Beruflich Dokumente
Kultur Dokumente
5900470521
CHEM ENG THERMODYNAMICS
PROBLEM 2
975
Using equation A =
18.4 + 3 ln . Guessing T and input to equation until we get A=2
T A
215 2,247
225 2,182
235 2,128
245 2,083 Using interpolation
255 2,047
265 2,018
273 2,000 UCST, A = 2
275 1,996
285 1,979
295 1,966
305 1,958
315 1,953
325 1,951
335 1,953
345 1,957
355 1,963
365 1,971 Using interpolation
375 1,981
385 1,992
391,15 2,000 LCST, A = 2
395 2,005
405 2,019
415 2,034
425 2,050
435 2,067
445 2,085
For UCST
T A1 X1 A2 X2
200 2,370 0,820 2,370 0,180
203 2,343 0,811 2,343 0,189
206 2,317 0,802 2,317 0,198
209 2,292 0,793 2,292 0,207
212 2,269 0,784 2,269 0,216
215 2,247 0,774 2,247 0,226
218 2,226 0,765 2,226 0,235
221 2,206 0,755 2,206 0,245
224 2,188 0,745 2,188 0,255
227 2,170 0,735 2,170 0,265
230 2,153 0,724 2,153 0,276
233 2,138 0,714 2,138 0,286
236 2,123 0,704 2,123 0,296
239 2,109 0,693 2,109 0,307
242 2,096 0,682 2,096 0,318
245 2,083 0,670 2,083 0,330
248 2,072 0,659 2,072 0,341
251 2,061 0,647 2,061 0,353
254 2,051 0,635 2,051 0,365
257 2,041 0,622 2,041 0,378
260 2,032 0,608 2,032 0,392
263 2,024 0,594 2,024 0,406
266 2,016 0,577 2,016 0,423
269 2,009 0,558 2,009 0,442
272 2,002 0,527 2,002 0,473
273 2,000 0,500 2,000 0,500
For LCST
T A1 X1 A2 X2
391,150 2,000 0,500 2,000 0,500
392 2,001 0,519 2,001 0,481
395 2,005 0,543 2,005 0,457
398 2,009 0,558 2,009 0,442
401 2,013 0,569 2,013 0,431
404 2,018 0,581 2,018 0,419
407 2,022 0,590 2,022 0,410
410 2,027 0,599 2,027 0,401
413 2,031 0,606 2,031 0,394
416 2,036 0,614 2,036 0,386
419 2,041 0,622 2,041 0,378
422 2,045 0,627 2,045 0,373
425 2,050 0,634 2,050 0,366
428 2,055 0,640 2,055 0,360
431 2,061 0,647 2,061 0,353
434 2,066 0,653 2,066 0,347
437 2,071 0,658 2,071 0,342
440 2,076 0,663 2,076 0,337
443 2,082 0,669 2,082 0,331
446 2,087 0,674 2,087 0,326
449 2,093 0,679 2,093 0,321
452 2,098 0,684 2,098 0,316
455 2,104 0,689 2,104 0,311
458 2,109 0,693 2,109 0,307
461 2,115 0,698 2,115 0,302
So, the graph will be
UCST
290
270
250
230
210
190
170
150
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700 0.800 0.900
LCST
470.000
460.000
450.000
440.000
430.000
420.000
410.000
400.000
390.000
380.000
0.200 0.300 0.400 0.500 0.600 0.700
UCST AND LCST
500
450
400
350
300
250
200
150
100
50
0
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700 0.800 0.900
Problem 4
Guess T => Until we get P=1600
5363.7
P1sat exp 19.1478
T
2048.97
P 2 sat exp 14.6511
T
T P1sat P2sat P y*
273 0,606863 1268,659 1269,265 0,000478
274 0,651976 1303,89 1304,542 0,0005
275 0,700078 1339,833 1340,533 0,000522
276 0,751341 1376,495 1377,246 0,000546
277 0,805947 1413,885 1414,691 0,00057
278 0,864084 1452,01 1452,874 0,000595
279 0,925954 1490,88 1491,805 0,000621
280 0,991763 1530,5 1531,492 0,000648
281 1,06173 1570,881 1571,943 0,000675
281,5 1,098344 1591,359 1592,457 0,00069
281,6 1,105801 1595,477 1596,583 0,000693
281,65 1,109546 1597,539 1598,649 0,000694
281,68 1,111799 1598,778 1599,889 0,000695
281,685 1,112175 1598,984 1600,10 0,000695
281,683 1,112025 1598,901 1600,014 0,000695
P1sat
y1
P
P 2sat
y2 1
P
281.71
281.705
Temperature
281.7
281.695
281.69
281.685
281.68
69.4800 69.5000 69.5200 69.5400 69.5600 69.5800 69.6000 69.6200 69.6400
y1 x 10^5
281.71
281.705
Temperature
281.7
281.695
281.69
281.685
281.68
0.0000 10.0000 20.0000 30.0000 40.0000 50.0000 60.0000 70.0000 80.0000
y2 x 10^5
281.71
281.705
Temperature
281.7
281.695
281.69
281.685
281.68
0.0000 10.0000 20.0000 30.0000 40.0000 50.0000 60.0000 70.0000 80.0000
y1 x 10^5
y2 x 10^5