m molar d

m amostra= 30
m agua= m1 18.01528 0.9975
m etanol= m2 46.06844 0.78

x2 fm1 fm2 m1 m2 V1 V2 m
0 1.0000 0.0000 30.0000 0.0000 30.0752 0.0000 25.6716
0.05 0.8814 0.1186 26.4413 3.5587 26.5076 4.5624 25.1323
0.1 0.7787 0.2213 23.3621 6.6379 23.4206 8.5101 24.7292
0.15 0.6891 0.3109 20.6716 9.3284 20.7234 11.9595 24.3462
0.2 0.6100 0.3900 18.3005 11.6995 18.3464 14.9993 23.9457
0.25 0.5398 0.4602 16.1952 13.8048 16.2358 17.6984 23.5657
0.3 0.4771 0.5229 14.3134 15.6866 14.3493 20.1110 23.1612
0.4 0.3697 0.6303 11.0914 18.9086 11.1192 24.2418 22.5637
0.5 0.2811 0.7189 8.4336 21.5664 8.4548 27.6492 22.0042
0.6 0.2068 0.7932 6.2038 23.7962 6.2193 30.5080 21.5782
0.7 0.1435 0.8565 4.3062 25.6938 4.3169 32.9408 21.2012
0.8 0.0891 0.9109 2.6717 27.3283 2.6784 35.0363 20.8132
0.9 0.0416 0.9584 1.2492 28.7508 1.2524 36.8600 20.5082
1 0.0000 1.0000 0.0000 30.0000 0.0000 38.4615 20.2511

x2 m1 m2 n1 n2 n
0 25.6716 0 1.4249903 0 1.4249903
0.05 22.151021 2.9812791 1.2295685 0.0647141 1.2942826
0.1 19.257523 5.4716765 1.068955 0.1187728 1.1877278
0.15 16.775809 7.5703908 0.9311989 0.1643292 1.0955281
0.2 14.6073 9.3383997 0.8108284 0.2027071 1.0135355
0.25 12.721742 10.843958 0.706164 0.235388 0.941552
0.3 11.050521 12.110679 0.6133972 0.2628845 0.8762816
0.4 8.3421222 14.221578 0.4630582 0.3087054 0.7717636
0.5 6.1858429 15.818357 0.3433665 0.3433665 0.6867329
0.6 4.4621959 17.116004 0.2476895 0.3715343 0.6192238
0.7 3.0431894 18.158011 0.1689227 0.3941529 0.5630756
0.8 1.8535637 18.959636 0.1028884 0.4115537 0.5144421
0.9 0.8539859 19.654214 0.0474034 0.4266308 0.4740342
1 0 20.2511 0 0.4395873 0.4395873
 Volum e m ola r da m istura / m L/m ol
Vpic d / g/mL M / g/mol Vm
25.7359 0.9975 18.01528 18.060431
Volume molar da mistura
0.9765449 19.41794 19.884328
70
0.9608819 20.82060 21.668214
0.946 22.22325 23.491811 60
f(x) 3.6205258453x^2
= 40.6240668796x
2.8819270972x^4++
- 3.0646011141x^337.1013626953x ++17.9389617676
+ 8.1483643838x^2
-17.4600853833
8.7459135486x^3 + 35.401988607
11.6307140153x^2 + 34.
0.9304381 23.62591 25.392244 f(x) =
R =
R = 0.9999918579
0.9999622478
0.9999935526
0.9994176672
50
0.9156728 25.02857 27.33353 f(x) = 51.4461112625 x^0.3820410313
R = 0.930817886
0.8999555 26.43123 29.369484 40

0.8767389 29.23654 33.346922

30
0.8549989 32.04186 37.475908
0.8384462 34.84718 41.561614 20

0.8237974 37.65249 45.70601 10

0.8087212 40.45781 50.026892
0
0.7968701 43.26312 54.291316 0 0.1 0.2 0.3 0.4 0.5 0.6

0.7868801 46.06844 58.545689 x etanol

Vs* delta V delta Vm

25.73594 0.0000 0
Volume de excesso molar
25.995271 -0.2593 -0.200366 0
0 f(x)
f(x) ==0.1 0.2
2.8819270972x^40.3- 8.7459135486x^3
- 3.0646011141x^3 0.4 0.5 + 11.6307140153x^2
+ 8.1483643838x^2 0.6 0.7 - 0.00
- 5.0832692309x 0.8
-5
26.259422 -0.5235 -0.440743 -0.1 R == 0.9862928323
R 0.9891458192
26.438621 -0.7027 -0.641409
-0.2
26.511537 -0.7756 -0.765239
26.534579 -0.7986 -0.848215 -0.3
26.468971 -0.7330 -0.836524
Vm / mL/mol

-0.4
26.436402 -0.7005 -0.907612
-0.5
26.303972 -0.5680 -0.827152
-0.6
26.225109 -0.4892 -0.789971
26.126771 -0.3908 -0.694101 -0.7
25.952903 -0.2170 -0.421745 -0.8
25.833519 -0.0976 -0.205848
-0.9
25.73594 0.0000 0
-1

x etanol
 molar da mistura

3x ++17.9389617676
43838x^2
x^3 + 35.4019886074x
11.6307140153x^2 + 18.0541003708
+ 34.7172260907x + 18.0786496625

0.4 0.5 0.6 0.7 0.8 0.9 1

x etanol

de excesso molar
0.5 + 11.6307140153x^2
86x^3
838x^2 0.6 0.7 - 0.0063307069
- 5.0832692309x 0.8 0.9
- 5.7680317476x +10.0182185848

Col umn M
3 gra u
4 gra u

x etanol