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Hamoudi et al / Journal of Environment (2014), Vol. 03, Issue 04, pp.

57-64 ISSN 2049-954X

Research Paper

Meteorology and Photochemical Air Pollution in Western


Mediterranean Basin; Focused Analysis on Algerian
Coast
Benameur Hamoudi1, Fethi Saidi1*, Boumedienne Beladjine1 and Abbes Azzi1
1
Laboratory of Naval Aero-Hydrodynamic, University of Sciences and Technology of Oran, Mohamed Boudiaf, Algeria
*E-Mail: hamoudi_benameur@yahoo.fr

Abstract
In this study a summer air pollution episode from 31st of July to 1st of August 2013 over the Western Mediterranean Basin
(WMB) is investigated and analysed through advanced atmospheric modelling. This episode was reported from the air
quality simulations performed during this period for the Transport and Transformation of air pollutants from South Europe
to North Africa. The present study is concentrated on ground level Ozone (O3), oxide nitric (NO), dioxide nitrogen (NO2)
concentrations variability in order to determine the role of large scale atmospheric transport on the behaviour of tropospher-
ic ozone and its precursors. During this episode the synoptic condition showed by the meteorological WRF model favours
the development of mesoscale circulation, which enhances the long range transport of polluted air masses toward the
Algerian Coast. Moreover, the photochemical model results of both days simulated are compared with observed data and it
shows a good concordance about the O3 and NOx, while a similarity in temporal variation of the concentrations of
compounds studied is detected during this episode

Keywords: CAMx, O3-NO-NO2, South Europe, North Africa, Algerian Coast

1. Introduction
The increasing incidence of photochemical smog and its ago that the photochemical process essentially stops at
irritating and damaging effects spurred a flurry of research ambient temperatures below the 15 C (Gerasopoulos et al,
activities in the early 1980 that continued at a record pace 2006).
through the 1990 (Le Bras, 1993).
Highly populated Western Mediterranean Basin (WMB) is
Millan et al (1997) is credited with reporting that the most surrounded on three sides by mountains (Alps, Atlas etc.)
injurious effect of smog could be attributed to oxidants up to 2500 m in elevation. Millions of automobiles and va-
(mainly ozone) produced in the lower atmosphere by a rious industrial sources (South Europe) release large quant-
complex, photochemically initiated process involving oxi- ities of various reactive organic gases and oxides of nitrog-
des of nitrogen and various hydrocarbons. More recently, en in the atmosphere (Kallos, 1997 and Kallos et al, 1998).
the factors affecting photochemical air quality [NOx, CO,
CH4 and Volatile Organic Compounds (VOCs)] were revi- In addition, the air pollution climatology of the Western
ewed by Jimnez & Baldasano (2004), this case, requisite Mediterranean Basin should be a major consideration (Mil-
two refers to a stagnant air condition that must confine and lan et al, 2002). Particular interested on the average wind
maintain reactant levels for a stagnant air condition that speed and direction in order to provide a rough estimate of
solar irradiation to take place and to initiate the smog proc- pollutant dispersion patterns. The effect of topography and
ess. Temperature must be included as a parameter because local wind systems, such as land sea breezes and mounta-
of its effect on the rate of the reaction. It was shown long in-valley winds, should be investigated with respect to dis-

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Hamoudi et al / Journal of Environment (2014), Vol. 03, Issue 04, pp. 57-64 ISSN 2049-954X

persion patterns and nearby residential and industrial areas From Western Mediterranean towards Eastern with
(Max Planck Society for the Advancement of Science, two branches i.e. towards NE Mediterranean and tow-
2002). ards SE Mediterranean, Middle East and Africa.

Additionally, great consideration should be given to the pr- During the cold period of the year, the washout mechanis-
oblem of trans boundary long-range ozone and its precurs- ms are important. Photochemical processes are not at their
ors within WMB during the summer (Bouchlaghem et al, peak due to limited insulation and cloud formations. Duri-
2012). As noted in previous studies i.e. Kallos et al (2002) ng the warm period, the wet removal processes are very
and Millan et al (2002), the synoptic and regional circulat- limited and insulation helps photochemical processes,
ion during the summer favours and promotes the transport moreover, they affect the weather at higher latitudes
of aged air masses maintained within the within the entire (Varinou et al, 2001).
Mediterranean Basin for a long-distance released from the
South-East Europe and Central Mediterranean to North The air masses coming towards North Africa are highly
Africa. influenced by strong sea-land breeze (differencing in temp-
erature) and the intensity of the Azores high-pressure syst-
The factors and processes spatially and temporally have em, which surrounds the Western Mediterranean Basin
been the subject of intense modelling efforts for more than (Millan et al, 2000).
three decades. The model currently in favour with various
projects at Mediterranean Region is a massive computer The western North Africa especially the Algerian Coast is
program, the Comprehensive Air quality Model with Exte- mainly located under the influence of topography and cli-
nsion (CAMx) (Kallos et al, 2002 and Tesche et al, 2006). mate of WMB, surrounded by high coastal mountains and
characterised by dry hot summers and mild winters. Preci-
The issue of air quality conditions and atmospheric pollut- pitations are poor, irregular and sometimes drought situate-
ion in Western North African countries, more specifically ion. Annual average temperature is 18 oC, annual average
Algerian Coast, has been addressed through consideration precipitation around 450 mm. Nevertheless, there is a dive-
of its relativity to Europe Region. Global, regional and rse climate, with strong contrasts through the year (United
local sources of air pollution in the Western Mediterranean Nations Environment Program, Regional Office for West
Region (WMR) have been considered. Indeed, the air poll- Asia, League of Arab states, 2006). The sun provides the
ution was highest during times of this episode when Mete- energy to drive the winds by heating the surface of the
orology factors like average wind speed and direction, also earth and in turn the air above it. This heat affects the Alg-
average temperature are favour for accumulation and trans- erian Coast most of the time. There are three major factors
port of pollutants mainly O3, NO and NO2 from South that influence the Algerian Coast weather and air quality:
Europe to Western North Africa. Typically, these conditi-
ons are identified with the combined systems of advanced The differential heating of the land and Mediterranean
atmospheric modelling WRF/CAMx (Saidi et al, 2014). masses

2. Re-Circulation and Transport over the The large scale seasonal weather regimes
WMR
The local topography.
The air pollution re-circulation and transport was the subj-
ect of many studies during the last 15 years (Gangoiti et al, 3. Model Systems
2001), such as MECAPIP and T-TRAPEM gave informati-
on about the re-circulation mechanisms, the layering, the A short description of the modelling system used in this
paths and transformation processes, mainly the photo-oxid- study is provided below.
ants, (Millan et al, 2000). Similarly, Max Planck Society
for the Advancement of Science, 2002, investigates atmos- Figure 1 shows the computational domain for the meteoro-
pheric pollution transport over the Mediterranean region logical (WRF) and the photochemical (CAMx) models.
resulting in large scale decrease of air quality and precipit-
ation (MINOS). These investigations were included in the The Weather Research and Forecasting (WRF) Model is a
BEMA, MAMCS, SUB-AERO and ADIOS projects. next-generation mesoscale numerical weather prediction
system designed to serve both atmospheric research and
The T-TRAPEM and MINOS projects developed two operational forecasting needs.
paths of transport as:
The Comprehensive Air Quality Model with Extensions
From SE Europe and Black Sea towards the Middle (CAMx) is an Eulerian photochemical model that allows
East and North Africa, across the Aegean Sea. integrated assessment of air pollution over many scales

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Hamoudi et al / Journal of Environment (2014), Vol. 03, Issue 04, pp. 57-64 ISSN 2049-954X

ranging from urban to regional. The CAMx performance 4. Case Study


running is summarised on Table 1 and Table 2.
4.1. Synoptic Situation during the Episode

The temperature distribution over the WMB was


associated with a weak Coast flow moving slowly
eastwards, this situation induced weak cyclonic circulation
over the Western and the Centre of Algeria and a
tropospheric anticyclonic circulation above these regions.
Under this weak synoptic forcing, strong insulation may
promote the development of mesoscale flows associated
with the local topography (mountain and valley), while the
difference in temperature between the sea and the land
enhances the development of sea-land breezes. Later in the
day, the surface air temperature decreases over the WMB,
land begins to cool, while the air temperature above the
Figure 1. Computing Domain for Resolution of (12*12 km) Grid- Mediterranean Sea is higher to generate an air flow betwe-
1/(5*5 km) Grid-2 (longitude*latitude) en sea and land, after the sunset on July 31st as well as the
next days (August 1st). A relatively stationary high pressu-
Table 1. CAMx Specifications
re area on North Africa provides an easterly flow of cool
upper air which subsides over the basin causing an inverse-
Specification Description ng in surface temperature. The resulting inversion, combi-
ned with a light sea breeze and the surrounding mountains.
Model CAMx v5.2
An additional effect of the Azore high pressure cell domin-
OS/compiler Linux, Ifort v.11.0-0 ates the WMB with clear skies.
CPU type USTO Cluster
Emissions source EMEP Inventory 4.1.1. Surface Temperature
Initial conditions camx.v 5.2. inst. 5.2 The general meteorological conditions simulated are char-
Boundary conditions camx.v 5.2.BC acterised by maximum surface air temperature at 1200
Meteorological data WRF Meteorological Model UTC (Coordinated Universal Time) ranging between 34
and 42 C over the North Africa at 31st of July, while the
Table 2. CAMx Run-Time Options next days (1st August) it varied between 34 and 40 C over
the same area (Figure 2). During the nights, the land cools
faster than the sea mass, causing a land breeze where the
WRAP PSAT Speciation Description
air flows slowly down the Algeria coastal areas into the
Advection Solver PPM Mediterranean basin. The increase in temperature accordi-
Chemistry Parameters CAMx.5.2.chemparam.5_CF ng to the altitude result an inversion coupled with stagnati-
on conditions near the surface of the Alps and the Atlas
Chemistry Solver CMC Mountains during the noon period drive to the formation of
Plume-in-grid Used a box over this both region. This last aid in traps the
emitted pollutants and provides a massive photochemical

Figure 2. Mean Sea Level Pressure and Surface Air Temperature at 12 UTC for the 31st of July and the 1st August, 2013

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Hamoudi et al / Journal of Environment (2014), Vol. 03, Issue 04, pp. 57-64 ISSN 2049-954X

reaction vessel. 4.1.2.2. Wind at 1500 m

4.1.2. Wind Field The wind field at 850 hPa shows the synoptic wind circul-
ation. Figure 4, shows the 850 hPa wind field on the 31st of
The two days of the episode, 31st of July and 1st of August July, and 1st of August. As for the wind at 10 m, the wind
2013, shows that the first and second layer of WRF model at 850 hPa blows out from Gulf of Lion towards the coas-
up to 850 hpa are in roughly similar for the wind direction. tal line of Algeria, while the wind from Gibraltar Strait
The air block '' very slow air flow'' extends from 10 m to blows towards North Africa. This flow pattern is maintain-
850 hpa (1500 m). Whereas, the wind coming by the Gulf ned during the whole period simulated.
of Lion breaks this wall (air block) to exit over the Algeri-
an Coast giving rise to a re-circulation over this area. 5. Results and Discussion
4.1.2.1. Wind at 10 m 5.1. Model Evaluation

For the two days simulated, the wind field is characterised The West of North Africa, more precisely Algeria, has a
by a North-Westerly direction from the Gulf of Lion towa- great lack of data in air quality. In this context, this study
rds Tyrrhenian Sea with the maximum offshore of the Tun- will give a clear sight on air quality of the WMR afterwa-
isian Coast. By 0600 UTC the situation over the Algerian rds on the whole Algerian coast.
Coast was almost stagnant with very low winds apart from
an area offshore where the wind has its maximum (5 ms-1). CAMx produce excellent simulation results, as shown in
At 1200 UTC the wind flow is similar as in the previous Figure 5. It presents ozone and two important precursor
period with slightly higher winds inland of Algeria. At the NO and NO2 exactly at South of France: AIR Languedoc-
early afternoon the air flow over the Mediterranean Sea Roussillon, Pyrnes measure Station situated at (latitude=
and the nearby coastal areas was enhanced as a result of 436; longitude= 388). The predicted results from a
the synoptic conditions (Figure 3). CAMx simulation of the Pyrnes Metropolitan area are

Figure 3. 10m Wind Field at 1200 UTC on July 31st and 1st August, 2013

Figure 4. Wind Field at 850 hpa at 1200 UTC on July 31st and 1st August, 2013

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Hamoudi et al / Journal of Environment (2014), Vol. 03, Issue 04, pp. 57-64 ISSN 2049-954X

compared with hourly monitoring data. A good concordan- Region where the daytime peaks are consistently over 0.07
ce between CAMx model and measure station is noticed. ppm in all simulated days, reaching more than 0.09 ppm
The light differences between the model results and meas- coincides with a steep decease in the precursor NO values
ured of the concentration are due to the grid refinement. (Figures 6a and 6b), not only the max values of ozone are
Bright and clear skies combined with an early morning te- associated with minimum values in NO, but the whole diu-
mperature in the range of 32-40 C. These factors produce rnal cycle of the two species is more or less opposite, from
a typical smog day at Algerian Coast. Figure 5 presents West, Central, East and South Europe, across the North
typical levels of NOx and ozone as the smog process prog- Africa more precisely across of the Algerian Coast. During
resses at Western North Africa. Both simulated days show this episode, the first day presents a similarity on the Grou-
a similarity on the day cycle of the three species studied nd-level ozone, in which from 31st of July to 1st of August
(O3, NO, NO2). the relatively higher concentrations extend from Southern

Figure 5. Hourly Average of Modelled and Measured Concentration for O3, NO2, NO at 31st of July and 1st of August, 2013

5.2. Hourly Average Concentration during this Episode Europe to Northern Algeria. Pockets of higher concentrate-
ons exist within this band where the means reach to 0.062
During the night of 31st of July, from roughly 0000 to 0600 ppm. For much of the region the mean modelled; ozone
UTC, the concentration of oxides of nitrogen remain at co- concentrations are between 0.045-0.060 ppm. Over much
astal levels. As traffic and industrial builds to reach a ma- of North Algerian, South France, East Iberian Peninsula
ximum at around 0800 UTC, there is an attendant rapid and Italy the maximum ozone concentrations varies betwe-
increase in the concentration of NO occurs first, as these en 0.062-0.082 ppm.
emitted from sources directly. The increase in NO2 gaps by
a short period because it is formed by atmospheric reacti- During this episode, several potential mechanisms for re-
ons. Shortly after sunrise and the photochemical reaction circulating O3 and its precursors have been shown by met-
sequence, the NO concentration begins a rapid decrease eorological pattern over North Algeria, including the hot
and the oxidant predominantly ozone concentration increa- surface air temperature and wind reversals along the coast
se at a similar rate. By 0900 UTC the photochemical proc- caused by thermal low circulation and formation of pollut-
ess oscillate over the equilibria. ion in South France (Gulf of Lion) and East Spain, subject
to long-range transport toward North Algeria.
If there is a noticeable pungent odour of ozone in the air,
ones eyes begin to water and burn and the panoramic A loft caused by the polluted layer system reaches the are-
view of the city begins to fade in a brownish aerosol haze as surrounding the Alps as well as Gibraltar, whereas, part
that will increase until about 1100 to 1300 UTC (noon). At of these pollutants could be above the trade winds domina-
1800 UTC the intensity of solar radiation has decreased to ting these regions (Azores high pressure). The processes
a low level and the photochemical process has dropped. could be favoured by a high relief injection level provided
Oxidant levels turn down rapidly as their production rates by the South Europe facing slopes of Alps, also of Sierra
go to zero. By 0000 UTC the concentration of oxides of ni- Nevada (South Spain) range (3000 m peaks). The pollutan-
trogen have again reached normal coastal levels (stagnant ts, however, remaining in the lower layers could travel
air conditions), and are ready to participate in more smog toward and along the Algerian Coast with the trade winds.
formation reactions the next day (1st of August). This transport mechanism could explain some high O3
levels at the Algerian Coast background occurred in this
5.3. Transport and Transformation during this Episode episode. Its formation takes place mainly above the Medit-
erranean Sea where primary pollutants have been accumul-
The diurnal cycle is most pronounced in the Mediterranean ating until early. The photochemical reactions are more

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Hamoudi et al / Journal of Environment (2014), Vol. 03, Issue 04, pp. 57-64 ISSN 2049-954X

pronounced this day over the domain study. The mechani- 5.4. Transect Along the Western Mediterranean Basin
sms occurred during this day for the transformation and
transport of pollutants was similar to the latest day. Those Figure 7 shows the O3 concentrations from South Europe
processes (mechanisms transformations) lead to the layeri- to North Africa at several times of the day. In Pyrnes,
ng of the aged pollutants, that is being trapped in strata located on the valley at slight of 400 m (Near the Gulf of
which are essentially uncoupled from each other and from Lion), O3 is still available from the reservoir layers (Costal
the surface, this layers are generated directly along the co- hills) that it has not been depleted fully from the drainage
astal mountains ranges (all over WMB) Figure 6b, and co- flow and the concentrations do not drop below 0.4 ppm
nvection toward the sea. The photochemical formation of during the night. While the O3 concentration at the Weste-
ozone at the Algerian Coast is influenced by ambient tem- rn North Africa, more precisely at the Algerian Coast, is
perature, solar radiation, NO and NO2 concentration. low as compared to the Pyrnes area. At the 0700 UTC,

Figure 6a. Hourly Average O3, NO2 and NO Concentration respectively at 06, 12 and 20 UTC for 31st of July, 2013

Figure 6b. Hourly Average O3, NO2 and NO Concentration respectively at 06, 12 and 20 UTC for 1st of August, 2013

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Hamoudi et al / Journal of Environment (2014), Vol. 03, Issue 04, pp. 57-64 ISSN 2049-954X

the O3 increases and reaches 0.6 ppm and the same beha- The polluted air reaching the areas surrounding the
viour has been seeing the next day. This increase occurs Alps, whereas part of these pollutants mainly O3 and
with a weak wind speed. By 1000 UTC the wind speed at NOx could be present above the trade winds dominat-
sea surface near ten North Africa areas increase to 3 ms-1. ing these two regions (Azores high).
These two factors (rise of O3 and wind field) create the
transport of O3 within the marine boundary layer in the res- The pollutants remaining in the lower layers could
ervoir layers above the sea. The O3 reaches its maximum travel through the marine boundary layer towards and
value of 0.85 ppm at 1200 UTC, at this time the situation along the Algerian Coast with trade winds, especially
is calm and stagnant. At this time the O3 keeps increasing the air flow in the lowest layers near the free sea
and when the maximum wind speed is attained the polluted surface.
air masses (O3, NO, NO2) are dispersed and transported to
release a new photochemical production and accumulated Acknowledgement
above the sea. It reaches a maximum around 1400 UTC
with a well-developed sea breeze at the Algerian Coast. We would like to express our special thanks of gratitude to

Figure 7. Hourly Average O3 Concentration along Distance between South French (AIR Languedoc-Roussillon [0 km]) and North Algeria (Algiers)
[700 km] at 06, 12 and 22 UTC Respectively for 31st of July (Top) and 1st of August (Bottom), 2013

6. Conclusion the director of the Aero-hydrodynamics laboratory, Mech-


anical Faculty, University of Sciences and technology of
During this study, the investigation and the analysis of gro- Oran, Mohamed Boudiaf, as well as the whole team for
und level concentration combined with meteorological co- giving us the golden opportunity to achieve this piece of
nditions show a direct relationship between primary (NO) work on the topic of air pollution in the Mediterranean
and secondary (O3, NO2) pollutants over the WMB. The Basin, focussing on the Algerian Coast, which also helped
analysis illustrate a continuous stream of pollutants (O3 and us in digging deep into the topic and we came to draw such
NO2) from South France by the Gulf of Lyon and East a conclusion.
Spain released into a steady wind in the atmosphere, then
bend over the mean wind, which will carry them toward References
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