REACTION MASS AND ENERGY BALANCES OF SODIUM DISILICATE SYNTESYS FROM SILICA AND SODA

REACTION MEAN TIME 4 h

MEAN RATE OF REACTION HEAT RELEASE -256,203 Kcal/h
TOTAL HEAT RELEASED -1,024,812 KCal
REACTION TEMPERATURE 200 C 473.15 K
THERMODINAMIC EQUILIBRIUM CONSTANT 1.413E+13
2.NaOH+2.SiO2-------->1.Na2Si2O5+1.H2O; DH=-28467 Kcal/Kmol
COMPOUNDS
VARIABLES SYMBOL UNITS NaOH SiO2 Na2Si2O5 H2O TOTAL / MEAN
STEQUIOMETRIC COEFICIENTS sc [] -2 -2 1 1 -2
HEATS OF FORMATION Hf Kca//Kmol -112193 -203350 -591236 -68317 -28467
MOLECULAR WEIGHT MW Kg/Kmol 40 60 182 18
STEQUIOMETRIC WEIGHT PROPORTIONS mw Kg 80 120 182 18
FINAL MIX COMPOUNDS MOLES nf Kmol 1 25 36 199 261
FINAL MIX COMPOUNDS MASSES mf Kg 50 1480 6552 3578 11660
FINAL MIX COMPOUNDS MASS FRACTION xfm Kg/Kg 0% 13% 56% 31% 100%
FINAL COMPOUNDS MOLAR FRACTION xfn Kmol/Kmol 0% 9% 14% 76% 100%
STECHIOMETRIC ACTIVITIS xfn^sc [] 4.350E+04 1.117E+02 1.381E-01 7.625E-01 5.116E+05
INICIAL MIX COMPOUNDS MOLES nx Kmol 73 97 0 163 333
INICIAL MIX COMPOUNDS MASSES mx Kg 2930 5800 0 2930 11660
INICIAL MIX COMPOUNDS MASS FRACTION xx Kg/Kg 25% 50% 0% 25% 100%
INICIAL INDIVIDUAL COMPOUNDS MOLES ni Kmol 147 97 0 0 243
INICIAL INDIVIDUAL COMPOUNDS MASSES mi Kg 5860 5800 0 0 11660
INICIAL INDIVIDUAL COMPOUNDS WATER DILUITION di Kg/Kg 50% 100% 100% 100%
FRACIONAL CONVERSION fcv [] 98% 74% 100% 18%
REACTION EXTENSION ext [] 36