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ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT JEE 2014 TW TEST MARKS:


TIME: 1 HR TOPIC: VOLUMENTRIC ANALYSIS DATE:

SINGLE CHOICE QUESTIONS

1. Calculate the normality of a solution containing 15.8 gram of KMnO4 in 50 ml acidic solution
(a) 5 N (b) 10 N (c) 20 N (d) 40 N

2. Find the number of moles of KMnO4 needed oxidize one mole of Cu 2s in acidic medium:
Mn 2 Cu 2 SO 2 (Not Blue)
KMnO 4 Cu 2 s
8 8
(a) 8 moles (b) 5 moles (c) moles (d) moles
5 3

3. Which of the following can give both type of reaction, acid base as well as oxide reduction
reactions:
(a) Na 2 CO3 (b) KOH (c) KMnO4 (d) H2C2O

4. Balance the given reaction of titration of KMnO4 against oxalic acid in presence of H 2SO4
K 2SO 4 MnSO 4 H 2 O CO 2 what is the value of x, y and z
x KMnO 4 y H 2SO 4 z H 2C 2O 4
respectively.
(a) 5, 3, 2 (b) 2, 3, 7 (c) 3, 2, 7 (d) 2, 3, 5

5. The sulphur content of a steel sample is determined by converting it into H 2S gas, absorbing the
H 2S in 10 ml of 0.005 M I 2 and then back titrating the excess I 2 with 0.002 M Na 2S2 O3 is required
for the titration, find how many milligram of sulphur are contained in the given sample
(a) 2.56 mg (b) 5.12 mg (c) 10.24 mg (d) 1.28 mg

6. In the reaction, H 2 O182 O 3


water oxygen which of the product is radioactive in nature:
(a) water (b) oxygen (c) Both A and B (d) None of these

7. Consider the reaction:


4
H SO aq.
CrO 24 aq.
2
Cr2 O72 aq.

AgNO3 aq. feSO4 aq. H aq.


Silver chromate Cr3
v1 Zn s H aq.

Cr 2
Which of the following statement is false:
(a) Silver chromate (VI) has the formula Ag 2CrO 4 .
(b) The minimum mass of zinc required to reduced 0.1 mole of Cr3 to Cr 2 is 6.54 gram
(c) The conversion of CrO 24 into Cr2 O 72 in not a redox reaction
(d) the equation reduction of Cr O 2 by acidified feSO
it2is
Cr2O72 14H 6fe 2 7 4

6fe3 2Cr3 7H 2O

8. Equivalent weight of chlorine molecule in the equation is:


3Cl 2 6NaOH 5NaCl NaClO 3 3H 2 O
(a) 42.6 (b) 35.5 (c) 59.1 (d) 71

9. The valency factor of I 2 when, (i) it is formed by the reaction of potassium iodide and potassium
iodate in acid medium and
(ii) When it reactx with Hypo, are respectively
5 3
(a) 2, 2 (b) , 2 (c) , 2 (d) 5, 2
3 5

10. 1.2 gram of carbon is burnt completely in oxygen to produce CO and CO2 . The mixture of gases is
treated with solid I2 O5 (to know the amount of co produced). The librated iodine required 120 ml of
0.1 M Hypo solution. The % of carbon converted into CO is :
(a) 60 % (b) 100 % (c) 50 % (d) 30 %

More than one choice:

11. The oxidation state of Fe in Fe3O4 is:


(a) 2 and 3 (b) 8/3 (c) 2 (d) 3

12. Consider the redox reaction


2S2 O32 I 2 S4 O 62 2I
(a) S2 O 32 gets reduced to S4 O 62 (b) S2 O32 gets oxidized to S4 O 62
(c) I 2 gets oxidized to I (d) I 2 gets oxidized to I

13. Which of the following are examples of disproportion reaction:


(a) HgO Hg O 2 (b) KClO 3 KCl O 2
(c) KClO 3
KClO 4 KCl (d) Cl2 OH
ClO Cl H 2 O

14. There are two sample of HCl having molarity 1 M and 0.25 M. Find volume of these sample taken in
order to prepare 0.75 M HCl solution (assume no water is used)
(a) 20 ml, 10 ml (b) 100 ml, 50 ml (c) 40 ml, 20 ml (d) 50 ml, 25ml

15. The incorrect order of decreasing oxidation number of s in compound is:


(a) H 2S2O7 Na 2S4 O6 Na 2S2O3 S8 (b) H 2SO5 H 2SO3 SCl2 H 2S
(c) SO3 SO 2 H 2S S8 (d) H 2SO 4 SO 2 H 2S H 2S2 O8
Subjective Questions
16. A 1 gram sample of H 2S2 solution containing x % H 2O2 by mass required x cm3 of a KMnO4
solution for complete oxidation under acidic condition. Calculate the normality of KMnO4 solution.

17. How many mole of feCl3 can be prepared by reaction of 10 gram KMnO4 , 1.07 mole feCl3 and
500 ml of 3m HCl. MnCl2 is the reduction product.

18. Pure Na 2 C2O 4 and KHC2O4 .H 2C2 O4 (three replaceable proton ; KH3 A2 ) one mixed in such a
proportion that each gram of the mixture will react with equal volume of 0.1 M KMnO4 and 0.1 M
NaOH. What is the mixing proportion by mass?

19. If an ore, the only oxidizable material is Sn 2 . This ore is treated with dichromate solution
containing 2.5 gram of K 2 Cr2 O7 in 0.5 litre. A 0.4 gram sample of ore required 10 cm3 of tirant to
reach the equivalence point. Calculate the percentage of tin in the ore.

20. A 0.5 gram sample containing MnO 2 is treated with HCl, liberating Cl2 . The Cl2 is passed into a
solution of KI and 30 cm3 of 0.1 M Na 2S2 O3 are required to titrate the liberated Iodine. Calculate
the percentage of MnO 2 in the sample.
Answer key

1. b 2. c 3. d 4. d 5. d 6. b 7.

8. a 9. b 10. 11.a, b 12. b, c 13. c, d 14. a, b, c, d

15. c, d 16. 0.588 N 17. 0.316 18. 3.38:1 19. 15.17% 20. 26.1%, MnO 2