CASE STUDY:

Additional Information
1) Constant holdup and perfect mixing assumed in the cooling Jacket
2) Constant flow rate of the cooling liquid is maintained
3) Density of the liquid in the system assumed constant.
4) Constant holdup assumed in the Cooling Jackets and Heat Exchanger

5) Rate constant : =

Question:
1) What are the dependent variables?
2) Create a mathematical model of the system (write the equations).
3) Plot the time variation of the different dependent variables (create subplot)
(t=1:0.1:500). Find the values at t=500.
Gravity tank area (A) = 1000 m2 Pipe (K1)= 0.05 m5/2/s

Feed stream conc. A (CA0 )= 9 mol/l CSTR1 Volume (V1) =3000 l

CP = 1100 J/kg.K Density of liquid () = 0.9 kg/l

CPC= 1000 J/kg.K Density of coolant (C) = 1kg/l

Inlet Temperature (T0)= 300 K Feed stream flow rate (F0 )= 1 l/s

= 1.97 x 1020 s-1 (Jacket 1 volume) VC1 = 500 l

R= 8.314 J/mol.K (Jacket 2 volume) VC1 = 600 l

E= 166000 J/mol (Exchanger volume) VEX = 2000 l

(CSTR1) U.AH1 = 7000 J/s = -200 J/mol

(CSTR2) U.AH2 = 8400 J/s (heat exchanger temperature) TEX = 250 K

(Heat Exchanger) U.AEX = 28000 J/s FJ = 1 l/s , F2 = 0.1 l/s

CA1(0)= 5 mol/l V2 (0) = 4000 l

T1(0)= 350 K T2 (0) = 350 K

V1(0)= 3000 l CA2 (0) = 1 mol/l

TJ1 (0) = 325 K h(0) = 0.2 m

TJ2 (0) = 400 K TJ0 (0) = 300 K

Function File
( z(1)=h, z(2)=CA1, z(3)=T1, z(4)=TJ1, z(5)=V2, z(6)=V2CA2, z(7)=V2T2, z(8)=TJ2,
z(9)=TJ0 )

function[zprime]=funcL20(t,z)
% case-study lecture 20
%parameters
A=1000; CA0=9000; V1=3; Cp=1100; Cpc=1000 ; rho=900; rhoC=1000;
T0=300; F0=0.001; VC1=0.5; VC2=0.6; Vex=2; UAh1=7000; UAh2=8400; UAex=28000;
Tex=250; FJ=0.001; F2=0.0001;

%equations
k1=(1.97*(10^20))*exp(-166000/(8.314*z(3)));
k2=(1.97*(10^20))*exp((-166000*z(5))/(8.314*z(7)));
F1=0.05*(z(1)^(0.5));
%ODE
[zprime]=[(F0-F1)/A;
(F1/V1)*(CA0-z(2))-k1*z(2);
(F1/V1)*(T0-z(3))+(200/(rho*Cp))*k1*z(2)-(UAh1/(rho*Cp*V1))*(z(3)-z(4));
(FJ/VC1)*(z(9)-z(4))+(UAh1/(rhoC*Cpc*VC1))*(z(3)-z(4));
F1-F2;
F1*z(2)-F2*(z(6)/z(5))-k2*z(6);
F1*z(3)-F2*z(7)/z(5)+(200/(rho*Cp))*k2*z(6)-(UAh2/(rho*Cp))*(z(7)/z(5)-z(8));
(FJ/VC2)*(z(4)-z(8))+(UAh2/(rhoC*Cpc*VC2))*(z(7)/z(5)-z(8));
(FJ/Vex)*(z(8)-z(9))-(UAex/(rhoC*Cpc*Vex))*(z(9)-Tex)];
end

Script File
clear all;
t=0:1:500;
z0=[0.2;5000;350;325;4;4000;1400;400;300];
[t,z]=ode45(@funcL20,t,z0);
subplot(3,3,1)
plot(t,z(:,1))
title('height');
subplot(3,3,2)
plot(t,z(:,2))
title('CA1');
subplot(3,3,3)
plot(t,z(:,3))
title('T1');
subplot(3,3,4)
plot(t,z(:,4))
title('TJ1');
subplot(3,3,5)
plot(t,z(:,5))
title('V2');
subplot(3,3,6)
plot(t,z(:,6)./z(:,5))
title('CA2');
subplot(3,3,7)
plot(t,z(:,7)./z(:,5))
title('T2');
subplot(3,3,8)
plot(t,z(:,8))
title('TJ2');
subplot(3,3,9)
plot(t,z(:,9))
title('TJ0');

Values at t=500:
h=0.189 m, CA1=8896 mol/m3 , T1= 300.2 K, TJ1=295.5 K, V2=14.98 m3, CA2=6076 mol/m3,
T2=324.6 K, TJ2=324.1 K, TJ0=252.7 K