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MATERIAL SAFETY DATA SHEET

1. CHEMICAL IDENTITY
Chemical Name: Crude Benzol
Chemical Classification: Toxic, Flammable Trade Name: Crude Benzol
Synonyms: Benzol
Dangerous Components
Name: Benzene (B) Formula: C6H6 CAS No: 71-43-2 UN No: 1114
Name: Toluene (T) Formula: C7H8 CAS No: 108-88-3 UN No: 1294
Name: Xylenes (X) Formula: C8H10 CAS No: 1330-20-7 UN No: 1307
Name: Solvent Naphtha Formula: CAS No: 8030-30-6 UN No:
Regulated Identification
Shipping Name: Crude Benzol Hazchem Code: 3YE
Codes / Label: Class 3, Toxic, Flammable Hazardous Waste ID No : 5
HAZARDOUS INGREDIENTS C.A.S. No. HAZARDOUS INGREDIENTS C.A.S. No.
1 Benzene 71-43-2 3 Xylenes 1330-20-7
2 Toluene 108-88-3 4 Solvent Naphtha 8030-30-6
2. PHYSICAL / CHEMICAL DATA
BENZOL:
Drop Pt. OC: 70 2 Dry Pt. OC: 205 5 Specific Gravity: 0.87-0.89
Moisture: Traces
BENZENE:
Boiling Pt. OC: 80.1 Physical State: Liquid Appearance: Colourless
O O
Relative Density at 25 C: 0.88 Vapour Pressure at 20 C mmHg: 75 Odour: Sweetish aromatic
Vapour Density(Air =1): 2.77 Solubility in water at 23.5C g/l: 1.88 Mol. wt.: 78.11
O O
Melting Point C: 5.5 Critical Temperature C: 288.9 Conductivity at 20OC: <50pSm
Others: Soluble in alcohol, chloroform, CS2, CCl4, glacial acetic acid, diethyl ether, acetone.

TOLUENE:
Boiling Pt. OC: 110.6 Physical State: Liquid Appearance: Colourless
O
Melting Point C: -94.9 Vapour Pressure at 25OC mmHg: 28.4 Odour: Sweetish aromatic
Vapour Density(Air =1): 3.14 Solubility in water at 25C mg/l: 526 Mol. wt.: 92.15
Others: Soluble in acetone, alcohol, ether Specific Gravity at 4-20 OC: 0.8636 pH: Neutral

XYLENES, o-, m-, p-:


Boiling Pt. OC: 138-144 Physical State: Liquid Appearance: Colourless
O O
Melting Point C: -48 to 13 Vapour Pressure at 25 C mmHg: 7-9 Odour: Sweetish aromatic
Vapour Density(Air =1): 3.7 Solubility in water at 25C g/100l: < 0.02 Mol. wt.: 106.17
Others: Soluble in alcohol, ethanol, ether, petroleum spirit Specific Gravity at 4-20 OC: 0.8636
SOLVENT NAPHTHA:
Boiling Pt. OC: 160-220 Physical State: Liquid Appearance: Colourless

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Melting Point OC: Vapour Pressure at 20OC mmHg: <5 Odour: Gasoline
O
Vapour Density(Air =1): 2.5 Solubility in water at 30 C : InsolubleMol. wt.: 110 approx.
Others: Soluble in benzene, toluene, xylene Specific Gravity (Water=1): 0.89 0.97
3. FIRE / EXPLOSION HAZARD DATA
BENZENE
Flammability : Yes LEL: 1.2 Flash Point C in OC:
TDG Flammability: UEL: 7.8 Flash Point C in CC: -11.1
Auto-ignition Temperature C : 497.78
Explosion sensitivity to impact : Stable
Explosion sensitivity to static Electricity : Stable
Hazardous Combustion Products :
Hazardous Polymerization : Will not occur.
Combustible Liquid : Yes Explosive Material : No Corrosive Material: No
Flammable Material : Yes Oxidiser : No Others:
Pyrophoric Material : No Organic Peroxide : No
TOLUENE
Flammability : Yes LEL: 1.2 Flash Point C in OC: 12.7
TDG Flammability: 3 UEL: 7.1 Flash Point C in CC: 4.5
Auto-ignition Temperature C : 535.5
Explosion sensitivity to impact : Stable
Explosion sensitivity to static Electricity :
Hazardous Combustion Products : Emits acrid smoke and irritating fumes
Hazardous Polymerization : Will not occur.
Combustible Liquid : Yes Explosive Material : No Corrosive Material: No
Flammable Material : Yes Oxidiser : No Others:
Pyrophoric Material : No Organic Peroxide : No
XYLENES
Flammability : Yes LEL: 0.9 Flash Point C in OC: 27
TDG Flammability: UEL: 7.0 Flash Point C in CC:
Auto-ignition Temperature C : 463 - 528
Explosion sensitivity to impact :
Explosion sensitivity to static Electricity :
Hazardous Combustion Products :
Hazardous Polymerization :
Combustible Liquid : Yes Explosive Material : No Corrosive Material: No
Flammable Material : Yes Oxidiser : No Others:
Pyrophoric Material : No Organic Peroxide : No
SOLVENT NAPHTHA
Flammability : Yes LEL: 1.1 Flash Point C in OC: about 40
TDG Flammability: UEL: 5.9 Flash Point C in CC:

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Auto-ignition Temperature C : 288
Explosion sensitivity to impact :
Explosion sensitivity to static Electricity :
Hazardous Combustion Products : Fire may produce irritating, corrosive and/or toxic gases
Hazardous Polymerization :
Combustible Liquid : No Explosive Material : No Corrosive Material: No
Flammable Material : Yes Oxidiser : No Others:
Pyrophoric Material : No Organic Peroxide : No
4. REACTIVITY DATA
BENZENE
Chemical Stability : Stable
Incompatibility with other material: Oxidizing agents, acids.
Reactivity : Benzene vapors + chlorine and light causes explosion. Reacts explosively with bromine
pentafluoride, chlorine, chlorine trifluoride, diborane, nitric acid, nitryl perchlorate,
liquid oxygen, ozone, silver perchlorate. Benzene + pentafluoride and methoxide (from
arsenic pentafluoride and potassium methoxide) in trichlorotrifluoroethane causes
explosion. Interaction of nitryl perchlorate with benzene gave a slight explosion and
flash. The solution of permanganic acid (or its explosive anhydride, dimanganese
heptoxide) produced by interaction of permanganates and sulfuric acid will explode on
contact with benzene. Peroxodisulfuric acid is a very powferful oxidant. Uncontrolled
contact with benzene may cause explosion. Mixtures of peroxomonsulfuric acid with
benzene explodes
Hazardous Reaction Products :
TOLUENE
Chemical Stability : Stable
Incompatibility with : Strong oxidizers may cause fire and explosions. Violent reaction with mixtures of nitric
other material and sulphuric acid.
Reactivity : Reacts vigorously with oxidising materials. Reacts explosively with N 2O4; AgClO4; H2SO4
+ HNO3; conc. HNO3, UF6 and 1,3-dichloro-5,5-dimethyl-2,4-imidazolididione.
Hazardous : Forms an explosive mixture with tetranitromethane
Reaction Products
XYLENES
Chemical Stability : Stable
Incompatibility with : Strong oxidizers; strong acids.
other material
Reactivity : Reacts violently with (strong) oxidizers: (increased) risk of fire/explosion. Reacts with
(some) acids.
Hazardous : CO; CO2
Reaction Products
SOLVENT NAPHTHA

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Chemical Stability : Volatile
Incompatibility with : Incompatible with strong oxidizing agents like nitric acid.
other material
Reactivity :
Hazardous Reaction Products : Oxides of Carbon
5. HEALTH HAZARD DATA
BENZENE
Routes of entry: Inhalation, Ingestion, Eyes and Skin
Effects of Exposure / Symptoms:
Short Term Exposure - Inhalation of Benzene may produce both nerve and blood effects. Irritation of the nose,
throat, and lungs may occur (3000 ppm may be tolerated for only 3060 min). Lung congestion may occur.
Nerve effects may include an exaggerated feeling of well-being, excitement, headache, dizziness, and slurred
speech. At high levels, slowed breathing and death may result. Death has occurred at 20,000 ppm for 5-10 min
or 7500 ppm for 30 min. Skin contact: Irritation may occur, with redness and blistering if not promptly
removed. Benzene is poorly absorbed. Whole body exposure for 30 min has been reported with no health
effects. Eye contact may cause severe irritation. Ingestion may cause irritation of mouth, throat, and stomach.
Symptoms are similar to those listed under inhalation. One tablespoon may cause collapse, bronchitis,
pneumonia, and death. Use of alcoholic beverages enhances the harmful effect.
Long Term Exposure - Benzene is a known human carcinogen. Exposure has been linked to increased risk of
several forms of leukemia. The liquid defats the skin. The substance may have effects on the blood forming
organs, liver and immune system. It may cause loss of appetite, nausea, weight loss, fatigue, muscle weakness,
headache, dizziness, nervousness and irritability. Mild anemia has been reported from exposures of 25 ppm for
several years and 100 ppm for 3 months. At levels between 100 and 200 ppm for periods of 6 months, or more,
severe irreversible blood changes and damage to liver and heart may occur. Temporary partial paralysis has
been reported.
Emergency Treatment:
Inhalation: Move victim to fresh air. Give artificial respiration if breathing has stopped and CPR if heart action
has stopped. Transfer promptly to a medical facility.
Skin : Remove contaminated clothing and wash immediately with soap and water. Seek medical attention
immediately.
Eyes : Remove contact lens, if any. Wash with plenty of water for 15 minutes. Seek medical aid.
Ingestion : Rinse mouth; do not induce vomiting. Seek medical aid.
Conversion factor: 1 ppm = 3.19 mg/m3 at 25OC & 1 atm
STEL: Confirmed human carcinogen. Limit exposure to lowest feasible level.
Odour Threshold: 4.9 mg/m3 in air; 2.0 mg/l in water.
PEL/TWA: 1 ppm TLV (ACGIH): 0.5 ppm
NFPA Hazard Health Flammability Reactivity Special
Signals 2 3 0
TOLUENE
Routes of entry: Inhalation, Ingestion, Eyes and Skin

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Effects of Exposure / Symptoms:
Vapours irritate eyes and upper respiratory tract. It causes dizziness, headache, anesthesia, respiratory arrest.
Liquid irritates eyes and causes drying of skin. If aspirated, causes coughing, gagging, distress and rapidly
developing pulmonary edema. If ingested, causes vomiting, griping, diarrhea, depressed respiration.
Emergency Treatment:
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical
aid. Do not use mouth-to-mouth respiration.
Skin : Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Eyes : Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower
eyelids. Get medical aid immediately.
Ingestion : Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk orwater. Never give
anything by mouth to an unconscious person. It is a possible aspiration hazard. Get medical aid
immediately.
LD50 (oral-rat) mg/kg: 5000 STEL: 150 ppm (560 mg/m3)
LC50 (rat) mg/kg: Odour Threshold: 2.14 ppm
3
PEL: 100 ppm (375 mg/m ) TLV (ACGIH): 100 ppm (375 mg/m3)
NFPA Hazard Health Flammability Reactivity Special
Signals 2 3 0
XYLENES
Routes of entry: Inhalation, Ingestion, Eyes and Skin
Effects of Exposure / Symptoms:
Short Term Exposure - Exposure to vapor can be irritating to the nose and throat. Inhalation of vapor at
concentrations above 200 ppm or 3-5 min can lead to xylene intoxication. Symptoms include headache,
dizziness, nausea, and vomiting. If exposure continues, central nervous system depression characterized
by shallow breathing and weak pulse can occur. Levels of 230 ppm for 15 min may cause lightheadedness
without loss of equilibrium. Reversible liver and kidney damage in humans has followed exposure to
sudden high concentrations of vapor. Such high levels may also give rise to lung congestion. Exposure to
extremely high concentrations (10,000 ppm or more) of xylene vapors can lead to a strong narcotic effect
with symptoms of slurred speech, stupor fatigue, confusion, unconsciousness, coma, and possible death.
Skin: Contact with vapor or liquid can cause defatting which may lead to irritation, drying, and cracking.
Eyes: Vapor and liquid may be irritating to the eye and eyelids at levels of 100 ppm for 15 min. Ingestion:
Swallowing liquid xylene will bring about an immediate burning sensation in the mouth and throat.
Irritation of the stomach and intestine can give rise to sharp stomach pains. Symptoms are the same as
inhalation, except that lung congestion will not usually develop.
Long Term Exposure - Inhalation of xylene vapor and skin contact with liquid are the two most probable
routes of long-term exposure. Symptoms of inhalation are dizziness, headache, and nausea. Long-term
exposure has been associated with liver and kidney damage, intestinal tract disturbances, and central
nervous system depression. Prolonged contact with skin can lead to irritation, dryness, and cracking.
Repeated exposure can cause poor memory, difficulty in concentration, and other brain effects. It can also
cause damage to the eye surface.

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Emergency Treatment:
Inhalation: Move victim to fresh air. Give artificial respiration if breathing has stopped and CPR if heart action
has stopped. Transfer promptly to a medical facility.
Skin : Remove contaminated clothing and wash immediately with soap and water. Seek medical attention
immediately.
Eyes : Remove contact lens, if any. Wash with plenty of water for 15 minutes. Seek medical aid.
Ingestion : Rinse mouth; do not induce vomiting. Seek medical aid.
LD50 (oral-rat) mg/kg: 3523 STEL: 150 ppm (651 mg/m3)
LC50 (rat) mg/l: 27.57/ 4 hr Odour Threshold: 0.081 - 40 ppm
3
PEL/TWA: 150 ppm (651 mg/m ) TLV (ACGIH): 100 ppm (434 mg/m3)
NFPA Hazard Health Flammability Reactivity Special
Signals 2 3 0
SOLVENT NAPHTHA
Routes of entry: Inhalation, Ingestion, Eyes and Skin
Effects of Exposure / Symptoms:
Inhalation: Coughing, choking, tachypnea, dyspnea, cyanosis, rales, hemoptysis, pulmonary edema,
pneumatoceles, lipoid pneumonia, or respiratory arrest may develop following ingestion and aspiration.
Ingestion : Nausea, vomiting, diarrhea, and abdominal pain may occur following ingestion.
Skin & eyes: May cause irritation or burns
Emergency Treatment:
Inhalation: Move victim to fresh air. Give artificial respiration if victim is not breathing. Administer oxygen
if there is breathing difficulty.
Skin : Remove and isolate contaminated clothing and shoes. Wash skin with soap and water. Flush with
running water for at least 20 minutes.
Eyes : Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain,
swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.
Ingestion : Call a physician immediately.
LD50 (oral-rat) mg/kg: STEL:
LC50 (rat) mg/kg: Odour Threshold:
3
PEL: 100 ppm (400 mg/m ) TLV (ACGIH):
NFPA Hazard Health Flammability Reactivity Special
Signals 2 2 0
6. PREVENTIVE MEASURES
Personal Protective : Do not eat or drink at work place. Provide safety shower, eye wash basin, safety goggles
Equipment /face shield, respirator (self-contained or air-line), rubber shoes, rubber gloves, rubber
apron. Avoid contact with liquid or vapours.
Handling : Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond
containers while transferring material. Avoid contact with eyes, skin, and clothing. Avoid
contact with skin and eyes. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat,

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sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage : Store in a well ventilated, cool, dry area, away from heat, spark, flame and oxidising
materials.
Precaution :
7. EMERGENCY / FIRST AID MEASURES
BENZENE
FIRE:
Fire Extinguishing Media: Dry chemical powder for small fire. Use water spray or fog for large fire.
Special Procedure : Use water spray to cool exposed containers from a secure, explosion-proof location.
Unusual Hazards : Vapors are heavier than air and will collect in low areas. Vapors may travel long
distances to ignition sources and flashback. Vapors in confined areas may explode when exposed to fire.
Storage containers and parts of containers may rocket great distances, in many directions.
EXPOSURE: First Aid Measures:
Inhalation: Move victim to fresh air. Give artificial respiration if breathing has stopped and CPR if heart action
has stopped. Transfer promptly to a medical facility.
Skin : Remove contaminated clothing and wash immediately with soap and water. Seek medical attention
immediately.
Eyes : Remove contact lens, if any. Wash with plenty of water for 15 minutes. Seek medical aid.
Ingestion : Rinse mouth; do not induce vomiting. Seek medical aid.
TOLUENE
FIRE:
Fire Extinguishing Media: CO2, dry chemical powder, foam.
Special Procedure : Keep containers cool by spraying water if exposed to heat or flame.
Unusual Hazards : Flashback along vapour-trail may occur.
EXPOSURE: First Aid Measures:
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical
aid. Do not use mouth-to-mouth respiration.
Skin : Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Eyes : Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower
eyelids. Get medical aid immediately.
Ingestion : Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give
anything by mouth to an unconscious person. It is a possible aspiration hazard. Get medical aid
immediately.
XYLENES
FIRE:
Fire Extinguishing Media: Water spray. Polyvalent foam. Alcohol-resistant foam. BC powder. Carbon dioxide.
Special Procedure : Keep containers cool by spraying water if exposed to heat or flame.
Unusual Hazards : May be ignited by sparks.

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EXPOSURE: First Aid Measures:
Inhalation: Move victim to fresh air. Give artificial respiration if breathing has stopped and CPR if heart action
has stopped. Transfer promptly to a medical facility.
Skin : Remove contaminated clothing and wash immediately with soap and water. Seek medical attention
immediately.
Eyes : Remove contact lens, if any. Wash with plenty of water for 15 minutes. Seek medical aid.
Ingestion : Rinse mouth; do not induce vomiting. Seek medical aid.
SOLVENT NAPHTHA
FIRE:
Fire Extinguishing Media: Use dry chemical, carbon dioxide, or alcohol foam extinguishers.
Special Procedure : Keep containers cool by spraying water if exposed to heat or flame.
Unusual Hazards : Flashback along vapour-trail may occur.
EXPOSURE: First Aid Measures:
Inhalation: Move victim to fresh air. Give artificial respiration if victim is not breathing. Administer oxygen
if there is breathing difficulty.
Skin : Remove and isolate contaminated clothing and shoes. Wash skin with soap and water. Flush with
running water for at least 20 minutes.
Eyes : Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain,
swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.
Ingestion : Call a physician immediately.
SPILLS:
Steps To Be Taken : Attempt to stop leak if without undue personnel hazard. Use water spray to knock-down
vapors. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid
material.
Waste Disposal Method: Seal all waste in vapour-tight plastic bags for eventual disposal.
8. ADDITIONAL INFORMATION / REFERENCES
A very dangerous fire hazard when exposed to heat, flame or oxidisers. Explosive in the form of
vapours, when exposed to heat or flame.
9. MANUFACTURERS / SUPPLIERS DATA
NAME OF FIRM : BOKARO STEEL PLANT, SAIL Contact person
MAILING ADDRESS : BOKARO STEEL CITY in Emergency : Mr. P PRASAD
TELEPHONE / TELEX NOS : 06542-273736 / 0628-201 Local Bodies involved : NONE
TELEGRAPHIC ADDRESS : BOKSTEEL Standard Packing : Unbreakable packaging
FAX : 06542-242099 Trem Card Details / Ref :
10. DISCLAIMER
Information contained in this material data sheet is believed to be reliable but no representation; guarantee or
warranties of any kind are made as to its accuracy, suitability for a particular application or results to be
obtained from them. Information contained in this publication or as otherwise supplied to Users is believed to
be accurate and is given in good faith, but it is for the Users to satisfy themselves of the suitability of
the product for their own particular purpose. Bokaro Steel Plant, SAIL gives no guarantee or warranty as to

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the fitness of the product for any particular purpose and any implied guarantee or warranty or condition
(statutory or otherwise) is excluded except to the extent that exclusion is prevented by law. Bokaro Steel Plant,
SAIL accepts no liability for loss or damage, resulting from reliance on this information.

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GLOSSARY
ACGIH The American Conference of Governmental Industrial Hygienists Inc., is an organization open to all practitioners in industrial
hygiene, occupational health, environmental health or safety. Their website is http://www.acgih.org/.
Asphyxiant An asphyxiant is a substance that can cause unconsciousness or death by suffocation (asphyxiation). Asphyxiants which
have no other health effects and are sometimes referred to as simple asphyxiants. Asphyxiants work by displacing so much
oxygen from the ambient atmosphere that the hemoglobin in the blood cannot pick up enough oxygen from the lungs to
fully oxygenate the tissues. As a result, the victim slowly suffocates.
O
C degree Celsius. It is a measure of temperature.
CAS Chemical Abstracts Service. It assigns a unique identification number in the format XXX-XX-X to all compounds registered
with it. The number allows one to identify a chemical regardless of the naming system.
CC Closed Cup
Chemical Classification (Hazardous) The chemicals hazard classification as per the CREFT (corrosive, reactive, explosive, flammable,
toxic) classification.
Codes/Label/Class The classifications identified are those adopted by the United Nations Committee of Experts on the Transport of
Dangerous Goods and on the Globally Harmonized System of Classification and Labelling of Chemicals, and are as follows:
Class 1: Explosives
Class 2: Gases
Gases which are compressed, liquefied or dissolved under pressure or refrigerated as detailed below. Some gases have
subsidiary risk classes; poisonous or corrosive.
2.1 Flammable Gas: Gases which ignite on contact with an ignition source, such as acetylene and hydrogen.
2.2 Non-Flammable Gases: Gases which are neither flammable nor poisonous. Includes the cryogenic gases/liquids
(temperatures of below -100 OC) used for cryopreservation and rocket fuels, such as nitrogen and neon.
2.3 Poisonous Gases: Gases liable to cause death or serious injury to human health if inhaled; examples are fluorine,
chlorine, and hydrogen cyanide.
Class 3: Flammable Liquids
Flammable liquids included in Class 3 are included in one of the following packing groups:
Packing Group I, if they have an initial boiling point of 35 OC or less at an absolute pressure of 101.3 kPa and any flash point,
such as diethyl ether or carbon disulfide etc.
Packing Group II, if they have an initial boiling point greater than 35 OC at an absolute pressure of 101.3 kPa and a flash point
less than 23 OC, such as gasoline (petrol) and acetone etc.; or
Packing Group III, if the criteria for inclusion in Packing Group I or II are not met, such as kerosene and diesel.
Class 4: Flammable, Others
4.1 Flammable Solids: Solid substances that are easily ignited and readily combustible (nitrocellulose, magnesium, safety or
strike-anywhere matches
4.2 Spontaneously Combustible: Solid substances that ignite spontaneously (aluminium alkyls, white phosphorus
Class 5: Oxidizing Agents and Organic Peroxides
5.1 Oxidizing agents other than organic peroxides (calcium hypochlorite, ammonium nitrate, hydrogen peroxide, potassium
permanganate).
5.2 Organic peroxides, either in liquid or solid form (benzoyl peroxides, cumene hydroperoxide).
5.3 Dangerous when wet: Solid substances that emit a flammable gas when wet or react violently with water (sodium,
calcium, potassium, calcium carbide).
Class 6: Toxic and Infectious Substances
6.1 Toxic substances which are liable to cause death or serious injury to human health if inhaled, swallowed or by skin
absorption (potassium cyanide, mercuric chloride).
6.2 Bio hazardous substances; the World Health Organization (WHO) divides this class into two categories: Category A:
Infectious; and Category B: Samples (virus cultures, pathology specimens, used intravenous needles
Class 7: Radioactive Substances
Class 8: Corrosive Substances
Class 9: Miscellaneous

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cP centi Poise. It is a measure of viscosity.
Flammable Limits Flammable limits apply generally to vapours and are defined as the concentration range in which a flammable
substance can produce a fire or explosion when an ignition source (such as a spark or open flame) is present. The
concentration is generally expressed as percent fuel by volume.
a. Above the upper flammable limit (UFL) the mixture of substance and air is too rich in fuel (deficient in oxygen) to
burn. This is sometimes called the upper explosive limit (UEL).
b. Below the lower flammable limit (LFL) the mixture of substance and air lacks sufficient fuel (substance) to burn.
This is sometimes called the lower explosive limit (LEL).
Any concentration between these limits can ignite or explode -- use extreme caution! Being above the upper limit is
not particularly safe, either. If a confined space is above the upper flammable limit and is then ventilated or opened to an air
source, the vapor will be diluted and the concentration can drop into the flammable limit range.
Flash Point The flash point of a volatile liquid is the lowest temperature at which it can vaporize to form an ignitable mixture in air in
the presence of an ignition source. Depending on the test method used, the values given are either Tag closed cup (C.C.)
(ASTM D56) or Cleveland open cup (O.C.) (ASTM D93). The values give an indication of the relative flammability of the
chemical. In general, the open cup value is about 5.5 O to 8.5OC higher than the closed cup value.
Hazchem Code Emergency Action Codes (EACs), also known as Hazchem, are for the use of the emergency services in conjunction
with Emergency Action Code Cards. EACs indicate to the emergency services actions that may be necessary, during the first
few minutes of an incident involving dangerous goods, should the officer in charge of the incident deem it necessary to take
immediate actions. The code uses one of the numerals 1, 2, 3 or 4 followed by one or two letters.
ICSC International Chemical Safety Cards
ID Identification. Hazardous Waste Identification number as indicated under categories of Wastes in the Schedule of the
Hazardous Wastes (Management and Handling) Rules 1989.
LC50 Lethal Concentration-The concentration of a substance in air that kills 50% of the test population
LD50 Lethal Dose-The dose of a substance administered by any route (other than inhalation) that causes
death to 50% of the test population
LEL Lower Explosive Limit in air, % by volume
N Normal. It is the concentration of a solution expressed in gram equivalents of solute per litre.
NFPA National Fire Protection Association (USA)
OC Open Cup
OSHA Occupational Safety and Health Administration (USA)
PEL Permissible Exposure Limit is the maximum amount or concentration of a chemical that a worker may be exposed to under
local regulations
pH potential of Hydrogen-negative 10 base log of the positive Hydrogen ion concentration, measure of acidity
ppm parts per million. Parts of a substance per million parts of air. It is a measure of concentration by volume in air. mg/litre
SAIL Steel Authority of India Limited
SOX Sulphur Oxides
STEL Short-Term Exposure Limit (generally 15 minutes)
Synonyms The other name by which the chemical is known
TDG Transport of Dangerous Goods. This term is based on Classifications of Dangerous Goods by the U.N. Committee of experts
on Transport of Dangerous Goods. The Classes indicated are 2 (flammable), 3, 4 and 5.
TLV Threshold Limit Value. These are guidelines prepared by ACGIH to assist industrial hygienists in making decisions regarding
safe levels of exposure to various hazards found in the workplace.
Trem Transport Emergency (Card)
TWA Time-Weighted Average (8 hour)
UEL Upper Explosive Limit in air, % by volume
UN United Nations. Numbers are four-digit numbers used world-wide in international commerce and transportation to identify
hazardous chemicals or classes of hazardous materials. These numbers generally range between 0000 and 3500 and are
ideally preceded by the letters "UN" (for example, "UN1008") to avoid confusion with other number codes.

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