Beruflich Dokumente
Kultur Dokumente
REACTION ENGINEERING
CONVERSION & REACTOR SIZING
(part 2)
MISMISURAYA MEOR AHMAD
School of bioprocess engineering
Unimap
REACTORS
IN
SERIES
objectives
DEFINE conversion and REWRITE all the
balance equation in term of conversion
EVALUATE the size of CSTR & PFR based on
conversion,
DETERMINE the reactor volume necessary
to achieved a specified conversion,
COMPARE CSTRs & PFRs and overall
conversion for reactor arranged in series.
IDENTIFY the best arrangement of reactors
in series.
Reactors are connected in series so that the
exit stream of one reactor is the feed stream
for another reactor.
Equation 1
So that
The rate of disappearance of A, rA2 is evaluated at the
conversion of the exit stream of reactor 2, X2.
A mole balance on reactor 2 gives:
Equation 3
2nd method Shade the area for Levenspiel Plot
For CSTRs in series, the rate rA1 is evaluated at X1 = 0.4
and rate rA2 is evaluated at X2 = 0.8.
Total reactor
volume for 2 PFR
in series = Reactor
volume for one
PFR
Example 2.6
(Sizing PFRs in Series)
Use the data below to calculate the reactor volumes V1 and
V2 for PFRs in series (shown below) when the intermediate
conversion is 40 % and final conversion is 80 %.The entering
molar flow rate is 0.4 mol/s.
There are 2 method to solve PFR:
Answer 1) Use the Simpsons rule
2) Shade the area for Levenspiel Plot
1st method
Use the simpsons three point rule:
Note: This volume same with a single PFR to achieve 80 %
conversion in Example 2-4
3) Combinations of CSTRs and PFRs in Series
Consider the dimerization reaction of propylene
into isohexanes.
The volume of the first two CSTRs in series are (Example 2-5):
1st method
2nd method: (Shade the area for Levenspiel Plot)
Example 2.7
(An Adiabatic Liquid Phase Isomerization)
The isomerization of butane was done adiabatically in liquid
phase and the data below are obtained.
Comparing the CSTR & PFR reactor volumes & reactor sequencing
It depends on:
1) the shape of Levenspiel plots (FAO/-rA) versus X
2) The relative reactor sizes
Suppose a Levenspiel plot (FAO/-rA) versus X will be given for
three reactors volumes in series VCSTR1 = 3 m3, VCSTR2 = 2
m3 & VPFR = 1.2 m3. Then find the highest possible
CONVERSION, X
Methods:
The methods we used to calculate reactor volumes
all apply, except the procedure is reversed & a
trial-and-error solution is needed to find the exit
overall conversion from each reactor.
The data of the reaction rate as a function of conversion (Experiment)
The reaction rate does not depends on CONVERSION only, it also affected by the initial
CONCENTRATION of the reactant, the TEMPERATURE & the PRESSURE.
Answer
Answer
SUMMARY
Lets think
Lets think
Lets think
Lets think
Q &A
THANK YOU