Course : VIJETA & VIJAY (ADP & ADR) Date : 11.05.2016 IN Resonence” Educating for better tomorrow TARGET : JEE (ADVANCED) 2016 DATE : 15.05.2016 JEE PREPARATORY TEST-02 (JPT - 02) Syltal bus : Full Syllabus DPP No. # 11 (JEE-ADVANCED) PHYSICAL / INORGANIC CHEMISTRY Total Marks : 94 ‘Max. Time : 70 min. Single correct Objective ('-1" negative marking) Q.1 to Q.8 (3 marks, 2 min.) (24, 16] One or more correct objective ('-2" negative marking) Q.9toQ.11 (4 marks, 2 min.) _—_—[12, 06] Assertion and Reason Comprehension (‘-1" neg: Single digit integer type (' negative marking) 2.12 to 0.13 (3 marks, 3 min.) [06, 08] marking) Q.14 to 0.19 (B marks, 2 min.) [18, 12] 4° negative marking) Q.20 to Q.24 @ marks, 3 min.) [15,15] Double digit integer type ('-1" negative marking) @.25 @ marks, 3 min.) [03,03] Match the Following (no negative marking) Q.26 to Q.27 (8 marks, 6 min.) —_[16, 12] ORGANIC CHEMISTRY Total Marks : 66 Max. Time : 48 min. Single correct Objective ('-1" negative marking) .28 to Q.34 (3 marks, 2 min.) (24, 14] One or more correct objective ('-2" negative marking) @.35 to Q.36 (4 marks, 2 min.) _—_[08, 04] Assertion and Reason ('-1" negative marking) Q.37 (3 marks, 3 min.) [03,03] Comprehension ('-1" negative marking) Q.38 to Q.40 ( marks, 2 min.) [09, 08] Single digit integer type ('-1" negative marking) Q.41 to Q.42 (3 marks, 3 min.) __[06, 08] Double digit integer type ('-1" negative marking) Q.43 ( marks, 3 min.) [03, 03] Match the Following (no negative marking) Q.44 to Q.45 (8 marks, 6 min.) —_[18, 12] PHYSICAL / INORGANIC CHEMISTRY 4. Which of the following is true when equal volume of 0.04 M NaCl solution is mixed with 0.1 M K[Ag(CN).1 Given: K,AQ(CN),) = 4 «10°, K,, (AGC) = 2.8% 10% and YS = 1.7) (A) More K[Ag(CN),| will be formed (©) AgC! willbe precipitated (©) There is no change in concentration of K’ (OD) None of these. 2. solid crystallises as cubic close packing of O* ions. A’ ions occupy 25% of the tetrahedral voids and B”* ions occupy 50% of the octahedral voids. The suitable values of x’ and 'y’ are (x=ty=3 @x=2y=1 ()x=3,y=2 x=1,y=2 3.1 mole of a compound Co(NH,),Cl,Br gives 2 moles of curdy white precipitate, when treated with excess of ‘AgNO, solution. Which of the following is incorrect about the compound ? (A) The compound may be represented as [Co(NH,),B1] Cl, (B) The Van't Hofts factor (i) is 3, when «= 1.0 (C) The boiling point of 1M —ag. solution of Co(NH,),Ci,Br should be triple ofits value, when it were non-electrolyte. (O) None of these Resonance’ fiz Educating for better tomorow40" For the two reactions cone. Reaction |:A->B ee Reaction Il: C+D osm " following curves are plotted lS ST! ‘Which ofthe following is incorrect option trvlmin) (A) (bed wacont™ Foden @ [A= [O]att= “> minutes (C) When [B] = [A] at that time [C] = [D] (©) If both [A], and [C], are 1 M then (t,. ; (ows Following data of osmotic prssure (x) is obtained when different moles of C,,H.,COONa are mixed in 1L solution at 25°C Moles o 0.01 0.02 0.03 0.04 aay (molestiter ° 0.02 0.04 0.088 0.076 Select the incorrect nature of mixture at different concentration. (A) Upto 0.02 M concentration, the mixture is true solution, (8) At aswell as greater than 0.03 M concentration, the mixture is a colloidal (C)At 0.04 M concentration, the mixture is homogenous. (0) The critical micelle concentration (CMC) of C,,H,.COONa may be 0.03 M. Calcium imide on hydrolysis gives gas (B) which on oxidation by bleaching powder gives gas (C).Gas (C) on reaction with magnesium give compound (D) which on hydrolysis gives again gas (B). Identify (B),(C) and (0). (A) NHN, Mg.N, (@)N, NH, , MgNH (C) N.N,O,, MQ(NO,), (O) NH, NO, , MQ(NO,), A+HO —> B+HCI B+HO —> C+HCI ‘Compound (A), (B) and (C) willbe respectively (A)PCI,, POCI,, H,PO, (©)PCI,, POCI,, H.PO, (©) SOCI,, POCI,, H,PO, (O)PCI,, POCI,, H.PO, Which of the following fails to react significantly with air at room temperature? (A) Be Li ©Ba (O)Allofthese Which of the following statement(s) is/are correct 7 (A) Chlorine dioxide (CIO,) is powerful oxidising agent but bleaching action is poorerthan Cl, (B) ClO, in alkaline solution undergoes disproportionation. (C) ClO, is diamagnetic in nature (©) ClO, isa yellow gas but deep red liquid The freezing point of a 0.08 molal aqueous solution of NaHSO, is -0,372°C, Which of the following is/are correct for the given solution? Assume no hydrolysis and m ~ M. (K, of water = 1.86 K kg/mole) (A) 0.2 moles of ions are present in 1 kg solvent (B) Degree of dissociation of HSO,- is 0.6. (©) Dissociation constant forthe reaction HSO,-—* H" + SO,?-is 4 « 102 9 (0) RLVP of the given solution is 55 Resonance’ fiz Educating for better tomorowne 12. 43. Anonvolatile solute X’ completely dimerises in water, ifthe temperature is below ~3.72°C and the solute completely dissociates as X -> Y + Z, ifthe temperature is above 100.26°C. In between these temperature (including both temperature) Xi neither dissociated nor associated. One mole of X is dissolved in tka water, Given K, ofwater=0.52K.Kgmol ; «Kk, of water= 1.86 K Kg mot! Which ofthe following statement(s) is/are true regarding the solution ? (A) The freezing point of solution is 1.86°C. (©) The boiling point of solution is 101.04°C. (C) When the solution is cooled to ~7.44°C, 75% of water present intially will separate as ice (©) When the solution is heated to 102.08°C, 50% of water present intially will escape out as vapor. Statement-1 : Knowing Ks, of CO, , pH can be determined of an aqueous solution of Na,CO, of known concentration. Statement-2 : Only first hydrolysis of CO2- ion is significant because for most of dibasic acids, Ke, >> K, (A) Statement-t is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 is True; Statement.2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2 is False (D) Statement- is False, Statement-2is True Statement-t : Salts of Be and Mg do not give flame test. Statement-2 : CaCl, gives apple green colour inflame test. (A) Statement-t is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 is True; Statement2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2 is False (D) Statement-1 is False, Statement-2is True Comprehension #1 14. 15. 16. ‘An ore of a common metal contain a green colored compound ‘M of metal, which dissolves readily in hydrochloric acid. However the dissolves readily in hydrochloric acid. However the metal does not dissolve in dilute hydrochloric acid. The compound 'M' gives effervescence of gas 'X’ and produces a blue colored solution of 'P' on treatment with HCI. The gas 'X' is non-combustible colorless and odorless. The gas 'X’ reacts with aqueous suspension obtained by adding 'Y'in water to give white precipate of 'Z'. Zon heating gives back X and Y. When gas Q is passed through 'P’ a black precipitate of R'is obtained. When agas'S’ is passed through P the blue solution turns deep blue. The compound "M" is (A)MgCO, , Mg(OH), @) CuFes, (©)CuCO,,.cuOH), (0) Feco, Gases 'Q' and ‘S' are allowed to enter a long tube of length 100 cm from opposite ends under identical conditions. What is the distance travelled by 'Q’ before it meets'S' ? (A) 50 em (B)41.40m. (©) 46.5om. ()59em Which of the following is used as raw material in Solvay's process to produce CO, ? aM ®Y Oz OR Comprehension #2 47. Two liquids A and B mixto form an ideal binary liquid solution, On adding non volatile solid solute C to the solution, A starts polymerising into a hexamer nen volatile soluble solid'A,’ following zero order kinetics, with arate constant = 10" moles’ min. Ifinitially 10 moles of A and 20 moles of B were taken to form liquid solution and 5 moles of C were added then answer the following questions based on above information and data given below: [Data: vapor pressure of pure A= 100 torr, vapor pressure of pure B= 90 tort] ‘The vapor pressure of the solution 1 hrs. after solid C is added will be given by 220 2200 2200 tor (8) 98 tor © Sp tor ©) Sy tor [errs Once 00 Toes A 0DP Ner Cy Ha Toe owt Kan Ra SOE Resonance’ fa : Educating for better tomorow18. 19. 20. 21. 22. 23. 24. 25. 26. Which of the following statementsis incorrect regarding the above process ? (A) The vapor pressure will keep on decreasing initially (B) The vapor pressure will become constant 100 min. after addition of C. (C) Two hours after addition of C, the vapor pressure will become 72 torr. (0) Four hours after addition of C, the vapor pressure will become 67.5 torr. IfC is not added so there is no polymerisation of A, then mol fraction of A in vapour phase will be sing oie ors (23 Find the number of molecules which are planar @CIr, sr, (OXeF, (Oxer, (xeF, Ho @HS (NH, PH, Pcl, WPCl, oct, diel > Gas a whit ppt Yellow 1 particles soluble in |. air dil, mineral acid yates ey Find the sum of number of px- pr and pz -dz bonds in trimer of 'C’ A metal A’ exists in the bec structure having uncovered length along the edge equal to 1.2 A. if molar mass. of the metal is 307.2 gm/mole then calculate density of the crystal in g/mL, [Use : N,= 6 x 10° and y3 = 1.7) Total number of isomers (including stereoisomers) for the complex [Pd(NH,)(H,0)(NO,),] are How many of he following elements have 4.H?> 0 at 298 K? ©, (g), Monoclinic sulphur, Diamond, Red phosporous, O, (@), Cl, (g), Rhombic sulphur, Br, (Q), O(@). L,(0. H, (g), Liquid sodium, Fe(s), Black phosphorous. The equilibrium partial pressure of N,O,(g) and NO,(g) are 4 and 2 atm, respectively. Now, at constant temperature, the equilibrium pressure of system is increased to 60 atm. The new equllibrium partial pressure Of N,O,(g) becomes : (/241 = 15) The standard reduction potential data at 25°C is given below. E° (Fe".Fe*) =+0.77V E° (Fe*.Fe) =-0.44V E*(Cu".Cu) =+0.34V; E*(Cu.Cu) = +0.52V; E* (Og) +4H'+ 4o- > 2H,0) =+1.23V; E°(0.(g) + 2,0 + 4 > 40H) = + 0.40V E°(Cr.C) =-0.74V; E*(Cr*.Gr) =-0.91V Match E° of the rebox pairin List withthe values given in List Il and select the correct answer using the code given below the lists List -1 List 11 a E° (Fe* Fe) © = 0.36 V —E°(4H.0 =e4H'+ 40H) @ av © — E*(Cur+ Cu 200") © -doav © = E"Cr,cr9 © 0.83 Resonance’ fiz Educating for better tomorow27. Column Column () Mohr salt aq.) +Na,O, © Colored solution © AgNO, +NaN, @ White and insoluble product possible © Chrome alumiaq) +Nao, (Colored and insoluble product possible © PbO, +HNO, () Colorless solution (© evolution of gas possible on heating ORGANIC CHEMISTRY 28. Which of the following structures are superimposable ? coon OOH oH 4 OH HO H H COOH HO cooH OH HO H H oH coo ‘OH COOH COOH COOH H (I) (ul) (un), (ly) (1&8 (Bua (cua (uaiv 29. The main positions of electrophilic attack for the given reactions are respectively 54 9° 1 i MeC-Ci _BrlFe 6 0- CH, -C-NH poe (A) 3,1 (B)6,3 (C)6,4 (0)3,6 30. The reactant X & Y of following reactions are HOO off XY ho? cHo cHo 9 “ or +CH,CHO © or + CH-C-CH, g q g Ech, + HoHO Ech, +CH-CH © or © or 31. Observe the following reaction I and II ky, k;’, kp and k,’ are rate constants. Select the correct option. oy & 0 ene CHI > Me et Oly CHCl “> (A) ky > ky" B)ka< (CO) ky < ky on P.5,.4; (C)>p,.5,4;O)>P.5.4 43. A>): B) +0: O>0:0)>+@ 44 (A) >p.g; 8) 1 (C)>s,O0)>q] 45. (A) pt) @) 6; (C)>g,t;D)>s IDPP No. # 11 (JEE-ADVANCED) PHYSICAL / INORGANIC CHEMISTRY 1 © 2 @A ® © 4 © & © & WA nD B 8. @) 9" GD) 10" Cc) 1* BD 12 O 82 © % © 5 © 6% © 7 AW 8 © 92 A 0% 6 WM 6 22. 2 0 27 TB 83 2H, (A) or 3 (B) 9 83(C) >; 0) 94 27. A) 6. 8,t:@)4,8,t:)>p:Or,s.t ORGANIC CHEMISTRY 2 AB © 0% ® 4 A 2 HO B O© MH © 35." (ACD) 36." (ABC) 37.) 8... 42. 6 43. BA 44, (A) 9 5 (8) 9S; (C) PIO) 9G A >45;85455;0>P: O45: >ans5 as. ————$—{[ _____oo= Educating for better tomorow