ORIGINAT

L/C no |LRWM06746S15 dated 151222 - H.s no 2922.19.90.00

MSDS
MATERIAL SAFETY DATA SHEET
lFg!a*E= o
Preparation Date't3.05-2010 R@tuion tu 07-10-2015

'I.1. Productkb tifier

51317
Product name Activated Amietol@ Ml2-?03

1.2. Relevsnt identified uses of the substa,ce or mb(ture snd uses arMsed aorlnst
Chemical intemediate

Uses advised against

1-3. Details of th6 Buprlier of the safttv daaa sheet

Mandacluier
-lamirco avBA
A subsidiary ot Easknan Chemir Company
PantseGchhsnaat 207
9000 Ghent

f: +32 I 2541411
F: ,32 I 254141A

Forturther iaforma{on. olease coniact

E-mail addres eBnmsds@eastnan.mm

1.4. EreEancr. telephone number

{+32) 9 254 10 36

2.2. Labl Eloments

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51317 Activated Amitot@ M't2-203 Revision Oate 07-1G2O15

@+
Danger

H315 Causes skln iritation

H319 Causes seriols eye iritation
H3l7 - lvlay.ause an alergic skin eaclion
H334 - May use aue.qy orasthma symptoms or breatning diFicullies ii Lnhated
H361ld - Suspecled oidamaging leittity Suspected ot damaging the unbon chrtd

Precautionary Statments - EU (!28,127212008)

P261 - Avo d breathing dusviumdgas/misyvapouu/spray
P280 WearpEtective gloves/protecnve ctorhinO/eye pmtectton/face protecton
P281 - Use personal polective equipmentas rqurcd
P235 n case ofinadequate venritation wearrespka$ry prclection
P30,1+P341 lF lN HALED: lf brerthing isdrtficltt, remove vicltm t iresh anand keep atresrin a postuon comfodabiefor

P342 + P311 lfexperie.cing respitory symptoms: Calt a POISON CENTRE ordocrortphysician

2.3. Other Ha4?rds

3.1 Substa.@s

;;gts{dni4tui.1
.{d:e'll&ti rn-L;i rnffiffiE
xf
r'
RiiFrr"qr{El l
o..tpt2oo{l
;1]{",.,'g

Fulltext of H' and EUH-ohEses: see seciion 16

4.1. Descdetion o, t!-slqid measurs

Remove to Fesh an rmd ately. Gel nedicat atienrio. tmm.diaiety. Show ihis aatenat
salely data sheei lo the doctor h atlendanc.. Take offconlaminated ctott ng and shoes
imfiedialely lf symptons pecisr,.att a physciai.

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51317 ActivitGd Amletol@ M.l2-203 Rvision DarE 07-10-2015

Move t fresh air lf bredthing ls dif,lcult, give orygen. lf not brealhing. give arn'ncial
lmmediate mdical aitenEcn is requircd-
'spjralion.
Wash otr immodiately with soap 5nd ple,ty of Mter while moving a,l onkminatd
dot6 ard sho6- Consull a physcian. ll/ash contaBina&d cloihing befo r-uEe-
Ihoreughly clean shoes beiorc reuse.

Rinse immedkrtely wih plenty ofwater. also undeilhe eyeljds,Ior al lest 15 mln'.fies.
Remove Entacl lsnsss- Oblain medical attenlion. Cantinue ,insing eyes duang aanspon to

dnse mouflr. Clean molth wi6t water and aitetuads dn.k plenty of water. l{eve. gire
anynhang by rnourh 10 an unconscious persor Do not hduce vomlting. ff swsllo' d, seek
medical a&ice immediatoly and show this container or label.
4.2. Mosl lfircrtar{ Bvmrtore.nd .ffects. both acute and .lelaved

se sadon 11: roxtcoloclcal INFoRMATIoN

4.3. lndlcatlon of any immodlate medical altention and soecial t atment nde.l

Sdtable extingrishinq rnedia

Alcohol-.6istani foam, dry chemical, carbon dioxide (CO2), wats spry

Extingulstrlng niedia rhich must nst be used ,o. safety reasons

hgts \,oluFwaLerler

5,2. Soecial h@rds arisirq ftom ths 3ubEbnca or irture

Thermal decomposilion can lead to relea* of iniblirg ald loxic sases and verors.

H@rdouB @mbusnoo p.oductsN r.gen oxidos (NOxl

erb.n oxids
No inlormalion available

5.3. Advicefo.fi.sfl{tt rE

wear*lf-conieaned lirealffnq appaBtus and p.ocnve suil. use pasoral prciectve eqliipmeni as requi.d Do rct allow run-off
l.om ,re-fighting to enier dEins orwatercourses ,

6.1. Peenal ffecaulies. lrot4liv6 eouidrrnt and e[Erreucv orocdurs

Persoflal pEcautlona
Avoid conlact with skin, eyes and clothing. Evacuate peEonnel !o sa, a.eas. Keep people away {rom and upwind of spill,,leak.
Wsr self-conta'nd brcrhing appatus and protectile .uir rubber gloves.

For ;mergncy rcspod.teE

Use oesolal protectio, recomrendeo rn Secnon 8.

6.2, Enviro0mental mcaulio{3

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51317 Activated Amietot@ M12-203 Revision Date 07,10-2015

Shouid.ot be.eleasd i.to the e.vkonme.r Remove m mediately adhering riiatter. Preveniproduct {iom enten'rg drdins. Do not
fllsh inio slrface w:leror sanitary sewer syslsm.

6 3 Methods and matenal ror con!qE!9!! a!! !!9!!

ilethods forco ainment Larle spilrs sholld be coilected mechanica ly (renrove by p! mping ) ilr dispo$ Keep in
s!itable,.l.sed.ontainers fo. disposaL.

iiethods for cleanitrg up Wear seif-co.tained brealhrnq apparahrs and prorec{ve s!il Absorb splliwiin ne.t male.ial
(e.q dry sand o. eadhl, ihen place ln a .hemica wastecontainer Neui.alize with
hydrochlor:c or sulturlc acids.

6.4, Relercnce to other sections

See sedon a fo. moE informatio. See section 13 iJr morc mfomalion

7.1. Precautions ior safejsllllllq

cuse igniuon oi orga. c vapo6). Use only i. area provideC

Tane necessary action 1o avo d stalic eleca. ry d scharJe lwhicn mjsnl
wLthapprotnaie exhaLsl venilallan. we.r peco. al pmtective e+ipment Do not eal, drlnk or smok-a when lsing ihis prodlct
U/ash hands after handli.g Renole co.taminaied c othin! and prolective eluipme.i belore ente.ing eadr! are6. Ensure thal
ayewash siations and safety showe.s are cose b tne irorkstalion locatioi. Alod breathlng !ap!rs or m sB.

!Vhe. lsing, do noi eat, Crink orsr.cke. Reg!!r clea. n9 ofequjpment, work area and clcth ng

7.2. Condilions tor safe storaqe. includino a.v in@moaiihiliiies

h ac@rdane wi:h local a.d nanonal relu ano.s Keep away iom op* flames, hol s! daces and scL..es oi ig.ilio. Keep
conlar.er tighuy closed. Keeo in a dry, coolaFd welr-ventiiated p ace. lrcoflpaiible w th strong acids and ox diz n! agenb.

7.3. Soecific end use(si

Risk Manasement Meihods (RtilM)

Ihe i.formanon .eauired is co.lained n ths ,aieria SaaeLv DataSh.et.

-8L!q!Iar-Eqa&qc

[VLA-EDI
lvLcTl

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51317 Activated Amietolo M12-203 Revision Date 07-10-2015

lrMWl I DSl

lKzwl lNDSChl

icKl

oe ved No Eflect Level {DNEL} No iniormalion availab e.

Predacted N o Eriect Con@nrration No irfor,naion available

(PNEC)

8.2. Exposurc controls

Engineerin9 measures

Personal protectlve equipment

liehtLyfitii.g safea, goggles. la.+sn Leld. Resotralo.wth a fullface niask.
rubber gioves. Neopren e g ovs The suirab lii ior a spe.ific workpl:ce should be
discussed with the prodlcers of the proteclive g oves The exacl break th.ouqh 1 me .an oe
obtained frod lhe prolecriveglove producer and tnis has to beobsetued. Gioves must be
dlsposed oi and rei. aced before the brcakhDugh time and when lhey showsigrs of

SkiD and bodv proteciion Wear su tabie oroteltive qLripme.i Codplete suit protecting againsi clremiGls.
RespiEtory protection ln the case ol lapor irrmatio. use a iespnator wiih iille. modeLA.

Environmentai exposure controls P.evefr!r.du irom enterinq d.ains. Do .o! ccnla.iinate sld5ce 6zler Avold slbsoll

9-l.lnfomation on basic Ehvsicaland chemil properties

liqud
Cobn.ss io liqhl yellow

ero-peillr
PH
Melting poina/f reezlng point
Ua!9s.
12
<-20'c/ 6'F
> 220 "C I 470 "F
> 120 'c / 280 "F
T*
No lnfon auon alailabie
Flammabiliiy (solid, sas)
Flammability Limit in Air
Upper nammability lamit:
Lower ilammability limit:
< t hPa @20'C

No i.lormation alai able

Auloignition temperalure 280 'C / 536 ',F
Decomposition temperatu.e

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 51317 Activakd Amielol@ M12-203 Rlision Oats 07-10-201s

Oissoclation consiant

No infoma0o. available

92. Other informatio

130 tnPas @20"C
'1.03 - 1.05 g/cm3
@20"C

10.'l . Racrivitv

102. chemi@t srabt[rv

Stable under nolp4l conditons. Hazardos polymerisation does not ocqr

Explosion daia
Sensittttyto Mechanicat tmpact None.
\__ Sensfivity to Sralic Otschae None.

l0-3. PGstbitftv ot hazi.d,oss reacfiois

polyrr|erl:atlon
Haardous poiyne.izaron do6 nor oc.J.

Possibility of haErdous reactlons

None under normal pmcessing.

10.4. Conditions to avoid

Heat, flames and spa(s. Take flecessary aclion ro avoiC staric erectricity dlscharge {which migm cause isniiion of oaanic vu po,s).

10.5. lncompalibl6 natertats

copper. strong acids and oxidinng agenls. tsocyanates.

, 0.6. Hrardou! docomrosititon rrcducrs

llealing o.trc can reteasa bxic aas. Niblgen oxides (NOx). No informaton avajtabte No intomaiion availabte.

{t-l- lntomano.} or toicotooicat effecrs

Product tnturmatlon

LDso/oEurrt = 4680 ms/ks

LDSo.ldeimat/rabbit = > 2000 mg/kg
LC50/inhalation/8h/rar = An Lc50^nha,aiion/4h/rat rtuld not be detemined because no mortatity of rats
!L?s observed at the maximum achievablB concedraton
Eye irftalion lr.italing to eyes
Skin iritation Non-irritating lo lh skin
No snsfizalion rcsponsEs w6r obseryed
mutagenic effects DId not show fiutagenic effecb in anlmal experiments
Reproductive toxicity
catcJnogonic effects

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51317 Activated Arnletol@ M'12-203 Revlsion Date 07-10'2015

Specific target orgrn systemic No obseNed adverse effect level : 750 mgikg/d, dermal, afrer s1 days
toxlciiy (rBpated ercosure)
Chemical Name Mthvldiethanolamlne
4680 mg,'kg
LD50/dermal/.abbii = 5990 mg/kg
Eye imitation lnitating to eyes
serlsitlsstion
Reproduclive toxicity Did not show leratogenic effects in animal experiments
Chomical t{ame Piperailne
LDso/oraurat = 2600 mg/kg
LDlio/dermal/rabblt = 8300 mg/tg
Skin irritdion
Eye irltadon
Causes sensitisation
Reproduclive toxicity Expdments have shown reprodudive toxidty efiects on laboratory aninrals May
impai.fertility

Human exee.ierce

Human experience Prolonged ska cofitacl may cause skin iniiation and/or dennattis
lrrtating to eyes, respimtory systern and skin
Risk of serious damase to eyes
lnhalatlon ol mist causes ifiilation of respiratory system

Comooneoa lnformalion lnfonnaiion rlels ro rhe nain component MDEA

12-l.Toxlcitv
P.oduct lnfomailon
Toxlcily to fish LC50: 1466 mg/l
ECs0/4ahlDaphnia magna = 233 mg/
Ec5o/72hlalgae = > 100 mgr'l
Toxlcit to bacteria EC20 (30 min) : > 1000 ms/l

ir$hwater Al93e Data 'r.shwatar Fish Species lvater Floa Data

\ilethvldiethanolamine >100 mo/l 1466 mq/l i33 mq/l

I800 mq/l :'l mq/
12.2. Persiston@and dogradabilitv
Accordir to the results of tsls of biodegdabiltty this product is considered as being eadily biodesEdable.

12.3. Bioac@Fulattv6 Elertlal

Noi expected

1214. Mobilitv ia soil

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5'1317 Acttv.ted Amietoto Mla203 Revlsion Date 07- lG2o15

Koc = 1

1?.s. R6$lt3 of PBf ad vA/B as+ssmflt

This substance is noi considered to be persistent, bioacormulaUng nor toxic (PBT)
This substance is not considered to be ve.y persistnt nor very bioaccumulating (vPvB)

12.6. Other *lveH .ffscts

No informatio. avaihble

13,1. Wast lrealrEn!fietiods

WastEtroln resl.Iues / nusd Dispose of in accodance with local reguh&ns- Wasta .od6 shsuld be assigned by the
products user based on lhe aooli:ation lDr which the prcducl was !sed.

Cotrl6mioated packaging Emply containrs shou6 b iaksn tr an appr.ved waste handling 3ite for recycllng or

IItDG/tiio
14.1 UN-No
142 F.oper shippins nare

til.s Mari.e pollutant NO

,,t.5 Spechl Provtuiom
14.7 Tmsport in bulk amrdirs to
Annex ll of i|I(RPOL 73178 ard the
IBC Co.le

Ets-
14.1 UN-No
142 Propdr shipdrlg name

1,L5 Environftstal h@rd

14-6 Sf'ecial Provisions

AD&
141 UN-No
14.2 Propr shlppirE 6 e

14.5 Etvironrental ha.ard

146 Sp'clal Prwisiotrs

ADIL
'14.1 uN"No
rLi Proler shippins name

l4-4 Paaking group

'145 Brvlronmntal h@rd
'14.6 Special ProYisions

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51317 Activared Ami.to@ ltt2-203 ReYision Dar 07-10-2015

rcAOAATA
1,t.1 UN-No
14.2 Proper 3hippiDg nam
143 H6:ard Class
111.5 Environmntal hard
14.6 Special Provisions

15.1. Safetv. healih and environmental rouldions{aois!.totr Boocifio tor the stiGtance or mixturo

Take note ol Direclive 98/24lEC on lhe ploteclion of the heal& and sdery of woll(els *om lhe iisks rcrated io chmical agenrs

lntematlonat lnventodes
TSCA
oslrNosL
EiNECSIELINCS
ENCS
lEcsc
KECL
Plccs
Alcs

Leoend:
TSCA Unitedsrar* Tdi. Slbsb.ces C@!DI Ac1 Serxion 8{b) lnvntory
DS!{DSI Canadian Dom*tc Substans LisuNonlom.6tic SubEra@ Llsl
lilEcslEu CS - Euopan lnwntory ot Eiistinq ehemicaL SubstaftEgEuropean Lisi ot Notified chsi@l subsian6
El'lCS - Japan Exisling and tlw Chmil Substances
|ECSC - China lnveniory of Exjstng Ch.mit Slbstances
(ECL - Koean Exis&ts and Evaluated Chomical Subtnc@
PICCB Philippjnes ln@nlory of CheBicls and Chefriel Substan@6
ArcS - Auslrdian Inventory o! Chemlcal Subslan6

152. Chemical safety assessmena

Kev or l{end to abbreviations apd ac.onvms used in the safee data sheet

Full text of H-Statemuls refrcd to und.r.ec{aon 3

H314 Causes severe skin bums and eye damage
H3l7 - l\,4ay caus an allergic skjn reacion
H319 - Causes serious eye iftilalion
H334 - llay cause allqy o. sslhma s,4nptoms or breathing difficuftie! il inhaled
H361id - Suspected oJ dahaging fedillty- Suspcled oi dalDaging the ubom child

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51317 A.tivat6d Ahietol@ M12-203 Revision Bate 07-10-2015

SVHC: Subsiaices ot Very Hia h

Concer lor Aurhorization:
- Seclion 8: EXPOSURE CONTROLSiPERSONAL PROTECTIOI{
TWA TWA (trm+weighled avezqe) S]EL SIEL (Shon Tem EYposure Limi!)
Ceiling

1&05-2010

07-10-2015

Provide adequab informalion, instru.lion and trarning lor operalols

This material safety d.ta sheet complies wtth the reqlirements of Eesutation (ECl No. .t907/2006

The intormation provided in this Safety Oata Sheet is coneci to the best oI our knowtedge, in,onnation .rd betief ai the
date of its publilion. The intorirEtiof, given is designed odly a a guidance for safe handling, 066, prcco$ing. storage,
trareponation. disposl and reloase and is not to be considered a wamniy or quality soeciEcation. The infomation
relales only to the specific malerla! designatod and may not be Elid fo. such material usd ln combinatlon with aDy other
matrials or in any prcas-s, unlars specjfied in the tex!

Erd of safety Dra sheet

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