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IN QUANTUM MECHANICS
OUTLINE OF THE COURSE
Spin systems
3. SPIN STATES
( )
: H H (H is the Hilbert space)
( )
PROJECTION OPERATOR
Let us consider the expansion of an arbitrary state in terms of a basis:
En En ( En En ) I
n 1 n 1
it is to select the corresponding state from the expansion factorized by its coefficient:
n En En c
i 1
i Ei ci En En Ei cn En
i 1
Analogously it is possible to obtain the spectral resolution of an Hermitian operator H
by observing that:
H H En En En En En ( En En En )
n 1 n 1 n 1
H En En En spectral resolution of the hermitian operator H
n 1
APPLICATION TO THE SPIN CASE
THE RESOLUTION OF IDENTITY:
1
2
1 1 1 1
I 1
Sz ; m Sz ; m Sz ;
2
Sz ;
2
S z ;
2
S z ;
2
m
2
1 1
S1 S z ; S z ;
2 2
1 1
S2 S z ; S z ;
2 2
THE PHYSICAL MEANING OF THE OPERATORS S1 AND S2:
Let us consider the action of the last two operators upon the basis states in spin space:
1 1 1 1 1
S1 S z ; S z ; S z ; z
S ; S z ;
2 2 2 2 2
1 1 1 1
S1 S z ; S z ; S z ; S z ; 0
2 2 2 2
1 1 1 1
S 2 S z ; S z ; S z ; S z ; 0
2 2 2 2
1 1 1 1 1
S 2 S z ; S z ; S z ; S z ; S z ;
2 2 2 2 2
S1 S ; S2 S
THE OPERATORS Sx AND Sy
From the sequential SG experiments resulted that when a beam of electrons in the state
1
S x ;
2
is subjected to a measurement of SGz type, the beam splits into two components with
equal intensities. This means that the probability of the system to jump into the eigenstate
with positive z-projection is equal to the probability jump into the state with negative
z-projection:
2
1 1 1 1 1 1
S z ; S x ; S z ; S x ;
2 2 2 2 2 2
2
1 1 1 1 1 1
S z ; S x ; S z ; S x ;
2 2 2 2 2 2
However we remark that the two scalar products can be determined only up to a phase
factor.
1
THE EXPANSION OF S x ;
2
Since the eigenvectors of an Hermitian operators generate a basis in Hilbert space:
ai ai
i
we have:
1 1 1 1 1 1 1
S x ; S z ; S x ; S z ; S z ; S x ; S z ;
2 2 2 2 2 2 2
Up to a global phase factor, taking into account the discussion concerning the values of
1 1 1 1
S z ; S x ; and S z ; S x ;
2 2 2 2
it is introduced the following expansion:
1 1 1 ei 1 1
S x ; S z ; S z ;
2 2 2 2 2
ANALOGOUSLY:
From the sequential SG experiments resulted that when a beam of electrons in the state
1
S x ;
2
is subjected to an measurement of SGz type the beam splits into two components with
equal intensities. This means that the probability of the system to jump into the eigenstate
with positive z-projection is equal to the probability jump into the state with negative
z-projection:
2
1 1 1 1 1 1
S z ; S x ; S z ; S x ;
2 2 2 2 2 2
2
1 1 1 1 1 1
S z ; S x ; S z ; S x ;
2 2 2 2 2 2
Also in this case the two scalar products can be determined only up to a phase factor.
1
THE EXPANSION OF S x ;
Since: 2
1 1 1 1 1 1 1
S x ; S z ; S x ; S z ; S z ; S x ; S z ;
2 2 2 2 2 2 2
up to a global phase factor, taking into account the discussion concerning the values of
1 1 1 1
S z ; S x ; and S z ; S x ;
2 2 2 2
we shall have:
1 1 1 ei 1 1
S x ; S z ; S z ;
2 2 2 2 2
With this choice it is observed that the scalar product of the states with different
x-components vanish:
1 1 1 1 1 1 i1 1 1 ei 1 1
S x ; S x ; S z ; S z ; e S z ; S z ;
2 2 2 2 2 2 2 2 2 2
1 e i1 ei1
0
2 2
as expected, since these vectors are eigenstates of a Hermitian operator and so
should be orthogonal.
SUMMARY
1 1 1 ei 1 1
S x ; S z ; S z ;
2 2 2 2 2
1 1 1 ei 1 1
S x ; S z ; S z ;
2 2 2 2 2
i1 1 1 1 1
Sx e S z ; S z ; ei1 S z ; S z ;
2 2 2 2 2
Proof: we start from the spectral resolution of the operator Sx and then employ the
previous results concerning the expansion of eigenvectors of Sx
1 1 1 1
S x S x ; S x ; S x ; S x ;
2 2 2 2 2 2
1 1 ei 1 1 1 1 1 1 i1
S z ; S z ; S z ; S z ; e
2 2 2 2 2 2 2 2
2 1 1 e i 1
1 1 1 1 1 i1
S ; S z ; ) S z ; S z ; e
2 z 2
2 2 2 2 2 2
i1 1 1 i1 1 1
e S z ; S z ; e S z ; S z ;
2 2 2 2 2
Sy OPERATOR
A fully analogous discussion for the y-component of spin leads to the following results:
1 1 1 ei 2 1
S y ; S z ; S z ;
2 2 2 2 2
1 1 1 ei 2 1
S y ; S z ; S z ;
2 2 2 2 2
i 2 1 1 i 2 1 1
S y e S z ; S z ; e S z ; S z ;
2 2 2 2 2
1 1 1 1 e i 2 1 1 1 ei1 1 1 ei (1 2 )
S y ; S x ; S z ; S z ; Sz ; S z ;
2 2 2 2 2 2 2 2 2 2 2 2
1 1
1 ei (1 2 ) 1 cos(1 2 ) i sin(1 2 ) 2
2 2
(1 cos(1 2 )) 2 sin 2 (1 2 ) 2 1 2 cos(1 2 ) cos 2 (1 2 ) sin 2 (1 2 ) 2
0 and
1 2
2
1 2
2
cos(1 2 ) 0
1 2 1 0 and 2 when work in a right - handed SC
2 2
FINAL SUMMARY
Let us summarize the important results obtained until now:
1 1 1 1 1
S x ; S z ; S z ;
2 2 2 2 2
1 1 1 1 1
S x ; S z ; S z ;
2 2 2 2 2
1 1 1 1
S x S z ; S z ; S z ; S z ;
2 2 2 2 2
1 1 1 i 1
S y ; S z ; S z ;
2 2 2 2 2
1 1 1 i 1
S y ; S z ; S z ;
2 2 2 2 2
1 1 1 1
Sy i S z ; S z ; i S z ; S z ;
2 2 2 2 2
A SIMPLE APPLICATION
y
x
SOLUTION
1
S n; the final state n (nx , n y , nz ) (sin cos , sin sin , cos )
2
1 1 1 1
1 S n; a S z ; b S z ;
S n S n ; S n ; 2 2 2
2 2 2
BUT:
1 1 1 1
S n S x nx S y n y S z nz sin cos S z ; S z ; S z ; S z ;
2 2 2 2 2
1 1 1 1
sin sin i S z ; S z ; i S z ; S z ;
2 2 2 2 2
1 1 1 1
cos z
S ; S z ; S z ; S z ;
2 2 2 2 2
SOLUTION:CONTINUATION
1 1 1 1 1 1 1
S x n x S n ; sin cos S z ; S z ; S z ; Sz ; ( a S z ; b S z ; )
2 2 2 2 2 2 2 2
1 1
sin cos b S z ; a S z ;
2 2 2
1 1 1 1 1 1 1
S y n y S n ; sin sin i S z ; S z ; i S z ; Sz ; ( a S z ; b S z ; )
2 2 2 2 2 2 2 2
1 1
sin sin ib S z ; ia S z ;
2 2 2
1 1 1 1 1 1 1
S z n z S n ; cos S z ; S z ; S z ; S z ; ( a S z ; b S z ; )
2 2 2 2 2 2 2 2
1 1
cos a S z ; b S z ;
2 2 2
SOLUTION:CONTINUATION
1
b sin cos ib sin sin a cos S z ;
1
S n S n ;
2 2 2
a sin cos ia sin sin b cos S z ; 1
2 2
1 1 1 1
S n S n; S n; (a S z ; b S z ; )
2 2 2 2 2 2
2
2 2
2 sin
2 2 a cos
b a
2
2
cos
2 b 2 sin 2
a 2 b2 1
2
PAULI TWO-COMPONENT FORMALISM
REALIZATION OF THE KET VECTORS
Let us consider A and B two different hermitian operators with discrete spectrum. We have:
A ai ai ai ai ai
i
B bi bi bi bi bi
i
The components of the vector can be written as column matrices and we can establish the
corespondences : a1 b1
a2 b2
3 a 3 b
a4 or b4
.......... ..........
n a n b
........... ...........
Then for the bra vectors we can introduce a similar correspondence to row matrices:
a1
*
a2
*
a3 ...... an ...
* *
or
b b2 b3 ...... bn ...
* * * *
1
When the ket and bra are realized in terms of matrices the scalar product of two vectors
Is the product between the corresponding row and column matrices.
REALIZATION OS THE VECTORS FOR SPIN CASE
For a vector state which belongs to the spin Hilbert space let us consider the expansion:
1
Sz ; m Sz ; m
m
2
The realization of the vector, associated to this basis, is a column vector with two elements
1
S z ;
2
1
S z ;
2
while the realization of the corresponding bra is a row vector with two elements:
1
*
1
*
S z ; S z ;
2 2
MATRICES ASSOCIATED TO THE BASIS VECTORS
For the basis vectors states results the following correspondences:
1 1
S z ; S z ;
S z ;
1
2 2 1
0
2 1
S z ; S z ;
1
2 2
1 1
S z ; S z ;
2 0
1 2
S z ;
2 1 1 1
S z ; S z ;
2 2
* *
1 1
S z ; S z ; S z ;
1 1
S z ; S z ;
1 1 0
2 2 2 2 2
* *
1 1
S z ; S z ; S z ;
1 1
S z ; S z ;
1 0 1
2 2 2 2 2
REALIZATION OF THE OPERATORS
B B a j a j B a j a j
j j
ai ai B a j a j
j
The last relation can be written as a product between a square matrix (the realization of
the operator B) and a column matrix (the realization of the initial state), the result being
a column vector (the realization of the new state):
a1 a1 B a1 a1 B a2 .............. a1
a2 a2 B a1 a2 B a2 ............. a2
.......... ............ ............ ..........
a a Ba ............ a
n n 1
n
........... ............ ............ ............ ...........
PAULI MATRICES
Definition: Pauli Matrices are matrices associated to the three operators
corresponding to the components of the spin, obtained as realizations
associated to the spin basis Sz ; 1 ; Sz ; 1
2 2
( k )mm ' S z ; m Sk S z ; m'
2
Explicitly: 1 1 1 1
S z ; Sk S z ; S z ; Sk S z ;
k
2 2 2 2
2 1 1 1 1
S z ; Sk S z ; S z ; Sk S z ;
2 2 2 2
0 1 Basic properties:
1 x
1 0 Tr i 0 ; Det i 1 ; i2 1
0 i , 2
i j ; i , j 2i ijk k
ij
2 y
i 0 ( a )(b ) a b I ( a b )
1 0 a3 a1 ia 2
3 z a ai i
0 1 a1 ia 2 a3