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EU-Safety Data Sheets relating 91/155/EEC number: 128-301

Home Nr.: 128-301 Revised at: 01.2010


Name in Cmrce. Electrolytic polishing solution A for Cr+Co

Version: 1.3 Class of: 01.2010


Product no.: 128-301-00, 128-401-00
Code:

01. Identification of the Substance and of the Company

Product Definition
Name in Cmrce.: Electrolytic polishing solution A for Cr+Co
Product-Infos: Electrolytic polishing solution
Manufacturer: DENTAURUM GmbH & Co. KG
Turnstrae 31 D-75228 Ispringen

Information from
Chemie
Emergency-Info: 07231-803-184/190

02. Composition/Information on Ingredients

Chemical Nature:
Ethanediol, sulfuric acid < 10%

Dangerous Contents:

CAS number/Description: Concentration: GS: R Phrases:


107-21-1 1,2-Ethanediol > 90% Xn 22
7664-93-9 sulfuric acid < 10% C 35

03. Hazards Identification

22 Harmful if swallowed.
36/38 Irritating to eyes and skin.

04. First-Aid Measures

- First aid measures / general information


Remove contaminated soaked clothing immediately and dispose of safely.
- First aid measures / inhalation
Ensure supply of fresh air.
In the event of symptoms refer for medical treatment.
- First aid measures / skin contact
In case of contact with skin wash off immediately with soap and water
Consult a doctor if skin irritation persists.
- First aid measures / eye contact
In case of contact with eyes rinse thoroughly with plenty of water and seek medical
advice
- First aid measures / ingestion
Do not induce vomiting.
Summon a doctor immediately.
Rinse out mouth and give plenty of water to drink.

Printing date: 12.08.2010 page: 1


EU-Safety Data Sheets relating 91/155/EEC number: 128-301

05. Fire-fighting Measures

- Suitable extinguishing media


dry powder
carbon dioxide
water spray jet
- Extinguishing media that must not be used for safety reasons
Full water jet
- Special protective equipment for firefighters
Use breathing apparatus.
- Additional informations (5.5)
Cool containers at risk with water spray jet.

06. Accidental Release Measures

- personal precautions
Use personal protective clothing.
- environmental precautions
Do not discharge into the drains/surface waters/groundwater.
- methods for cleaning up/taking up
Take up with absorbent material (e.g. kieselguhr).
Dispose of absorbed material in accordance with the regulations.

07. Handling and Storage

- Requirements for storage rooms and vessels


Do not use zinc containers.
- Advice on storage compatibilty
Do not store together with oxidizing agents.
- Further information on storage conditions
Store in a dry place.
Keep in a cool place.

08. Exposure Controls/Personal Protection

- Hand protection
Gloves (acid-resistant)
- Eye protection
goggles
- General protective measures
Do not inhale vapours
Avoid contact with skin
- Hygiene measures
Remove soiled or soaked clothing immediately.
After work-time and during work intervals the affected skin areas must be thoroughly
cleaned.
Keep away from food and drink.

Ingredients relating to Workplace-Limits to get supervised

CAS number/Description: Concentration: Typ: Value:


107-21-1 1,2-Ethanediol - MAK 26,000 mg/m3
10,000 ml/m3

Printing date: 12.08.2010 page: 2


EU-Safety Data Sheets relating 91/155/EEC number: 128-301

09. Physical and chemical Properties

- Form
Liquid
- Colour
colourless
- Odour
characteristic
- pH-value / remark: 20C/ 3-4
- Changes in physical state 2, liquid - gaseous and others
Boiling range: 190-200C
- Flash point / remarks: > 120C
- Lower explosion limit / remarks: 3 Vol.%
- Vapour pressure at T1 / remarks: 20C/ > 0,1 mbar
- Density / remarks: 20C/ 1,2 g/ml
- Solubility in water / remarks
miscible

10. Stability and Reactivity

- Hazardous reactions
Reactions with oxidising agents.
Spontaneous reactions with alkali metals.
Reactions with earth alkali metals.
Reactions with alkalies.

11. Toxicological Information

- Acute oral toxicity / LD50


- Acute oral toxicity / species
rat: 4700 mg/kg
- Experiences made in practice
Can be absorbed through the skin.
Irritates the eyes and the skin.
- General remarks
The toxicological data are those of the pure product.

12. Ecological Information

- General information / ecology


Do not allow to enter soil, waterways or waste water

13. Disposal Considerations

- Disposal / product
For recycling, consult manufacturer
Waste code no. (only EC): 110105

Printing date: 12.08.2010 page: 3


EU-Safety Data Sheets relating 91/155/EEC number: 128-301

14. Transport Information

- UN 3265
- Land transport / lorry / international / remarks
3265 Corrosive liquid, acidic, organic, n.o.s. (containing sulphuric acid)
- Marine transport / remarks
Corrosive liquid, acidic, organic, n.o.s. (containing sulphuric acid)
- Air transport / remarks
Proper shipping name:
Corrosive liquid, acidic, organic, n.o.s. (containing sulphuric acid)

GGVS/E-Class: 8, III AS-No.: 110105


3265 ADR/RID-Class: 8, III
ADNR-class: Category:
IMDG/GGVSee-Cl/Digit: 8 EmS: F-A, S-B
MFAG: 760 ICAO/IATA: 8
PG: III

15. Regulatory Information

- Labelling
The product is classified and labelled in accordance with EC directives/German
regulations on dangerous substances.
Hazard symbols
Xn Harmful
R phrases
22 Harmful if swallowed.
36/38 Irritating to eyes and skin.
S phrases
1/2 Keep locked up. Keep out of the reach of children.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
Water hazard class / remarks
Weakly water hazardous WGK 1

Harmfull

16. Other Information

The information contained herein is based on the present state of our knowledge. It
characterizes the product with regard to the appropriate safety precautions. It does not
represent a guarantee of the properties of the product.

Printing date: 12.08.2010 page: 4

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