Series GBM aie a. 56/3 Code No. daa. Roll No. iden +e a sacgiear & gaye we ora fer | Candidates must write the Code on the title page of the answer-book. ¢ per ata a a f sa ser Gi gies ye 16 Z| o see 8 aft ce at sik feu me ais Ten FT Or Sie H FEET fort | ° grr sis ax a fh ge weaaa F 269 E | © BUT es oor See erat yw aes S veel, Wea a NT stage fers | ee ae & fee is fre ww ama fer aT 2 ea a fe ale F 10.15 8 far aE | 10.15 a a 10.90 a aH OM Dae se A SH ak ge staf & dhs 3 sac-yferer Hag sae Tet FSA | * Please check that this question paper contains 15 printed pages. * Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. ¢ Please check that this question paper contains 26 questions. * Please write down the Serial Number of the question before attempting it. * 15 minute time has been allotted to read this question paper. The question paper will be distributed at 10.15 am, From 10.15 a.m. to 10.30 a.m., the students will read the question paper only and will not write any answer on the answer-book during this period. ware fest (atarfeen) CHEMISTRY (Theory) Rafa arr: 3 0d YEARS PTA 3% 70 QUESTION PAPER.COM Time allowed ; 3 hours Maximum Marks : 70 56/3 1 P.T.O.ararer Fags: @ Gi) (iti) (iv) @ (vi) (vii) aratt wer oifrart & 1 WRT AOL AS Te ale og-saOT wer & site ede eT % Fie 1 ae F | WRT FON 6 B10 aa cys wer aikt sede wer % Fre 2 sien F 1 “MPT FON 11 322 7H Hf Ig-Tee TET & otk odes wer H hres aie F | Wer Hen 23 yerentta wer 8 ike sae tere 4 aie BY WRT eT 24 326 TH ael-aada wer @ aie weds ver & re 5 ater F 1 we srrererea Bh, a att dara ar wei ae | Hep & svabt A aegahy wee | . General Instructions: @ (ii) (ii) (iv) wo wi) (vii) 56/3 All questions are compulsory. Questions number 1 to 5 are very short answer questions and carry I mark each. Questions number 6 to 10 are short answer questions and carry 2 marks each, Questions number 11 to 22 are also short answer questions and carry 3 marks each, Question number 23 is a value based question and carries 4 marks. Questions number 24 to 26 are long answer questions and carry § marks each, Use log tables, if necessary. Use of calculators is not allowed. CHCl, Cc C1 ate Ce a ater ae ter sere & 7 CHC, CH,CH,C! Out of Cr and Cy which is an example of a benzylic halide ? YEARS 2 QUESTION PAPER.COM56/3 (a) afean Sat B,), sit >) afar At frog sat (4G) W salen A safes ar er waa wea B 7 What is the effect of adding a catalyst on (a)~ Activation energy (B,), and (&) Gibbs energy (AG) of a reaction ? ‘Fig HNO, et I, ar Sia ae KS are wm ats set eter 2, vent aa faftae | Write the formula of the compound of iodine which is obtained when conc, HNOs oxidises I. wa tte at ga 4 oftfira fen ore 2, at fea warn ar alcigs aaa 2 2 eH saree Ge | What type of colloid is formed when a gas is dispersed in a liquid ? Give an example. Prefifaa ate a and.qteal. arr fae : CH I CH, - 0-C- CH, | CH CH, | CH, -0-C~ CH, | CH, Prafefaa a deat sitfad sifie : (a) XeF, (b) BrF; Draw the structures of the following : (a) XeFy b) Bri, Write the IUPAC name of the following compound : gz 1 I 1 2 10 YEARS P.T.O. QUESTION PAPER.COM3a da a am fefac ra ara: gift A sae fear are @ | ge aa SH is wo Sats AF ach PRPs at SfeR | 2 Write the name of the cell which is generally used in transistors. Write the reactions taking place at the anode and the cathode of this cell. (a) feafefad afet + ws ora ame S agt aan a afer ifn : pahtaia, pareghhric, sfiviet >) Freafefaa after ft (Guaen ak sist ar Sri eee BE) Heafahy ferftay ; H,0* \ CH,=CH, —~—> CH - CH} +H,0 141-2 seat we-2sia A Fafefed & ae aii & et ae ger A deat ferfiay : 141-2 (a) CrO3 b) SOCl, (a) Arrange the following compounds in the increasing order of their acid strength : p-cresol, p-nitrophenol, phenol (b) Write the mechanism (using curved arrow notation) of the following reaction : _ H,0* 4: CH,=CH, —*— > CH,- CH} +H,0 OR Write the structures of the products when Butan-2-0l reacts with the following : (a) Cr0, ) SOCl, , YEARS QUESTION PAPER.COM10. 11, 12. 56/3 a awa. arr ar sehr Aa ge Preafeiftad % fare ga fear : (a) Haram gesiiedeaitgtrteam (bo) cigarette (W-1,2-srteha laTee CO) Using IUPAC norms write the formulae for the following : (a). Potassium trioxalatoaluminate(II1) (b) _ Dichloridobis(ethane-1,2-diamine)cobalt(I1) Yghad H a1 g a fort ww aisant shh ae we wera -sthee wie (ae.atah.) aca H fieecettepa Fier B 2 (ALT TTY FEMI = 27 g mol) Calculate the number of unit cells in 8-1 g of aluminium if it crystallizes in a face-centred cubic (f.c.c.) structure. (Atomic mass of Al = 27 g mol) (a) Gem [Co(NHy)s (SCN)|* fore wer A era fearar & 2 (>) (NCL)? aggahta 2 wal IN(CN),)?- whereas 2 | zat 2 (Ni I FAY] HHT = 28) (©) Ft vem agonechta ager Hil ea A Aa ara 7 1x3=3 (a) What type of isomerism is shown by the complex [Co(NHg)s (SCN)I?* 2 (b) Why is [NiC1,]?- paramagnetic while [Ni(CN),]?- is diamagnetic ? (Atomic number of Ni = 28) (c) Why are low spin tetrahedral complexes rarely observed ? Prafatad 4 8 wets & sha una aie fear : 1x8=3 (a) agama aitciigs att aeaNt Bietigs (bo) Ghee afte Ber (cere) () -aaih seem att fesse seater aeret () qa aif waren sik aieaor aren fear | (>) fer after atk wera afte a eta us waa ferftae | (©) FeCl; @ Fe(OH), ata & at are carafe, fle ser ama feiag | 1x3=3 5 10. pro YEARS : QUESTION PAPER.COM13. 14, 56/3 Write one difference in each of the following : (a) (b) (c) (a) (b) (e) (a) ) (a) (b) (a) b) (©) Multimolecular colloid and Associated colloid Coagulation and Peptization Homogeneous catalysis and Heterogeneous catalysis OR Write the dispersed phase and dispersion medium of milk. Write one similarity between physisorption and chemisorption. Write the chemical method by which Fe(OH), sol is prepared from FeCl,. we dc fred Prafafiad abit att 2 : 2 Fe3+ (ag) + 217 (aq) —> 2 Fe”* (aq) + Iq (s) I 208 K aT RE. = 0-236 V2 | det aaftiiner A aI flot Sat uftcaftra Afr | (feat Ta 8 : 1 F = 96,500 C mol“) ae ass enfeeras ae F 0-5 Ofer A ener 2 uel & fore wenlea att 2, at ARG A fet ectaela vanes et 2 (Rar mas :1F=96,500C mol) 3 The cell in which the following reaction occurs : 2 Fe®* (aq) + 2 I~ (aq) —> 2 Fe”* (aq) +Iy(s) has E°., = 0-236 V at 298 K. Calculate the standard Gibbs energy of the cell reaction. (Given : 1 F = 96,500 C mol) How many electrons flow through a metallic wire if a current of 0'5 A is passed for 2 hours ? (Given : 1 F = 96,500 C mol) sinuses seit A wpe Bs are we feafatar stat at afiga ifs: aifean wake, Teg wa Slat 3 FA CdCl, Fl AgCL are Sifter wea & 2 Sijaers ved wit vitctegaara vert St ster feat grarha I wefiia art & 7 10 Ix3=3 8 YEARS QUESTION PAPER.COM15. 56/3 (a) Based on the nature of intermolecular forces, classify the following solids : Sodium sulphate, Hydrogen 3} | What happens when CdCl, is doped with AgCl? 1) Why do ferrimagnetic substances show better magnetism than antiferromagnetic substances ? (a) Reese oiteaen & Praia a fear | >) Hie TURE & Pear} wea cia wept Fal ears Bary 2 (co) a cera fat Hf orarrent ft aa after 2 2 1x3=3 (a) Write the principle of electrolytic refining. (8) Why does copper obtained in the extraction from copper pyrites have a blistered appearance ? (c) | What is the role of depressants in the froth floatation process ? Reafafaa aftinenstt A, Baer Cate A deerrd fafa: 1x23 NH,/A_, Br,/KOH CHCl, + alc. KOH f@ cx,—coon MHA, 4 Bu/HOH Gd, , CHOl+ele KOH NaNO, /C: CH,COC1/ fit ) CgH,NZ BF, = A Fe/ HCl. B CH,COCL/ Moet Cc Write the structures of compounds A, B and C in the following reactions : NH,/A_ , Br,/KOH (Cl, + alle, KOI (a) CF—coon NSA, 4 Br! KOH (aq) 5 CHClp+ ale. KOH, ¢ (b) C,H,NSBF; Benois A Fe/ HCL B CH,COCI/ pyridine c i YEARS P.O. QUESTION PAPER.COM17. 18) 19, 56/3 Fraferfian % aro aagT : Ix3=3 (a) Weta ar Defect eam ahha wea aH TT z | >) CH,NH, CgH,NB, Ft gern a aftr: emda et 2 | (waft NH, BAR ofp Fax rar @, fe sft Ofretta aTegheneM gre aE tat § maggie ect 2 | Give reasons for the following : (a) Acetylation of aniline reduces its activation effect. (h) CH NHy is more basic than CgH;NH2. @) Although -NHp is o/p directing group, yet aniline on nitration gives a significant amount of m-nitroaniline. Frraferfiaa & sree aangy : 1x33 (a) Te Prepka, waa went Ft ger A an oiftifipensticn ain 2 | (b) detent A etagia wife erat arrears seo att F | (©) NOs, NoO, Ht aida aiftres arctie 8 | Give reasons for the following : (a) Red phosphorus is less reactive than white phosphorus. (b) Electron gain enthalpies of halogens are largely negative. (c) _N,Os is more acidic than N03. Pataca a afontte Fife: 1x3=3 (@) wart arate () Raeqa aaga afta © waa Define the following : (a) Cationic detergents (b) Broad spectrum antibiotics 1 (c) Tranquilizers : YEARS QUESTION PAPER.COM20. 21. 56/3 ° Prafefan agerel Al sea ee & fare sam cereal A dead efe: 1x33 () Ria >) Fare -stiifesergs ARE © Paiste Write the structures of the monomers used for getting the following polymers : (a) Teflon (b) Melamine-formaldehyde polymer (c) Neoprene anrat frafafad aire faq aS : 2a, 2i-2ARrerega, iit @) Sy2afifren 4 aaa afte afiieerstier afte cor arm ferfiar | ) yam ales ate ar ae fafa | (©) pAaeter sire Haat sift arfipenstter alfres ser am fafee | 1x3=9 ‘The following compounds are given to you : 2-Bromopentane, 2-Bromo-2-methylbutane, 1-Bromopentane (a), Write the compound which is most reactive towards Sy2 reaction. (b) = Write the compound which is optically active. Xc) Write the compound which is most reactive towards B-elimination reaction, 25% Rete % fore we yam aE Ht afer 20 filme Sel @ | afta st 15% TO we Ft aaa aT, Te ToT AAT | ig (far 7A @ : log 2 = 0:3010, log 3=0-4771, log 4 = 0-6021) A first order reaction takes 20 minutes for 25% decomposition. Calculate the time when 75% of the reaction will be completed. (Given : log 2 = 03010, log 3 = 0-4771, log 4 = 0:6021) 9 .T.O. YEARS PTO QUESTION PAPER.COM56/3 Gat. Few som F Fs we aet Sad sere F Mehra saz stk Ge aTedse 3a Seawr (hacer) wart Ft safle Bar & are, warett, ane wen A Om, 3 Get B Grewal F a dare BS are wae weal 3 aR Fare aot on fires fet | ae Spe were 2 fet sik Se ome fier fe 3 Geta Shan St sneer & fH ae Renal at afta, flow, wi ait aut den0 ser 4 ad | werent 3 qe Haq sand EU Seda Shen a aad sere A ame ge Ta wi frat a seg wre-verf Fa Ha, ae, aight vert cat ar are Rar i ge Pete ar asf aren-fict cen fenfeiat > zara fear | wade uitedg at agt & are, Pevferftac meat & see afte : (a) Bareft gra fea geet (@aA-wa Oh) at aalar vee 7 ) aad @ As 4 aralerssee ar SM vieaags weH safer Sat 2? () hast St fetes dort & ower fear @) set faa ratte & & sere Are | After watching a programme on TV about the presence of carcinogens (cancer causing agents) Potassium bromate and Potassium iodate in bread and other bakery products, Rupali a Class XII student decided to make others aware about the adverse effects of these carcinogens in foods. She consulted the school principal and requested bim to instruct the canteen contractor to stop selling sandwiches, pizzas, burgers and other bakery products to the students. The principal took an immediate action and instructed the canteen contractor to replace the bakery products with some protein and vitamin rich food like fruits, salads, sprouts, etc. The decision was welcomed by the parents and the students. After reading the above passage, answer the following questions : (a) What are the values (at least two) displayed by Rupali ? (b) Which polysaccharide component of carbohydrates is commonly present in bread ? (c) Write the two types of secondary structures of proteins. (d) _ Give two examples of water soluble vitamins. ‘0 10 YEARS QUESTION PAPER.COM56/3 (a) (b) (a) (b) (a) Freafefad afitsearsit & sorel ar fear : ° ® Cr + HON —> ? COONa Ga cr + NaoH 80, » Gi) CH,-CH=-cH-cn @DIBALH, , (6) H,0 Pefetan afte grat F fig ae fare eet waar wer AR : @ Seta sik eer-2-377 Gi) ange ara ait Grier 342=5 awa frafafad 4 ea areft afifiersit st fafan ; @ fad after @) at aa Prafeitad at og aftrraa et acai # fre ware waratter ae @ aaigs ae a Aatreegs i) Wha a aigw ore / Gi) Whigs ore 3 o-eggitehign ara 24325 Write the product(s) in the following reactions : 0 @ CY + HON —> ? COONa Gi) Cr + NaOH 0, 2 rr (a) DIBAL-H CH,-CH=CH-CN ——————", ? Gi) CH, BED ? 1 1 P.T.O. YEARS QUESTION PAPER.COM56/3 b) {a) (b) (a) b) Give simple chemical tests to distinguish between the following pairs of compounds : @ Butanal and Butan-2-one ii) Benzoic acid and Phenol OR Write the reactions involved in the following : (i) Etard reaction (ii) Stephen reduction How will you convert the following in not more than two steps : @ — Benzoic acid to Benzaldehyde Gi) Acetophenone to Benzoic acid Gii) Ethanoic acid to 2-Hydroxyethanoic acid fated & srer aire : G) Mammo eng oat artaettcmeor srereed gute & 1 Gi) Za, Cd ait Hea (4g) era B 1 Git), Mn3*/Mn** gr & fae E° et a Cr*#/Cr At ert A ae safe TATA (4 1:57 V) ST? | arias sik teenies cal & RR & ate tH aaa ait wai stat feftae | 34225 = 10 YEARS 12 QUESTION PAPER.COM56/3 (a) b) (a) (b) (a) Prafaftaa 3d Soft & dam engatt % area z : Ti, V+, Mn®*, or3+ (RAT SHH : Ti = 22, V= 23, Mn = 25, Cr = 24) frafattaa % set afi : @ Baar are vela ere F wae siftres cart @ otk wai 7 Gi) BERT ARH vas aeons 8 ait eat 2 Gil) BAT AP UTE 2 ait wa ? Prafetiad stare st yr AiR : @® 2Mn0z +16Ht+58* —+ Gi) KMno, —, 34225 Account for the following : @) ‘Transition metals show variable oxidation states. + Gi) Zn, Cd and Hg are soft metals. (iti) E° value for the Mn**/Mn?* couple is highly positive (+ 1-57 V) as compared to Cr9*/Cr**, Write one similarity and one difference between the chemistry of Janthanoid and actinoid elements. OR . Following are the transition metal ions of 3d series : Ti, V2+, Mn, Cri+ (Atomic numbers : Ti = 22, V = 23, Mn = 25, Cr = 24) Answer the following : (i) ~~ Which ion is most stable in an aqueous solution and why ? Gi) Which ion is a strong oxidising agent and why ? (iii) Which ion is colourless and why ? 13 P.T.O, YEARS QUESTION PAPER.COM56/3 (b) (a) (b) ) (a) Complete the following equations : (@) 2 MnO; +16 Ht +58" ——» Gi) KMno, —B@t, aera % 10% (soma H) acta frase AIH 269-15 KZ | a UE ae a femias 273-15 K2, a ewe % 10% ella fertar & fear Ht Trop FHI | Fen maT 8 : (agra an tet gems - 342 g mol”) (repere HT Wee FOAM = 180 g mol”) Prafetad vet at sfonfta Afr : @) Weer Gn) Gi) STaTART AER ETAT 34225 aat 30 g aftr (M = 60 g mol) +t 846 g Wet 4H Sten Sra ze | Ae 208 K RYE FA BH AMT Ts 23-8 mm He &, A ee fees & fare va H arer ara ar Uae AAT | omest fer aft orareet Pere & ara ef aiex fora | 34255 A 10% solution (by mass) of sucrose in water has a freezing point of 269-15 K. Calculate the freezing point of 10% glucose in water if the freezing point of pure water is 273-15 K. Given: (Molar mass of sucrose = 342 g mol") (Molar mass of glucose = 180 g mol7}), 1 “ YEARS QUESTION PAPER.COM56/3 ©) (a) (b) Define the following terms : @ ~~ Molality (m) Gi) Abnormal molar mass OR 30 g of urea (M=60 g mol”) is dissolved in 846 g of water. Calculate the vapour pressure of water for this solution if vapour pressure of pure water at 298 K is 23-8 mm Hg. Write two differences between ideal solutions and non-ideal solutions. 10 15 YEARS QUESTION PAPER.COM