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1
New International Standard:
Venting of atmospheric and low-pressure
storage tanks ISO 28300
ISO 28300
API 2000
Petroleum, EN 14015
5th edition petrochemical and
Annex L
natural gas industries
Venting of atmospheric
and low-pressure
storage tanks TRbF 20
API 2000
6th edition
2
Background and development of ISO 28300 Standard
3
Why new calculation methods for determining normal
venting requirements?
4
Validation of results for inbreathing
Prof. Salatino Model calculation at University of
Napoli, 1999
Tank: V = 63000 m3; D = 70 m; H = 15 m
T = 40 C
Water (rain) flow density
Refined model calculation
- Dynamic simulation (pressure
differential at vent)
- Different start temperatures of roof, shell
and product
5
Validation of results for inbreathing
API 2000
TRbF 20
ISO 28300
6
Validation of results for inbreathing
7
Validation of results for inbreathing
8
Summary
The new section is based on the European EN 14015 Standard.
The approach used is more general than API (the API approach
is centered around hexane or similar services).
Calculated vent rates with the new approach can be substantially
higher for certain tank sizes than what is shown in API-2000.
A research paper from Prof. Salatino and research results from
Hoechst in Frankfurt, which had been provided by Dr. Hans
Foerster from the PTB justified this change.
An advantage of the new calculation method is that it does allow
to consider full and partial insulation of the tank for normal in- and
out-breathing.
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ISO 28300 venting requirements
Normal out-breathing and normal inbreathing flows
are defined as the combination of tank vent flows
due to:
Liquid flows into and out of the tank
=V
V +
V
out thermal out pump in
=V
V +
V
in thermalin pump out
10
Liquid filling capacities - out-breathing
out-breathing rate = filling rate
11
Liquid filling capacities - inbreathing
in-breathing rate = discharging rate
12
Basis: Model calculations for a fixed roof above
ground storage tank of steel
General assumptions and approximations:
Uniform (time dependent) temperatures of wall, tank
atmosphere, ambient air and rainwater-film
Primary result is the temperature of the tank atmosphere in
dependence on time ; volume flow rates are then deduced
by an isobaric approach (constant ratio of volume to
temperature)
Tank atmosphere is air at ambient pressure
Wall thickness is according to common tank standards (
4 mm)
No heat flux via tank bottom
13
Determining of normal & emergency venting requirements
V dTg
V=
Tg dt
Energy balance to describe temperature
distribution with respect to time
Q = k A (Tg Ts ) = V g c g
dTg
dt
14
Heat flows during heating by solar radiation
(outbreathing)
solar irradiation
far IR radiation loss
convection convection
15
Solution if solving differential equation:
80
G
60
Volume Flow V in m3/h
Temperature in oC
25
40
VG,B
20
20
Maximum volume flow occurs
at maximum delta T
0 15
0 900 1800 2700 3600 4500 5400 6300 7200
Time t in s 16
Thermal out-breathing simplified as in ISO 28300
V = C V 0,9
R in
thermal out out T
17
Heat flows during cooling by rain
(inbreathing)
Rain water flow to wall
conduction
convection convection
and
evaporation
VG,B
240
45
Volume Flow V in m3/h
Temperature in oC
180 G
35
120
W
25
60
Maximum volume flow occurs
at maximum delta T
0 15
0 180 360 540 720 900
Time t in s 19
Thermal - inbreathing
Vthermalin = Cin VT R in
0,7
vapour pressure
Cin haxane or similar higher than hexane,
or unkown
storage temperature
latitude < 25 C 25C < 25 C 25C
> 58 2,5 4 4 4
42 - 58 3 5 5 5
< 42 4 6,5 6,5 6,5
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Calculation Examples
Tank 1
Tank:
Height: 5m
Diameter: 7m
Tank volume: 192.4 m3
Pump in rate: 96 m3/h
Pump out rate: 96 m3/h
Vertical tank
No insulation
MAWP: + 7.5 mbar
MAWV: - 2.5 mbar
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Inbreathing Requirements (Total) for Tank 1
400
350
Venting requirements [m3/h]
300
250
200
150
100
50
0
API 2000 EN 14015, EN 14015, EN 14015, 42- EN 14015, 42- EN 14015, EN 14015, TRbF 20
North, VP North, VP> 58, VP Hexane 58, VP> South, VP South, VP>
Hexane Hexane Hexane Hexane Hexane
22
Outbreathing Requirements (Total) for Tank 1
250
226
200
Venting requirements [m3/h]
116 117
100 118 122
109
50
0
API 2000, FP API 2000, FP EN 14015, EN 14015, 42- EN 14015, TRbF 20 TRbF 20-2 TRbF 20-3
<37.8C >=37.8C North 58 South
Pump in Thermal
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Calculation Examples
Tank 2
Very Large Size Tank (outside of scope of API 2000):
Height: 15 m
Diameter: 75 m
Tank volume: 66,268 m3
Pump in rate: 1,400 m3/h
Pump out rate: 1,400 m3/h
Vertical tank
No insulation
MAWP: + 7.5 mbar
MAWV: - 2.5 mbar
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Inbreathing Requirements (Total) for Tank 2
18000
16000
Venting requirements [m3/h]
14000
12000
10000
8000
6000
4000
2000
0
API 2000 EN 14015, EN 14015, EN 14015, 42- EN 14015, 42- EN 14015, EN 14015, TRbF 20
North, VP North, VP> 58, VP 58, VP> South, VP South, VP>
Hexane Hexane Hexane Hexane Hexane Hexane
25
Outbreathing Requirements (Total) for Tank 2
10000
9000
8000
Venting requirements [m3/h]
7000
6000
5000
4000
3000
2000
1000
0
API 2000, FP API 2000, FP EN 14015, North EN 14015, 42-58 EN 14015, South TRbF 20
<37.8C >=37.8C
Pump in Thermal
26
Calculation example considering insulation:
27
Overview Venting Requirements
(API 2000, ISO 28300)
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How to consider insulation during thermal in-
and out-breathing
Reduction factor for insulation according to ISO 28300
1
RIN =
h LIN
1+
IN
= heat conduction coefficient
30
How to determine inert gas blanketing rates
ISO 28300 Annex F provides guidance for inert
gas blanketing of tanks for flashback protection
This guidance is based on the German TRbF 20
standard
The concept has provided proven safety to the
industry for decades
It is simple way to assure sufficient inert gas
blanketing levels
The amounts result from the inbreathing rates of
the ISO 28300 equations
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3 different levels of inert gas blanketing
Level 1
minimum inert gas blanketing requirements in
combination with a specific flame arrester classification
Level 2
more stringent inert gas blanketing requirements with
different flame arrester classification
Level 3
the highest inert gas blanketing requirements with no
flame arrester
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Tank inbreathing needs to be considered
33
Inert gas level 1:
VI = 0,1 C VT + Vpe
0,7
expressed in m3/h
=
VI 0, 04 VT expressed in m3
Additional conditions:
monitor inert gas supply
alarm shall be triggered when set pressure of the vacuum vent is
reached.
inside of the tank can be classified as Zone 1 (according to the
IEC)
An end-of-line flame arrester shall be installed which has been
tested for atmospheric deflagration and endurance burning for IEC
explosion group IIA (NEC Group D) vapours.
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Inert gas level 2:
VI = 0, 2 C VT + Vpe
0,7
expressed in m3/h
=
VI 0, 08 VT expressed in m3
Additional conditions:
The alarm specified under inert gas stage 1 shall activate the
shutdown of the liquid outflow.
At this level of inert gas blanketing the inside of the tank can be
classified as Zone 2 in accordance with IEC 60079-10.
An end-of-line flame arrester shall be installed which has been
tested for atmospheric deflagration for IEC explosion group IIA
(NEC Group D) vapours.
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Inert gas level 3:
VI = 0,5 C VT + Vpe
0,7
expressed in m3/h
=
VI 0,12 VT expressed in m3
Additional conditions:
The tank pressure shall be kept above atmospheric pressure and the monitoring
system shall have redundancy in the design.
The inert gas supply shall be kept above the tank pressure and in particular the
required flow rate of shall be achieved with a tank pressure at least equal to the
atmospheric pressure.
The trip pressure at which the liquid outflow will be shut down shall be set above
atmospheric pressure. (Pump Shut Off)
Alarms shall be triggered at the trip pressure.
At this level of nitrogen blanketing the inside of the tank can be classified as
Zone 2 in accordance with IEC 60079-10. At this level of inert gas blanketing no
additional protection against flame propagation from the outside to the inside of
the tank is required.
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Why conservation vents do not function as flame arresters:
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Why conservation vents do not function as flame arresters:
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5 major vent manufacturers where tested
pressure
pallet
vacuum
pallet
40
Typical settings for API 650 tanks
set pressure:
10 mbar
( 4.0 in WC)
41
Atmospheric Deflagration - Test set-up
1 ignition source
2 plastic bag 1,2 m, length 2,5m
foil thickness >0,05 mm
3 conservation vent
4 explosion proof container
5 mixture inlet with shut-off valve
6 mixture outlet
7 bursting diaphragm
1 ignition source
6
2 plastic bag 1,2 m,
length 2,5m foil
2 thickness >0,05 mm
3 conservation vent
4 explosion proof container
1
5 mixture inlet with shut-off
valve
3
6 mixture outlet
7 bursting diaphragm
5 4
7
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44
Atmospheric
Deflagration
Test No 1
P/V VALVE
28.03.2007
45
Atmospheric
Deflagration
Test No 2
P/V VALVE
28.03.2007
46
Atmospheric
Deflagration
Test No 3
P/V VALVE
28.03.2007
47
High Velocity Burning - Test set-up
1 continuous flame
2 pressure vacuum valve
3 explosion proof container
4 mixture inlet
5 bursting diaphragm
7 pilot flame
10 shut-off valve
P/V VALVE
stoichiometric propane
air mixture
V= 85 m/h
28.03.2007
49
High Velocity Burning
Test No 5
P/V VALVE
stoichiometric propane
air mixture
V= 100 m/h
28.03.2007
50
Recommendation of ISO 28300 regarding
explosion prevention:
Different tank selection
Inert gas blanketing
Flame arresters
51
Summary
- p/v valves cannot stop an atmospheric deflagration
- p/v valves are not able to stop a flame by dynamic
effects
hence:
- p/v valves cannot substitute flame arresters
- p/v valves are not high velocity vent valves
- only devices approved according flame arrester
standards* are flame arresters
* ISO 16852, EN 12874, USCG 33 CFR part 154, CSA Z343-98
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Thank you very much
for your attention !
Any questions?
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