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Reservoir Fluid Study

for
Vetra Group
Cohembi-1
RFLA 1003241

FINAL REPORT

The analyses, opinions or interpretations in this report are based on observations and material supplied by the client to
whom, and for whose exclusive and confidential use, this report is made. The interpretations or opinions expressed
represent the best judgement of Core Laboratories(Colombia), (all errors and omissions excepted); but Core Laboratories
(Colombia) and its officers and employees assume no responsibility and make no warranty or representations as to the
productivity, proper operation or profitability of any oil, gas or any other mineral well formation in connection with which
such report is used or relied upon.

Petroleum Services Division


Core Laboratories (Colombia)

Carrera 20 No. 168-52/56


Tel: +57 (1) 674 0400 Fax: +57 (1) 673 0060 Web: http://www.corelab.com
Petroleum Services Division
Core Laboratories (Colombia)
Carrera 20, No 168-52/56
Bogot, Colombia
Tel: +57 (1) 674 0400
Fax: +57 (1) 673 0060
Web: http://www.corelab.com

28th September 2010

Vetra Group,
Carrera 7, No.71-52,
Torre A, Piso 10
Bogota, Colombia

Attention: Ing. Javier Aguillon,

Dear Ing. Javier Aguillon,

Subject: Reservoir Fluid Study; well Cohembi-1; our file RFLA 1003241.

On 23rd June 2010 two (2) bottomhole samples were collected by Core Lab representative and delivered
to our Colombia laboratory. The samples were subject to a programme of analyses as specified by Vetra
Group. Presented in the following report are the final results of all PVT analyses performed for well
Cohembi-1.

Bottomhole sample cylinders 820357 and 815667 were transferred into a Core Laboratories (Colombia)
owned cylinders and a Reservoir Fluid Study performed. Bottomhole sample 815667 was consumed
during analysis.

Core Laboratories (Colombia) are very pleased to have been of service to Vetra Group in this work.
Should any questions arise concerning the data presented in this report, or if Core Laboratories (Colombia)
may be of assistance in any other matter, please do not hesitate to contact us.

Yours sincerely,

Core Laboratories (Colombia)

Jeffrey Thomasson
Reservoir Fluids Manager Colombia
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________
Table of Contents

Section A - Summary of Analysis Methods and PVT Data Page

Summary of analysis methods.............................................................................................................. A.1-A.2

Summary of PVT data .......................................................................................................................... A.3

Section B - Summary of Bottomhole Samples Received and Compositional Analysis

Reported well and sampling information - bottomhole samples............................................................ B.1

Summary of bottomhole samples received and validation data............................................................ B.2

Compositional analysis of bottomhole sample 815667 to C36+............................................................ B.3-B.4

Section C - Constant Composition Expansion - Bottomhole Sample 815667

Constant composition expansion at 205F............................................................................................ C.1-C.2

Graphs of Constant composition expansion at 205F........................................................................... C.3

Section D - Differential Vaporisation - Bottomhole Sample 815667 Page

Differential vaporisation at 205F.......................................................................................................... D.1

Graphs from differential vaporisation at 205F...................................................................................... D.2

Compositional analysis of differential vaporisation gases to C11+....................................................... D.3

Compositional analysis of differential vaporisation residual oil to C36+................................................ D.4-D.5

Differential vaporisation data converted to separator test conditions.................................................... D.6-D.7

Section E - Viscosity Data - Bottomhole Sample 815667

Reservoir fluid viscosity data at 205F.................................................................................................. E.1

Section F - Separator Test Data - Bottomhole Sample 815667

Separator test 1 data............................................................................................................................. F.1

Compositional analysis of separator test 1 gases to C11+................................................................... F.2

Section G - Appendix

Data used in compositional calculations............................................................................................... G.1

Data used in liquid compositional calculations...................................................................................... G.2

________________________________________________________________________________________
Core Laboratories (Colombia)
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Section A - Summary of Analysis Methods and Data

________________________________________________________________________________________
Core Laboratories (Colombia)
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Summary of Analysis Methods

Sample Handling and Validation


The bubble point pressure of the bottomhole samples were determined at reservoir temperature as a quality check.

The selected bottomhole sample was heated to a temperature of 200F and stabilised at 7000 psig prior to any sample
removal in order to eliminate any possible wax precipitation.

Compositional Analysis
The compositions of the bottomhole sample were determined using a flash/separation technique and gas
chromatography. The samples were flashed at 120F and separated into gas and liquid phases. The gases were
analysed by extended gas analysis technique (see below) and the liquids by temperature programmed high resolution
capillary gas chromatography (see below). The two analyses were then combined mathematically on a weight basis to
produce a C36+ weight percent composition.

Liquid Compositions
Residual/stocktank liquid composition were measured using a HP-6890 chromatograph. The gas chromatograph utilizes
a cold on column, "sandwich injection" technique to ensure that a representative sample is injected and swept onto the
column. The sample is run twice; first the original fluid and then fluid spiked with n-tetradecane. This allows the
laboratory to take into account any heavy end (C36+) losses that may have occurred during the chromatographic run, and
make an accurate correction prior to reporting the liquid composition. The data obtained from the gas chromatograph is
in weight %. Calculations to mole% and the plus fractions properties are described later.

The chromatograph for liquid samples is checked daily, using a gravimetric n-paraffin mix containing a range of pure
components from C8 through C36 and a synthetic gas-oil mix (D2887) with known composition. The resultant calibration
data is checked statistically against previous calibrations prior to performing analyses on unknown samples.

Gas Compositions
Gas composition were measured using a "one shot" Varian 3800 gas analyzer using GPA 2286 method. The gas
chromatograph utilizes 3 columns to clearly identify all of the eluted components from N2, CO2 and C1 through C11+.

The chromatograph is calibrated weekly using air and synthetic hydrocarbon gas with a known composition. The
resultant calibration data is checked statistically against previous calibrations prior to performing analyses on unknown
samples.

Calculation of Mole% Compositions and Plus Fraction Properties


The residue or stocktank liquid whole sample molecular weight and density are measured using a cryoscope and a PAAR
densitometer respectively.

The mole% data is calculated using GPSA mole weight and density data, where individual components are identified,
from carbon dioxide through decanes. Katz and Firoozabadi data are used from undecanes through pentatriacontanes.
The residue mole weight and density values are calculated so that the pseudo average mole weight and density are the
same as the measured values. This can lead to anomalous residue mole weights and densities where the Katz and
Firoozabadi values may not be suitable for the isomer groups detected.

Other alternatives are to use an assumed C36+ molecular weight and density value, use a linear extrapolation technique
for components from C10 to C35 to calculate the C36+ properties or to utilise distillation analysis to produce a C11+,
C20+ or C36+ residual oil fraction and physically measure the molecular weight and density

Review of Validation Data


The bottomhole oil sample 815667 showed minimal level of water. It was decided that bottomhole sample 815667 would
be suitable for further compositional and PVT analysis.

________________________________________________________________________________________
Core Laboratories (Colombia)
A.1
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Summary of Analysis Methods (Continued)

Partial Constant Composition Expansion (PCCE)


A portion of bottomhole oil sample 815667 was charged to a high pressure visual PVT cell and thermally expanded to the
reservoir temperature. A partial constant composition expansion was carried out during which the bubble point pressure
was determined. Pressure-volume data for the single phase were also determined. The density of the single phase fluid
was determined using a high pressure coil density method. Density data for other pressures were calculated using the
volumetric data.

Constant Composition Expansion


A portion of bottomhole oil sample 815667 was charged to a high pressure visual PVT cell and thermally expanded to the
reservoir temperature. A constant composition expansion was carried out during which the bubble point pressure was
determined. Pressure-volume data for the single phase and two phase fluid were also determined. The density of the
single phase fluid was determined using a coil density methodology at 6000 psig (see page A.3). Density data for other
pressures were calculated using the volumetric data.

Differential Vaporisation
This was carried out in a high pressure visual PVT cell, at reservoir temperature on the same subsample used for the
CCE test. At several pressure stages, below the observed saturation pressure, the sample was stabilised. The gas
evolved was then pumped out of the cell and the volume, compressibility and composition were determined. The final
stage was carried out at atmospheric pressure when the residual liquid was pumped out of the cell and its density and
composition were determined.

Viscosity
This test was carried out using a Cambridge electro-magnetic viscometer (EMV) on a portion of bottomhole sample
815667. The instrument contains two magnetic coils inside a stainless steel body. A low mass stainless steel piston
inside the measurement chamber is magnetically forced back and forth in the fluid. The time required for the piston to
move a fixed distance is then very accurately related to the viscosity of the fluid in the chamber by use of calibration
constants.

The viscosity measurements were run from 6000 psig down to atmospheric pressure at reservoir temperature. The
measurements were repeated at each pressure stage until five consistent viscosity measurements were obtained within
0.5% of each other.

Separator Test
Finally, one single-stage separator tests were carried out using a pressurized test separator cell. A portion of the
bottomhole fluid sample, at a pressure above saturation pressure, was pumped into the separator cell and stabilized at
the pressure and temperature required for the first stage separation. The gas evolved was pumped out of the cell and the
volume and composition were determined. The final stage was carried out at atmospheric pressure and separator
temperature and the density of the residual liquid was determined.

________________________________________________________________________________________
Core Laboratories (Colombia)
A.2
6000 3784 205 Bottomhole Sample 815667

Vetra Group FINAL REPORT


Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Summary of PVT Data - Bottomhole Sample 815667

Constant Composition Expansion at 205F

Saturation pressure (bubble-point) 579 psig

Average single phase compressibility 6.17 x 10-6 psi from 3784 psig to 579 psig

Thermal expansion at 6000 psig 1.0563 vol at 205F / vol at 60F

Differential Vaporisation at 205F

Solution gas-oil ratio at saturation pressure, Rsd (1) 123 scf/bbl of residual oil at 60F

Relative oil volume at saturation pressure, Bod (2) 1.122 vol/vol of residual oil at 60F

Density at saturation pressure (579 psig) 0.8836 g cm-3

Reservoir Fluid Viscosity at 205F

Viscosity at reservoir pressure 24.086 cP at 3784 psig

Viscosity at saturation pressure 17.211 cP at 579 psig

Separator Test 1 Data


Total Solution Formation Volume Stocktank Oil
Pressure Temperature Gas-oil ratio Factor Bofb Density at 60F
(psig) (F) (Scf/bbl) (g cm-3)

579 205 68 1.098

35 100
0 60 0.9430
(API = 18.4)

________________________________________________________________________________________
Core Laboratories (Colombia)
A.3
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Section B - Summary of Samples Received and Validation Data

________________________________________________________________________________________
Core Laboratories (Colombia)
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Reported Well and Sampling Information - Bottom Hole Samples

Reservoir and Well Information

Field............................................................................................... N/A
Well................................................................................................ Cohemb-1
Reservoir Fluid............................................................................... Black Oil

Formation....................................................................................... N/A
Current Reservoir Pressure ........................................................... 205 F
Reservoir Temperature................................................................... 3784 psig

Geographical Location.................................................................... N/A


Sand............................................................................................... N/A
Perforated Interval ......................................................................... N/A

Sampling Information

Date sampled................................................................................. 23-Jun-10


Time sampled ................................................................................ N/A
Type of samples............................................................................. BHS
Sampling company......................................................................... Core Laboratories

Choke............................................................................................. N/A
Status of well.................................................................................. N/A

Flowing bottomhole pressure.......................................................... N/A


Bottomhole temperature................................................................. N/A

Wellhead pressure.......................................................................... N/A


Wellhead temperature.................................................................... N/A

Separator pressure ........................................................................ N/A


Separator temperature ................................................................... N/A

Pressure base................................................................................ 14.7 psia


Temperature base ......................................................................... 60 F

Separator gas rate.......................................................................... *


Separator oil rate ........................................................................... *
Gas/oil rate..................................................................................... *
Water flowrate................................................................................ *
Gas gravity (Air = 1)........................................................................ *
Supercompressibility factor............................................................. *
H2S................................................................................................ *
CO2................................................................................................ *
BS&W............................................................................................ *
Oil gravity ...................................................................................... *

Comments:
Datanotprovided
** Data submitted by Occidental
to Core de
Laboratories Colombia

________________________________________________________________________________________
Core Laboratories (Colombia)
B.1
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Summary of Bottomhole Samples Received

Sampling Laboratory Free


Depth Laboratory opening bubble point Water Sample
Sample Cylinder MDRKB Pressure Temp. Pressure Temp. Recovered volume
Number Number (feet) (psig) (F) (psig) (F) (cm3) (cm3)

1.1 815667 7870 N/A N/A 549 205 0.00 500

1.2 820357 7870 N/A N/A 660 205 0.00 500

Note:

1) Sample cylinder number 815667 was selected for PVT analysis.

________________________________________________________________________________________
Core Laboratories (Colombia)
B.2
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Compositional Analysis of Bottomhole Sample 815667 to C36+

Component Flashed Liquid Flashed Gas Reservoir Fluid


Mole % Weight % Mole % Mole % Weight %
H2 Hydrogen 0.00 0.00 0.00 0.00 0.00
H2S Hydrogen sulphide 0.00 0.00 0.00 0.00 0.00
CO2 Carbon dioxide 0.00 0.00 1.77 0.40 0.06
N2 Nitrogen 0.00 0.00 2.62 0.59 0.06
C1 Methane 0.00 0.00 39.19 8.89 0.51
C2 Ethane 0.04 0.00 10.75 2.47 0.27
C3 Propane 0.46 0.06 19.84 4.86 0.77
iC4 i-Butane 0.24 0.04 3.54 0.99 0.21
nC4 n-Butane 1.10 0.18 10.56 3.25 0.68
C5 neo-Pentane 0.03 0.01 0.02 0.02 0.01
iC5 i-Pentane 0.97 0.20 3.35 1.51 0.39
nC5 n-Pentane 1.27 0.26 3.28 1.73 0.45
C6 Hexanes 2.39 0.59 2.60 2.43 0.75
Me-Cyclo-pentane 0.97 0.23 0.59 0.88 0.27
Benzene 0.18 0.04 0.08 0.16 0.04
Cyclo-hexane 0.38 0.09 0.31 0.36 0.11
C7 Heptanes 3.11 0.89 0.86 2.60 0.93
Me-Cyclo-hexane 1.09 0.31 0.21 0.89 0.31
Toluene 0.30 0.08 0.03 0.24 0.08
C8 Octanes 4.17 1.36 0.30 3.29 1.35
Ethyl-benzene 0.55 0.17 0.01 0.42 0.16
Meta/Para-xylene 0.49 0.15 0.00 0.38 0.15
Ortho-xylene 0.32 0.10 0.00 0.25 0.09
C9 Nonanes 3.92 1.44 0.08 3.05 1.40
Tri-Me-benzene 0.45 0.15 0.00 0.35 0.15
C10 Decanes 4.20 1.71 0.01 3.25 1.66
C11 Undecanes 4.41 1.86 0.00 3.41 1.80
C12 Dodecanes 3.58 1.65 0.00 2.77 1.60
C13 Tridecanes 4.13 2.07 0.00 3.20 2.01
C14 Tetradecanes 3.35 1.82 0.00 2.59 1.77
C15 Pentadecanes 3.26 1.92 0.00 2.52 1.86
C16 Hexadecanes 2.80 1.78 0.00 2.16 1.72
C17 Heptadecanes 2.33 1.58 0.00 1.80 1.53
C18 Octadecanes 2.53 1.81 0.00 1.95 1.76
C19 Nonadecanes 2.45 1.85 0.00 1.90 1.79
C20 Eicosanes 1.93 1.52 0.00 1.50 1.48
C21 Heneicosanes 1.79 1.49 0.00 1.39 1.45
C22 Docosanes 1.62 1.42 0.00 1.25 1.37
C23 Tricosanes 1.55 1.41 0.00 1.20 1.37
C24 Tetracosanes 1.44 1.37 0.00 1.11 1.32
C25 Pentacosanes 1.43 1.41 0.00 1.11 1.37
C26 Hexacosanes 1.22 1.25 0.00 0.94 1.21
C27 Heptacosanes 1.22 1.30 0.00 0.94 1.26
C28 Octacosanes 1.13 1.26 0.00 0.88 1.22
C29 Nonacosanes 1.27 1.47 0.00 0.99 1.42
C30 Triacontanes 1.13 1.35 0.00 0.87 1.31
C31 Hentriacontanes 1.14 1.41 0.00 0.88 1.36
C32 Dotriacontanes 1.00 1.28 0.00 0.78 1.24
C33 Tritriacontanes 0.99 1.29 0.00 0.76 1.25
C34 Tetratriacontanes 0.97 1.31 0.00 0.75 1.27
C35 Pentatriacontanes 0.90 1.25 0.00 0.69 1.21
C36+ Hexatriacontanes plus 23.80 53.81 0.00 18.40 52.19
_____ _____ _____ _____ _____
Totals: 100.00 100.00 100.00 100.00 100.00
Note: 0.00 means < 0.005.

________________________________________________________________________________________
Core Laboratories (Colombia)
B.3
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Compositional Analysis of Bottomhole Sample 815667 to C36+

Calculated Properties Flashed Liquid Flashed Gas Reservoir Fluid

C7+
Mole% 93.50 2.48 72.86
Molecular Weight (g mol-1) 369 96 367
Density at 60F (g cm-3) 0.9525 0.7443 0.9519

C11+
Mole% 73.37 0.00 56.74
Molecular Weight (g mol-1) 438 147 438
Density at 60F (g cm-3) 0.9738 0.7890 0.9737

C20+
Mole% 44.53 34.44
Molecular Weight (g mol-1) 593 593
Density at 60F (g cm-3) 1.0127 1.0127

C36+
Mole % 23.80 18.40
Molecular Weight (g mol-1) 791 790
Density at 60F (g cm-3) 1.0717 1.0716

Calculated Properties Flashed Liquid Flashed Gas Reservoir Fluid

Average mole weight (g mol-1) 350 37.37 279

Real relative density


(Air = 1.000 at 14.73 psia and 60F) 1.307

Measured density at 60F (g cm-3) 0.9459

Note: Data from atmospheric flash performed at 120F.

________________________________________________________________________________________
Core Laboratories (Colombia)
B.4
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Section C - Constant Composition Expansion - Bottomhole Sample 815667

________________________________________________________________________________________
Core Laboratories (Colombia)
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Constant Composition Expansion at 205F

Single-phase Fluid Properties

Saturation pressure (bubble-point pressure) 579 psig

Thermal expansion factor of single phase fluid at 6000 psig


(Vol at 205F)/(Vol at 60F) 1.0563 vol / vol

Average single phase compressibility


(From 3784 psig to 579 psig) 6.17 x 10 -6 psi-1

Density at saturation pressure 0.8756 g cm-3

Mean Single-phase Compressibilities

Pressure Range Mean


Initial Pressure Final Pressure Compressibility
(psig) (psig) (psi-1) (1)

6000 4500 5.23 x 10 -6

4500 3000 5.66 x 10 -6

3000 1500 6.09 x 10 -6

1500 579 6.64 x 10 -6

(1) Mean compressibility = (V2-V1) / [(V1+V2)/2] x 1/(P1 - P2)

________________________________________________________________________________________
Core Laboratories (Colombia)
C.1
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Constant Composition Expansion at 205F

Pressure Relative Density Instantaneous Y-Function (3)


(psig) Volume (1) (g cm-3) Compressibility
(psi-1 x 10-6) (2)

6000.0 0.9689 0.9037 4.99


5500.0 0.9714 0.9014 5.15
5000.0 0.9739 0.8991 5.31
4500.0 0.9765 0.8967 5.46
4000.0 0.9792 0.8942 5.60
3784.0 Reservoir pressure 0.9804 0.8931 5.66
3500.0 0.9820 0.8917 5.73
3000.0 0.9849 0.8891 5.87
2500.0 0.9878 0.8864 6.01
2000.0 0.9908 0.8837 6.17
1500.0 0.9939 0.8810 6.36
1000.0 0.9971 0.8781 6.64
900.0 0.9978 0.8775 6.71
800.0 0.9985 0.8769 6.80
700.0 0.9992 0.8763 6.89
600.0 0.9999 0.8757 6.97
579.0 Saturation pressure 1.0000 0.8756
565.0 1.0039
556.0 1.0066
550.0 1.0085
543.0 1.0108
538.0 1.0125
517.0 1.0203 5.731
488.0 1.0331 5.475
457.0 1.0497 5.200
405.0 1.0875 4.740
338.0 1.1648 4.147
259.0 1.3391 3.448
184.0 1.7139 2.785
137.0 2.2301 2.369
103.0 2.9559 2.068
74.0 4.1436 1.811

(1) Relative Volume = V / Vsat ie. volume at indicated pressure per volume at saturation pressure.
(2) Instantaneous compressibility = (V2-V1) / V1 x 1/(P1-P2)
(3) Y-function = (Psat - P ) / ((Pabs)(V/Vsat - 1)).

________________________________________________________________________________________
Core Laboratories (Colombia)
C.2
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Graphs of Constant Composition Expansion Data

Relative Volume vs. Pressure

1.005

1.000

0.995
Relative Volume, V/Vsat

0.990

0.985

0.980

0.975

0.970

0.965
500 1500 2500 3500 4500 5500 6500
Pressure (psig)

Y Function vs. Pressure

6.000

5.500

5.000
Relative Volume, V/Vsat

4.500

4.000

3.500

3.000

2.500

2.000

1.500
0 100 200 300 400 500 600
Pressure (psig)

________________________________________________________________________________________
Core Laboratories (Colombia)
C.3
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________

Section D - Differential Vaporization

________________________________________________________________________________________
Core Laboratories (Colombia)
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________
Differential Vaporisation at 205F

Solution Relative Relative Deviation Gas Incremental


Pressure Gas-Oil Oil Total Density Factor Formation Gas Gravity
(psig) Ratio Volume Volume (g cm-3) (Z) Volume (Air = 1.000)
Rs(1) Bod(2) Btd(3) Factor (4)

579 123 1.122 1.122 0.8836 Saturation Pressure


450 110 1.118 1.196 0.8841 0.870 0.03529 1.021
350 96 1.115 1.332 0.8842 0.900 0.04651 1.031
250 82 1.110 1.584 0.8852 0.930 0.06620 1.057
150 66 1.103 2.202 0.8873 0.959 0.10970 1.113
80 50 1.094 3.603 0.8909 0.979 0.19467 1.195
0 0 1.058 0.9013 1.859

At 60F = 1.000

Residual Oil Properties

Density of residual oil 0.9538 g cm-3 at 60F

API 16.7

(1) GOR in cubic feet of gas at 14.73 psia and 60F per barrel of residual oil at 60F.
(2) Volume of oil at indicated pressure and temperature per volume of residual oil at 60F.
(3) Volume of oil plus liberated gas at indicated pressure and temperature per volume of residual oil at 60F.
(4) Volume of gas at indicated pressure and temperature per volume at 14.73 psia and 60F.

________________________________________________________________________________________
Core Laboratories (Colombia)
D.1
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________
Graphs From Differential Vaporisation at 205F

Solution Gas-Oil Ratio v Pressure

140

120

100
Gas-Oil Ratio (scf / bbl)

80

60

40

20

0
0 100 200 300 400 500 600 700
Pressure (psig)

Relative Oil Volume v Pressure

1.140

1.120
Relative Oil Volume (V/Vr)

1.100

1.080

1.060

1.040

1.020

1.000
0 100 200 300 400 500 600 700
Pressure (psig)

________________________________________________________________________________________
Core Laboratories (Colombia)
D.2
Vetra Group FINAL REPORT
Cohembi-1 RFLA 1003241
________________________________________________________________________________________
Compositional Analysis of Differential Vaporisation Gases to C11+

Sample I.D.

Test Stage 1 2 3 4 5 6
Stage Pressure (psig) 450 350 250 150 80 0

Component (Mole%)

H2 Hydrogen 0.00 0.00 0.00 0.00 0.00 0.00


H2S Hydrogen Sulphide 0.00 0.00 0.00 0.00 0.00 0.00
CO2 Carbon Dioxide 1.39 1.64 1.41 2.22 2.47 1.16
N2 Nitrogen 7.83 6.68 2.90 5.49 0.60 0.21
C1 Methane 47.12 56.37 40.44 51.82 38.88 9.47
C2 Ethane 4.77 6.31 6.35 11.13 15.57 11.44
C3 Propane 20.54 15.08 26.92 15.56 22.27 28.56
iC4 i-Butane 2.93 2.05 3.76 2.06 3.26 5.73
nC4 n-Butane 5.96 4.56 7.59 5.17 8.43 16.82
C5 Neo-Pentane 0.07 0.04 0.08 0.02 0.02 0.35
iC5 i-Pentane 2.15 1.60 2.61 1.55 2.40 6.20
nC5 n-Pentane 2.11 1.58 2.48 1.50 2.28 6.40
C6 Hexanes 2.27 1.67 2.45 1.37 1.72 5.69
M-C-Pentane 0.26 0.22 0.29 0.25 0.37 1.37
Benzene 0.07 0.06 0.08 0.05 0.05 0.20
Cyclohexane 0.47 0.36 0.48 0.26 0.21 0.76
C7 Heptanes 0.83 0.68 0.88 0.58 0.58 2.36
M-C-Hexane 0.35 0.29 0.36 0.22 0.15 0.62
Toluene 0.14 0.12 0.14 0.08 0.07 0.14
C8 Octanes 0.43 0.40 0.46 0.34 0.55 1.17
E-Benzene 0.01 0.01 0.01 0.01 0.01 0.06
M/P-Xylene 0.05 0.04 0.05 0.04 0.00 0.05
O-Xylene 0.01 0.01 0.01 0.01 0.00 0.02
C9 Nonanes 0.18 0.17 0.19 0.18 0.09 0.52
1,2,4-TMB 0.00 0.00 0.00 0.00 0.00 0.02
C10 Decanes 0.06 0.06 0.06 0.07 0.02 0.27
C11+ Undecanes plus 0.00 0.00 0.00 0.02 0.00 0.41
_____ _____ _____ _____ _____ _____
Totals : 100.00 100.00 100.00 100.00 100.00 100.00

Calculated Gas Properties

Gas Gravity 1.172 1.043 1.282 1.063 1.235 1.856


(Air = 1.000)

Note: 0.00 means less than 0.005.

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Compositional Analysis of Differential Vaporisation Residual Oil to C36+

Component Mole % Weight %


H2 Hydrogen 0.00 0.00
H2S Hydrogen Sulphide 0.00 0.00
CO2 Carbon Dioxide 0.00 0.00
N2 Nitrogen 0.00 0.00
C1 Methane 0.00 0.00
C2 Ethane 0.01 0.00
C3 Propane 0.30 0.04
iC4 i-Butane 0.19 0.03
nC4 n-Butane 0.54 0.09
C5 Neo-Pentane 0.08 0.02
iC5 i-Pentane 0.89 0.18
nC5 n-Pentane 1.17 0.23
C6 Hexanes 2.08 0.49
M-C-Pentane 0.87 0.20
Benzene 0.15 0.03
Cyclohexane 0.32 0.08
C7 Heptanes 3.09 0.85
M-C-Hexane 1.10 0.30
Toluene 0.25 0.06
C8 Octanes 4.25 1.33
E-Benzene 0.53 0.16
M/P-Xylene 0.46 0.13
O-Xylene 0.30 0.09
C9 Nonanes 3.89 1.37
1,2,4-TMB 0.39 0.13
C10 Decanes 4.47 1.75
C11 Undecanes 4.39 1.77
C12 Dodecanes 3.53 1.56
C13 Tridecanes 4.16 2.00
C14 Tetradecanes 3.32 1.73
C15 Pentadecanes 3.24 1.83
C16 Hexadecanes 2.73 1.66
C17 Heptadecanes 2.20 1.43
C18 Octadecanes 2.45 1.69
C19 Nonadecanes 2.49 1.80
C20 Eicosanes 1.90 1.44
C21 Heneicosanes 1.76 1.41
C22 Docosanes 1.59 1.33
C23 Tricosanes 1.50 1.31
C24 Tetracosanes 1.40 1.27
C25 Pentacosanes 1.39 1.32
C26 Hexacosanes 1.19 1.17
C27 Heptacosanes 1.15 1.18
C28 Octacosanes 1.12 1.19
C29 Nonacosanes 1.22 1.35
C30 Triacontanes 1.09 1.24
C31 Hentriacontanes 1.08 1.27
C32 Dotriacontanes 0.93 1.13
C33 Tritriacontanes 0.88 1.11
C34 Tetratriacontanes 0.86 1.11
C35 Pentatriacontanes 0.77 1.03
C36+ Hexatriacontanes plus 26.33 57.11
_____ _____
Totals: 100.00 100.00
Note: 0.00 means < 0.005.

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Compositional Analysis of Differential Vaporisation Residual Oil to C36+

Calculated Residue Properties

C7+
Mole% 94.74
Molecular Weight (g mol-1) 380
Density at 60F (g cm-3) 0.9591

C11+
Mole% 74.67
Molecular Weight (g mol-1) 451
Density at 60F (g cm-3) 0.9804

C20+
Mole% 46.16
Molecular Weight (g mol-1) 608
Density at 60F (g cm-3) 1.0184

C36+
Mole % 26.33
Molecular Weight (g mol-1) 791
Density at 60F (g cm-3) 1.0717

Calculated Whole Sample Properties

Average mole weight (g mol-1) 364

Density at 60F (g cm-3) [Measured] 0.9538

API () 16.7

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Differential Vaporisation Data Converted to Production Separator Conditions

Oil Solution Formation Gas Formation


Pressure Density Gas/Oil Volume Volume
(psig) (g cm-3) (scf / bbl) Factor Factor
Rs(1) Bo(1) Bg(2)

6000 0.9120 1.064


5500 0.9097 1.067
5000 0.9073 1.069
4500 0.9048 1.072
4000 0.9023 1.075
3784 Reservoir pressure 0.9012 1.077
3500 0.8998 1.078
3000 0.8972 1.081
2500 0.8945 1.085
2000 0.8918 1.088
1500 0.8890 1.091
1000 0.8861 1.095
900 0.8855 1.096
800 0.8849 1.096
700 0.8843 1.097
600 0.8837 1.098
579 Saturation pressure 0.8836 68 1.098
450 0.8841 56 1.094 0.03529
350 0.8842 42 1.091 0.04651
250 0.8852 29 1.086 0.06620
150 0.8873 13 1.079 0.10970
80 0.8909 0 1.070 0.19467

Notes:

(1) Differential data corrected to surface separator conditions of :-

Stage 1 35 psig and 100F


Stage 2 0 psig and 60F

Rs = Rsfb - (Rsdb - Rsd) x (Bofb / Bodb)

Bo = Bod x (Bofb/Bodb)

(2) Volume of gas at indicated pressure and temperature per volume at 14.73 psia and 60F.

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Section E - Reservoir Fluid Viscosity Data

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Reservoir Fluid Viscosity Data at 205F


Cylinder 815667

Pressure Oil Calculated Oil/Gas


(psig) Viscosity Gas Viscosity Viscosity
(cP) (cP) (1) Ratio

6000 30.803
5000 27.621
4000 24.685
3784 Reservoir pressure 24.086
3000 22.031
2000 19.714
1000 17.832
579 Saturation pressure 17.211
450 17.752 0.0121 1,472.0
350 18.363 0.0122 1,506.3
250 19.184 0.0113 1,704.9
150 20.371 0.0117 1,734.1
0 33.724 0.0092 3,657.6

Reservoir Fluid Viscosity v Pressure at 205F

35.00

30.00

25.00
Viscosity (cP)

20.00

15.00

10.00
0 1000 2000 3000 4000 5000 6000 7000
Pressure (psig)

(1) Calculated using the method of Lee, Gonzales and Eakin, JPT, Aug 1966.

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Section F - Separator Test Data

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Separator Test 1 Data

Gas-Oil Gas-Oil Formation Separation


Ratio Ratio Oil Volume Volume Gas Gravity
Pressure Temperature Rs Rsfb Density Factor Factor of flashed gas
(psig) (F) (1) (2) (g cm-3) Bofb (3) (4) (Air = 1.000)

579 205 - 68 0.8756 1.098 Saturation Pressure

35 100 47 49 0.9023 1.052 0.882


0 74 18 18 0.9379 1.005 1.584
0 60 0 0 0.9430
(API = 18.4)
Total Rsfb = 68

Residual Oil Properties

Density of residual oil 0.9430 g cm-3 at 60F

Reminder: Delete / Amend above text if appropriate

Evolved gas collected and analysed to C11+.

*** Stocktank oil collected and analysed to C36+.

Note :

(1) GOR in cubic feet of gas at 14.73 psia and 60F per barrel of oil at indicated pressure and temperature.
(2) GOR in cubic feet of gas at 14.73 psia and 60F per barrel of stocktank oil at 60F.
(3) Volume of saturated oil at 579 psig and 205F per volume of stocktank oil at 60F.
(4) Volume of oil at indicated pressure and temperature per volume of stocktank oil at 60F.

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Compositional Analysis of Separator Test 1 Gases to C11+

Sample I.D.

Test Stage 1 Stocktank


Stage Pressure (psig) 35 0

Component (Mole%)
H2 Hydrogen 0.00 0.00
H2S Hydrogen Sulphide 0.00 0.00
CO2 Carbon Dioxide 2.44 1.54
N2 Nitrogen 4.64 2.04
C1 Methane 62.16 14.03
C2 Ethane 11.76 13.78
C3 Propane 12.58 32.09
iC4 i-Butane 1.49 6.17
nC4 n-Butane 3.19 16.80
C5 Neo-Pentane 0.01 0.06
iC5 i-Pentane 0.63 4.35
nC5 n-Pentane 0.51 4.23
C6 Hexanes 0.26 2.65
M-C-Pentane 0.06 0.54
Benzene 0.01 0.08
Cyclohexane 0.03 0.26
C7 Heptanes 0.10 0.73
M-C-Hexane 0.03 0.17
Toluene 0.01 0.04
C8 Octanes 0.05 0.26
E-Benzene 0.00 0.01
M/P-Xylene 0.00 0.01
O-Xylene 0.00 0.00
C9 Nonanes 0.03 0.10
1,2,4-TMB 0.00 0.00
C10 Decanes 0.01 0.04
C11+ Undecanes plus 0.00 0.02
_____ _____
Totals: 100.00 100.00

Calculated Gas Properties

Gas Gravity
(Air = 1.000) 0.882 1.584

Note: 0.00 means < 0.005.

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Section G - Appendix

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Data Used in Gas Compositional Calculations

Component Mole Weight Density Component Mole Weight Density


(g mol-1) (g cm-3 at 60F) (g mol-1) (g cm-3 at 60F)

Hydrogen * 2.016 N/A 33DMC5 * 100.20 0.6954


Oxygen/(Argon) ** 31.999 1.1410 Cyclohexane * 84.16 0.7827
Nitrogen (Corrected) ** 28.013 0.8086 2MC6/23DMC5 * 100.20 0.6917
Methane ** 16.043 0.2997 11DMCYC5/3MC6 * 99.20 0.7253
Carbon Dioxide ** 44.010 0.8172 t13DMCYC5 * 98.19 0.7528
Ethane ** 30.070 0.3558 c13DMCYC5/3EC5 * 99.20 0.7262
Hydrogen Sulphide ** 34.080 0.8006 t12DMCYC5 * 98.19 0.7554
Propane ** 44.097 0.5065 Heptanes (nC7) * 100.20 0.6875
i-Butane ** 58.123 0.5623 22DMC6 * 114.23 0.6994
n-Butane ** 58.123 0.5834 MCYC6 * 98.19 0.7740
Neo-Pentane * 72.15 0.5968 ECYC5 * 98.19 0.7704
i-Pentane ** 72.150 0.6238 223TMC5/24&25DMC6 * 114.23 0.7060
n-Pentane ** 72.150 0.6305 ctc124TMCYC5 * 112.21 0.7511
22DMC4 * 86.18 0.6529 ctc123TMCYC5 * 112.21 0.7574
23DMC4/CYC5 * 78.16 0.7129 Toluene * 92.14 0.8734
2MC5 * 86.18 0.6572 Octanes (nC8) * 114.23 0.7063
3MC5 * 86.18 0.6682 E-Benzene * 106.17 0.8735
Hexanes (nC6) * 86.18 0.6631 M/P-Xylene * 106.17 0.8671
22DMC5 * 100.20 0.6814 O-Xylene * 106.17 0.8840
M-C-Pentane * 84.16 0.7533 Nonanes (nC9) * 128.26 0.7212
24DMC5 * 100.20 0.6757 Decanes *** 134 0.778
223TMC4 * 100.20 0.6947 Undecanes *** 147 0.789
Benzene * 78.11 0.8820 Dodecanes *** 161 0.800

Data Source Refs :

* ASTM Data Series Publication DS 4B (1991) - Physical Constants of Hydrocarbon and Non-Hydrocarbon
Compounds.

** GPA Table of Physical Constants of Paraffin Hydrocarbons and Other Components of Natural Gas,
GPA 2145-96.

*** Journal of Petroleum Technology, Nov 1978, Pages 1649-1655.


Predicting Phase Behaviour of Condensate/Crude Oil Systems Using Methane Interaction Coefficients
- D.L. Katz & A. Firoozabadi.

Note :
The gas mole % compositions were calculated from the measured weight % compositions using the most detailed analysis results,
involving as many of the above components as were identified. The reported component mole % compositions were then sub-grouped
into the generic carbon number components.

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Data Used in Liquid Compositional Calculations

Component Mole Weight Density Component Mole Weight Density


(g mol-1) (g cm-3 at 60F) (g mol-1) (g cm-3 at 60F)

Hydrogen * 2.016 N/A Undecanes *** 147 0.789


Hyd. sulphide ** 34.080 0.8006 Dodecanes *** 161 0.800
Carbon Dioxide ** 44.010 0.8172 Tridecanes *** 175 0.811
Nitrogen ** 28.013 0.8086 Tetradecanes *** 190 0.822
Methane ** 16.043 0.2997 Pentadecanes *** 206 0.832
Ethane ** 30.070 0.3558 Hexadecanes *** 222 0.839
Propane ** 44.097 0.5065 Heptadecanes *** 237 0.847
i-Butane ** 58.123 0.5623 Octadecanes *** 251 0.852
n-Butane ** 58.123 0.5834 Nonadecanes *** 263 0.857
i-Pentane ** 72.150 0.6238 Eicosanes *** 275 0.862
n-Pentane ** 72.150 0.6305 Heneicosanes *** 291 0.867
Hexanes ** 86.177 0.6634 Docosanes *** 305 0.872
Me-cyclo-pentane * 84.16 0.7533 Tricosanes *** 318 0.877
Benzene 78.11 0.8820 Tetracosanes *** 331 0.881
Cyclo-hexane * 84.16 0.7827 Pentacosanes *** 345 0.885
Heptanes ** 100.204 0.6874 Hexacosanes *** 359 0.889
Me-cyclo-hexane * 98.19 0.7740 Heptacosanes *** 374 0.893
Toluene * 92.14 0.8734 Octacosanes *** 388 0.896
Octanes ** 114.231 0.7061 Nonacosanes *** 402 0.899
Ethyl-benzene * 106.17 0.8735 Triacontanes *** 416 0.902
Meta/Para-xylene * 106.17 0.8671 Hentriacontanes *** 430 0.906
Ortho-xylene * 106.17 0.8840 Dotriacontanes *** 444 0.909
Nonanes ** 128.258 0.7212 Tritriacontanes *** 458 0.912
1-2-4-T-M-benzene * 120.19 0.8797 Tetratriacontanes *** 472 0.914
Decanes ** 142.285 0.7334 Pentatriacontanes *** 486 0.917

Data Source Refs :

* ASTM Data Series Publication DS 4B (1991) - Physical Constants of Hydrocarbon and Non-Hydrocarbon
Compounds.

** GPA Table of Physical Constants of Paraffin Hydrocarbons and Other Components of Natural Gas
GPA 2145-96.

*** Journal of Petroleum Technology, Nov 1978, Pages 1649-1655.


Predicting Phase Behaviour of Condensate/Crude Oil Systems Using Methane Interaction Coefficients
- D.L. Katz & A. Firoozabadi.

Note :
The residue mole weight and density values ( eg heptanes plus, undecanes plus, eicosanes plus) are calculated so that the calculated
average mole weights and densities correspond with the measured values. This can lead to anomalous residue mole weights and
densities where the Katz and Firoozabadi values may not be suitable for the isomer groups detected.

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Report prepared by Report approved by

Jeffrey Thomasson Jeffrey Thomasson


Reservoir Fluids Manager Colombia Reservoir Fluids Manager Colombia

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