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SI Units
temperature: C
amount: g-mol
Please read cell comments
AFT-Calc
mass: g
energy: J An Adiabatic Flame Temperature Calculator for E
Combustion of Natural Gas
Please read Calculations based on combustion of 1 gram-mole of fue
this document.
Document

Fuel
Burner Flame:
CO2, H2O, O2, N2
Oxidant

Enter/Edit values in blue-bordered cells only! Heat loss, J


Like these

Natural Gas/Fuel Properties Oxidant Properties


Species mol % % O2 in Oxidant
Methane CH4 96.40% Upper limit on % excess oxidant
Ethene C2H4 0.15% Oxidant temperature, C
Ethane C2H6 0.30% Stoichiometric amount of oxidant
Propane C3H8 0.25%
Butanes & higher C4H10 + 0.10% Fuel temperature, C
Hydrogen H2 0.20% Element Balance of Fuel
Carbon monoxide CO 0.15% Element moles mass
Carbon dioxide CO2 0.20% C 0.988 11.866
Water vapor H2O 0.00% H 3.914 3.945
Nitrogen (by diff.) N2 2.25% O 0.006 0.088
N 0.045 0.630
Graphite C 0.0% Sum 4.953 16.529

Thermodynamic Data
Table I. Molar DHform at 25 C Table II. Molar DHreax at 25 C
J/g-mol Reaction to form H2O(g)
CH4 -74,810 2O2 + CH4 CO2 + 2H2O(g)
C2H4 52,467 3O2 + C2H4 2CO2 + 2H2O(g)
C2H6 -84,684 3O2 + C2H6 2CO2 + 3H2O(g)
NG reactant species C3H8 -103,847 5O2 + C3H8 3CO2 + 4H2O(g)
C4H10 -126,148 6O2 + C4H10 4CO2 + 5H2O(g)
H2 0 O2 + H2 H2O(g)
CO -110,529 O2 + CO CO2

Combustion CO2 -393,509 C + O2 CO2


products H2O(g) -241,814
H2O(liq) -285,830 H2O(g) H2O(liq)

Table III. Heat Content Above 25 C, J/g-mol


T, C O2, (g) N2, (g) H2O, (g) CO2, (g)
1000 32371 30595 37719 48624
Heat Conten

heat content, J/mol


1100 35977 34009 42222 54347
1200 39614 37460 46831 60136 110,000
1300 43278 40944 51541 65982 f(x) = 0.0020055915x^2 + 53.43
1400 46967 44457 56347 71877 100,000
1500 50680 47998 61243 77817
1600 54416 51563 66223 83795 90,000
1700 58174 55150 71282 89808 f(x) = 0.0042038585x^2 + 36.60
1800 61954 58756 76414 95851 80,000
2000 69576 66017 86872 108015
70,000
f(x) = 0.0011726951x^2 + 33.69
Data from FREED database program. f(x) = 0.0012285294x^2 + 31.76
Excel's Trendline tool used to fit data to quadratic equation. 60,000
Chart equations valid between 900 - 2100 C.
50,000

40,000

30,000
1000 1200 1
Calc AFT-Calc is a Thermart
Software program. 2013
by Arthur E. Morris.
ure Calculator for Excess Air www.thermart.net
f Natural Gas
stion of 1 gram-mole of fuel

AFT vs. % Excess Oxidant


2200
f(x) = -308.5138154314 ln(x) + 1258.7164407551
2100 R = 0.9702695844

2000 f(x) = 454.0145766696x^2 - 1283.9126915922x + 2042.2631557013

1900
0
1800
AFT, deg. C

1700

Oxidant Properties 1600


21% 1500
100% 1400
25
1300
9.351
1200
0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100%
25
% excess oxidant

Figure 1. Relationship between the AFT and the % excess oxidant used for combustion.
Chart and table will reconfigure when any blue-cell entry value is changed.
Excel's Trendline tool can be used to give a quadratic equation fit to the results. For x, use %/100.

Summary of Results
% XS oxidant 0.0% 10.0% 20.0% 40.0% 60.0% 80.0% 100%
AFT, C 2051 1914 1795 1598 1441 1313 1207

AFT-Calc Operation
The Calculator has two main worksheets, plus one for stored results. Enter data only on
J/g-mol
this worksheet, in blue-bordered cells only. Data will be copied into the Calcs worksheet
-802,327
Figure 1 summarizes the results. The chart legend shows a quadratic Trendline fit.
-1,323,113
The calculator contains a sample system. Changing any blue-bordered cell value will result in recalculatio
-1,427,776
of all other dependent values. Please read cell comments (cells with red corner), and the document.
-2,043,936
-2,656,958 1. Enter the fuel composition in column E, making sure that the value in cell F29 is non-negative. Th
%C (E31) should be 0% (or 100% for graphite combustion).
-241,814 2. Enter the oxidant properties in range K19:K21 and the heat loss in cell K16. Enter 0 for an
adiabatic calculation. The oxidant temperature range should be between 0 - 100C.
3. Enter the fuel temperature in cell K24, in the range should be between 0 - 100C.
4. Enter the upper limit on the range of calculations of % excess air in cell K20. Seven values will be
used in the % available heat calculation, starting at stoichiometric oxidant (0% excess).
5. A complete summary of the available heat results are shown on worksheet Calcs.
of all other dependent values. Please read cell comments (cells with red corner), and the document.

1. Enter the fuel composition in column E, making sure that the value in cell F29 is non-negative. Th
%C (E31) should be 0% (or 100% for graphite combustion).
2. Enter the oxidant properties in range K19:K21 and the heat loss in cell K16. Enter 0 for an
-282,980 adiabatic calculation. The oxidant temperature range should be between 0 - 100C.
3. Enter the fuel temperature in cell K24, in the range should be between 0 - 100C.
4. Enter the upper limit on the range of calculations of % excess air in cell K20. Seven values will be
-393,510 used in the % available heat calculation, starting at stoichiometric oxidant (0% excess).
5. A complete summary of the available heat results are shown on worksheet Calcs.
-44,020 6. If desired, you can copy results for several different fuels or oxidant properties to worksheet
StoredResults, and chart them. This worksheet has results for pure methane combustion for the
conditions noted in the IH article, plus a chart for other species.
7. Please read the cell comments and documents.

Heat Content of Offgas Species Above 25C


000
f(x) = 0.0020055915x^2 + 53.4328621367x - 6847.3387411164
000

000
f(x) = 0.0042038585x^2 + 36.6052926736x - 3123.5631055861
000

000
f(x) = 0.0011726951x^2 + 33.6999325847x - 2509.1194199172
f(x) = 0.0012285294x^2 + 31.7667882685x - 2417.0153732532
000

000 O2, (g)


Polynomial
000 (O2, (g))
N2, (g)
000
1000 1200 1400 1600 1800 2000
temperature, deg. C
1557013

80% 90% 100%

combustion.

ults. For x, use %/100.

sults. Enter data only on


nto the Calcs worksheet.
quadratic Trendline fit.
alue will result in recalculation
orner), and the document.

ell F29 is non-negative. The

K16. Enter 0 for an


0 - 100C.
0 - 100C.
K20. Seven values will be
(0% excess).
eet Calcs.
orner), and the document.

ell F29 is non-negative. The

K16. Enter 0 for an


0 - 100C.
0 - 100C.
K20. Seven values will be
(0% excess).
eet Calcs.
perties to worksheet
ne combustion for the
Please read cell comments

Calculator created Fuel


Flame:
by Burner
CO2, H2O, O2, N2
A. E. Morris
Thermart Software Oxidant
www.thermart.net

Legend
Do not edit/enter values in any cells!
Values Entered on MainEntry Vol. % O2 in ox
Natural Gas/Fuel Properties
Species Cp Mol. mass Vol % Mass, g Mass % DHcomb
Methane CH4 36 16.04 96.40% 15.47 93.56% -773,443
Ethene C2H4 43 28.05 0.15% 0.04 0.25% -1,985
Ethane C2H6 54 30.07 0.30% 0.09 0.55% -4,283 Stoichiometric oxid
Propane C3H8 75 44.10 0.25% 0.11 0.67% -5,110
Butanes & higher C4H10 + 103 58.12 0.10% 0.06 0.35% -2,657
Hydrogen H2 29 2.02 0.20% 0.00 0.02% -484
Carbon monoxide CO 30 28.01 0.15% 0.04 0.25% -424
Carbon dioxide CO2 38 44.01 0.20% 0.09 0.53% 0
Water vapor H2O 33.6 18.02 0.00% 0.00 0.00% 0
Nitrogen (by diff.) N2 29.1 28.01 2.25% 0.63 3.81% 0
Graphite C 10 12.01 0.00% 0.00 0.00% 0
O2 29.4 32.00 ---
DHcomb of Fuel, kJ/g-mol -788,386
Molecular mass of NG 16.53

moles mass
CO2 produced by combustion 0.986 43.39
H2O produced by combustion 1.957 35.26
Stoich. O2 required for combustion 1.965 62.86 Composition,

Table IV. Heat content eq'n. parameters, J/g-mol = A + BT + CT2


N2, 900 - 2100C O2, 900 - 2100C
A B C A B C
-2420 31.77 1.229E-03 -2510 33.70 1.173E-03

H2O(g), 900 - 2100C CO2, 900 - 2100C


A B C A B C
-3120 36.61 4.204E-03 -6850 53.43 2.006E-03
AFT Heat loss, J 0
Oxidant temperature, C 25
Fuel temperature, C 25
Calculational Strategy 3
1
2 1
1 1
1 1 at 25C 2
DHcomb
1 2 1
2 1. Bring reactants
Step 1 to 25C.
1 2. Burn fuel at 25C. Cell I20
Step Values for Quadratic Formula
Step 3. Heat products to AFT.
Step 4. Sum of all heats = 0. M47:S47 HT-H25 for oxidant & fuel
S(HT-H25 of reactants + HT-H25 of products + Hloss + DHcomb) = 0
Step 5. Calculate AFT using quadratic formula (M52:S52).
Quadratic Formula based on: aX2 + bX + c = 0

b b 4ac
X
2a
Flame:
CO2, H2O, O2, N2

in any cells! Material Balance Calculations


Vol. % O2 in oxidant gas 21.00%
% XS oxidant 0.0% 10.0% 20.0% 40.0% 60.0% 80.0% 100%

Combustion products 2.968


Stoichiometric oxidant 9.35
Stoichiometric oxidant inerts 7.39
Oxidant gas required 9.35 10.29 11.22 13.09 14.96 16.83 18.70
Excess oxidant 0.00 0.94 1.87 3.74 5.61 7.48 9.35
%O2 in offgas 0.00% 1.74% 3.21% 5.57% 7.38% 8.81% 9.97%
Offgas amount 10.355 11.290 12.225 14.095 15.966 17.836 19.706
Dry stack gas amount 8.398 9.333 10.268 12.138 14.009 15.879 17.749
%O2 in dry offgas 0.00% 2.10% 3.82% 6.47% 8.41% 9.89% 11.06%
Oxidant mass 269.79 296.77 323.75 377.71 431.67 485.63 539.58
Oxidant/Fuel mass ratio 16.32 17.95 19.59 22.85 26.11 29.38 32.64

Offgas H2O 2.0 2.0 2.0 2.0 2.0 2.0 2.0


Amount, Offgas CO2 1.0 1.0 1.0 1.0 1.0 1.0 1.0
g-mol Offgas N2 7.41 8.15 8.89 10.36 11.84 13.32 14.80
Offgas O2 0.00 0.20 0.39 0.79 1.18 1.57 1.96

Offgas H2O 18.9% 17.3% 16.0% 13.9% 12.3% 11.0% 9.9%


Composition, Offgas CO2 9.5% 8.8% 8.1% 7.0% 6.2% 5.5% 5.0%
vol. % Offgas N2 71.6% 72.2% 72.7% 73.5% 74.2% 74.7% 75.1%
Offgas O2 0.0% 1.7% 3.2% 5.6% 7.4% 8.8% 10.0%

Heat Balance Calculations


% XS oxidant 0.0% 10.0% 20.0% 40.0% 60.0% 80.0% 100.0%
A -6106 -6106 -6106 -6106 -6106 -6106 -6106
Offgas H2O B 71.65 71.65 71.65 71.65 71.65 71.65 71.65
C 8.227E-03 8.227E-03 8.227E-03 8.227E-03 8.227E-03 8.227E-03 8.227E-03
A -6768 -6768 -6768 -6768 -6768 -6768 -6768
Offgas CO2 B 52.79 52.79 52.79 52.79 52.79 52.79 52.79
C 1.982E-03 1.982E-03 1.982E-03 1.982E-03 1.982E-03 1.982E-03 1.982E-03
A -17932 -19720 -21508 -25083 -28659 -32234 -35810
Offgas N2 B 235.41 258.88 282.35 329.29 376.23 423.17 470.11
C 9.107E-03 1.001E-02 1.092E-02 1.274E-02 1.455E-02 1.637E-02 1.819E-02
A 0 -493 -986 -1972 -2957 -3943 -4929
Offgas O2 B 0 6.62 13.24 26.47 39.71 52.94 66.18
C 0 2.303E-04 4.607E-04 9.214E-04 1.382E-03 1.843E-03 2.303E-03

c -819192 -821472 -823753 -828314 -832876 -837437 -841998


es for Quadratic Formula b 359.85 389.94 420.02 480.20 540.37 600.55 660.73
a 0 2.045E-02 2.159E-02 2.387E-02 2.615E-02 2.842E-02 3.070E-02
HT-H25 for oxidant & fuel 0 0 0 0 0 0 0

AFT 2051 1914 1795 1598 1441 1313 1207


Vol. % O2 in oxidant gas 21.00%
Desired %O2 in comb. flame 0.00% 1.25% 2.50%

Combustion products 2.968 Calculator


Stoichiometric oxidant 9.35 #1
Stoichiometric oxidant inerts 7.39
Excess oxidant 0.00 0.66 1.40
% stoichiometric oxidant gas 100.0% 107.0% 115.0%
% excess oxidant gas 0.00% 7.01% 14.96%
Required oxidant 9.35 10.01 10.75
Combustion water 1.957
Stack gas volume 10.355 11.010 11.754
Dry stack gas volume 8.398 9.053 9.797
%O2 in dry stack gas 0.00% 1.52% 3.00%

Oxidant mass #REF! 280.30 301.14


Ox/NG mass ratio #REF! #REF! #REF!
3.75% 5.00%

Calculator
#1

2.25 3.24
124.1% 134.6%
24.07% 34.60%
11.60 12.59

12.606 13.591
10.649 11.634
4.44% 5.84%

325.00 352.59
#REF! #REF!
Results of Sample Calculations

AFT vs. % Excess Oxidant for CH4 Combustion


2200 WordPad
Document
2100

2000 f(x) = 454.6899588877x^2 - 1284.6932480283x + 2052.2071579021

1900

1800
AFT, deg. C

1700

1600

1500

1400

1300

1200
0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100%
% excess oxidant
Figure 1. Relationship between the AFT and % excess oxidant for article example.
As noted in article text, AFT = 1608C with 40% excess oxygen. Air enters at 38C and methane at 20C.
Excel's Trendline tool can be used to give a quadratic equation fit to the results. For x, use %/100.

Summary of Results--Methane Text Example


% XS oxidant 0.0% 10.0% 20.0% 40.0% 60.0% 80.0% 100%
AFT, C 2061 1924 1805 1608 1451 1323 1217

Theoretical vs. Equilibrium AFT


2200

2100 Theo
rC
2000 Theo
rCH4
1900

1800
AFT, deg. C

1700

1600

1500

1400
AFT, deg.
1700

1600

1500

1400

1300

1200
0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100%
% excess oxidant

Figure 3. Comparison between theoretical (solid lines) and equilibrium (dashed lines) AFT for combustion
Notice the increasing deviation between the two versions above about 1650C.
The difference is caused by increasing thermal disproportion of H 2O and CO2 at elevated temperatures (se

Summary of Results--Methane
% XS oxidant 0.0% 10.0% 20.0% 30.0% 40.0% 50.0% 60.0%
AFT, C 1954 1872 1772 1676 1588 1508 1436
CO 0.911% 0.265% 0.087% 0.030% 0.011% 0.004% 0.002%
CO2 8.5% 8.4% 7.9% 7.4% 7.0% 6.5% 6.2%
N 0.000% 0.000% 0.000% 0.000% 0.000% 0.000% 0.000%
N2 70.9% 71.8% 72.4% 72.9% 73.3% 73.7% 74.0%
N2O 0.000% 0.000% 0.000% 0.000% 0.000% 0.000% 0.000%
NO 0.199% 0.319% 0.336% 0.308% 0.267% 0.224% 0.185%
O 0.021% 0.024% 0.016% 0.009% 0.005% 0.003% 0.001%
O2 0.5% 1.7% 3.0% 4.3% 5.4% 6.4% 7.3%
H2 0.368% 0.107% 0.037% 0.014% 0.006% 0.002% 0.001%
H2O 18.4% 17.1% 15.9% 14.9% 13.9% 13.1% 12.3%
OH 0.294% 0.282% 0.202% 0.133% 0.085% 0.053% 0.034%

Summary of Results--Graphite
% XS oxidant 0% 10% 20% 30% 40% 50% 60%
AFT, C 2027 1952 1852 1748 1651 1562 1482
CO 2.23% 0.889% 0.326% 0.116% 0.042% 0.016% 0.006%
CO2 18.5% 18.1% 17.1% 16.0% 15.0% 14.0% 13.1%
N 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
N2 77.9% 78.4% 78.6% 78.7% 78.8% 78.8% 78.9%
N2O 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
NO 0.35% 0.45% 0.45% 0.41% 0.35% 0.29% 0.23%
O 0.047% 0.046% 0.030% 0.017% 0.009% 0.004% 0.002%
O2 0.92% 2.10% 3.42% 4.69% 5.84% 6.86% 7.76%
Please read

AFT vs. % Excess Oxidant for Different Fuels


WordPad 2400
Document CH
4
2200 C2
H6
C3
H8
2000

AFT, deg. C
1800

1600

1400

1200
0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100%
% excess oxidant
Figure 2. Relationship between the theoretical AFT and % excess oxidant for differe
d methane at 20C. Oxidant and fuel enter at 25C.
use %/100. Summary of Results--Methane
% XS oxidant 0.0% 10.0% 20.0% 40.0% 60.0%
AFT, C 2053 1916 1797 1599 1442

Summary of Results--Ethane
% XS oxidant 0.0% 10.0% 20.0% 40.0% 60.0%
AFT, C 2106 1964 1840 1636 1473

Summary of Results--Propane
% XS oxidant 0.0% 10.0% 20.0% 40.0% 60.0%
AFT, C 2119 1975 1850 1644 1480
Theo
rC Summary of Results--Graphite
Theo % XS oxidant 0.0% 10.0% 20.0% 40.0% 60.0%
rCH4 AFT, C 2185 2024 1886 1662 1488

Summary of Results--Hydrogen
% XS oxidant 0.0% 10.0% 20.0% 40.0% 60.0%
AFT, C 2247 2112 1992 1789 1624

Summary of Results--Carbon Monoxide


% XS oxidant 0.0% 10.0% 20.0% 40.0% 60.0%
AFT, C 2384 2248 2127 1922 1754

0% 90% 100%

hed lines) AFT for combustion of CH 4 and C(graphite).

2
at elevated temperatures (see data below).

70.0% 80.0% 90.0%


1370 1310 1256
0.001% 0.000% 0.000%
5.8% 5.5% 5.2%
0.000% 0.000% 0.000%
74.3% 74.6% 74.8%
0.000% 0.000% 0.000%
0.151% 0.122% 0.099%
0.001% 0.000% 0.000%
8.1% 8.8% 9.4%
0.000% 0.000% 0.000%
11.6% 11.0% 10.5%
0.021% 0.013% 0.009%

70% 80% 90%


1410 1344 1285
0.002% 0.001% 0.000%
12.4% 11.7% 11.1%
0.00% 0.00% 0.00%
78.9% 78.9% 78.9%
0.00% 0.00% 0.00%
0.19% 0.15% 0.12%
0.001% 0.001% 0.000%
8.55% 9.26% 9.89%
ferent Fuels

CH
4
C2
H6
C3
H8

70% 80% 90% 100%

nd % excess oxidant for different fuels.

s--Methane
80.0% 100%
1313 1207

80.0% 100%
1341 1232

s--Propane
80.0% 100%
1347 1237

s--Graphite
80.0% 100%
1348 1233

--Hydrogen
80.0% 100%
1488 1373

s--Carbon Monoxide
80.0% 100%
1615 1496

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