Aont 3 Chemistry

P26-16
Code
0
ADVANCED PATTERN ONLINE TEST-3 (AONT-3) XI
TARGET : JEE (MAIN+ADVANCED) 2017
SUBJECT : CHEMISTRY
COURSE : VIJETA (JP), VISHWAAS (JF)
Date (fnukad) : 19-01-2017 Time: 1 Hour (le; : 1 ?k.Vk) Max. Marks (egke vad) : 80
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
i;k bu funsZ'kksa dks /;ku ls i<+saA vkidks 5 feuV fo'ks"k :i ls bl dke ds fy, fn;s x;s gSaA
INSTRUCTIONS / funsZ'k :
A. General : A. lkekU; %
1. This booklet is your Question Paper. Do not break 1. ;g iqfLrdk vkidk iz'u&i=k gSA bldh eqgjsa rc rd u
the seals of this booklet before being instructed to do rksMsa tc rd fujh{kdksa ds }kjk bldk funsZ'k u fn;k tk;sA
so by the invigilators.
DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

2. Blank spaces and blank pages are provided in the 2. dPps dke ds fy;s [kkyh i`"B vkSj [kkyh txg bl
question paper for your rough work. No additional iqfLrdk esa gh gSA dPps dke ds fy, dksbZ vfrfjDr dkxt
sheets will be provided for rough work.
ugha fn;k tk;sxkA
3. Blank papers, clipboards, log tables, slide rules, 3. dksjs dkxt] fDyi cksMZ (CLIP BOARD)] ykWx rkfydk]
calculators, cameras, cellular phones, pagers and LykbM:y] dSYdqysVj] dSejk] lsyQksu] istj vkSj fdlh
electronic gadgets are NOT allowed inside the
examination hall. izdkj ds bysDVkfud midj.k ijh{kk d{k esa vuqefr ugha
tc rd ifjos"kd funsZ'k ugha nsa rc rd iz'u i=k dh lhy dks ugha [kksaysA
gSA
4. Write you name and roll number in the space 4. bl iqfLrdk ds fiNys i`"B ij fn, x, LFkku esa viuk uke
provided on the back cover of this booklet. vkSj jksy uEcj fyf[k,A
5. Using a black ball point pen, darken the bubbles 5. ijh ewy i`"B ds cqycqyksa (BUBBLES) dks dkys ckWy
on the upper original sheet. IokbaV dye ls dkyk djsaA
6. DO NOT TAMPER WITH/MUTILATE THE ORS OR 6. vks-vkj-,l- (ORS) ;k bl iqfLrdk esa gsj&Qsj@fofr u
THE BOOKLET. djsaA
7. On breaking the seals of the booklet check that it 7. bl iqfLrdk dh eqgjsa rksM+us ds i'pkr~ i;k tkp ysa fd blesa
contains all the 20 questions and corresponding lHkh 20 iz'u vkSj muds mkj fodYi Bhd ls i<+s tk ldrs gSaA
answer choices are legible. Read carefully the
Instructions printed at the beginning of each section. lHkh [kaMksa ds izkjaHk esa fn;s gq, funsZ'kksa dks /;ku ls i<+saA
B. Filling the ORS B.
vks-vkj-,l (ORS) Hkjuk % ORS dks Hkjus ds fy, dsoy dkys
Use only Black ball point pen only for filling the ORS. cky iSu dk mi;ksx dhft,A
8. Write your Roll no. in the boxes given at the top left 8. ORS ds lcls ij cka;s dksus esa fn, x, ckDl esa viuk
corner of your ORS with black ball point pen. Also, jksy uEcj dkys cky ikbUV ls fyf[k, rFkk laxr xksys Hkh
darken the corresponding bubbles with Black ball
point pen only. Also fill your roll no on the back side of dsoy dkys isu ls Hkfj;sA ORS ds ihNs dh rjQ Hkh viuk
your ORS in the space provided (if the ORS is both side jksy uEcj fyf[k, (;fn ORS nksuksa rjQ Nih gqbZ gSA)
printed).
9. Fill your Paper Code as mentioned on the Test Paper and 9. ORS ij
viuk isij dksM fyf[k, rFkk laxr xksyksa dks dkys
darken the corresponding bubble with Black ball point pen. cky isu ls dkys dhft,A
10. If student does not fill his/her roll no. and paper code 10. ;fn fo|kFkhZ viuk jksy uEcj rFkk isij dksM lgh vkSj
correctly and properly, then his/her marks will not be mfpr rjhds ugha Hkjrk gS rc mldk ifj.kke jksd fy;k
displayed and 5 marks will be deducted (paper wise)
from the total. tkosxk rFkk iz'u&i=k esa izkIrkad ls 5 vad dkV fy, tkosaxsaA
(Please read the last page of this booklet for rest of the instructions)
i;k 'ks"k funsZ'kksa ds fy;s bl iqfLrdk ds vfUre i`"B dks i<+sA
Resonance Eduventures Ltd.
CORPORATE OFFICE : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | Toll Free : 258 5555
Reg. Office : J-2, Jawahar Nagar, Main Road, Kota (Raj.)-324005 | Ph. No.: +91-744-3192222 | FAX No. : +91-022-39167222
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN: U80302RJ2007PLC024029 P26-16
CHEMISTRY
CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
CHEMISTRY
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION 1 : (Maximum Marks : 40)

[kaM 1 : (vf/kdre vad : 40)
This section contains TEN questions
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
1 In all other cases
bl [kaM esa nl iz'u gSaA
izR;sd iz'u dk mkj 0 ls 9 rd, nksuksa 'kkfey] ds chp dk ,d ,dy vadh; iw.kkd gSA
izR;sd iz'u esa] vks- vkj- ,l- ij lgh iw.kkd ds vuq:i cqycqys dks dkyk djsaA
vadu ;kstuk :
+4 ;fn mkj ds vuq:i cqycqys dks dkyk fd;k tk,A
0 ;fn dksbZ Hkh cqycqyk dkyk u fd;k gksA
1 vU; lHkh voLFkkvksa esa
Space for Rough Work d Ppsd k;Zd sfy , LFkku
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
CJP/JFAONT3190117C0-1
Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PLC024029
CHEMISTRY
1. An aqueous solution contains 10% ammonia by mass and has a density of 0.85 g/mL. If [H3O+] in
this solution is 'yM', then the value of 'y 1012' is (Ka for NH4+ = 5.0 1010 M)
CHEMISTRY
,d tyh; foy;u esa Hkkj ds vuqlkj 10% veksfu;k gS rFkk bldk ?kuRo 0.85 g/mL gSA ;fn bl foy;u esa
[H3O+] 'yM' gS] rc 'y 1012' dk eku gksxk (NH4+ ds fy, Ka = 5.0 1010 M)
2. Consider the following reactions :

fuEu vfHkf;kvksa dk voyksdu dhft,&
CaC2 + H2O Ca(OH)2 + M
Al4C3 + H2O Al(OH)3 + N
Mg2C3 + H2O Mg(OH)2 + P
If no. of carbon atoms in M, N and P are x, y and z respectively, value of (x + z) y is:
;fn M, N rFkk P esa dkcZu ijek.kqvksa dh la[;k e'k% x, y rFkk z gS] rks (x + z) y dk eku gS &
3. Value of x in silicate mineral Be3Al2SixO18 is:

flfydsV [kfut Be3Al2SixO18 esa x dk eku gS&
3 2
4. In structure of Borax, if x is number of sp hybridised Boron atoms, y is number of sp hybridized
Boron atoms and z is number of water molecules. Value of x y + z is :
cksjsDl dh lajpuk esas] ;fn x sp3 ladfjr cksjksu ijek.kq dh la[;k gS] y sp2 ladfjr cksjksu ijek.kq dh la[;k gS
rFkk z ty v.kqvksa dh la[;k gS] rks x y + z dk eku gS &
CHEMISTRY
5. A substance has normal boiling point of 400 K. If Svap at 1 atm and 400 K is 1000 J/K-mol, then
CHEMISTRY
calculate |Ssurrounding| at 1 atm and 200 K, for the vaporisation process
[Express your answer in KJ/K-mol]
,d inkFkZ 400 K lkekU; DoFkukad j[krk gSA ;fn 1 atm rFkk 400 K ij Svap 1000 J/K-eksy gS] rks
ok"ihdj.k ize ds fy, 1 atm rFkk 200 K ij |Sifjos'k | ifjdfyr dhft,A
[viuk mkj KJ/K-eksy esa O;Dr dhft,]
6. How many of the following reactions are possible ?
fuEu esa ls fdruh vfHkf;k, lEHko gSa\
conc. H2SO 4 lkUnz H2SO4

(a) 4BF3 + 3LiAlH4 2B2H6 + 3LiF + 3AlF3 (b) HCOOH CO2 + H2

(c) 6NaH + 2BF3 B2H6 + 6NaF (d) C + O2 + 4N2 CO2 + 4N2

(e) 3B2H6 + 6NH3 B3N3H6 (f) B2H6 + 2Me3N [BH2(Me3N)2]+ [BH4]
CHEMISTRY
7. Consider the following compounds :
fuEufyf[kr ;kSfxdksa ij fopkj dhft,as %
CHEMISTRY
H

B
(i) (ii) (iii)
O O
O O

(iv) N (v) (vi)
H H
(vii) (viii) (ix)
How many compounds are aromatic in nature.

mijksDr eas ls fdrus ;kSfxd ,sjkseSfVd gSaA
H
CH3
8. (X) (Y)
CH3 CH3

H
Total no. of hydrogen atoms involved in Hyperconjugation in X and Y.
X rFkk Y esa vfrla;qXeu esa iz;qDr gkbMkstu ijek.kqvksa dh dqy la[;k gSa&
CHEMISTRY
9. How many free radicals are stabilized by resonance ?
CHEMISTRY
fuEu esa ls fdrus eqDr ewyd vuqukn }kjk LFkk;hr gksrs gSa\

(i) CH2 CH (ii) (iii) (iv)
(v) (vi) H3C CH2 (vii)

CH3

10. How many resonating structures of are possible (Including given structure) :

dh fdruh vuquknh lajpuk,sa lEHko gSa (nh x;h lajpuk dks ekurs gq,s )%
CHEMISTRY
SECTION 2 : (Maximum Marks : 40)
CHEMISTRY
This section contains TEN questions
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
1 In all other cases
[kaM 2 : (vf/kdre vad : 40)
bl [kaM esa nl iz'u gSaA
izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
izR;sd iz'u esa] lHkh lgh fodYi fodYiksa ds vuq:i cqycqys cqycqykas dks vks- vkj- ,l- esa dkyk djsaA
vadu ;kstuk :
+4 ;fn flQZ lHkh lgh fodYi fodYiksa ds vuq:i cqycqys cqycqykas dks dkyk fd;k tk,A
0 ;fn dksbZ Hkh cqycqyk dkyk u fd;k gksA
1 vU; lHkh voLFkkvksa esa
CHEMISTRY
11. A solution is 0.1 M in Cl and 0.001 M in CrO42. Solid AgNO3 is gradually added to this solution.
Identify the correct statement(s).
CHEMISTRY
Given Ksp (AgCl) = 1.7 1010 M2
Ksp (Ag2CrO4) = 1.9 1012 M3
(A) On addition of AgNO3, AgCl will precipitate first.
(B) Concentration of Cl is 6.9 106 M when Ag2CrO4 starts precipitated.
(C) Almost all Cl is precipated out when Ag2CrO4 starts precipitated.
(D) Concentration of Ag+ ion required for precipitate of Ag2CrO4 is 4.3 105 M.
,d foy;u Cl esa 0.1 M rFkk CrO42 esa 0.001 M gSA bl foy;u esa Bksl AgNO3 dks /khjs&/khjs feykrs gSA lgh
dFku@dFkuksa igpkfu,A
fn;k gS Ksp (AgCl) = 1.7 1010 M2
Ksp (Ag2CrO4) = 1.9 1012 M3
(A) AgNO3 dks feykus ij loZizFke AgCl dk vo{ksi.k izkIr gksrk gSA

(B) Cl dh lkanzrk 6.9 106 M gS] tc Ag2CrO4 vo{ksfir gksuk izkjEHk gksrk gSA
(C) izk;% leLr Cl vo{ksfir gksrs gSa] tc Ag2CrO4 vo{ksfir gksuk izkjEHk gksrk gSA
(D) Ag2CrO4 ds vo{ksi.k ds fy, vko';d Ag+ vk;u dh lkUnzrk 4.3 105 M gSA
CHEMISTRY
12. H2CO3 ionizes as :
H2CO3 H+ + HCO3 ; K1 = 4.0 106
CHEMISTRY
HCO3 H+ + CO32 ; K2 = 5.0 1011
The correct information(s) related with 0.5 M Na2CO3 solution is/are
(A) The degree of hydrolysis of Na2CO3 is 0.02
(B) pH of solution is 2.0.
(C) pOH of solution is 2.0
(D) [H2CO3] = 2.5 109 M
H2CO3 fuEu izdkj vk;fur gksrk gS %&

H2CO3 H+ + HCO3 ; K1 = 4.0 106
HCO3 H+ + CO32 ; K2 = 5.0 1011
0.5 M Na2CO3 foy;u ls lEcfU/kr lgh lwpuk gS@gSa &
(A) Na2CO3 ds ty vi?kVu dh ek=kk 0.02 gSA
(B) foy;u dh pH 2.0 gSA
(C) foy;u dh pOH 2.0 gSA
(D) [H2CO3] = 2.5 109 M
CHEMISTRY
13. Degree of hydrolysis for a salt of strong acid and weak base :
(A) is independent of dilution. (B) increases with dilution.
CHEMISTRY
(C) increases with decrease in kb of the base. (D) decreases with decrease in temperature.
izcy vEy rFkk nqcZy {kkj ds yo.k ds fy, ty vi?kVu dh ek=kk gksrh gS&
(A) ruqrk ls LorU=k (B) ruqrk ds lkFk o`f)
(C) {kkjksa ds kb eas deh ds lkFk o`f) (D) rki esa deh ds lkFk deh
14. Identify the correct statement(s):

(A) The law of thermodynamics cannot predict the rate of a chemical reaction.
(B) A catalyst alters the rate of reaction. Hence effects the spontaneity and Gibbs Free energy of
the reaction.
(C) At low temperature, enthalpy change dominates the Gibbs Free energy where as at high
temperature entropy change dominates the value of Gibbs Free energy.
(D) Phase transition is done at constant temperature and pressure so change in internal energy for
phase transition is zero.
lgh dFku igpkfu,&
(A) "ekxfrdh dk fu;e jklk;fud vfHkf;k dh nj dk iwokZuqeku ugha yxk ldrk gSA
(B) ,d mRizsjd vfHkf;k dh nj dks ifjofrZr djrk gS] blfy, Lor% izo`fkrk rFkk vfHkf;k dh fxCl eqDr
tkZ izHkkfor gksrh gSA
(C) U;wu rki ij] ,UFkSYih ifjorZu fxCl eqDr tkZ ij izHkkoh gksrk gS tcfd mPp rki ij ,UVkWih ifjorZu
fxCl eqDr tkZ dsSpace
eku ijfor gksrk gSAWork d Ppsd k;Zd sfy , LFkku
izHkkohRough
(D) izkoLFkk lae.k fu;r rki rFkk nkc ij fd;k tkrk gSA blfy, izkoLFkk lae.k ds fy, vkUrfjd tkZ esa
ifjorZu 'kwU; gksrk gSA
CHEMISTRY
15. Which of the reactions is/are correct ?
dkSulh vfHkf;k@vfHkf;k, lgh gS@gSa \
CHEMISTRY
(A) H3BO3 + 3C2H5OH B(OC2H5)3 + 3H2O
(B) B2O3 + 5NaOH 2 Na3BO3 + 3H2O
(C) Na2B4O7 + H2SO4 + 5H2O Na2SO4 + 4H3BO3 ()
(D) B3H6N3 + 9H2O 3H3BO3 + 3NH3 + 3H2
16. Carbon monoxide is prepared by:

(A) Heating formic acid with conc. H2SO4
(B) Heating potassium ferrocyanide with conc. H2SO4
(C) Heating malonic acid with P4O10
(D) Hydrolysis of Mg2C3
dkcZu eksuksvkWDlkbM fuEu }kjk cuk;k tkrk gS &
(A) lkUnz H2SO4 ds lkFk QkWfeZd vEy dks xeZ djdss
(B) lkUnz H2SO4 ds lkFk iksVsf'k;e Qsjkslk;ukbM+ dks xeZ djdsa
(C) P4O10 ds lkFk esyksfud vEy dks xeZ djds
(D) Mg2C3 dk ty vi?kVu djds
CHEMISTRY
17. Choose the correct statement(s).
(A) B does not react with water. (B) PbO is an amphoteric oxide.
CHEMISTRY
(C) All B H bond in diborane are similar. (D) B2(CH3)6 can be prepared by B2H6
lgh dFku@dFkuksa dk p;u dhft, &
(A) B ty ls vfHkf;k ugha djrk gSA (B) PbO ,d mHk;/kehZ vkWDlkbM gSA
(C) MkbZcksjsu es leLr B H ca/k leku gksrk gSA (D) B2(CH3)6, B2H6 }kjk cuk;k tk ldrk gSA
18. Which of the following compounds give Hell-Volhard Zelinski (HVZ) reaction ?
fuEu esa ls fdrus ;kSfxd gkWy&okygkMZ ftfyaLdh (HVZ) vfHkf;k nsrs gSa \
COOH
COOH
(A) (B)
COOH
(C) COOH (D)
CHEMISTRY
19. Hydrocarbon (M) on reductive ozonolysis gives one carbonyl compound P. In basic medium P
gives benzoic acid and benzyl alcohol. Structure of hydrocarbon M is?
CHEMISTRY
,d gkbMksdkcZu (M) vipf;r vkstksuhvi?kVu ij ,d dkcksZfuy ;kSfxd P nsrk gSA {kkjh; ek/;e esa ;kSfxd P
csUtksbd vEy ,oa csfUty ,YdksgkWy nsrk gSA vr% gkbMksdkcZu M dh lajpuk fuEu gS \
CH3
(A) PhCH=CH2 (B) PhCH=CHPh (C) PhC=CH2 (D) PhCH=C
CH3
CH3
SoCl2 H2 / PdBaSO4 (1) dil.NaOH

20. CH3COOH X Y
(2)
Z
Choose the correct option :

(A) X is CH2COOH
Cl
(B) Y is CH3CH=O
(C) Z is CH3CH=CHCH=O
(D) Conversion of Y to Z is known as aldol condensation reaction.
SoCl2 H2 / PdBaSO4 (1) dil.NaOH
CH3COOH X Y
(2)
Z
lgh fodYi dk p;u dhft, &

(A) X, CH2COOH gSA
Cl
(B) Y, CH3CH=O gSSpace
A for Rough Work d Ppsd k;Zd sfy , LFkku
(C) Z, CH3CH=CHCH=O gSA
(D) Y dk Z esas :ikUrj.k dks ,YMkWy la?kuu vfHkf;k ds :i esa tkurs gSaA
ADVANCED PATTERN ONLINE TEST-3 Code
P26-16
(AONT-3) XI 0
TARGET : JEE (MAIN+ADVANCED) 2017
COURSE : VIJETA (JP), VISHWAAS (JF)
11. Since it is not possible to erase and correct pen filled 11. pawfd isu ls Hkjs x, xksys feVkuk vkSj lq/kkjuk laHko ugha gS
bubble, you are advised to be extremely careful while
blfy, vki lko/kkuh iwoZd vius mkj ds xksyksa dks HkjsaA
darken the bubble corresponding to your answer.
12. Neither try to erase / rub / scratch the option nor 12. fodYi dks u feVk,a@u Lsp djsa vkSj u gh xyr (X) fpUg
make the Cross (X) mark on the option once filled.
dks HkjsaA ORS dks dkVs u gh QkMs u gh xUnk ugha djsa rFkk
Do not scribble, smudge, cut, tear, or wrinkle the
dksbZ Hkh fu'kku ;k lQsnh ORS ij ugha yxk;sA
ORS. Do not put any stray marks or whitener
anywhere on the ORS.
13. If there is any discrepancy between the written data 13. ;fn ORS esa fdlh izdkj dh fy[ks x, vkadMksa rFkk xksys
and the bubbled data in your ORS, the bubbled data
fd, vkadMksa esa fojks/kkHkkl gS] rks xksys fd, vkadMksa dks gh
will be taken as final.
lgh ekuk tkosxkA
C. Question Paper Format C. iz'u&i=k dk izk:i
The question paper consists of one part. This part bl iz'u&i=k esa ,d Hkkx gSaA bl Hkkx esa nks [kaM gSaA
consists are two section.
14. Section 1 contains 10 questions. The answer to 14. [kaM 1 esa 10 iz'u gSaA izR;sd iz'u dk mkj 0 ls 9 rd nksuksa
each question is a single-digit integer, ranging from 'kkfey ds chp ,d ,dy vadh; iw.kkZad gSA
0 to 9 (both inclusive).
15. Section 2 contains 10 multiple choice questions. 15. [kaM 2 esa 10 cgqfodYi iz'u gaSA gj iz'u esa pkj fodYi (A),
Each question has Four choices (A), (B), (C) and (D) (B), (C) vkSj (D) gSa ftuesa ls ,d ;k ,d ls vf/kd fodYi
out of which ONE OR MORE THAN ONE is correct.
lgh gSaA
D. Marking Scheme D. vadu ;kstuk
16. For each question in Section 1, you will be awarded 16. [kaM 1 esa gj iz'u esa dsoy lgh mkj okys cqycqys(BUBBLES)
4 marks if you darken the bubble corresponding to
dks dkyk djus ij 4 vad vkSj dksbZ Hkh cqycwyk dkyk ughaa djus ij
only the correct answer and zero mark if no bubbles
(0) vad iznku fd, tk;saxsA vU; lHkh fLFkfr;ksa esa _.kkRed ,d
are darkened. In all other cases, minus one (1) mark
will be awarded. (1) vad iznku fd;k tk;sxkA
17. For each question in Section 2, you will be awarded 17. [kaM 2 esa gj iz'u esa dsoy lgh mkj okys cqycqys(BUBBLES)
4 marks if you darken the bubble corresponding to dks dkyk djus ij 4 vad vkSj dksbZ Hkh cqycwyk dkyk ughaa djus ij
only the correct answer and zero mark if no bubbles
(0) vad iznku fd, tk;saxsA vU; lHkh fLFkfr;ksa esa _.kkRed ,d
are darkened. In all other cases, minus one (1) mark
(1) vad iznku fd;k tk;sxkA
will be awarded.
Name of the Candidate (ijh{kkFkhZ dk uke) : Roll Number (jksy uEcj) :
I have read all the instructions and shall I have verified all the information filled by
abide by them the candidate.
eSaus lHkh funsZ'kksa dks i<+ fy;k gS vkSj eSa mudk ijh{kkFkhZ }kjk Hkjh xbZ lkjh tkudkjh dks eSusa
vo'; ikyu d:xk@d:xhA tkp fy;k gSA
...................................... ......................................
Signature of the Candidate Signature of the Invigilator
ijh{kkFkhZ ds gLrk{kj ijh{kd ds gLrk{kj
Resonance Eduventures Ltd. P26-16
CORPORATE OFFICE : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | Toll Free : 1800 258 5555
Reg. Office : J-2, Jawahar Nagar, Main Road, Kota (Raj.)-324005 | Ph. No.: +91-744-3192222 | FAX No. : +91-022-39167222
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN: U80302RJ2007PLC024029
(CHEMISTRY) H
O
B
1. Concentration of ammonia veks
fu;k d h lkanzrk= 5 M
7. , and are aromatic species.
[OH ] K b C 2 105 5 10 2 M
O

, , and are non
2. M is CH CH; x=2 O N
N is CH4; y=1 H H
P is CH3 C CH; z=3 aromatic species.
H
M, CH CH gS( x=2 O
B
N, CH4 gS; y=1 , o ,jkseSfVd Lih'kht gSaA
O
P, CH3 C CH gS; z=3

,
N , o ukWu ,jkseSfVd
3. Change balance (lUrq
yu cny sa) O
3 2 + 2 3 + 4 x = 36
H H
x=6 Lih'kht gSA
4. x = 2, y = 2, z = 8 refer course material for borax structure.

8. does not show hyperconjugation. vfrla
;qXeu ughan'kkZrk
x = 2, y = 2, z = 8 cks
jsDl lajpuk d sfy , ikB~; lkezxh ns[ksaA
gSA
Hvap
5. Svap = 9. [(iv) & (vii)]
TB.pt.
Hvap K sp ( AgCl)
1000 = Hvap = 400 KJ/mol 11. [Ag+] for ppt of AgCl = = 1.7 109 M
400 0 .1
Hvap [Ag+] for ppt of Ag2CrO4 = 1.9 10 12 M3 = 4.3 105 M

400
Ssurrounding ifjos'k = = KJ/Kmol 0.001 M
200 200
[Cl] concentration when Ag2CrO4 ppt out
= 2 kJ/k-mole = |Ssurrounding ifjos'k |
=2
1.7 10 10
[Cl] =
5
3.9 10 6 M
4.3 10
6. (a) 4BF3 + 3LiAlH4 2B2H6 + 3LiF + 3AlF3 K sp ( AgCl)
i.k d sfy , [Ag+] =
AgCl d svo{ks = 1.7 109 M
(c) 6NaH + 2BF3 B2H6 + 6NaF 0 .1
(d) C + O2 + 4N2

CO2 + 4N2 1.9 10 12 M3
i.k d sfy , [Ag+] =
Ag2CrO4 d svo{ks
0.001 M

(e) 3B2H6 + 6NH3 B3N3H6 = 4.3 105 M
conc . H2SO 4 , [Cl] lkUnz

rk t c Ag2CrO4 vo{ksfir gksrk gSA
(b) HCOOH CO + H2O
(f) B2H6 + 2Me3N 2H3B NMe3 1.7 10 10

[Cl] = 3.9 10 6 M
4.3 105
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
SOLJP/JFAONT3190117-6
Kw
12. h 0.02
K2 C
[OH] = Ch = 0.5 0.02 = 0.01 M
CO32 + H2O OH + HCO3
HCO3 + H2O H2CO3 + OH
CO32 + 2H2O H2CO3 + 2OH
Kw Kw
Kh = K h1 K h2 =
K a2 K a1
(10 14 )2 10 4 [H2CO3 ]
or =
20 10 17 0.5
or [H2CO3] = 2.5 109 M
Kw
13. h , h increases as C decreases.
K b .C
Kw
h , h es
aof) gksrh gSD;ksafd C esad eh gksrh gSA
K b .C
T Kh h
T Kh h
SoCl2
20. CH3COOH CH3COCl
H2 / PdBaSO 4

CH3CH=O
(1) dil.NaOH

(2)
CH3CH=CHCH=O
SOLJP/JFAONT3190117-7
CHEMISTRY
1. (1) 2. (5) 3. (6) 4. (8) 5. (2) 6. (4) 7. (3)
8. (2) 9. (2) 10. (6) 11. (ACD) 12. (ACD) 13. (BCD) 14. (AC)
15. (ABCD) 16. (AB) 17. (AB) 18. (BC) 19. (B) 20. (BCD)
SOLJPSCTSTREAM-A170416-15

Aont 3 Chemistry

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P26-16

DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

SECTION 1 : (Maximum Marks : 40)

Space for Rough Work d Ppsd k;Zd sfy , LFkku

2. Consider the following reactions :

3. Value of x in silicate mineral Be3Al2SixO18 is:

Space for Rough Work d Ppsd k;Zd sfy , LFkku

[Express your answer in KJ/K-mol]

ok"ihdj.k ize ds fy, 1 atm rFkk 200 K ij |Sifjos'k | ifjdfyr dhft,A

[viuk mkj KJ/K-eksy esa O;Dr dhft,]

6. How many of the following reactions are possible ?

fuEu esa ls fdruh vfHkf;k, lEHko gSa\

conc. H2SO 4 lkUnz H2SO4

Space for Rough Work d Ppsd k;Zd sfy , LFkku

(vii) (viii) (ix)

How many compounds are aromatic in nature.

Space for Rough Work d Ppsd k;Zd sfy , LFkku

(v) (vi) H3C CH2 (vii)

Space for Rough Work d Ppsd k;Zd sfy , LFkku

SECTION 2 : (Maximum Marks : 40)

Space for Rough Work d Ppsd k;Zd sfy , LFkku

Space for Rough Work d Ppsd k;Zd sfy , LFkku

H2CO3 fuEu izdkj vk;fur gksrk gS %&

Space for Rough Work d Ppsd k;Zd sfy , LFkku

14. Identify the correct statement(s):

Space for Rough Work d Ppsd k;Zd sfy , LFkku

16. Carbon monoxide is prepared by:

Space for Rough Work d Ppsd k;Zd sfy , LFkku

lgh dFku@dFkuksa dk p;u dhft, &

(C) COOH (D)

Space for Rough Work d Ppsd k;Zd sfy , LFkku

SoCl2 H2 / PdBaSO4 (1) dil.NaOH

Choose the correct option :

lgh fodYi dk p;u dhft, &

Name of the Candidate (ijh{kkFkhZ dk uke) : Roll Number (jksy uEcj) :

Resonance Eduventures Ltd. P26-16

x=6 Lih'kht gSA

4. x = 2, y = 2, z = 8 refer course material for borax structure.

Hvap [Ag+] for ppt of Ag2CrO4 = 1.9 10 12 M3 = 4.3 105 M

conc . H2SO 4 , [Cl] lkUnz

(f) B2H6 + 2Me3N 2H3B NMe3 1.7 10 10

[OH] = Ch = 0.5 0.02 = 0.01 M

CO32 + H2O OH + HCO3

HCO3 + H2O H2CO3 + OH

CO32 + 2H2O H2CO3 + 2OH

or [H2CO3] = 2.5 109 M

1. (1) 2. (5) 3. (6) 4. (8) 5. (2) 6. (4) 7. (3)

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