYi 'u gSaA R;sd 'u esa pkj fodYi (A), (B), (C) vkSj (D) gSa] ftuesa ls dsoy ,d lgh gSA

+
37. Fe(+III) and Ru(+III) form basic acetates of the type [Fe3O(CH3COO)6(H2O)3] .
The structure consists of a triangle of three Fe atoms with an O atom at the centre. The six acetate
groups act as bridges between the Fe atoms, two groups across each edge of the triangle. Thus
each Fe atoms is linked to four acetate groups and the central O and the sixth position of the
octahedron is occupied by water or another ligand. Spin only magnetic moment of
+
[Fe3O(CH3COO)6(H2O)3] per octahedral unit is :

Space for Rough Work / (dPps dk;Z ds fy, LFkku )

(A) Zero (B) 1.73 BM (C) 4.9 BM (D) 5.9 BM

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Fe(+III) rFkk Ru(+III), [Fe3O(CH3COO)6(H2O)3]+ izdkj ds {kkjh; ,flVsV dk fuekZ.k djrs gSA bldh

CHEMISTRY
lajpuk esa dsUnz ij] ,d vkWDlhtu ijek.kq ds lkFk] rhu Fe ijek.kq f=kdks.kh; :i ls O;ofLFkr gksrs gSaA N%

,flVsV lewg] Fe ijek.kqvksa ds e/; lsrq ds leku dk;Z djrs gSaA f=kdks.k ds izR;sd Hkqtk ij nks lewg mifLFkr

gksrs gSA bl izdkj izR;sd Fe ijek.kq] pkj ,flVsV lewgksa rFkk ,d dsfUnz; O ijek.kq ls la;ksftr gksrk gS rFkk

v"VQyd dh 6th fLFkfr ty vFkok vU; fyxs.M }kjk iw.kZ dh tkrh gSA ladqy [Fe3O(CH3COO)6(H2O)3]+

dk p.k dsoy pqEcdh; vk?kw.kZ izfr v"VQyd bdkbZ gS %

(A) 'kwU; (B) 1.73 BM (C) 4.9 BM (D) 5.9 BM

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38. What is difference in the density (in gram/litre) of dry air at 1 atm and 27C and moist air with
relative humidity 40% under same condition. Given that the vapour pressure of water is 19 torr at

CHEMISTRY
1
27C and dry air has 80% N2 and 20% O2 by volume. [Take R = atm mol K ]
12
27C rFkk 1 atm ij 'kq"d ok;q ds ?kuRo rFkk leku ifjfLFkfr;ksa ij 40% vkisf{kd vknzZrk ;qDr ue ok;q ds
?kuRo (xzke@yhVj) esa D;k vUrj gS\ fn;k x;k gS fd] 27C ij ty dk ok"i nkc 19 Vksj gS rFkk 'kq"d ok;q esa
1
80% N2 rFkk 20% O2 vk;ru ds vuqlkj mifLFkr gSA [yhft;s R = atm mol K ]
12
3 3 3 3
(A) 2.32 10 g/L (B) 6.24 10 g/L (C) 1.64 10 g/L (D) 4.32 10 g/L

39. Which reaction is possible ?


dkSulh vfHkf;k lEHko gS \
(A) MgCl2 (aq) + NaNO3 (aq) (B) BaCO3 (s) + CH3COOH (aq)

(C) BaSO4 (s) + HCl(aq) (D) CoCl2 (aq) + H2S(aq) + HCl (aq)

40. A real gas obeys the equation P(Vm b) = RT, where b = 0.1 L/mol. If 2 mole of gas is slowly
compressed from 1.2 L to 0.6 L at a constant temperature of 300 K, calculate the work done by the
gas in this process.
,d okLrfod xSl] lehdj.k P(Vm b) = RT dk ikyu djrh gS] ;gk b = 0.1 L/mol gSA ;fn 300 K fu;r
rki ij 2 eksy xSl /khjs&/khjs 1.2 L ls 0.6 L rd lEihfMr gksrh gSA rc bl ize esa xSl }kjk fd;k x;k dk;Z
ifjdfyr dhft,A
(A) 4.59 KJ (B) 3.65 KJ (C) 5.35 KJ (D) Zero 'kwU;

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41. Which of the following statements is incorrect ?
(A) CH3COCH3 & CHCl3 Hsolution < 0 & Vsolution < 0

CHEMISTRY
(B) When mercuric iodide is added to an aqueous solution of potassium iodide then freezing point
of KI solution is raised and its boiling point is lowered.
(C) NaCl is less soluble in acetone than H2O.
(D) H2O and (CH3)3OH Hsolution < 0 & Vsolution < 0

fuEu esa ls dkSulk dFku xyr gS\


(A) CH3COCH3 o CHCl3 Hfoy;u < 0 o Vfoy;u < 0

(B) tc ejD;wfjd vk;ksMkbM dks iksVsf'k;e vk;ksMkbM ds ,d tyh; foy;u esa feykrs gSa rc KI foy;u ds
fgekad esa o`f) gksrh gS rFkk blds DoFkukad esa deh gksrh gSA
(C) NaCl, H2O dh vis{kk ,lhVksu esa de foys;'khy gSA
(D) H2O rFkk (CH3)3OH Hfoy;u < 0 o Vfoy;u < 0

42. (i) S8 + NaOH(aq) (ii) SF4 + H2O(l)


(iii) Na2S2O3 + HCl(aq) (iv) H2S(aq) + SO2(g)
Which of the above reactions give one of the product as precipitate?
(A) (i) only (B) (i) and (iii) (C) (iii) and (iv) (D) (ii) and (iv)
mijksDr esa ls dkSulh vfHkf;k vo{ksi ds :i esa ,d mRikn nsrh gS\
(A) dsoy (i) (B) (i) rFkk (iii) (C) (iii) rFkk (iv) (D) (ii) rFkk (iv)

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CONH2

CHEMISTRY
43.

Which statement is incorrect :


(A) Reduced product of P and Q will be metamers to each other.
(B) By dry distillation of hydrolysed products of P with Ca(OH)2, gives benzophenone.
(C) Hydrolysed product of Q, reacts with NaNO2 + HCl followed by reaction with phenol, gives
orange red dye.
(D) Electrophile involved in the formation of Q is dichlorocarbene.

dkSulk dFku xyr gS %


(A) P rFkk Q ds vipf;r mRikn vkil esa e/;ko;oh gSA
(B) P ds tyvi?kV~u }kjk izkIr mRikn dk 'kq"d vklou] Ca(OH)2 ds lkFk djus ij csatksfQukWu curk gSA
(C) Q ds tyvi?kVu }kjk izkIr mRikn dh NaNO2 + HCl ls vfHkf;k dj QhukWy ls vfHkf;k djkus ij
ukjaxh&yky jatd izkIr gksrk gSA
(D) Q ds cuus esa bysDVkWuLusgh MkbDyksjksdkchZu Hkkx ysrk gSA

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44. Match each of the following four structures with one of the compounds AD on the basis of the

following experimental facts. Compounds A, B and C are optically active, but compound D is not.

CHEMISTRY
Compound C gives the same products as compound D on treatment with periodic acid, but

compound B gives a different product. Compound A does not react with periodic acid.

fuEufyf[kr izk;ksfxd rF;ksa ds vk/kkj ij fuEu izR;sd pkj lajpukvksa dks A-D ;kSfxdksa esa ls ,d ds lkFk

lqesfyr dhft;sA ;gk ;kSfxd A, B rFkk C izdkf'kd lf; gS] fdUrq D ugha gSA ;kSfxd C ogh leku mRikn

nsrk gS tks D dks ijvk;ksfMd vEy ds lkFk mipkfjr djus ij curk gSA ijUrq B ;kSfxd fHkUu mRikn nsrk gSA

;kSfxd A ijvk;ksfMd vEy ls f;k ugha djrk gSA

CH2OH CH2OCH3 CH2OCH3 CH2OCH3

CHOCH3 H OH H OH CHOCH3
(I) (II) H OH (III) HO H (IV)
CHOH CHOH
CH2OCH3 CH2OCH3 CH2OCH3 CH2OH

Choose the correct match :

lgh feyku dk p;u dhft;s &

(A) A III ; B II ; C I ; D IV (B) A III ; B I ; C IV ; D II

(C) A I ; B IV ; C III ; D II (D) A I ; B IV ; C II ; D III

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SECTION - 2

CHEMISTRY
Matrix - Match Type
This section contains 2 question. Each question contains statements given in
two columns, which have to be matched. The statements in Column-I are
labelled A, B, C and D, while the statements in Column-II are labelled p, q, r, s
and t. Any given statement in Column-I can have correct matching with ONE
OR MORE statement(s) in Column-II. The appropriate bubbles corresponding
to the answers to these questions have to be darkened as illustrated in
the following example.
If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s and t; then the correct
darkening of bubbles will look like the following :
[k.M - 2
eSfVDl&lqesy izdkj
bl [k.M esa 2 iz'u gSaA izR;sd iz'u esa nks dkWye esa oO; (statements) fn;s gq, gSa
ftudk lqesy (match) djuk gSA dkWye-I (Column-I) ds oO;ksa dks A, B, C rFkk D
ukfer fd;k x;k gSa tcfd dkWye-II (Column-II) ds oO;ksa dks p, q, r, s rFkk t ukfer
fd;k x;k gSaA dkWye-I (Column-I) esa fn, x, dksbZ ,d oO; dkWye-II (Column-II)
ds ,d ;k ,d ls vf/kd oO; oO;ksa ls lgh lqesy djrk gSA bu iz'uksa ds mkj
fuEufyf[kr mnkgj.k ds vuqlkj mfpr cqYyksa dks dkyk djds n'kkZuk gSA
;fn lgh leqsy A-p, s vkSj t ; B-q vkSj r; C-p vkSj q; rFkk D-s vkSj t gS; rks lgh fof/k ls dkys fd, x, cqYys
,sls fn[krs gSa tks fuEufyf[kr gSaA

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45. Match the column :
Columnn Columnn

CHEMISTRY
3
(A) [CoF6] (p) Hybridisation of central atom involving penultimate
d-orbital(s)
3
(B) [Co(C2O4)3] (q) Paramagnetic
2+
(C) [Cu(NH3)4] (r) Chelating ligand
(D) [RhC (PPh3)3] (s) Central atom belonging to 5d series.
(t) One of the d-orbital used in hybridisation of central
2 2
atom is dx y

fuEu dks lqesfyr dhft, :


dkWye dkWye
3
(A) [CoF6] (p) dsUnzh; ijek.kq ds ladj.k esa mikUr; (penultimate) dks'k ds
d-d{kd lfEefyr gSA
3
(B) [Co(C2O4)3] (q) vuqpqEcdh;
2+
(C) [Cu(NH3)4] (r) oy;dkjh fyxsUM dhysV fyxsUM
(D) [RhC (PPh3)3] (s) dsUnzh; ijek.kq 5d Js.kh ls lEcfU/kr gSA
(t) dsUnzh; ijek.kq ds ladj.k esa iz;qDr ,d d-d{kd dx2y2 gSA

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46. Columnn Columnn

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(Reaction) (Stereochemistry of product)

CH3CH2 CH3
H2
C=C
(A) Pt (p) stereoselective
D D

Bayers reagent
(B) (q) stereospecific
D D

(i) BH3/THF
(C) (r) syn addition
(ii) H2O2/OH
CH3 CH3

CH 3 CH2CH3
Br 2
(D) C=C (s) anti addition
CCl4
H H

(t) meso compound

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dkWye dkWye

CHEMISTRY
(vfHkf;k) (mRikn dk f=kfoe jlk;u)

CH3CH2 CH3
H2
C=C
(A) Pt (p) f=kfoe p;ukRed
D D

cs;j vfHkdeZd
(B) (q) f=kfoe fof'k"B
D D

(i) BH3/THF

(C) (ii) H2O2/OH (r) flu&;ksx


CH3 CH3

CH 3 CH2CH3
Br 2
(D) C=C (s) izfr&;ksx
CCl4
H H

(t) felks&;kSfxd

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SECTION 3 : (Integer value correct Type)


[k.M 3 : (iw.kkd eku lgh dkj)

CHEMISTRY
This section contains 8 questions. The answer to each question is a single digit integer, ranging
from 0 to 9 (both inclusive).
bl [k.M esa 8 'u gSaA R;sd 'u dk mkj 0 ls 9 rd nkus ksa 'kkfey ds chp dk ,dy vadh; iw.kkd gSA

47. How many of the following give colourless gas/gases with conc. H2SO4 :
fuEu esa ls fdrus ;kSfxd lkUnz H2SO4 ds lkFk jaxghu xSl@xSls nsrs gS\
H2C2O4, NaCl, K,
HCOOH, KClO3, Na2CO3
KBr, Na3PO4, K4[Fe(CN)6]

x
M +
+ x+
48. It is observed that the voltage of a galvanic cell using the reaction M(s) + xH H2
2
x+
varies linearly with the log of the square root of the hydrogen pressure and the cube root of the M
concentration. The value of x is :
x
,d lsy M(s) + xH+ Mx+ + H2 vfHkf;k ds fy, ;fn xsYosfud lsy dk oksYVst gkbMkstu xSl ds
2
nkc ds oxZ ewy ds log rFkk Mx+ lkUnzrk ds ?kuewy ds lkFk js[kh; :i ls ifjofrZr gksrk gSA x dk eku Kkr
djksA

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49. Solid BaF2 is added to a solution containing 0.1 mole of sodium oxalate solution (1 litre) until
6 7
equilibrium is reached. If the Ksp of BaF2 and BaC2O4(s) is 10 & 10 respectively. Assume

CHEMISTRY
addition of BaF2 does not cause any change in volume and no hydrolysis of any of the cations or
anions. (Given : 116 = 10.77)
2+ x
If concentration of Ba ions in resulting solution at equilibrium is represented as 2.7 10 , then x
is :

0.1 eksy lksfM;e vkWDtsysV foy;u (1 yhVj) esa lkE; LFkkfir gksus rd Bksl BaF2 feykrs gSA ;fn BaF2 rFkk
6
BaC2O4(s) dk Ksp e'k% 10 rFkk 107 gS] rks ekuk BaF2 dks feykus ls vk;ru esa dksbZ ifjorZu ugh gksrk gS
rFkk fdlh Hkh /kuk;uksa ;k _.kk;uksa dk tyvi?kVu ugha gksrk gSA (fn;k gS : 116 = 10.77)
;fn lkE; ij ifj.kkeh foy;u esa Ba2+ vk;uksa dh lkUnzrk dks 2.7 10x, ds :i esa iznf'kZr djrs gS] rks x
gS&

50. Consider the following chemical reaction and the corresponding kinetic data showing the initial
reaction rate as a function of the initial concentrations of the reactants :
H3AsO4(aq) + 2H3O (aq) + 3I-(aq) HAsO2(aq) + I3-(aq) + 4H2O(liq)
+

Initial Rate 10 (M/sec)


-5 +
[H3AsO4] [H3O ] [I-]
3.7 0.001 0.01 0.10
7.4 0.001 0.01 0.20
7.4 0.002 0.01 0.10
3.7 0.002 0.005 0.20
Using the data, establish the correct reaction composite order.

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fuEUk jklk;fud vfHkf;k ij fopkj dhft, rFkk vfHkf;k dh izkjafHkd nj ds vkadM+s] f;kdkjdks dh izkjafHkd
lkUnzrkvksa ds Qyu ds :i esa uhps n'kkZ;s x, gSaA

CHEMISTRY
H3AsO4(aq) + 2H3O (aq) + 3I-(aq) HAsO2(aq) + I3-(aq) + 4H2O(liq)
+

izkjafHkd nj 10-5 (M/sec) [H3AsO4] [H3O ]


+
[I-]

3.7 0.001 0.01 0.10


7.4 0.001 0.01 0.20
7.4 0.002 0.01 0.10
3.7 0.002 0.005 0.20
vkadMksa dk mi;ksx djrs gq, vfHkf;k dh lgh la;qDr dksfV crkb,A

51. How many of the following involves carbon reduction during extraction of metal from ore?
Bauxite Al ; Copper pyrites Cu ; Haematite Fe

Galena Pb ; Carnallite Mg ; Sylvine K

Cassiterite Sn ; Zinc blende Zn ; Silica Si


fuEu esa ls fdrus ize esa v;Ld ls /kkrq ds fu"d"kZ.k ds nkSjku dkcZu vip;u gksrk gS \
ckWDlkbV Al ; dkWij ikbjkbV Cu ; gsesVkbV Fe
xsysuk Pb ; dkusZykbV Mg ; flYokbu K
dsflVsjkbV Sn ; ftad Cys.M Zn ; flfydk Si

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52. How many of the following statements are correct?
(1) Soap acts as emulsifier in its cleansing action

CHEMISTRY
(2) Bredig's arc method is particularly suitable for preparing sulphur sol.
(3) Coagulation of sol can be caused by electrophoresis.
(4) Greater is the zeta potential, greater is the stability of colloid.
(5) Methylene blue sol is a negatively charged sol whereas TiO2 sol is a positively charged sol.
fuEu esa ls fdrus dFku lgh gS \
(1) lkcqu bldh LoPN f;k esa ik;lhdkjd dh rjg dk;Z djrk gSA
(2) czsfMx vkdZ fof/k lYQj lksy cukus ds fy, fo'ks"k :i ls mfpr gSA
(3) bl lksy dk Ldanu oS/kqr d.k lapyu ds dkj.k gks ldrk gSA
(4) thVk foHko dk eku vf/kd gksus ij dksykWbM dk LFkkf;Ro vf/kd gksrk gSA
(5) esFkkbyhu Cyw lksy _.kkosf'kr lksy gS tcfd TiO2 lksy /kukosf'kr lksy gSA

53. A six membered cyclic compound A (C7H14O) gives instant turbidity with lucas reagent and forms a
compound B. B on reaction with alcoholic KOH gives major product C. C on reductive ozonolysis
gives D. D in aq. alkali medium forms an unsaturated carbonyl compound E. Find the sum of
ring size (if any) and degree of unsaturation (hydrogen deficency index) of E.

,d N% lnL;h ph; ;kSfxd A (C7H14O) Y;wdkWl vfHkdeZd ds lkFk rqjUr vo{ksi nsrk gS vkSj ,d ;kSfxd B
cukrk gSA B dks ,YdksgkWfyd KOH ds lkFk vfHkd`r djus ij eq[; mRikn C nsrk gSA C vip;h vkstksuhdj.k
ij D nsrk gSA D tyh; {kkjh; ek/;e esa vlar`Ir dkcksZfuy ;kSfxd E nsrk gSA E ds oy; dk vkdkj ;fn
dksbZ gS vkSj vlar`Irrk dh dksfV dk ;ksx crkb;sA

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54. Consider the figure :

CHEMISTRY
mixture separation
of amino of amino
acids acids

filter paper
Buffer solution
Buffer solution (pH = 5.0)
(pH = 5.0)

(Electrophoresis) (After Electrophoresis)

pKa Values
S.No. Amino acids
side chain

1. Arginine 2.17 9.04 12.48

2. Alanine 2.34 9.69 ------

3. Aspartic acid 2.09 9.82 3.86

4. Lysine 2.18 8.95 10.79

5 Glutamic acid 2.19 9.67 4.25

6. Valine 2.32 9.62 ------

Calculate :
Spaceamino
Number of non essential for Rough Work
acids move / (dPpscathod
towards dk;Z ds=fy,
x LFkku )
Number of essential amino acids move towards anode = y
Number of amino acids move towards cathod = z
FIND x+y+z=?

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P1JRAIOT1ADV220215C0-35
Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PTC024029
CHEMISTRY

CHEMISTRY
,ehuks vEyksa ,ehuks vEyksa
dk feJ.k dk i`Fddj.k

fQYVj i=
cQj foy;u cQj foy;u
(pH = 5.0) (pH = 5.0)

oS|qr viksgu oS|qr viksgu ds i'pkr


fuEu fp=k dk voyksdu dhft, &

Space for Rough Work / (dPps dk;Z ds fy, LFkku )


x.kuk dhft;s :
dSFkksM dh vksj xeu djus okys vu vko';d ,ehuks vEyks dh la[;k = x
,uksM dh vksj xeu djus okys vko';d ,ehuks vEyks dh la[;k = y
dSFkksM dh vksj xeu djus okys ,ehuks vEyks dh la[;k = z
Kkr dhft;s& x + y + z = ?

Space for Rough Work / (dPps dk;Z ds fy, LFkku )

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
P1JRAIOT1ADV220215C0-36
Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PTC024029
ALL INDIA OPEN TEST-1 (AIOT-1) (JEE ADVANCED PATTERN)
PAPER-1 COURSE : VIJETA (JP), VISHWAAS (JF), VIJAY (JR) & VIVEK (JCC) CODE - 0
IMPORTANT INSTRUCTIONS / egoiw.kZ funsZ'k
C. Question Paper Format C. iz'u&i=k dk izk:i
The question paper consists of three parts bl iz'u&i=k rhu Hkkx xf.kr] HkkSfrd foKku vkSj jlk;u
(Mathematics, Physics and Chemistry). Each part
consists of three sections.
foKku gSA gj Hkkx ds rhu [k.M gSaA

14. Section 1 contains 8 multiple choice questions. 14. [kaM 1 esa 8 cgqfodYi iz'u gSaA gj iz'u esa pkj fodYi (A),
Each question has Four choices (A), (B), (C) and (D)
(B), (C) vkSj (D) gSa ftuesa ls dsoy ,d lgh gSA
out of which only ONE is correct.
15. Section 2 contains 2 question. Each question 15. [kaM 2 esa 2 iz'u gSA izR;sd iz'u esa nks dkWye esa oDRO;
contains statements given in two columns which have
(statements) fn;s gq, gSa ftudk lqesy (match) djuk gSA
to be matched. Statements in Column I are labelled
as A, B, C and D whereas statements in Column II dkWye (Column-I) esa fn;s x;s oDrO;ksa (A, B, C, D) dks
are labelled as p, q, r, s and t. The answers to these dkWye (Column-II) esa fn;s x;s oDrO;ksa (p, q, r, s, t) ls lqesy
questions have to be appropriately bubbled as
djuk gSA bu iz'uksa ds mkj fn;s x;s mnkgj.k ds vuqlkj
illustrated in the following example.
mfpr cqYyksa dks dkyk djds n'kkZuk gSA

16. Section 3 contains 8 questions. The answer to each 16. [kaM 3 esa 8 iz'u gSaA izR;sd iz'u dk mkj 0 ls 9 rd nksuksa
question is a single-digit integer, ranging from 0 to 9 'kkfey ds chp ,d ,dy vadh; iw.kkZad gSA
(both inclusive).
D. Marking Scheme D. vadu ;kstuk
17. For each question in Section 1, you will be awarded
17. [kaM 1 esa gj iz'u esa dsoy lgh mkj okys
3 marks if you darken the bubble corresponding to
only the correct answer and zero mark if no bubbles
cqycqys(BUBBLES) dks dkyk djus ij 3 vad vkSj dksbZ Hkh
are darkened. In all other cases, minus one (1) cqycwyk dkyk ugha djus ij (0) vad iznku fd, tk;saxsA vU;
mark will be awarded. lHkh fLFkfr;ksa esa _.kkRed ,d(1) vad iznku fd;k tk;sxkA
18. For each question in Section 2, you will be awarded 18. [kaM 2 esa gj ,d iz'u esa R;sd iafDr esa ;fn dsoy lgh mkj
3 marks for each row in which you have darkened the
dk cqycqyk cqycqys dkyk fd;k x;k gks rks 3 vad iznku fd;k
bubble corresponding to the correct answer. Thus,
each question in this section carries a maximum of
tk;sxkA vr% bl [k.M dk R;sd 'u vf/kdre 12 vadksa dk
12 marks. There is no negative marking for incorrect gksxkA bl [k.M esa xyr mRrj ds cqYys dks dkyk djus ij
answer(s) in this section. _.kkRed vad ugha fn;k tk;sxkA
19. For each question in Section 3, you will be awarded 19. [kaM 3 esa gj iz'u esa dsoy lgh mkj okys
3 marks if you darken the bubble corresponding to
cqycqys(BUBBLES) dks dkyk djus ij 3 vad vkSj dksbZ Hkh
only the correct answer and zero mark if no bubbles
are darkened. There is no negative marking for
cqycwyk dkyk ugha djus ij (0) vad iznku fd, tk;saxsA bl
incorrect answer(s) in this section. [k.M esa xyr mRrj ds cqYys dks dkyk djus ij _.kkRed vad
ugha fn;k tk;sxkA

Name of the Candidate (ijh{kkFkhZ dk uke) : Roll Number (jksy uEcj) :

I have read all the instructions and shall I have verified all the information filled by
abide by them the candidate.
eSaus lHkh funsZ'kksa dk i<+ fy;k gS vkSj eSa mudk ijh{kkFkhZ }kjk Hkjh xbZ lkjh tkudkjh dks eSusa
vo'; ikyu d:xk@d:xhA tkp fy;k gSA
...................................... ......................................
Signature of the Candidate Signature of the Invigilator
ijh{kkFkhZ ds gLrk{kj ijh{kd ds gLrk{kj

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