P2 ANSWER:

2.
3 (a) H+ , Cu+2 1

(b) Copper electode becomes thicker//brown solid is deposited 1

(i)
Cu+2 + 2e → Cu 1
(ii
) Cu →Cu+2 + 2e 1

(iii Oxygen 1
)

(iv 1
(from zinc plate to copper plate)
)
Oxidation 1

0 to +2 1
(c) (i)
Increases 1
(ii
)

(iii Zn + Cu+2 → Cu + Zn+2 1...10

)

(iv
)

(d)

4 (a) J: alkene 1

K: alcohol 1

(b)(i) Butan-2-ol 1
 (ii Hydration/addition of steam 1
)

Orange to green 1
(c)(i)

C3H7COOH 1
(ii
)
C4H8 + 6O2 → 4CO2 + 4H2O 1

(d)(i) 5.6
No of mole C4H8 =
4(12 ) +8(1)
(ii) 1
5.6
=
56

= 0.1

1 mole of C4H8 → 4 mole CO2

0.1 mole of C4H8 → 0.4 mole CO2

1
Volume of CO2 = 0.4(24)

= 9.6 dm3 / 9600 cm3

1…10
6 (a) Reduce heat released to the surrounding

(b)(i) Heat change = 200 x 4.2 x 13

= 10920 J

(b) Mole of H+/OH-/water = 100 x 2.0 // 0.2 mol

(ii)
1000 1

Heat of displacement = - 10920 J // -54.6 kJmol-1

0.2 mol 1
Energy

H+ +
(c) OH-

H2O

1. Label the energy axis & correct energy level of the

 reactants and product
2. Correct chemical equation// ionic equation
1

Heat released/ produced when 1 mol of water is formed

(d) 1

decreases

(e)(i) 1

1. Ethanoic acid is a weak acid

2. Some of the heat given out during the neutralization is
(ii used to ionize/dissociate the ethanoic acid 1
)
1…10
9 (a N2 + 3H2  2NH3 1
)

• Use iron as catalyst 1+1

• The reaction is carried out in high temperature /450oC to +1
550oC
• The reaction is carried out in high pressure/200 atm 4

(b (i) Experiment I 1+1

) Copper(II) sulphate / copper sulphate
2

(ii)
Energy 


Ea 
E’a 
Zn + 2HCl

ZnCl2 +
H2 1

1
Reaction
path

1
• Label of energy on vertical axis
• The position of the energy level of the reactants is 1
higher than the energy level of the product.
4
• Correct position for Ea
• Correct position for E’a
(iii) 1. When a positive catalyst/copper(II) sulphate is used in
Experiment I,
it provides an alternative path with a lower the activation 1
energy / lower the 1
activation energy.
1
2. More colliding particles /zinc atoms and hydrogen ions are
able to overcome 1
that lower activation energy.
4
3. This causes the frequency of effective collision increases.

4. Hence, the rate of reaction of Experiment I increases.

(c
)

Volume of carbon
dioxide (cm3)

Experiment III

Experiment II

Experiment I
1

1
Time (s)
1

3
• Correct position of the curve of Experiment I
• Correct position of the curve of Experiment II
• Correct position of the curve of Experiment III
• The volume of carbon dioxide gas in Experiment I is the 1
same as in Experiment II.
• The concentration of H+ ions in Experiment I and 1
Experiment II is the same.
1
• The volume of carbon dioxide gas in Experiment III is
1
double/two times greater than in Experiment II.

• The concentration of H+ ions in Experiment III is double then

in Experiment II // Max
The concentration/number of hydrogen ions in sulphuric
acid is double/two times the concentration/number of 3
hydrogen ions in hydrochloric acid // Suphuric acid is a
diprotic acid whereas hydrochloric acid is a monoprotic
acid.

Total 20
10 (a)

Reaction I Reaction II 1

Endothermic//heat absorbed from the Exothermic//heat

surrounding released to the
surrounding

The total energy of content of calcium The total energy of the 1

nitrate and potassium carbonate/reactant content of zinc and
is lower than the total energy content of copper(II)
calcium carbonate and potassium sulphate/reactants is
nitrate/product higher than the total
energy content of zinc 1
sulphate and
copper/product

Heat absorbed during the reaction is 66 Heat released during

kJ mol-1 the reaction is 50.4 kJ
mol-1

(b) Heat of combustion of butanol is higher than propanol 1

The molecular size/number of carbon atom per molecule butanol is 1

bigger/higher
1
than propanol

Butanol produce more carbon dioxide and water molecules than

propanol//released more heat energy

(c Methanol/ethanol/ propanol, 1
)
Diagram: 1

-labelled diagram +

-arrangement of apparatus is functional 1

Max=
4