PHYSICAL CHEMISTRY

TARGET : JEE (Main) 2017

Course : ABHINAV (EA) NO. 15

This DPP is to be discussed in the week (20-07-2015 to 25-07-2015)

DPP No. # 15
Total Marks : 51 Max. Time : 34 min.
Single choice Objective ('1' negative marking) Q.1 to Q.13 (3 marks, 2 min.) [39, 26]
REVISION QUESTIONS
Single choice Objective ('1' negative marking) Q.14 to Q.17 (3 marks, 2 min.) [12, 08]

1. If P, V, T represents the pressure, volume and temperature of gas respectively, then according to Boyle's
law, which is correct for a fixed amount of ideal gas :
1
(1) V (At constant P) (2) V P (At constant T)
T
1
(3*) V (At constant T) (4) PV = nRT
P
;fn P, V, T e'k% xSl ds nkc] vk;ru ,oa rki gSa] rks ckW;y ds fu;ekuqlkj vkn'kZ xSl dh ,d fuf'pr ek=kk ds fy, fuEu
esa ls dkSulk lgh gS %
1 1
(1) V (fLFkj P ij) (2) V P (fLFkj T ij) (3*) V (fLFkj T ij) (4) PV = nRT
T P

2. A vessel of 120 mL capacity contains a certain mass of an ideal gas at 20C and 750 mm pressure. The gas
was transferred to another vessel, whose volume is 180 mL. Then the pressure of gas at 20C is :
(1*) 500 mm (2) 250 mm (3) 1000 mm (4) None of these
,d ik=k] ftldh {kerk 120 mL gS] dks 20C rki ij rFkk 750 mm nkc ij ,d vkn'kZ xSl ls Hkjk x;k gSA bl xSl dks
,d nwljs ik=k] ftldh {kerk 180 mL gS] esa LFkkukUrfjr dj fn;k x;kA rc 20C ij xSl dk nkc D;k gksxk %
(1*) 500 mm (2) 250 mm (3) 1000 mm (4) buesa ls dksbZ ughaA
Sol. P1 V1 = P2 V2 750 120 = P2 180
P2 = 500 mm Ans.

3. 5 L of a sample of a gas at 27C and 1 bar pressure is compressed to a volume of 1000 mL keeping the
temperature constant. The percentage increase in pressure is :
27C rki vkSj 1 ckj nkc ij ,d xSl ds 5 L uewus dks 1000 mL ds vk;ru rd] rki dks fu;r j[krs gq,] LkEihfMr djrs
gSaA rc nkc esa fdrus % dh o`f) gksxh %
(1) 100 % (2*) 400 % (3) 500% (4) 80%
1 2.5 5 1
Sol. P2 = = 5 atm % increase = 100 = 400%
0.5 1
4. For a fixed amount of ideal gas at constant temperature, which of the following plots is correct :
fLFkj rki ij ,d vkn'kZ xSl dh fuf'pr ek=kk ds fy, fuEu esa ls dkSulk vkjs[k lgh gS %

(1*) (2) (3) (4)

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5. For a fixed amount of ideal gas at constant temperature, which of the following plots is/are correct :
fLFkj rki ij ,d vkn'kZ xSl dh fuf'pr ek=kk ds fy, fuEu esa ls dkSulk@dkSuls vkjs[k lgh gS@gSa %

(1) (2) (3) (4*) All of these (mijksDr lHkh)

6. What should be the percentage increase in pressure for a 5% decrease in volume of an ideal gas at constant
temperature ?
fu;r rki ij ,d vkn'kZ xSl ds vk;ru esa 5% deh ds fy;s nkc esa fdrus % dh o`f) djuh pkfg, \
1
(1) 5 % (2) % (3*) 5.26 % (4) 4.76 %
5
5V
Sol. Given, P1 = P, V1 = V, T1 = T P2 = P2, V2 = V ,T =T
100 2
5V 100
P x V = P2 x V 100 ; P2 = P P2 = 1.0526 P
95
Increase in P = 0.0526 % increase in P = 0.0526 x 100 = 5.26 Ans.

7._ In which of the following cases is the pressure of air in air column maximum : (Assume same length of Hg
column in each case) :

(1*) (2) (3) (4)

fuEu esa ls fdl ifjfLFkfr esa ok;q LrEHk esa ok;q dk nkc vf/kdre kIr gksxk % (R;sd ifjfLFkfr esa Hg LrEHk dh yEckbZ leku
ekusa) :

(1*) (2) (3) (4)

8. Compare the values of pressure at different points in the given diagram :

fn;s x;s fp=k esa fofHkUu fcUnqvksa ij nkc dh rqyuk dhft, %

(1) P1 > P2 > P3 > P4 (2) P1 < P2 < P3 < P4 (3*) P1 > P2 = P3 > P4 (4) P1 < P2 = P3 < P4

9._ If some gas is trapped above the mercury column in a Barometer during measurement of atmospheric
pressure, the height of Hg column is observed to be h. Then :
(1) h > 76 cm (2*) h < 76 cm (3) h = 76 cm (4) cannot be predicted.
;fn ok;qe.Myh; nkc ukirs le; cSjksehVj uyh esa ikjs ds LrEHk ds ij dqN xSl mifLFkr gS] rFkk Hg LrEHk dh pkbZ
h sf{kr gksrh gS] rc %
(1) h > 76 cm (2*) h < 76 cm (3) h = 76 cm (4) vuqeku ugha yxk;k tk ldrk

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10. In the following arrangement, find the pressure of the confined gas (in cm of Hg).
fuEu O;oLFkk esa xSl dk nkc (Hg ds cm esa Kkr djksA

(1) 45 (2) 121 (3*) 31 (4) 76

Sol. Pgas = 76 45 = 31 cm of Hg

11._ If another liquid L ( = 10.2 g/cm3) is used in place of mercury, then what should be the minimum length of
Barometer tube to measure normal atmospheric pressure ?
(Take normal atmoshperic pressure to be 76 cm of Hg).
(1) 101.3 cm (2) 57 cm (3) 1 m (4) Cannot be determined
;fn ,d dkp dh uyh esa ikjs ds LFkku ij fdlh vU; nzo L ( = 10.2 g/cm3) dk ;ksx fd;k tk;s] rc lkekU; ok;qe.Myh;
nkc ukius ds fy, cSjksehVj ufydk dh U;wure yEckbZ D;k gksuh pkfg, \
(ekuk fd lkekU; ok;qe.Myh; nkc dk eku Hg dk 76 cm gSA)
(1) 101.3 cm (2) 57 cm (3) 1 m (4) Kkr ugha dh tk ldrh
12. The molarity of a HCl solution, which is 1.825 % (w/v) is :
(1) M/10 (2*) M/2 (3) M/5 (4) M/20
ml HCl foy;u dh eksyjrk D;k gksxh] tks 1.825 % (w/v) gks %
(1) M/10 (2*) M/2 (3) M/5 (4) M/20
1.825
1
Sol. M = 36.5 1000 = M
2
100

13. 300 ml of 3.0 M NaCl solution is added to 200 ml of 4.0 M BaCl2 solution. The concentration of Cl ions in the
resulting solution is
3.0 M NaCl foy;u ds 300 ml dks] 4.0 M BaCl2 foy;u ds 200 ml ds lkFk feyk;k tkrk gSA ifj.kkeh foy;u esa Cl
vk;u dh lkUnzrk fuEu gS %
(1) 7 M (2) 6 M (3) 5.5 M (4*) 5 M
300 3 200 4 2 2500
Sol. [Cl] = = =5M
500 500

Revision Questions
14. The radii of two of the first four Bohr orbits of the Hydrogen atom are in the ratio 1 : 4. The energy difference
between them may be : [Atomic structure]
(1) Either 12.09 eV or 3.4 eV (2*) Either 2.55 eV or 10.2 eV
(3) Either 13.6 eV or 3.4 eV (4) Either 3.4 eV or 0.85 eV
gkbMkstu ijek.kq dh izFke pkj cksj d{kkvksa esa ls nks dh f=kT;kvksa dk vuqikr 1 : 4 gSA buds e/; tkZ vUrj D;k gksxk
%
(1) ;k rks 12.09 eV ;k 3.4 eV (2*) ;k rks 2.55 eV ;k 10.2 eV
(3) ;k rks 13.6 eV ;k 3.4 eV (4) ;k rks 3.4 eV ;k 0.85 eV
r1 1 r3 9 r2 1
Sol.
r2 4 r4 16 r4 4

1
So corresponding energy of ratio is E2 E1 and E4 E2.
4

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15. In a sample of H-atom, electrons make transition from 5th excited state upto ground state, producing all
possible types of photons. Then, total number of lines not in infrared region are :
H-ijek.kq ds ,d uewus esa bysDVkWu] 5th mksftr voLFkk ls ewy voLFkk rd lae.k dj lHkh laHko QksVkWu mRikfnr djrs
gSaA rc js[kkvksa dh dqy la[;k fuEu gS] tks vojDr {ks=k esa ugha gSa %
(1) 4 (2) 5 (3*) 9 (4) 6
6(6 1)
Sol. infrared lines = total lines visible lines UV lines = 45 = 15 9 = 6.
2
(visible lines = 4 62, 52, 42, 32) (UV lines = 5 61, 51, 41, 31, 21)
6(6 1)
gy % vojDr js[kk = dqy js[kk n`'; ns[kk ijkcSaxuh js[kk = 2
4 5 = 15 9 = 6.

(n`'; js[kk,sa = 4 62, 52, 42, 32) (ijkcSaxuh js[kk = 5 61, 51, 41, 31, 21)

16. Which of the following sets of quantum numbers can be correct for an electron in 4f-orbital :
4f-d{kd ds ,d bysDVkWu ds fy, pkjksa DokaVe la[;kvksa dk dkSulk lewg lgh gks ldrk gS %
1 1
(1) n = 4, = 3, m = 4, s = + (2) n = 4, = 2, m = 1, s =
2 2
1 1
(3*) n = 4, = 3, m = +1, s = + (4) n = 4, = 4, m = 0, s = +
2 2
Sol. For n = 4, 4, for = 3, m 4
gy . n = 4, 4, for = 3, m 4 ds fy,

17. Which of the following ions has maximum value of spin magnetic moment :
izp.k pqEcdh; vk?kw.kZ dk vf/kdre eku fuEu esa ls fdl vk;u dk gS %
(1) 28Ni2+ (2) 24Cr3+ (3) 27Co3+ (4*) 25Mn
2+

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