ORGANIC CHEMISTRY

TARGET : JEE (Main) 2017

Course : ABHINAV (EA) Date : 08-06-2015 NO. 06
TEST INFORMATION

DATE : 21.06.2015 PART TEST-2 (PT-2) (MAIN)

Syllabus : IUPAC-Nomenclature, Structural Isomers , Structural Identification , POC, atomic & ionic
radius and Lanthanoid contraction

This DPP is to be discussed in the week (08-06-2015 to 13-06-2015)

DPP No. # 06
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

1. The IUPAC name of the compound CH3CH(Cl)CH2CH=O is :

;kSfxd CH3CH(Cl)CH2CH=O dk IUPAC uke gSA
(1*) 3-Chlorobutanal (2) 2-Chlorobutanal
(3) 3-Chlorobutanone (4) 2-Chlorobutanone
(1*) 3-DyksjksC;wVus Sy (2) 2-DyksjksC;wVsuSy
(3) 3-DyksjksC;wVsukWu (4) 2-DyksjksC;wVsukWu

2. The IUPAC name of the following compound is :

fuEu ;kSfxd dk IUPAC uke gSA

(1) 1-Chloropentanone (2) 3-Chlorocarbonylpentane

(3*) 2-Ethylbutanoyl chloride (4) 3-Pentanoyl chloride
(1) 1-DyksjksisUVsukWu (2) 3-DyksjksdkcksfZ uyisUVsu
(3*) 2-,sfFkyC;wVsukW;y DyksjkbM (4) 3-isUVsukW;y DyksjkbM

3. The IUPAC name of the compound is :

;kSfxd dk IUPAC uke gSA

(1) 3-Ethyl-2-methylbutanenitrile (2*) 2, 3-Dimethylpentanenitrile
(3) 2-Cyano-3-methylpentane (4) 3-Methylpentane-2-nitrile
(1) 3-,sfFky-2-esfFkyC;wVsuukbVkby (2*) 2, 3-MkbesfFkyisUVsuukbVkby
(3) 2-lk;uks-3-esfFkyisUVsu (4) 3-esfFkyisUVsu-2-ukbVkby

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4. The IUPAC name of the compound is :

(1) 3-Ethylbut-2-enoic acid (2*) 3-Ethylbut-3-enoic acid

(3) 2-Ethylbut-1-en-4-oic acid (4) 3-Ethylenebutanoic acid

;kSfxd dk IUPAC uke gSA

(1) 3-,sfFkyC;wV-2-bZu-1-vksbd vEy (2) 3-,sfFkyC;wV-3-bu-1-vksbd vEy
(3) 2-,sfFkyC;wV-1-bZu-4-vksbd vEy (4*) 3-,sfFkyhuC;wVsuksbd vEy

5. IUPAC name of compound is

(1) 2-Methyl-3-bromo-4-sulphohexanoic acid (2*) 3-Bromo-2-methyl-4-sulphohexanoic acid

(3) 4-Bromo-5-carboxyhexane-3-sulphonic acid (4) 5-Carboxy-4-bromo-3-sulphonic acid

;kSfxd dk IUPAC uke gksxk %

(1) 2-esfFky-3-czkseks-4-lYQksgsDlsukWbd vEy (2*) 3-czkseks-2-esfFky-4-lYQksgsDlsukWbd vEy

(3) 4-czkseks-5-dkcksZDlhgsDlsu-3-lYQksfud vEy (4) 5-dkckZDs lh-4-czkks eks-3-lYQksfud vEy

6. The correct IUPAC name of the following compound is :

(1) 5-Cyclopropylhept-2-en-1-oic acid (2*) 6-Cyclopropylhex-2-en-1-oic acid

(3) 5-Cyclopropylpent-1-enecarboxylic acid (4) 6-Cyclopropylpent-1-enecarboxylic acid
fuEu ;kSfxd dk lgh IUPAC uke gksxkA

(1) 5-lkbDyksikz fs iygsIV-2-bZu-1-vksbd vEy (2*) 6-lkbDyksikz sfiygsDl-2-bZu-1-vksbd vEy

(3) 5-lkbDyksikz fs iyisUV-1-bZudkcksfZ Dlfyd vEy (4) 6-lkbDyksikz fs iyisUV-1-bZudkcksfZ Dlfyd vEy

O O
7. IUPAC name of the compound H C O C CH3 is
(1*) Ethanoic methanoic anhydride (2) Methanoic ethanoic anhydride
(3) Methanoic anhydride ethanoic anhydride (4) Formic acetic anhydride
O O
;kSfxd H C O C CH3 dk IUPAC uke gS
(1*) ,FksukWbd esFksukWbd ,ugkbMkbM (2) esFksukWbd ,FksukWbd ,ugkbMkbM
(3) esFksukWbd ,ugkbMkbM ,FksukWbd ,ugkbMkbM (4) QkfeZd ,lhfVd ,ugkbMkbM

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 O

O
8. Correct IUPAC name of the compound is
Me
O
(1*) Methylbutenedioic anhydride (2) 3-Methylbut-2-enedioic anhydride
(3) 2-Methyl-1,4-diketobutene epoxy (4) 2-Methylcyclopentanoxy-1,4-dione
O

O
;kSfxd dk lgh IUPAC uke gksxk
Me
O
(1*) esfFkyC;wVbZuMkbZvksbd ,ugkbMkbM (2) 3-esfFkyC;wV-2-bZuMkbZvksbd ,ugkbMkbM
(3) 2-esfFky-1,4-MkbZdhVksC;wVhu bikWDlh (4) 2-esfFkylkbDyksiUs VuksDlh-1,4-MkbZvkWu

9. The IUPAC name of the compound is :

(1*) 2-Chloropropanoic anhydride (2) 2,2-Dichlorodipropanoic anhydride

(3) 2-Chloroethoxypropanoic acid (4) 2-Chloro-1-oxopropyl propanoate

;kSfxd dk IUPAC uke gS %

(1*) 2-Dyksjksksisuksbd ,ugkbMkbM (2) 2,2-MkbZDyksjksMkbksisuksbd ,ugkbMkbM

(3) 2-Dyksjks,FkkWDlhksisuksbd vEy (4) 2-Dyksjks-1- vkWDlksksfiy ksisuks,V

10. The IUPAC name of the compound is :

(1) Cyclopentanedioic anhydride (2) Pentanedicarboxylic anhydride

(3) Cyclopentanedicarboxylic anhydride (4*) Pentanedioic anhydride

;kSfxd dk lgh IUPAC uke gS %

(1) lkbDyksisUVsuMkbZvksbd ,ugkbMkbM (2) isUVsuMkbZdkcksZfDlfyd ,ugkbMkbM

(3) lkbDyksisUVsuMkbZdkcksZfDlfyd ,ugkbMkbM (4*) isUVsuMkbZvksbd ,ugkbMkbM

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11. The IUPAC name of following carbohydrate (common name D-glucose) is

(1) 2, 3, 4, 5, 6-Pentahydroxyhexanedial (2) 1, 2, 3, 4, 5-Pentahydroxyhexanal

(3*) 2, 3, 4, 5, 6-Pentahydroxyhexanal (4) 6-Oxohexane-1, 2, 3, 4, 5-pentaol
fuEu dkcksZgkbMsV dk IUPAC uke gksxk (lk/kkj.k uke D-Xywdksl) gS &

(1) 2, 3, 4, 5, 6-isUVkgkbMkWDlhgsDlsuMkb,y (2) 1, 2, 3, 4, 5-isUVkgkbMkDlhgsDlsusy

(3*) 2, 3, 4, 5, 6-isUVkgkbMkWDlhgsDlsusy (4) 6-vkDlksgsDlsu-1, 2, 3, 4, 5-isUVkvkWy

O
12. Correct IUPAC name of the compound CH3 CH2 O C is :
CH CH2 CH3
CH2
CH3
(1) Ethyl pentanecarboxylate (2) Ethyl-3-pentanoate

(3) Ethoxy-3-pentanoate (4*) Ethyl-2-ethylbutanoate

O
;kSfxd CH3 CH2 O C dk lgh IUPAC uke gksxkA
CH CH2 CH3
CH2
CH3
(1) ,fFky isUVsudkcksZfDlysV (2) ,fFky-3-isUVkuks,sV

(3) ,FkksDlh-3-isUVkuks,sV (4*) ,fFky-2-,fFkyC;wVsuks,sV

O
CH3
13. The IUPAC name of the compound H C N is :
CH2 CH3
(1*) N-Ethyl-N-methylmethanamide (2) N-Methyl -N-ethylmethanamide
(3) N-Ethyl- N-methylformamide (4) N-Ethylmethylmethanamide
O
;kSfxd dk IUPAC uke gS H C N CH3
CH2 CH3
(1*) N-,fFky-N-esfFkyesFksukekbM (2) N-esfFky-N,fFkyesFksukekbM
(3) N,fFky- N-esfFkyQkekZekbM (4) N,fFkyesfFkyesFksukekbM

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14. The IUPAC name of is :

(1) 1phenyl1acetyloxyethane (2) 1acetoxyethylbenzene

(3*) 1phenylethyl ethanoate (4) 1methylbenzyl acetate

;kSfxd dk IUPAC uke gSA

(1) 1Qsfuy1,lhVkbZyvkWDlh,Fksu (2) 1,lhVkWDlh,fFkycsUa thu

(3*) 1Qsfuy,fFky ,Fksuks,V (4) 1eSfFkycsfUty ,lhVsV

Sol. 1-phenylethyl ethanoate 1Qsfuy,fFky ,Fksuks,V

15. IUPAC name of the compound :

(1) Ethyl-2-methyl-2-(m-nitrophenyl) propionate (2) Ethyl-2-methyl-2-(m-nitrophenyl) propanoate

(3*) Ethyl-2-methyl-2-(3-nitrophenyl) propanoate (4) Ethyl-2-methyl-2-(3-nitrophenyl) propanoate
fn, x, ;kSfxd dk IUPAC uke gS %

(1) ,fFky-2-esfFky-2-(m-ukbVkQs fs uy) ksfi;ksusV (2) ,fFky-2-esfFky-2-(m-ukbVkQ

s fs uy) ksius ks,V
(3*) ,fFky-2-esfFky-2-(3-ukbVkQs fs uy) ksius ks,V (4) ,fFky-2-esfFky-2-(3-ukbVkQs fs uy) ksius ks,V

16. The IUPAC name of the following compound is :

(1) 2-(Ethoxycarbonyl)benzenecarbonylchloride (2) Ethyl-2-(chloroformyl)benzoate

(3) Ethyl-2-(chloromethanoyl)benzoate (4*) Ethyl-2-(chlorocarbonyl)benzenecarboxylate
fuEu ;kSfxd dk IUPAC uke gS %

(1) 2-(,FkkWDlhdkcksfZ uy)csUthudkcksfZ uyDyksjkbM (2) ,fFky-2-(DyksjksQkWfeZy)csUtks,V

(3) ,fFky-2-(DyksjkseFs ksukW;y)csUtks,V (4*) ,fFky-2-(DyksjksdkcksfZ uy)csUthudkcksfZ DlysV

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17. The correct IUPAC name of the compound is

(1) 2-formyl-5-methoxynitrobenzene (2) 4-formyl-3-nitroanisole

(3*) 4-methoxy-2- nitrobenzaldehyde (4) 4-methoxy-6-nitrobenzaldehyde

;kSfxd dk lgh IUPAC uke gS

(1) 2-QkfeZy-5-esFkkWDlhukbVkc s at
s hu (2) 4-QkfeZy-3-ukbVk,
s uhlksy
(3*) 4-esFkkWDlh-2-ukbVkscsUtsfYMgkbM (4) 4-esFkkWDlh-6-ukbVkscsUtsfYMgkbM

18. The IUPAC name of which of the following compounds is not correct ?
Compound IUPAC name

(1*) cyclohexanoic acid

(2) 1, 2, 4-benzene tricarboxylic acid

(3) 4-methylcyclohexane-carboxylic acid

(4) 4-bromobenzoic acid

fuEu esa ls dkSuls ;kSfxd dk IUPAC uke lgh ugha gS ?

;kS f xd IUPAC uke

(1*) lkbDyksgSDlsuksbd vEy

(2) 1, 2, 4-csUthu VkbZdkcksZfDlyhd vEy

(3) 4-esfFkylkbDyksgDS lsu-dkcksZfDlfyd vEy

(4) 4-czke
s kscUs tksbd vEy

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19. IUPAC name of the following compound is :

(1) N-phenyl benzamide (2) N-Cyclohexyl benzamide

(3*) N-Phenyl cyclohexane carboxamide (4) None of these

fuEu ;kSfxd dk IUPAC uke gS %

(1) N-Qsfuy csUt,ekbM (2) N-lkbDyksgSfDly csUt,ekbM

(3*) N-Qsfuy lkbDyksgSDlsu dkcksZfDlekbM (4) mijks esa ls dksbZ ugha

20. IUPAC name of the following compound is :

(1) N-Methyl-N-ethyl-2-bromo-3-oxobutanamide (2*) N-Ethyl-N-methyl-2-bromo-3-oxobutanamide

(3) N-Ethyl-N-methyl-2-bromo-3-oxobutyramide (4) N-Methyl-N-ethyl-3-oxo-2-bromobutanamide

fuEu ;kSfxd dk IUPAC uke gS %

(1) N-esfFky-N-,fFky-2-czkseks-3-vkWDlksC;qVsu,ekbM (2*) N-,fFky-N-esfFky-2-czkseks-3-vkWDlksC;qVsu,ekbM

(3) N-,fFky-N-esfFky-2-czkseks-3-vkWDlksC;qVk;j,ekbM (4) N-esfFky-N-,fFky-3-vkWDlks-2-czkseksC;qVsu,ekbM

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