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ENGINEERING COLLEGE
TIRUCHIRAPALLI-621213.
UNIT II
SECOND LAW, ENTROPY &AVAILABILITY
GIVEN:
REVERSIBLE HEAT PUMP
Temp high (T1) = 27oC +273
=300K
Temp low (T2) = 0oC +273
= 273K
Heat removal rate (Q) = 1500/60 KJ/min
= 25 KJ/ sec
REVERSIBLE ENGINE
Temp (T3) = 400oC + 273
= 673K
TO FIND:
(i) C.O.P
(ii) work input
(iii) over all C.O.P of the system
SOLUTION:
STEP: 1 Reversible heat pump
C.O.P machine = THigh
THigh - TLow
= 300
300 273
Thigh - Tlow
Work input(machine) = Q1
Thigh
300 273
= 25
300
STEP:2
Reversible heat engine
C.O.P engine = Q1/Q2
Where
Q3/T3 = Q4/T4
Q4 + W = Q4/T4
T3
Q4 +2.25 = Q4/300
673
(Q 4 + 2.25)300 = Q 4 673
675 = 373 Q 4
Q4 = 675/373
Q4 = 1.8096 KJ/S
Q3 = Q4 + W
Q3 = 1.8096 + 2.25
L.VIJAYAKUMAR /A.P-MECH Page 2
Q3 = 4.0596 KJ/S
= 25 / 4.0596
STEP:3
To find over all COP
C.O.Pov erall = Q2 + Q4
Q3
Where
Q2 = Q1 + W
Q2 = 25 + 2.25
Q2 = 27.25 KJ/S
C.O.P ov erall = Q2 + Q4
Q3
= 27.25 + 1.8096
4.0596
C.O.P ov erall = 7.1582
GIVEN:
Reversible heat engine
TO FIND:
a) Heat supplied by each source per min
b) Efficiency of the engine
SOLUTION:`
STEP:1
= 123.333 KJ/sec
STEP:2
Q1 1 + (Q Q1) 2 =w
Where
1 = T H - Tlow 100
TH
2 = T 2 T3 100
T2
2 = 600 300
600
2 = 0.5 100
2 = 50%
Q1 1 + (Q Q1) 2 = w
Q1 0.6666 + ( 123.3333 Q ) 0.5 1 =70
0.1666 Q1 = 8.3333
Q1 = 8.3333
0.1666
Q1 = 50.020 KJ/S
STEP:3
Q2 = 123.3333 50.020
Q2 = 73.3131 KJ/S
GIVEN:
(Q1) = 200 KJ
TO FIND:
SOLUTION:
STEP:1
T2 = T1 + 2 T3
T2 = 694 + (2 278)
T2 = 416.666K
STEP:2
a= T T
1 2 100
T1
L.VIJAYAKUMAR /A.P-MECH Page 6
a= 694 416.666 100
694
a = 0.3996 100
a = 39.96%
b = T 2 T3
T2
= 416.6666 278
416.6666
b = 0.3328 100
b = 33.28%
STEP:3
a = 1 - Q2 / Q4
a = 1 - Q2 / Q4
0.3996 = 1 - Q2 / 200
Q2 / 200 = 1- 0.3996
Q2 / 200 = 0.6004
Q2 = 200 0.6004
STEP:4
b = 1- Q3 Q2
0.3328 = 1 - Q3 / 120.08
Q3 / 120.08 = 1 0.3328
Q3 / 120.08 = 0.6672
Q3 = 0.6672 120.08
Q3 = 80.1173KJ
GIVEN:
Isolated system problem
Mass (m 1) = 2 kg
Temp (T1) = 00C + 273 =273K
(T2) = 900C + 273 = 363K
(T3) = 100C +273 = 283K
(m 2) = 3 kg
Mass = m 1 + m 2
= 2 + 3 =5 kg
TO FIND:
Change in entropy due to mixing
SOLUTION:
STEP:1
Total energy before mixing = total energy after mixing
m 1 cpw (T2 T1) + m 2 cpw (T3 T1) = mass cpw (Tm T1)
2 (90 0) + 3 (10 0) = 5 (Tm -0)
180 + 30 = 5 Tm
210 = 5 Tm
210/5 = Tm
420C = Tm
Tm = 420C + 273
Tm = 315 K
STEP:2
Initial entropy of the system
= m 1 cpw ln T2 + 273 + m 2 cpw ln T3 + 273
T1 T1
= 2 ln 363 + 3 ln 283
273 273
= 0.5698 + 0.1079
S1 = 0.6777 KJ /K
=m cpw ln Tm
T1
= 5 ln 315
273
S2 = 0.7155 KJ/KG
L.VIJAYAKUMAR /A.P-MECH Page 9
Change in entropy ( S) = S2 - S1
= 0.7155 0.6777
S = 0.0378 KJ / Kg.K
GIVEN:
Carnot cycle
TO FIND:
a) COP of refrigerator
SOLUTION:
Carnot efficiency ( c) = Th TL
TH
( c) = TH 273
TH
0.75 = TH 273
TH
0.75 TH = TH 273
273 = TH 0.75 TH
273 = 0.25 TH
273 / 0.25 = TH
1092 K = TH
(COP)ref rigerator = TL
TH - TL
= 273
1092 273
(COP)ref = 0.3333
GIVEN:
Temp (Tice) = -50C +273 = 268K
Temp (Tatm ) = 200C +273 =293K
(Cpice) = 2.093 KJ/KG.K
Latent heat of fusion (l) =333.3 KJ/Kg.K
TO FIND:
a) Entropy increase of universe ( s)univ =?
b) Minimum amount of work (W) =?
SOLUTION:
STEP:1
Where
( s)atm = - (SQ)
Tatm
Where
Heat absorbed by air from atm (SQ) = m Cpice (To -Ti) + m l + m CpW ( Tatm 0)
= 427.505 KJ
( s)atm = - (SQ)
Tatm
= - 427.505
293
Where
TO
STEP:2
= -1.4590 + 1.5554
= 0.0964 KJ/K
STEP:3
Where
( s)ref = 0
( s)atm = Q+W
0 = -1.5554 + 0 + Q + W
0 = -(1.5554 293) + Q + W
0 = -455.7322 + ( Q + W)
455.7322 = Q + W
455.7322 - Q = W
455.7322 427.505 = W
W min =28.2272 KJ
SOLUTION:
STEP:1
Q1 = T1 = 1245
Q2 + Q3 T2 + T3 400 + 300
= 1.78
STEP :2
Efficiency ( ) = 1 - Q2 Q3 100
Q1
= 1- 1 100
1.78
= 0.4382 100
Efficiency ( ) = 43.82%
GIVEN:
Mass of water (m w) = 50 Kg
Temp water (T1) = 313K
Temp ice (T2) = -5oC + 273 = 268K
(T3) = 0oC + 273 = 273K
(Cp)water = 4.2 KJ / Kg.K
(Cp)ice = 2.1 KJ/Kg.K
Latent heat of ice (L)ice = 335 KJ/Kg
TO FIND:
a) Mass of ice (m ice)
b) Change in entropy of water and ice
SOLUTION:
STEP:1
Energy balance equation
m w Cpw T1 + m ice Cpice T2 + m ice L = (m w + m ice) Cpw T3
= (50 4.187 313) + ( m ice 2.1 268) + (m ice 335)
= (50 + m ice)4.187273
=65526.55 + 562.8 m ice + 335 m ice = (50 + m ice) 1143.09
=65526.55 + 897.8 m ice = 57152.55 + 1143.051 m ice
1143.05 m ice - 897.8 m ice = 65526.55 57152.55
245.25 m ice = 8374
m ice = 8374 / 245.25
m ice = 34.1447 Kg
STEP:2
Change in entropy of water
( s)w = m w Cpw ln (T2/T3)
GIVEN:
Temp (T1) = 1000K
(T2) = 300K
Efficiency of heat engine = 40% of max possible efficiency
C.O.P heat pump = 50% of max possible COP rate of supply heat engine
Qs1 = 50 KW
TO FIND:
The temp of the reservoir (T4)
SOLUTION:
STEP:1
T1
= 1000 300 100
1000
= 0.7 100
= 70 %
STEP:2
Actual efficiency = 40% carnot efficiency
= 0.4 0.7
= 0.28
STEP:3
Qs2 = 2 Qr2
Qs2 = 2 36
Qs2 = 72KW
Work output of heat engine (W E) = Qs1 Qr1
= 50 36
= 14 KW
Qr2 = Qs2 + work output of H.E
Qr2 = 72 + 14
Qr2 = 86 KW
(C.O.P) Heat pump = Heat supplied
Work done
= Qr2
Qr2 Qs2
= 86
86 72
= 6.14
Actual co-efficient of
Performance of heat pump = 50 % COP carnot
T4
6.14 = 0.5 T4 300
6.14 = T4
0.5 T4 300
12.28 = T4
T4 300
12.28 T4 3684 = T4
12.28 T4 T4 = 3684
T4 = (3684 / 11.28)
T4 = 326.5957 K
GIVEN:
Mass ( m) = 1 Kg
Pressure (P1) = 10 bar 100 =1000 KN / m 2
Temp (T1) = 500K
Pressure (P2) = 2 bar 100 =200 KN / m 2
Temp (T2) = 350K
Environmental condition
Po = 1 bar 100 = 100 KN / m 2
To = 290 K
TO FIND:
a) Availability of initial state
b) Availability of final state
c) Max . work
SOLUTION:
STEP:1
Availability of initial state
1 = m Cp T1 - To Cp ln T2 - R ln P1
To Po
= 1 502.5 - - 32.8712
= 535.3712 K
STEP:3
2 = m Cp T2 - To Cp ln T2 - R ln P2
To Po
= 351.75 - - 2.9
2 = 354.65 KJ
STEP :3
11) A house hold refrigerator is maintained at a temperature of 275 K. Every time the
door is opened, warm material is placed inside ,introducing an average of 420 kJ, but
making only a small change in the temperature of the refrigerator. The door is
opened 20 times a day, and there refrigerator operates at 15% of the ideal COP. The
cost of work is Rs.2.50 per kW hr. What is the bill for the month of April for this
refrigerator? The atmosphere is at 303 K.
(AUC DEC 07)
GIVEN:
Temp (Tlow) = 273 K
Temp (Thigh) = 303 K
COP of refrigerator = 15 % COP of ideal carnot ref
Heat supplied by the ref1 (Qr) = 420 KJ for one time
In one day = 20 times opened
Total heat rejected in sec = Q r 20 times open
24 3600
= 420 20
24 3600
= 0.0972 KW
TO FIND:
Electricity charges of april month
SOLUTION:
STEP:1
COP ref = TL = 275
TH - TL 303 275
STEP:3
Work done (W) = heat rejected
C.O.Pref
= 0.0972
1.4732
= 0.06597
GIVEN:
Heat receives (Q s ) = 1000 KJ
Work (w) = 0.12 KW 3600
= 432 KJ
Temphigh(T1) = 160oC +273 = 433K
Templow(T2) = 5oC+273 = 278K
TO FIND:
Is this a valid claim?
SOLUTION:
STEP:1
carnot = 1 - TL / TH
= 1 278 / 433
= 0.3579 100
carnot = 35 . 79%
STEP:2
Heat 100
= 0.432 100
STEP:3
GIVEN:
Mass = 1Kg
tempice = -10oC + 273 = 263 K
tempatm = 30oC.+ 273 = 303 K
specific heat of ice (Cpice) = 2 KJ / Kg.K
latent heat of ice (L) = 335 KJ / Kg
TO FIND:
a. Change in entropy of ice
b. Change in entropy surrounding (or) atm
c. Change in entropy universe
SOLUTION:
STEP:1
= 20 + 335 + 125 . 61
(SQ) = 480.61 KJ
STEP:2
Tice
= 1 2 ln 273
263
= 0.07463 KJ /K
STEP:3
Tatm
= - (480.61)
303
= -1.5861 KJ/K
STEP:4
1.The interior lighting of refrigerator is provided by incandescent lamps whose switches are
actuated by the opening of the refrigerator door.consider a refrigerator whose 40 w light bulb
remains on continuously as a result of malfunction of the switch.If the refrigerator has a co-
efficient of performance of 1.3 and the cost of electricity of be RS 8 per kwh determine the
increase in energy consumption of the refrigerator and its cost per year if the switch is no fixed
Given:-
Cop = 1.3
To find:
Solution:
Step:1
Cop = QR /W
1.3 = QR /40
1.3 40 = QR
52 watts/1000 = Q R
Step:2
Work(W) = QS - QR
QR w = QS
Step:3
= (0.012 3600)
= 43.2 kwh
Step:4
= Rs 345.6
Given:
To find:
Solution:
Step:1
3. A heat engine receives reversibly 420KJ / cycle of heat from a source at 327C , and rejects
heat reversibly to a sink at 27C . There are no other heat transfers in (i) (ii) and (iii) below
compute dQ / T from these results show which case in irreversible, reversible and
impossible:
Given:
To find:
Solution:
Step:1
dQ/T = 0.35
Step:3
dQ/T = -0.35
Temperature(T1) = 1173K
Temperature(T2) = 800K
(T3) = 268K
To find:
Solution:
= 0.7442 13.3333
Step:3
(QR1) = QS1 w
=>C.O.PRef = T3 / T2 T3
C.O.PRef = 8.375
=>C.O.PRef = QS2 / W
C.O.PRef W = QS2
Maximum rate of heat rejection to the ambient air (Q R2) = QS2 + W 2 note:W 2 = W 1
= 83.0967 + 9.9226
Given:
To find:
Solution:
Step:1
max = TH TL / TH
max = 0.7008 100 = 70.08%
max = W 1 / QS1
max QS1 = W 1
W = QS1 QR1
QR1 = 5086.4J
Step:2
H.P = W 2 / QS2
QS2 = W 2 / => 30 1000 / 0.1651
The rate of heat supply from 840C => Q S2 = 181708.0557J
QR2 = QS2 W 2
=181708.0557 30000
QR2 = 151708.0557J
= 5086.4 + 151708.0557
The rate of heat rejection to the 60C sink => Q=156.7944 103 KJ