#04 Belando, Emilia 21 March 2017
#08 Dela Cruz, Patty Elaine 3E-PH
#11 Drona, Mheriz
#25 Mendoza, Janice Leslie
#34 Ramos, Gianina Rae
#36 Sta. Ana, Zsannel Bianca
After pretreatment to convert the arsenic to the +5 state, a 0.821-g sample of a pesticide
was treated with 25.00-mL of 0.0800-M AgNOs. The AgsAsO, was filtered, washed free of
excess silver ion, and then redissolved by treatment with nitric acid. The resulting solution
required a 7.40-mL titration with 0.0865-M KSCN.
Molar Mass: As2Os = 197.9
(a) Express the results of this analysis in terms of percentage As2Os in the sample.
Given:
O.8214 &
25.b0 mL of 0-0800-M AgNO,
FAO mL of 0 -OBLE-M ESEN
Formula: Ge
= Fema ggg ASME Beads
: [heme agus = [ome es a lp ne M4,0,2
1 heyy n a
wh af Sx Og)
Substitution: a hago
[{tisentxecton, [tment EN] pitta | Sahn ¥ 8
100
tehsg0, O-balg
+5.YL3341U5a oF
(b) If the analysis had been completed by titrating the excess silver ion in the filtrate and
washings, what volume of 0.0865-M KSCN would have been used?
Given:
25-00 mL of 0-080 ™ AgNO
J-Homt of 0-DUUS Hm KSUN
Formula:
0,
Lomas [OO ||
4g,
wh
ee Musew
Substitution: AV AgNoy.
om = 0.p9usw
_ [tasomocae, go [Lomb You ee =
wh ysen”
0.0865 Myers