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TIANJIN ICASON TECHNOLOGY CO., LTD.

TEL:86 022 60938150 FAX: 86 022 25621236


http://www.icason.com email: icason018@icason.com

MATERIAL SAFETY DATA SHEET

1, IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY


/ UNDERTAKING

Chemical name: caprolactam, -caprolactam


Product name: Nylon 6 Monomer
English name: Caprolactam
Company Name: TIANJIN ICASON TECHNOLOGY CO., LTD
Address: TIANJIN
Zip code: 300000
E-mail address: icason018@icason.com
Fax number: 86-22-25621236
Business Phone: 86-22-60938150
Technical Specification Number: CSDS / JL 02-2002
Effective date: 1 September 2009

2, COMPOSITION / INFORMATION ON INGREDIENTS

Pure mixture
Chemical Name: Caprolactam
Ingredient Content: Caprolactam 99%
CAS No: 105-60-2

3, HAZARDS IDENTIFICATION

Hazard class: Not available


Intrusion: inhalation, ingestion, percutaneous absorption
Health hazards: This product is a low-toxic category. On the eyes, skin, respiratory tract has a
direct stimulating effect, can inhibit central nervous system inhibitory media and produce seizures,
seizures. Acute poisoning is rare. Frequent contact with the vapor or dust, there may be headaches,
fatigue, anxiety, can cause nose bleeding, nasal dryness, upper respiratory tract inflammation,
digestive discomfort. This product can cause skin damage, contact with the skin dry, stratum
corneum thickening, chapped skin, scaling, etc., and sometimes allergic reactions can occur
systemic dermatitis. High exposure can damage the development of embryos and male fertility,
and damage the liver, exposure to this product can cause abnormal menstrual workers and so on.
Environmental hazards: harmful to the environment, should pay special attention to water
pollution.
Flammability: Flammable
TIANJIN ICASON TECHNOLOGY CO., LTD.
TEL:86 022 60938150 FAX: 86 022 25621236
http://www.icason.com email: icason018@icason.com

4, FIRST AID MEASURES

Skin contact: Remove contaminated clothing, rinse with plenty of water.


Eye contact: immediately filed eyelid, with plenty of water or normal saline irrigation. Get
medical attention.
Inhalation: Remove from fresh air. Such as breathing difficulties when oxygen. Get medical
attention.
Ingestion: drink plenty of warm water, induce vomiting. Get medical attention.

5, FIRE-FIGHTING MEASURES

Hazardous characteristics: case of fire, high fever combustible. Hand pyrolysis, resulting in toxic
nitrogen oxides. Powder and air can form an explosive mixture, when a certain concentration, the
case of Mars will explode.
Hazardous combustion products: carbon monoxide, nitrogen oxides
Fire fighting methods and extinguishing agents: firefighters to wear gas masks, wear body fire
service, the wind in the fire. Use mist water, foam, dry powder, carbon dioxide fire extinguisher
and sand.
Fire extinguishing Note: In the air concentration exceeds the standard or air concentration is high,
should wear gas masks.

6, ACCIDENTAL RELEASE MEASURES

Emergency treatment: isolation leakage contaminated areas, restrictions on access. Cut off the fire
source. Recommended emergency personnel wearing a dust mask (full cover), wear protective
clothing. Use clean shovel collection in dry, clean, covered containers, transferred to a safe place.
Elimination: If a large number of leaks, collected or transported to the disposal of waste disposal
sites.

7, HANDLING AND STORAGE

Operation Note: closed operation, local exhaust. Operators must be specially trained to strictly
abide by the operating procedures. Recommended operating personnel wear self-absorption filter
dust masks, wearing chemical safety glasses, wear anti-poison permeate overalls, wear latex
gloves. Keep away from fire, heat, smoking in the workplace. The use of explosion-proof
ventilation systems and equipment to avoid dust. Avoid contact with oxidants, alkalis. Handling to
light loading and unloading to prevent damage to packaging and containers. Equipped with the
corresponding variety and quantity of fire equipment and leakage emergency treatment equipment.
Empty containers may contain harmful substances.

Storage Precautions: Store in a cool, ventilated warehouse. Away from fire, heat, to prevent direct
TIANJIN ICASON TECHNOLOGY CO., LTD.
TEL:86 022 60938150 FAX: 86 022 25621236
http://www.icason.com email: icason018@icason.com

sunlight. Should be oxidant, alkali, food chemicals stored separately, avoid mixing reservoir.
Equipped with the appropriate variety and quantity of fire equipment. The storage area shall be
provided with suitable material to contain the spill.

8, EXPOSURE CONTROLS / PERSONAL PROTECTION

The maximum allowable concentration: China PC-TWA: 5mg / m3


China PC-STEL: 12.5mg / m3
Monitoring method: ammonium hydroxide - ferric chloride spectrophotometry.
Engineering control: closed operation, local exhaust.
Respiratory protection: air concentration exceeded, it is recommended to wear filter-type gas
masks. Emergency rescue or evacuation, you should wear an air respirator.
Eye protection: Wear chemical safety glasses.
Physical protection: Wear protective overalls.
Hand protection: Wear latex gloves.
Other protection: work is completed, bathing clothes. Pay attention to personal hygiene.

9, PHYSICAL AND CHEMICAL PROPERTIES

Appearance and properties: white crystal.


PH value: meaningless
Melting point ( C): 69
Boiling point (): 270
Relative density (water = 1): 1.05 (10% aqueous solution)
Relative vapor density (air = 1): Not available
Saturated vapor pressure (kPa): 0.048 (69.15 C)
Heat of combustion (kJ / mol): 851
Critical temperature ( C): Not available
Critical pressure (MPa): Not available
Octanol / Water Distribution system log Pow: Not available
Flash point (): 125
Ignition temperature (): 375
Lower explosion limit% (v / v): 1.84
Upper Explosive Limit% (v / v): 8.0
Solubility: soluble in water and ethanol, ether, chloroform and other organic solvents.
Main purposes: for the preparation of caprolactam resin, caprolactam fiber and leather, also used
as pharmaceutical raw materials.
Other physical and chemical properties: Combustion: flammable

10, STABILITY AND REACTIVITY

Stability: Stable
TIANJIN ICASON TECHNOLOGY CO., LTD.
TEL:86 022 60938150 FAX: 86 022 25621236
http://www.icason.com email: icason018@icason.com

Materials to avoid: Strong oxidizing agents, strong bases


Polymerization hazards: can occur
Avoid contact with the conditions: exposure to air, moisture, heat, light
Decomposition products: carbon monoxide, carbon dioxide, nitrogen oxides

11, TOXICOLOGICAL INFORMATION


Acute toxicity: LD50: 1155mg / kg (rat oral)
Subacute and chronic toxicity: guinea pigs inhaled 51 mg / m2, 5 to 8 hours / day, a total of 26 to
30 days, in addition to mild irritation of the nasal mucosa symptoms, no significant damage.
Irritation: 5%, 10% aqueous solution of this product is applied to the skin of mice and guinea pigs,
and into the rabbit eyes, did not cause irritation; 25 ~ 50% solution eye drops can cause corneal
burns.

12, ECOLOGICAL INFORMATION

Ecotoxicity: water concentration of 10.mg / L, affecting the self-purification of water, the


concentration of 100mg / L or more when the sludge nitrification of ammonia nitrogen decreased.
Ecological information Mobility: Not available
Non-biodegradable: No information available

13, DISPOSAL

Waste nature: hazardous waste


Disposal methods: disposal by controlled incineration. Oxides from the incinerator are removed
by scrubbing.
Disposal considerations: before disposal should refer to national and local laws and regulations.
See "Storage and Handling Precautions" for waste storage.

14, TRANSPORT INFORMATION

Dangerous Goods Code: Not found


UN Number: Not available
Packing symbol: flammable solid
Packaging categories: class packaging
Packing: double bag. Inside the bag for the polyethylene film bag, heat sealing; outer bag for the
three-in-one polyethylene bag, mechanical sewing seal.
Transportation Notes: The packaging should be complete at the time of shipment, loading should
be secure. Transport process to ensure that the container does not leak, do not collapse, do not fall,
not damaged. Do not mix with oxidants, alkalis, edible chemicals, etc. Transit should be
anti-exposure, rain, high temperature. Completely clean the vehicle after it is transported.

15, REGULATORY INFORMATION


TIANJIN ICASON TECHNOLOGY CO., LTD.
TEL:86 022 60938150 FAX: 86 022 25621236
http://www.icason.com email: icason018@icason.com

Regulations on the Safety Management of Dangerous Chemicals (Order No. 344 of the State
Council, implemented on March 15, 2002). Production, storage, transportation, handling and other
aspects of the provisions of the People's Republic of China national standard GB13690-92
(GB13690-92) for the safe use of dangerous chemicals "Commonly used classification and mark
of dangerous chemicals", GB16483-2000 "Chemical Safety Technical Specification"

16, OTHER INFORMATION

References:
1. Zhou Guotai, Chemical Dangerous Goods Safety Technology Book, Chemical Industry Press,
1997
2. He Fengsheng, Chinese Occupational Medicine, People's Medical Publishing House, 1999
3. Zhang Wei Fan, commonly used safety manual of dangerous chemicals, China Petroleum Press,
1998
4. National Environmental Protection Agency Office of Hazardous Chemicals Management,
Beijing Institute of Chemical Industry, ed., Environmental Data Manual on Toxicological Laws of
Chemicals, China Environmental Science Press, 1992
Fill in time: May 30, 2009
Fill in the form: TIANJIN ICASON TECHNOLOGY CO., LTD
Data review unit: ICASON Group Production Department
Revised description: May 30, 2009