11 04 2014 PDF

PART A PHYSICS A
1. In terms of resistance R and time T, the 1. U R U T , m

m m
dimensions of ratio of the permeability l e
e e
m and permittivity e is :
(1) [RT22] (1) [RT22]
(2) [R2 T21] (2) [R2 T21]
(3) [R2] (3) [R2]
(4) [R2 T2] (4) [R2 T2]
2. The initial speed of a bullet fired from a 2. U U U

rifle is 630 m/s. The rifle is fired at the 630 m/s SU U 700 m U
centre of a target 700 m away at the same U U
level as the target. How far above the U
centre of the target the rifle must be aimed U ?
in order to hit the target ?
(1) 1.0 m (1) 1.0 m
(2) 4.2 m (2) 4.2 m
(3) 6.1 m (3) 6.1 m
(4) 9.8 m (4) 9.8 m
English : 1 Set : 11 Hindi : 1 Set : 11

3. A body of mass 5 kg under the action of 3. r
SU F5Fx i 1 Fy j U
r
constant force F5Fx i 1 Fy j has velocity
5 kg S t50s U
at t50s as
r
(
)

v 5 6 i 22 j m/s and at r
(

v 5 6 i 22 j m/s ) U t510 s
r r r r
t510 s as v516 j m/s. The force F is : U v516 j m/s F :
(1) (23 i 14 j ) N

(1) (23 i 14 j ) N

3 4 3
(2) 2 i1 j N 4
5 5 (2) 2 i1 j N
5 5
(3) (3 i 2 4 j ) N

(3) (3 i 2 4 j ) N

3 4 3
(4) i 2 j N 4
5 5 (4) i 2 j N
5 5

4. A small ball of mass m starts at a point A 4. m UU A vo
with speed v o and moves along a U U U AB U
frictionless track AB as shown. The BC
track BC has coefficient of friction m. The m C U U L
ball comes to stop at C after travelling a L L :
distance L which is :
2h v2
(1) 1 o
2h v2 m 2m g
(1) 1 o
m 2m g
h v2
(2) 1 o
h v2 m 2m g
(2) 1 o
m 2m g
h v2
(3) 1 o
h v2 2m mg
(3) 1 o
2m mg
h v2
(4) 1 o
h v2 2m 2m g
(4) 1 o
2m 2m g

5. The average mass of rain drops is 5. 3.031025 kg
3.031025 kg and their average terminal U 9 m/s
velocity is 9 m/s. Calculate the energy S U 100 cm S
transferred by rain to each square metre UU cU U mU SU
of the surface at a place which receives 100
cm of rain in a year. (1) 3.53105 J
(1) 3.53105 J (2) 4.053104 J
(2) 4.053104 J (3) 3.03105 J
(3) 3.03105 J (4) 9.03104 J
(4) 9.03104 J 6. L U
6. A thin bar of length L has a mass per unit l U U U
length l, that increases linearly with U M
distance from one end. If its total mass U U U lo ,
is M and its mass per unit length at the U U
lighter end is lo, then the distance of the
L l L2
centre of mass from the lighter end is : (1) 2 o
2 4M
L l L2 l L2
(1) 2 o L
1 o
2 4M (2)
3 8M
L l L2 l L2
(2) 1 o L
1 o
3 8M (3)
3 4M
L l L2 l L2
(3) 1 o 2L
2 o
3 4M (4)
3 6M
2L l L2
(4) 2 o
3 6M

7. From a sphere of mass M and radius R, a 7. R M ,
smaller sphere of radius R 2 is carved out R 2 UU U
such that the cavity made in the original
sphere is between its centre and the U ( )
periphery. (See figure). For the U U U
configuration in the figure where the U 3R ,
distance between the centre of the original L
sphere and the removed sphere is 3R, the
gravitational force between the two
spheres is :
41 GM 2
(1)
3600 R 2
41 GM 2
41 GM 2 (2)
(1) 450 R 2
3600 R 2
59 GM 2
41 GM 2 (3)
(2) 450 R 2
450 R 2
GM 2
59 GM 2 (4)
(3) 2 225 R 2
450 R
GM 2
(4)
225 R 2

8. The Bulk moduli of Ethanol, Mercury and 8. , U S
water are given as 0.9, 25 and 2.2 109 Nm22 0.9, 25 2.2
respectively in units of 109 Nm22. For a ,
given value of pressure, the fractional 9

9 V
compression in volume is . Which of
V 9
U
9 V
the following statements about for
V ?
these three liquids is correct ?
(1) Ethanol > Water > Mercury (1) > > U
(2) Water > Ethanol > Mercury (2) > > U
(3) Mercury > Ethanol > Water (3) U > >
(4) Ethanol > Mercury > Water (4) > U >
9. A tank with a small hole at the bottom has 9. UU U U ^

been filled with water and kerosene ( 0.8) U
(specific gravity 0.8). The height of water 3 m U ^ 2 m U
is 3 m and that of kerosene 2 m. When the ,
hole is opened the velocity of fluid coming : (g510 ms 22 U
out from it is nearly : (take g510 ms22 5103 kg m23)
and density of water 5103 kg m23)
(1) 10.7 ms21 (1) 10.7 ms21
(2) 9.6 ms21 (2) 9.6 ms21
(3) 8.5 ms21 (3) 8.5 ms21
(4) 7.6 ms21 (4) 7.6 ms21

10. An air bubble of radius 0.1 cm is in a liquid 10. cU 0.06 N/m U 103 kg/m3
having surface tension 0.06 N/m and 0.1 cm
density 103 kg/m3. The pressure inside U U
the bubble is 1100 Nm22 greater than the 1100 Nm22 cU
atmospheric pressure. At what depth is U U ? (g59.8 ms22)
the bubble below the surface of the
liquid ? (g59.8 ms22)
(1) 0.1 m (1) 0.1 m
(2) 0.15 m (2) 0.15 m
(3) 0.20 m (3) 0.20 m
(4) 0.25 m (4) 0.25 m
11. A hot body, obeying Newtons law of 11. U U
cooling is cooling down from its peak value S 808C U
808C to an ambient temperature of 308C. 308C UU 808C 408C
It takes 5 minutes in cooling down from UU 5 U 628C 328C
808C to 408C. How much time will it take U ?
to cool down from 628C to 328C ? ( ln 250.693, ln 551.609)
(Given ln 250.693, ln 551.609) (1) 3.75 U
(1) 3.75 minutes (2) 8.6 U
(2) 8.6 minutes (3) 9.6 U
(3) 9.6 minutes (4) 6.5 U
(4) 6.5 minutes

12. During an adiabatic compression, 830 J of 12. Lhc U, mU
work is done on 2 moles of a diatomic ideal 2 50%
gas to reduce its volume by 50%. The 830 J U
change in its temperature is nearly : U (R58.3 JK21 mol21)
(R58.3 JK21 mol21)
(1) 40 K (1) 40 K
(2) 33 K (2) 33 K
(3) 20 K (3) 20 K
(4) 14 K (4) 14 K

13. An ideal monoatomic gas is confined in a 13. S U 8.031023 m2
cylinder by a spring loaded piston of cross U U SU mU U
section 8.031023 m2. Initially the gas is at U U 300 K U U
300K and occupies a volume of 2.431023 m3 U U
2.4310 23 m3 and the spring is in its o S
relaxed state as shown in figure. The gas is UU UU mU UU
heated by a small heater until the piston SU U 0.1 m U
moves out slowly by 0.1 m. The force 8000 N/m U
constant of the spring is 8000 N/m and the U 1.03105 N/m2
atmospheric pressure is 1.03105 N/m2. SU cU SU
The cylinder and the piston are thermally U SU
insulated. The piston and the spring are
massless and there is no friction between (UU U U
the piston and the cylinder. The final U UU U cU ) :
temperature of the gas will be :
(Neglect the heat loss through the lead
wires of the heater. The heat capacity of
the heater coil is also negligible)
(1) 300 K
(2) 800 K
(3) 500 K
(4) 1000 K
(1) 300 K
(2) 800 K
(3) 500 K
(4) 1000 K

14. The angular frequency of the damped 14.
oscillator is given by, ,
k r2 k r2
v5 2 where k is the spring v5 2 k SU ,
m 4m 2 m 4m 2
constant, m is the mass of the oscillator and m U r SU
r2
r is the damping constant. If the ratio 5 8% ,
mk
r2
U
is 8%, the change in time period
mk
compared to the undamped oscillator is
approximately as follows :
(1) increases by 1% (1) 1% h
(2) increases by 8% (2) 8% h
(3) decreases by 1% (3) 1% U
(4) decreases by 8% (4) 8% U
15. Two factories are sounding their sirens 15. UU U 800 Hz U U

at 800 Hz. A man goes from one factory 2 m/s UU
to other at a speed of 2 m/s. The velocity U
of sound is 320 m/s. The number of beats 320 m/s U mU
heard by the person in one second will S
be :
(1) 2 (1) 2
(2) 4 (2) 4
(3) 8 (3) 8
(4) 10 (4) 10

16. A cone of base radius R and height h is 16. U R h U

located in a uniform electric field E U l E S
parallel to its base. The electric flux U l :
entering the cone is :
1 1
(1) EhR (1) EhR
2 2
(2) EhR (2) EhR
(3) 2EhR (3) 2EhR
(4) 4EhR (4) 4EhR

17. A parallel plate capacitor is made of two 17. U U U U
plates of length l, width w and separated l, U w U U d U U
by distance d. A dielectric slab (dielectric Ul ^ (Ul K) U
constant K) that fits exactly between the U , U U
plates is held near the edge of the plates. U U U U
It is pulled into the capacitor by a force U
F5 2 mU U U
U x
F5 2 where U is the energy of the
x Ul U U x U
capacitor when dielectric is inside the U ( ) U U Q ,
capacitor up to distance x (See figure). If
Ul U , U ,
the charge on the capacitor is Q then the
force on the dielectric when it is near the
edge is :
Q2 d
(1) K
2 wl 2 eo
Q2 d
(1) K Q2 w
2 wl 2 eo (2) ( K21)
2 dl 2 eo
Q2 w
(2) ( K21) Q2 d
2 dl 2 eo (3) ( K21)
2 wl 2 eo
Q2 d
(3) ( K21) Q2 w
2 wl 2 eo (4) K
2 dl 2 eo
Q2 w
(4) K
2 dl 2 eo

18. In the circuit shown, current (in A) 18. U , 50 V 30 V UU
through the 50 V and 30 V batteries are, U (A )
respectively :
(1) 2.5 and 3 (1) 2.5 3

(2) 3.5 and 2 (2) 3.5 2
(3) 4.5 and 1 (3) 4.5 1
(4) 3 and 2.5 (4) 3 2.5
19. Three straight parallel current carrying 19. U U
conductors are shown in the figure. The 25 cm mU
force experienced by the middle conductor :
of length 25 cm is :
(1) 331024 N toward right (1) 331024 N U

(2) 631024 N toward left (2) 631024 N U
(3) 931024 N toward left (3) 931024 N U
(4) Zero (4) U

20. Three identical bars A, B and C are made 20. M U A, B C
of different magnetic materials. When Z
kept in a uniform magnetic field, the field U , U U
lines around them look as follows : U
Make the correspondence of these bars U Z (D),

with their material being diamagnetic (D), (F) (P) U U U :
ferromagnetic (F) and paramagnetic (P) :
(1) A D, B P, C F (1) A D, B P, C F
(2) A F, B D, C P (2) A F, B D, C P
(3) A P, B F, C D (3) A P, B F, C D
(4) A F, B P, C D (4) A F, B P, C D
21. A coil of circular cross-section having 21. 1000 U 4 cm2

1000 turns and 4 cm2 face area is placed S U U
with its axis parallel to a magnetic field U U
which decreases by 10 22 Wb m 22 in 1022 Wb m22 0.01 s U U
0.01 s. The e.m.f. induced in the coil is : U l
(1) 400 mV (1) 400 mV
(2) 200 mV (2) 200 mV
(3) 4 mV (3) 4 mV
(4) 0.4 mV (4) 0.4 mV

22. An electromagnetic wave of frequency 22. 131014 U l U
131014 hertz is propagating along z - axis. z - U U U U l
The amplitude of electric field is 4 V/m. If 4 V/m
e o58.8310 212 C 2/N-m 2, then average eo58.8310212 C2/N-m2, l
energy density of electric field will :
be :
(1) 35.2310210 J/m3 (1) 35.2310210 J/m3
(2) 35.2310211 J/m3 (2) 35.2310211 J/m3
(3) 35.2310212 J/m3 (3) 35.2310212 J/m3
(4) 35.2310213 J/m3 (4) 35.2310213 J/m3
23. An object is located in a fixed position 23. SU S S S
in front of a screen. Sharp image is 10 cm U U S
obtained on the screen for two positions U ScU S
of a thin lens separated by 10 cm. The size U 3 : 2 S
of the images in two situations are in the U ?
ratio 3 : 2. What is the distance between
the screen and the object ?
(1) 124.5 cm (1) 124.5 cm
(2) 144.5 cm (2) 144.5 cm
(3) 65.0 cm (3) 65.0 cm
(4) 99.0 cm (4) 99.0 cm

24. Two monochromatic light beams of 24. 16 9
intensity 16 and 9 units are interfering. U U U
The ratio of intensities of bright and dark U S
parts of the resultant pattern is :
16 16
(1) (1)
9 9
4 4
(2) (2)
3 3
7 7
(3) (3)
1 1
49 49
(4) (4)
1 1
25. In a compound microscope the focal length 25.

of objective lens is 1.2 cm and focal length 1.2 cm U
of eye piece is 3.0 cm. When object is kept 3.0 cm S
at 1.25 cm in front of objective, final image 1.25 cm U U U ,
is formed at infinity. Magnifying power U
of the compound microscope should be :
(1) 200 (1) 200
(2) 100 (2) 100
(3) 400 (3) 400
(4) 150 (4) 150

26. A photon of wavelength l is scattered 26. o S U U l
from an electron, which was at rest. The U U SU
wavelength shift Dl is three times of l and Dl U l U
the angle of scattering u is 608. The angle u5608 U f U
at which the electron recoiled is f. The tan f (U
value of tan f is : (electron speed is much )
smaller than the speed of light)
(1) 0.16 (1) 0.16
(2) 0.22 (2) 0.22
(3) 0.25 (3) 0.25
(4) 0.28 (4) 0.28
27. A radioactive nuclei with decay constant 27. 100 U SU U SU

0.5/s is being produced at a constant rate 0.5/s UU U
of 100 nuclei/s. If at t50 there were no t50 U S ,
nuclei, the time when there are 50 nuclei 50
is :
(1) 1s (1) 1s
4 4
(2) 2 ln s (2) 2 ln s
3 3
(3) ln 2 s (3) ln 2 s
4 4
(4) ln s (4) ln s
3 3

28. A Zener diode is connected to a battery 28. U UU UU U
and a load as shown below : U U
The currents I, IZ and IL are respectively I, IZ IL
(1) 15 mA, 5 mA, 10 mA (1) 15 mA, 5 mA, 10 mA
(2) 15 mA, 7.5 mA, 7.5 mA (2) 15 mA, 7.5 mA, 7.5 mA
(3) 12.5 mA, 5 mA, 7.5 mA (3) 12.5 mA, 5 mA, 7.5 mA
(4) 12.5 mA, 7.5 mA, 5 mA (4) 12.5 mA, 7.5 mA, 5 mA

29. Match the List - I (Phenomenon associated 29. -I (l U h U)
with electromagnetic radiation) with -II (l SU )
List - II (Part of electromagnetic spectrum) U
and select the correct code from the
choices given below the lists :
List - I List - II - I - II
Visible
I Doublet of sodium A
radiation
I U m A U
Wavelength
corresponding to cU
II temperature associated B Microwave II U UU h B UU
with the isotropic UU
radiation filling all space
Wavelength emitted by UU U
Short
III atomic hydrogen in C
radiowave
III UU mU C UUU UU
interstellar space UU
Wavelength of radiation
UU SU
IV arising from two close D X - rays IV D X - U
energy levels in hydrogen U UU
(1) (I)-(A), (II)-(B), (III)-(B), (IV)-(C) (1) (I)-(A), (II)-(B), (III)-(B), (IV)-(C)
(2) (I)-(A), (II)-(B), (III)-(C), (IV)-(C) (2) (I)-(A), (II)-(B), (III)-(C), (IV)-(C)
(3) (I)-(D), (II)-(C), (III)-(A), (IV)-(B) (3) (I)-(D), (II)-(C), (III)-(A), (IV)-(B)
(4) (I)-(B), (II)-(A), (III)-(D), (IV)-(A) (4) (I)-(B), (II)-(A), (III)-(D), (IV)-(A)

30. In the circuit diagrams (A, B, C and D) 30. U (A, B, C D) , R
shown below, R is a high resistance and S U U S U G
is a resistance of the order of galvanometer U U U
resistance G. The correct circuit, h-
corresponding to the half deflection U
method for finding the resistance and
figure of merit of the galvanometer, is the
circuit labelled as :
(A)
(A)
(B)
(B)
(C)
(C)

(D)
(D)
RS
(1) Circuit A with G5 ( RS
R 2 S)
(1) G5 (
R 2 S)
U A
(2) Circuit B with G5S
(2) G5S U B
(3) Circuit C with G5S
(3) G5S U C
RS
(4) Circuit D with G5 RS
R2 S (4) G5 U D
R2 S

PART B CHEMISTRY B U
31. If lo and l be the threshold wavelength 31. lo U l $ U U
and wavelength of incident light, the U S
velocity of photoelectron ejected from the U
metal surface is :
2h 2h
(1) ( lo 2 l ) (1) ( lo 2 l )
m m
2hc 2hc
(2) ( lo 2 l ) (2) ( lo 2 l )
m m
2 h c lo 2 l 2 h c lo 2 l
(3) m l lo (3) m l lo
2h 1 1 2h 1 1
(4) 2 (4) 2
m lo l m lo l
32. The appearance of colour in solid alkali 32. U U U U U

metal halides is generally due to :
(1) Schottky defect (1) U
(2) Frenkel defect (2) $
(3) Interstitial position (3) U S
(4) F-centres (4) F-

33. In the reaction of formation of sulphur 33. mU $U UU
trioxide by contact process 2SO21O2 2SO3
d [O2 ]
2SO21O2 2SO3 the rate of reaction was U 522.531024 L21 s21
dt
measured as M U [SO2] M
d [O 2 ]
dt
522.531024mol L21 s21. The L21 s21
rate of reaction in terms of [SO2] in mol
L21s21 will be :
(1) 21.25310 24 (1) 21.25310 24
(2) 22.50310 24 (2) 22.50310 24
(3) 23.75310 24 (3) 23.75310 24
(4) 25.00310 24 (4) 25.00310 24
34. Assuming that the degree of hydrolysis is 34. U (U)
small, the pH of 0.1 M solution of sodium , U U U 0.1M
acetate (Ka=1.031025) will be : (Ka=1.031025) pH
(1) 5.0 (1) 5.0
(2) 6.0 (2) 6.0
(3) 8.0 (3) 8.0
(4) 9.0 (4) 9.0

35. For the reaction, 2N2O5 4NO21O2, the 35. 2N2O5 4NO21O2, U
rate equation can be expressed in two U U
d[N2O5 ] d[N2O5 ]
ways 2 5 k [ N 2 O 5 ] and 2 5 k [N2O5 ] U
dt dt
d [ NO 2 ] d [ NO 2 ]
1 5 k9 [ N 2 O 5 ] 1 5 k9 [ N 2 O 5 ]
dt dt
k and k are related as : k U k M ?
(1) k5k (1) k5k
(2) 2k5k (2) 2k5k
(3) k52k (3) k52k
(4) k54k (4) k54k
36. In some solutions, the concentration of
H3O1 remains constant even when small 36. U U U
amounts of strong acid or strong base are U H3O1 SU
added to them. These solutions are known U
as :
(1) Ideal solutions
(2) Colloidal solutions (1)
(3) True solutions (2) U
(4) Buffer solutions (3) S
(4) U (Buffer)

37. Given 37. -
Fe31(aq)1 e2Fe21(aq); E8=10.77 V Fe31()1 e2Fe21(); E8 =10.77 V
A l 3 1 ( a q ) 1 3 e2 A l ( s ) ; E 8 = 2 1 . 6 6 V Al31()13 e2Al(s); E8 = 21.66 V
2
Br2(aq)12 e22B r2 ; E8=11.09 V Br2()12 e 2B r2 ; E8 = 11.09 V
Considering the electrode potentials, UU U U
which of the following represents the S U ?
correct order of reducing power ?
(1) Fe21< Al < B r2
(1) Fe21< Al < B r2
(2) B r2 < Fe21< Al
(2) B r2 < Fe21< Al
(3) Al < B r2 < Fe21
(3) Al < B r2 < Fe21
(4) Al < Fe21< B r2
(4) Al < Fe21< B r2 38. U U U
750.0 mL UU
38. The initial volume of a gas cylinder is 840.0 mm Hg U 360.0 mm Hg
750.0 mL. If the pressure of gas inside the
cylinder changes from 840.0 mm Hg to
360.0 mm Hg, the final volume the gas will (1) 1.750 L
be : (2) 3.60 L
(1) 1.750 L (3) 4.032 L
(2) 3.60 L (4) 7.50 L
(3) 4.032 L
(4) 7.50 L

39. The molar heat capacity (Cp) of CD2O is 39. CD2O U c U (Cp) 1000 K U
10 cals at 1000 K. The change in entropy 10 cals 32 g CD2O c 1000 K
associated with cooling of 32 g of CD2O 100 K SU U UU U U h
vapour from 1000 K to 100 K at constant U U
pressure will be : (D = UUU, U U
(D = deuterium, at. mass = 2 u) = 2 )
(1) 23.03 cal deg21 (1) 23.03 cal deg21
(2) 223.03 cal deg21 (2) 223.03 cal deg21
(3) 2.303 cal deg21 (3) 2.303 cal deg21
(4) 22.303 cal deg21 (4) 22.303 cal deg21
40. Based on the equation : 40. U
1 1 1 1
(523 218 - 2 2 (523 218 - 2 2
n 2
n 1 n 2
n 1
2 2
the wavelength of the light that must be U U U U SU n=1
absorbed to excite hydrogen electron from SU n=2 U ,
level n=1 to level n=2 will be : , U
(h = 6.625310234 Js, C= 33108 ms21)
(h = 6.625310234 Js, C = 33108 ms21)
(1) 1.325310 27 m (1) 1.325310 27 m
(2) 1.325310210 m (2) 1.325310210 m
(3) 2.650310 27 m (3) 2.650310 27 m
(4) 5.300310210 m (4) 5.300310210 m

41. Which of the following series correctly 41. U$ X U Y
represents relations between the elements M U ?
from X to Y ?
X Y X Y
(1) 3Li 19K Ionization enthalpy (1) 3Li U
19K
increases
(2) 9F 35Br Electron gain enthalpy (2) 9F 35Br U
with negative sign
increases
(3) 6C 32Ge Atomic radii increases (3) 6C 32Ge U
(4) 18Ar 54Xe Noble character increases (4) 18Ar 54Xe C S
2
42. The correct order of bond dissociation 42. S N2, O2, O2
energy among N2, O2, O2 2
is shown in
which of the following arrangements ? ?
(1) N2 > O2
2
> O2 (1) N2 > O2
2
> O2
2 2
(2) O 2 > O2 > N2 (2) O 2 > O2 > N2
(3) N2 > O2 > O2

2
(3) N2 > O2 > O2
2
(4) O2 > O2
2
> N2 (4) O2 > O2
2
> N2

43. Which of the following statements about 43. Na2O2
Na2O2 is not correct ? ?
(1) It is diamagnetic in nature. (1)
(2) It is a derivative of H2O2. (2) H2O2
(3) Na2O2 oxidises Cr31 to CrO422 in (3) Na 2O 2 Cr 31
acid medium. CrO422
(4) It is the super oxide of sodium. (4) U U- U
44. Which of the following statements about 44. SU U

the depletion of ozone layer is correct ? ?
(1) The problem of ozone depletion is less (1) $ U S
serious at poles because NO 2 U NO2 U U
solidifies and is not available for U ClO U
consuming ClO radicals.
(2) The problem of ozone depletion is (2)
$ U S
more serious at poles because ice U U
crystals in the clouds over poles act SU Cl U ClO
as catalyst for photochemical UU mU U $
reactions involving the -U
decomposition of ozone by Cl and
ClO radicals.
(3) Freons, chlorofluorocarbons, are (3) (UU ) U M
inert chemically, they do not react U U
with ozone in stratosphere. S $ U
(4) Oxides of nitrogen also do not react (4) U U $ UU
with ozone in stratosphere. U U

45. A gaseous compound of nitrogen and 45. U U U
hydrogen contains 12.5%(by mass) of 12.5% U U U
hydrogen. The density of the compound 16
relative to hydrogen is 16. The molecular
formula of the compound is :
(1) NH2 (1) NH2
(2) N3H (2) N3H
(3) NH3 (3) NH3
(4) N2H4 (4) N2H4
46. Shapes of certain interhalogen compounds 46. U U
are stated below. Which one of them is ?
not correctly stated ?
(1) IF7 : pentagonal bipyramid (1) IF7 : mUU
(2) BrF5 : trigonal bipyramid (2) BrF5 : mUU
(3) BrF3 : planar T-shaped (3) BrF3 : T-U
(4) ICl3 : planar dimeric (4) ICl3 : UU ( S)
47. Consider the following equilibrium 47.

1 1
AgCl 12NH3 Ag ( NH 3 )2 1 Cl2 AgCl 12NH3 Ag ( NH 3 )2 1 Cl2
White precipitate of AgCl appears on U U AgCl

adding which of the following ? ?
(1) NH3 (1) NH3
(2) aqueous NaCl (2) NaCl
(3) aqueous HNO3 (3) HNO3
(4) aqueous NH4Cl (4) NH4Cl

48. Which of the following name formula 48. - ?
combinations is not correct ?
Formula Name
Potassium
(1) K2[Pt(CN)4] (1) K2[Pt(CN)4] U UU UU (II)
tetracyanoplatinate (II)
(2) [Mn(CN)5]22 Pentacyanomagnate (II) ion (2) [Mn(CN)5]22 U U(II)

Potassium diammine U
(3) K[Cr(NH3)2Cl4] (3) K[Cr(NH3)2Cl4]
tetrachlorochromate (III)
UUUUU(III)
Tetraammine aquaiodo UU UU
(4) [Co(NH3)4(H2O)I]SO4 (4) [Co(NH3)4(H2O)I]SO4
cobalt (III) sulphate
(III) $$U
49. Consider the coordination compound, 49. [Co(NH3)6]Cl3

[Co(NH3)6]Cl3. In the formation of this UU U
complex, the species which acts as the (Lewis acid) ,
Lewis acid is :
(1) [Co(NH3)6]31 (1) [Co(NH3)6]31
(2) Cl2 (2) Cl2
(3) Co31 (3) Co31
(4) NH3 (4) NH3
50. Which one of the following does not have 50. M UU ?

a pyramidal shape ?
(1) (CH3)3 N (1) (CH3)3 N
(2) (SiH3)3 N (2) (SiH3)3 N
(3) P(CH3)3 (3) P(CH3)3
(4) P(SiH3)3 (4) P(SiH3)3

51. The following reaction 51.
is known as : ?
(1) Perkin reaction (1) U
(2) Gattermann-Koch Formylation (2) UU - $U
(3) Kolbes reaction (3)
(4) Gattermann reaction (4) UU
52. The reagent needed for converting 52. U
is : U
(1) Cat. Hydrogenation (1) U. U
(2) H2/Lindlar Cat. (2) H2/UU U.
(3) Li/NH3 (3) Li/NH3
(4) LiAlH4 (4) LiAlH4
53. Complete reduction of benzene-diazonium 53. Zn/HCl mU $ U$ UU
chloride with Zn/HCl gives : U
(1) Aniline (1)
(2) Phenylhydrazine (2) $U$
(3) Azobenzene (3) $$
(4) Hydrazobenzene (4) U$$

54. An organic compound A, C5H8O; reacts 54. U A, C5H8O; U
with H 2 O, NH 3 and CH 3 COOH as H2O, NH3 U CH3COOH U
described below :
A is : A
(1) (1)
(2) (2)
(3) (3)
(4) (4)
55. In allene (C 3 H 4 ), the type(s) of 55. C3H4 () U (U)

hybridization of the carbon atoms is (are): U
(1) sp and sp3 (1) sp U sp3
(2) sp2 and sp (2) sp2 U sp
(3) only sp2 (3) sp2
(4) sp2 and sp3 (4) sp2 U sp3

56. Chlorobenzne reacts with trichloro 56. H 2 SO 4 S U $
acetaldehyde in the presence of H2SO4 UUU UU
The major product formed is :
(1) (1)
(2) (2)
(3) (3)
(4) (4)
57. Tischenko reaction is a modification of : 57. U M

(1) Aldol condensation (1) U
(2) Claisen condensation (2) $
(3) Cannizzaro reaction (3) $U
(4) Pinacol-pinacolon reaction (4) -

58. Which one of the following is used as 58. U SU M
Antihistamine ? U ?
(1) Omeprazole (1) $
(2) Chloranphenicol (2) U $
(3) Diphenhydramine (3) UU
(4) Norethindrone (4) UU
59. Which one of the following statements is 59. ?

not correct ?
(1) Alcohols are weaker acids than (1)
water
(2) Acid strength of alcohols decreases (2) U
in the following order -
RCH2OH > R2CHOH > R3COH RCH2OH > R2CHOH > R3COH
(3) Carbon-oxygen bond length in (3) , CH3OH -
methanol, CH3OH is shorter than $ C2O
that of C2O bond length in phenol. UU
(4) The bond angle in methanol (4) 108.98
is 108.98
60. The gas liberated by the electrolysis of 60. UU U l

Dipotassium succinate solution is :
(1) Ethane (1)
(2) Ethyne (2)
(3) Ethene (3)
(4) Propene (4)

PART C MATHEMATICS C
61. Let f be an odd function defined on the set 61. f S
of real numbers such that for x/0, U f(x)53 sin x14 cos x mU
f(x)53 sin x14 cos x. 11p
U x/0 , x5 2 U
6
11p
Then f(x) at x 5 2 is equal to : f(x) UU
6
3
(1) 12 3 3
2 (1) 12 3
2
3
(2) 2 12 3 3
2 (2) 2 12 3
2
3
(3) 22 3 3
2 (3) 22 3
2
3
(4) 2 22 3 3
2 (4) 2 22 3
2
62. If z1, z2 and z3, z4 are 2 pairs of complex

conjugate numbers, then 62. z1, z2 z3, z4 o
, -
z z
arg 1 1 arg 2 equals : z z
z4 z3 arg 1 1 arg 2 UU
z4 z3
(1) 0
(1) 0
p
(2) p
2 (2)
2
3p
(3) 3p
2 (3)
2
(4) p
(4) p

63. If a and b are roots of the equation, 63. a b
, U
k
2 4 ln k
x 2 2 4 2 kx 1 2e 4 ln k2 1 5 0 for some k, x 2 4 2 kx 1 2e 2 1 5 0
and a21b2 5 66, then a31b3 is equal to : a 1b 5 66, , a 1b3 UU
2 2 3
(1) (1) 248 2

248 2
(2) (2) 280 2
280 2
(3) (3) 232 2
232 2
(4) (4) 2280 2
2280 2
64. Let A be a 333 matrix such that 64. A 333
1 2 3 0 0 1 1 2 3 0 0 1
A 0 2 3 5 1 0 0 A 0 2 3 5 1 0 0
,

0 1 1 0 1 0 0 1 1 0 1 0
Then A21 is : A21
3 1 2 3 1 2
3 0 2 3 0 2
(1) (1)

1 0 1 1 0 1
3 2 1 3 2 1
3 2 0 3 2 0
(2) (2)

1 1 0 1 1 0
0 1 3 0 1 3
0 2 3 0 2 3
(3) (3)

1 1 1 1 1 1
1 2 3 1 2 3
0 1 1 0 1 1
(4) (4)

0 2 3 0 2 3

65. Let for i51, 2, 3, pi(x) be a polynomial of 65. i51, 2, 3, pi(x), x 2
degree 2 in x, pi(x) and pi(x) be the first , pi(x) pi(x) U
and second order derivatives of p i (x) m U
respectively. Let,
p1 ( x ) p19 ( x ) p10 ( x ) p1 ( x ) p19 ( x ) p10 ( x )
A( x ) 5 p2 ( x ) p29 ( x ) p20 ( x ) A( x ) 5 p2 ( x ) p29 ( x ) p20 ( x )
p3 ( x ) p39 ( x ) p30 ( x ) p3 ( x ) p39 ( x ) p30 ( x )
and B(x) = [A(x)]T A(x). Then determinant B(x) = [A(x)] T A(x) , B(x)
of B(x) : U
(1) is a polynomial of degree 6 in x. (1) x 6
(4) does not depend on x. (4) x U U U
66. An eight digit number divisible by 9 is to 66. 0 9 , U
be formed using digits from 0 to 9 without , 9 , U
repeating the digits. The number of ways U ,
in which this can be done is :
(1) 72 (7!) (1) 72 (7!)
(2) 18 (7!) (2) 18 (7!)
(3) 40 (7!) (3) 40 (7!)
(4) 36 (7!) (4) 36 (7!)

67. The coefficient of x 50 in the binomial 67. (11x) 1000 1 x(11x) 999 1x 2 (11x) 998 1
expansion of ......1x1000 m U x50
(11x) 1000 1 x(11x) 999 1x 2 (11x) 998 1
......1x1000 is :
(1000) ! (1000) !
(1) (1)
(50) ! (950) ! (50) ! (950) !
(1000) ! (1000) !
(2) (2)
(49) ! (951) ! (49) ! (951) !
(1001) ! (1001) !
(3) (3)
(51) ! (950) ! (51) ! (950) !
(1001) ! (1001) !
(4) (4)
(50) ! (951) ! (50) ! (951) !
68. In a geometric progression, if the ratio of 68. U o 5

the sum of first 5 terms to the sum of their 49
reciprocals is 49, and the sum of the first U U 35 , U
and the third term is 35. Then the first term o
of this geometric progression is :
(1) 7 (1) 7
(2) 21 (2) 21
(3) 28 (3) 28
(4) 42 (4) 42

69. The sum of the first 20 terms common 69. oU 3171111151..... U
between the series 3171111151..... and 1161111161..... , cU
1161111161..... , is : 20
(1) 4000 (1) 4000
(2) 4020 (2) 4020
(3) 4200 (3) 4200
(4) 4220 (4) 4220
70. If 70.
tan ( x 2 2 ){x 2 1 (k22)x 2 2k} tan ( x 2 2 ){x 2 1 (k22)x 2 2k}
lim 55 , lim 55
x 2 x 2 2 4x 1 4 x 2 x 2 2 4x 1 4
then k is equal to : , k UU
(1) 0 (1) 0
(2) 1 (2) 1
(3) 2 (3) 2
(4) 3 (4) 3
71. Let f(x)5x?x?, g(x) = sin x and 71. f(x)5x?x?, g(x) = sin x
h(x) 5(gof )(x). Then h(x) 5(gof ) (x) ,
(1) h(x) is not differentiable at x50. (1) h(x), x50 U
(2) h(x) is differentiable at x50, but (2) h(x), x50 U U h(x),
h(x) is not continuous at x50. x50 U
(3) h(x) is continuous at x50 but it is (3) h(x), x50 U , U x50 U
not differentiable at x50.
(4) h(x) is differentiable at x50. (4) h(x), x50 U

72. For the curve y = 3 sin u cos u, x5eu sin u, 72. y = 3 sin u cos u, x5e u sin u,
0 [ u [ p, the tangent is parallel to x-axis 0 [ u [ p, SU x- U ,
when u is : u UU
(1) 3p (1) 3p
4 4
(2) p (2) p
2 2
(3) p (3) p
4 4
(4) p (4) p
6 6
73. Two ships A and B are sailing straight 73. $ A B, O U
away from a fixed point O along routes Z U U U AOB 1208
such that AOB is always 1208. At a U , OA = 8
certain instance, OA = 8 km, OB = 6 km OB = 6 $ A, 20 /U
and the ship A is sailing at the rate of U $ B, 30 /U
20 km/hr while the ship B sailing at the U , A B U
rate of 30 km/hr. Then the distance U (/U ) U ,
between A and B is changing at the rate
(in km/hr) :
(1) 260 37
(1) 260 37
(2) 260 37
(2) 260 37
(3) 80 37
(3) 80 37
(4) 80 37
(4) 80 37

74. The volume of the largest possible right 74. 3 ,
circular cylinder that can be inscribed in a
sphere of radius5 3 is :
4 4
(1) 3 p (1) 3 p
3 3
8 8
(2) 3 p (2) 3 p
3 3
(3) 4p (3) 4p
(4) 2p (4) 2p
2 2
21 1 2 x
75. The integral x cos dx (x > 0) 75. x cos21 1 2 x 2 dx , (x > 0) UU
1 1 x2 11x
is equal to :
(1) 2 x1(11x2) tan21 x1c (1) 2 x1(11x2) tan21 x1c
(2) x2 (11x2) cot21 x1c (2) x2 (11x2) cot21 x1c
(3) 2 x1(11x2) cot21 x1c (3) 2 x1(11x2) cot21 x1c
(4) x2 (11x2) tan21 x1c (4) x2 (11x2) tan21 x1c
e e
n
76. If for n/1, Pn 5 (log x ) d x , then 76. n/1 , Pn 5 (log x )n d x ,
1 1
P10290P8 is equal to : P10290P8 UU
(1) 29 (1) 29
(2) 10e (2) 10e
(3) 29e (3) 29e
(4) 10 (4) 10

77. If the general solution of the differential 77. F U
y x y x
equation y9 5 1 F , for some y9 5 1 F , y ln ?cx?5x,
x y x y
function F, is given by mU , c SU U , F(2)
y ln ?cx?5x, where c is an arbitrary UU
constant, then F (2) is equal to :
(1) 4 (1) 4
1 1
(2) (2)
4 4
(3) 24 (3) 24
1 1
(4) 2 (4) 2
4 4
78. A stair-case of length l rests against a 78. l U U U

vertical wall and a floor of a room,. Let P U
be a point on the stair-case, nearer to its P, U U
end on the wall, that divides its length in U , U
the ratio 1 : 2. If the stair-case begins to 1 : 2 U U
slide on the floor, then the locus of P is : U , P
1 1
(1) an ellipse of eccentricity (1)
2 2
3 3
(2) an ellipse of eccentricity (2)
2 2
l l
(3) a circle of radius
2
(3) 2

3 3
(4) a circle of radius
2
l (4) l
2

79. The base of an equilateral triangle is along 79. U U 3x14y = 9
the line given by 3x14y = 9. If a vertex of (1, 2)
the triangle is (1, 2), then the length of a
side of the triangle is :
2 3 2 3
(1) (1)
15 15
4 3 4 3
(2) (2)
15 15
4 3 4 3
(3) (3)
5 5
2 3 2 3
(4) (4)
5 5
80. The set of all real values of l for which 80. l S ,

exactly two common tangents can be x21y224x24y1650
drawn to the circles x 2 1y 2 210x210y1l50 U U
x21y224x24y1650 and cU SU ,
x21y2210x210y1l50 is the interval : U ,
(1) (12, 32)
(1) (12, 32)
(2) (18, 42)
(2) (18, 42)
(3) (12, 24)
(3) (12, 24)
(4) (18, 48)
(4) (18, 48)

81. Let L1 be the length of the common chord 81. L1, x21y259 y258x,
of the curves x21y259 and y258x, and cU , L2, y258x
L2 be the length of the latus rectum of ,
y258x, then :
(1) L1 > L 2 (1) L1 > L2
(2) L15L2 (2) L15L2
(3) L1 < L 2 (3) L1 < L2
L1 L1
(4) 5 2 (4) 5 2
L2 L2
82. Let P (3 sec u, 2 tan u) and

x2 y2
82. U 2 5 1 U
p 9 4
Q (3 sec f, 2 tan f) where u 1 f 5
, be
2 P (3 sec u, 2 tan u) Q (3 sec f, 2 tan f)
two distinct points on the hyperbola p
2 2 , u1f 5
2
, P Q U
x y
2 5 1 . Then the ordinate of the
9 4 U U (ordinate)
point of intersection of the normals at P
and Q is :
11 11
(1) (1)
3 3
11 11
(2) 2 (2) 2
3 3
13 13
(3) (3)
2 2
13 13
(4) 2 (4) 2
2 2

83. Let A (2, 3, 5), B (21, 3, 2) and 83. A (2, 3, 5), B (21, 3, 2)
C (l, 5, m) be the vertices of a DABC. If the C (l, 5, m) ABC A
median through A is equally inclined to U , U
the coordinate axes, then : ,
(1) 5l28m50 (1) 5l28m50
(2) 8l25m50 (2) 8l25m50
(3) 10l27m50 (3) 10l27m50
(4) 7l210m50 (4) 7l210m50
84. The plane containing the line x 21 y 22 z 23

84. U 5 5 c U
x 21 y 22 z 23 1 2 3
5 5 and parallel to
1 2 3 x y z
U U 5 5 U ,
x y z 1 1 4
the line 5 5 passes through the
1 1 4 U ,
point :
(1) (1,22, 5) (1) (1,22, 5)
(2) (1, 0, 5) (2) (1, 0, 5)
(3) (0, 3,25) (3) (0, 3,25)
(4) (21,23, 0) (4) (21,23, 0)

2
85. If ? c ? 5 60 and c 3( i12 j15 k )50 , 85. ? c ?2 5 60 c 3( i12 j15 k )50 , ,

then a value of c . (2 7 i 1 2 j 1 3 k ) is : c . (2 7 i 1 2 j 1 3 k )
(1) 4 2 (1) 4 2
(2) 12 (2) 12
(3) 24 (3) 24
(4) 12 2 (4) 12 2

86. A set S contains 7 elements. A non-empty 86. S 7 S U
subset A of S and an element x of S are A S x , U
chosen at random. Then the probability , xA
that xA is :
1 1
(1) (1)
2 2
64 64
(2) (2)
127 127
63 63
(3) (3)
128 128
31 31
(4) (4)
128 128
87. If X has a binomial distribution, B(n, p) 87. X m U, B(n, p) ,

with parameters n and p such that n, p , U P(X52)5P(X53)
P(X52)5P(X53), then E(X), the mean of , U X E(X)
variable X, is :
(1) 22p (1) 22p
(2) 32p (2) 32p
p p
(3) 2 (3) 2
p p
(4) 3 (4) 3

p p
88. If 2 cos u1sin u51 u 2 ,

88. 2 cos u1sin u51 u 2

,
then 7 cos u16 sin u is equal to : 7 cos u16 sin u UU
1 1
(1) (1)
2 2
(2) 2 (2) 2
11 11
(3) (3)
2 2
46 46
(4) (4)
5 5
89. The angle of elevation of the top of a 89. U P U U

vertical tower from a point P on the U a P U
horizontal ground was observed to be a. U 2 . U,
After moving a distance 2 metres from P U b , (.) U
towards the foot of the tower, the angle of
elevation changes to b. Then the height (in
metres) of the tower is :
2 sin a sin b 2 sin a sin b

(1) sin (b2a ) (1) sin (b2a )
sin a sin b sin a sin b

(2) cos (b2a ) (2) cos (b2a )
2 sin (b2a ) 2 sin (b2a )

(3) (3)
cos (b2a ) cos (b2a )

(4) (4)

90. The proposition ~ (p ~ q) ~ (pq) 90. ~(p~q)~(pq) M
is logically equivalent to : ,
(1) p (1) p
(2) q (2) q
(3) ~p (3) ~p
(4) ~q (4) ~q
-o0o- -o0o-

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PART A PHYSICS A

1. In terms of resistance R and time T, the 1. U R U T , m

2. The initial speed of a bullet fired from a 2. U U U

English : 1 Set : 11 Hindi : 1 Set : 11

English : 2 Set : 11 Hindi : 2 Set : 11

English : 3 Set : 11 Hindi : 3 Set : 11

English : 4 Set : 11 Hindi : 4 Set : 11

English : 5 Set : 11 Hindi : 5 Set : 11

9. A tank with a small hole at the bottom has 9. UU U U ^

English : 6 Set : 11 Hindi : 6 Set : 11

English : 7 Set : 11 Hindi : 7 Set : 11

English : 8 Set : 11 Hindi : 8 Set : 11

English : 9 Set : 11 Hindi : 9 Set : 11

15. Two factories are sounding their sirens 15. UU U 800 Hz U U

English : 10 Set : 11 Hindi : 10 Set : 11

(2) EhR (2) EhR

(3) 2EhR (3) 2EhR

(4) 4EhR (4) 4EhR

English : 11 Set : 11 Hindi : 11 Set : 11

English : 12 Set : 11 Hindi : 12 Set : 11

(1) 2.5 and 3 (1) 2.5 3

(1) 331024 N toward right (1) 331024 N U

English : 13 Set : 11 Hindi : 13 Set : 11

Make the correspondence of these bars U Z (D),

21. A coil of circular cross-section having 21. 1000 U 4 cm2

English : 14 Set : 11 Hindi : 14 Set : 11

English : 15 Set : 11 Hindi : 15 Set : 11

25. In a compound microscope the focal length 25.

English : 16 Set : 11 Hindi : 16 Set : 11

27. A radioactive nuclei with decay constant 27. 100 U SU U SU

English : 17 Set : 11 Hindi : 17 Set : 11

(1) 15 mA, 5 mA, 10 mA (1) 15 mA, 5 mA, 10 mA

English : 18 Set : 11 Hindi : 18 Set : 11

English : 19 Set : 11 Hindi : 19 Set : 11

English : 20 Set : 11 Hindi : 20 Set : 11

English : 21 Set : 11 Hindi : 21 Set : 11

32. The appearance of colour in solid alkali 32. U U U U U

English : 22 Set : 11 Hindi : 22 Set : 11

English : 23 Set : 11 Hindi : 23 Set : 11

English : 24 Set : 11 Hindi : 24 Set : 11

English : 25 Set : 11 Hindi : 25 Set : 11

English : 26 Set : 11 Hindi : 26 Set : 11

(4) 18Ar 54Xe Noble character increases (4) 18Ar 54Xe C S

(3) N2 > O2 > O2

English : 27 Set : 11 Hindi : 27 Set : 11

44. Which of the following statements about 44. SU U

English : 28 Set : 11 Hindi : 28 Set : 11

47. Consider the following equilibrium 47.

White precipitate of AgCl appears on U U AgCl

English : 29 Set : 11 Hindi : 29 Set : 11

(2) [Mn(CN)5]22 Pentacyanomagnate (II) ion (2) [Mn(CN)5]22 U U(II)

49. Consider the coordination compound, 49. [Co(NH3)6]Cl3

50. Which one of the following does not have 50. M UU ?

English : 30 Set : 11 Hindi : 30 Set : 11

52. The reagent needed for converting 52. U

English : 31 Set : 11 Hindi : 31 Set : 11

55. In allene (C 3 H 4 ), the type(s) of 55. C3H4 () U (U)

(2) sp2 and sp (2) sp2 U sp

(3) only sp2 (3) sp2

(4) sp2 and sp3 (4) sp2 U sp3

English : 32 Set : 11 Hindi : 32 Set : 11

The major product formed is :

57. Tischenko reaction is a modification of : 57. U M