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1. An air (B) Water (A) sample has a dry bulb temperature of 50C and a wet bulb
temperature of 35C. Estimate its properties at a total pressure of 1 atm.
1 atm = 1.0133 x 10 5 N/m 2
Average molecular weight of air =28.84
Solution.
(i) Y (Chart) = 0.03 kg water vapour/kg dry air
= 0.0483 kmol/kmol
(ii) % Humidity (Chart) = 35%
(iii) % Relative saturation = Partial pressure/ Vapour pressure Partial pressure under the
given condition is given by
p A
Molal humidity =
( Pt p) A
p A
0.0483 =
[1.0133x105 p]
A
% R.H. = 37.86 %
PA 18
Ys /
Pt PA 28.84
PA 18
0.0145
1 PA 28.84
PA 0.0227 atm.
P
R.H. = A 100
PA
R.H. = (0.227/0.0393) x 100 = 57.77% Ans.
(iv) Dew point = 19. 5oC Ans.
Cs 1005 1884Y /
(v) Humid heat,
1005 1884 0.0415 1032.32 J / kg C
H C S t G 2502300Y /
Enthalpy,
(1032.32 25) (2502300 0.0415)
= 65188.25 J/kg dry air. Ans.
PA 58
(ii) Y/
Pt PA 28
P A = 159.54 mm Hg Ans.
PA
(iii) Y 0.249 kmol acetone/kmol N 2 Ans.
Pt PA
(iv) Volume of 0.249 k mole acetone vapour at NTP 0.249 22.414 5.581 m3
Volume of 1 kmol of N 2 at NTP 22.414 m3
Calculating volume of acetone and N 2 at 25 C , using Ideal gas law,
P1v1 P2V2
T1 T2
Volume of acetone at 25 C =
298 5.581 760 5.787 m3
800 273
Volume of N 2 at 25 C =
298 22.414 760 23.243 m3
800 273
Hence,
Total volume of mixture = 5.787 + 23.243 = 29.03 m3
Thus,
5.787
% volume of acetone = 100 19.93% Ans.
29.03
PA 13.3
(i) Y/
Pt PA 106.6 13.3
= 0.14255 kmol water vapour/kmol dry air
18
Y / Y 0.08897 Kg water vapour/kg dry air Ans.
28.84
P
(ii) Mole fraction = A 0.1248 Ans.
Pt
(iii) Volume fraction = Mole fraction = 0.1248 Ans.
P
(iv) Relative humidity = A 100 64.6%
PA
1 Y / t G 273
VH 8315
M B M A Pt
Humid volume,
1 0.08897 333
8315 3
28.84 18 106.6 10
3
= 1.029 m mixture/kg dry air Ans.
/
Y 0.08897
(v) g water/m3 mixture =
VH 1.029
= 0.0865 kg water/m3 mixture
= 86.5 g water/m3 mixture Ans.
5.