MATERIAL SAFETY DATA SHEET

Product PENTA HD-20

1. Product and Company Information

A. Product Name PENTA HD-20
B. Recommended use and restrictions
on use of the product
Recommended use of the product Not available
Restrictions on use of the product Not available
C. Provider information (if available Emergency
Imports domestic supplier information base)
Company DYC CORPORATION
Address 42-20, Sandan3-ro, Jeonggwan-eup, Gijang-gun, Busan, Korea

Emergency phone numbers Tel : +82(0)51-722-8600

Fax : +(82(0)51-727-8601

2. Hazard
A. Hazard, risk classification Reproductive toxicity: Category 1B
Specific target organ toxicity (single exposure): Category 1
Specific target organ toxicity (repeated exposure): Category 1
B. Label precautions stationery items, including
Pictograms

signal world Hazard

Hazard statement H360 That can cause damage to the fetus or the reproductive ability
H370 Causes damage to the of the body
H372 Prolonged or repeated exposure causes damage to the of the body
Precautionary Statements
Prevention P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe (dust, fumes, gas, vapor, mist, spray) to (a).
P264 Wash thoroughly after handling the treated area.
P270 Eat when using this product, Do not drink or smoke.
P281 Wear appropriate personal protective equipment.
Corresponding P307+P311 After exposure, call a poison center or physician.
P308+P313 If there is a risk of exposure Get medical attention or exposure.
P314 If you feel uncomfortable Get medical attention.
P321 Please (...) treatment.
Save P405 Store in a locked storage unit.
abrogation P501 (As specified in the relevant legislation) Dispose of the contents of the container.

The. Not included in other Hazard Hazard classification (NFPA)

N,N-Dimethyl formamide
Health 2
Fire 2
Reactivity 0
 Health 1
Fire 3
Reactivity 0
polyurethane
Health Not available
Fire Not available
Reactivity Not available

3. COMPOSITION, INFORMATION ON
INGREDIENTS
INGREDIENTS other name CAS number Content(%)

N,N-Dimethyl formamide N-Formyldimethylamine 68-12-2 80

p-Toluenesulfonic acid - 104-15-4 20

4. First-aid measures
A. Eye Contact Receive emergency medical attention
Wash the skin and eyes on contact material flowing over immediately and 20 minutes
in the water please
B. Skin contact Remove contaminated clothing and shoes and isolate the contaminated area please
Wash the skin and eyes on contact material flowing over immediately and 20 minutes
in the water please
Keep a slight contamination by skin contact area Proliferation
After exposure, call a poison center or physician.
C. Inhalation Move to fresh air please
Oh, warm and stable haejusi
D. Ingestion If inhaled substances do not eat artificial respiration by mouth-to-Mouth Please use
proper respiratory medical equipment
E. Other medical attention Please contact the staff at exposure and take special emergency measures such as
follow-up.
Please be sure to take protective measures for the substances of medical personnel

5. FIRE-FIGHTING MEASURES
N,N-Dimethyl formamide
Wear appropriate protective equipment rescuer.
Keep out of the area to keep a safe distance digestion
Please note shipping may be melted so
For the disposal of the digestive parser street gutters and please do not scatter
material
If you do not risk moving the containers from fire area please
Extinguishing tank fire from maximum distance or use unmanned Keep fire fighting
equipment
Evolved after digestion tank fire cool containers with plenty of water please
Pressure relief device from the tank fire treble or discoloration of tank immediately if
you please step aside
Caught in a flame of fire from the tanks withdrew tanks please

6. ACCIDENTAL RELEASE MEASURES

A. Measures to protect human health and the Measures to protect human health and the protection
protection Please isolate the contaminated area.
Do not people need to go out or not having the protective equipment.

A. Measures to protect human health and the Remove all sources of ignition
protection
 Stop leak if without risk please
Wear suitable protective clothing Do not touch damaged containers or the leaked
water
Covered with a plastic sheet to prevent spreading Do
Please note that the materials and conditions to avoid
Do not breathe (dust, fumes, gas, vapor, mist, spray) to (a).
B. Environmental precautions Number, please avoid entering into sewers, basements, enclosed space
C. Methods for cleaning up Absorb the spill with inert material (eg dry sand or earth), please put a chemical
waste container.
Please absorb the liquid and rinse the contaminated area with water and
detergent.

7. Handling and storage

A. Handling Follow all MSDS / label precautions because it may retain some product residues even
after container is emptied.
Please use care in handling / storage.
Please open carefully before opening the cap.
Without adequate ventilation Do not access the storage area.
Please note that the materials and conditions to avoid
Do not handle until all safety precautions have been read and understood.
Wash thoroughly after handling the treated area.
Eat when using this product, Do not drink or smoke.
B. Safe storage Please return to the drum adjuster immediately notgeona completely drained and
properly disposed properly save the empty drum.
Keep away from food and beverages.
Store in a locked storage unit.

8. Exposure controls and personal

protection
A. Such as chemical exposure limits and
biological exposure limits
Domestic regulations
N,N-Dimethyl formamide TWA - 10ppm 30mg/m3 (Skin)
ACGIH
N,N-Dimethyl formamide TWA 10 ppm
N,N-Dimethyl formamide 15mg/L(N-Methylformamideurine,collectedat the end ofwork),
40 mg / L (urineofN-Acetyl-S- (N-methylcarbamoyl) cysteine,weekendworkharvestedat
the end)
B. Engineering Controls Isolation process, use local exhaust, or other engineering controls to control Keep in
air levels below the exposure guidelines.
Please install the washing facilities and safety shower facilities storing or using this
material.
C. Personal Protection
Respiratory Protection Vapor and mist
Eye Protection Not available
Hand Protection Not available
Body Protection Not available

9. Physical and chemical properties

A. Appearance
Appearance Liquid
Color Transparency
B. Odor Fishy
C. Odor threshold 300 /
D. pH 6.7 (0.5mol/L
E. Melting / freezing point -
 F. Initial boiling point and boiling range 153
G. Flashpoint 58 (c.c.)
H. Evaporation rate <1
I. Flammability (solid, gas) Not available
J. Flammable or explosive range of upper /
15.2 / 2.2 % (100 )
lower
K. Vapor pressure 3.87 Hg (25)
L. Solubility (Availability)
M. Vapor density 2.5 (air=1)
N. Gravity 0.95 (water=1)
O. n- octanol / water partition coefficient -0.87
P. Ignition temperature 445
Q. Decomposition temperature Not available
R. Viscosity -
S. Molecular Not available

10. Stability and reactivity

A. Chemical stability and the possibility of Is decomposed at a high temperature can generate toxic gases
hazardous reactions
Containers may explode when heated
Can take part, but not easily ignited
Non-flammable, but the Taj itself can cause a corrosive substance / toxic fumes when
heated to decomposition
B. Conditions to Avoid Heat, sparks, flame ignition source
C. Materials to avoid Combustible materials, reducing materials
D. Hazardous decomposition products Corrosive / toxic fumes
Irritating, corrosive and toxic gases

11. Toxicological information

A. Information on the likely route of exposure Not available
B. Health Hazard Information
Acute toxicity
Oral LD50 4000 / Rat
Dermal LD50 10600 / Rabbit
Inhalation Not available
Skin corrosion or irritation Rabbit, guinea pig skin irritation test results in a weak stimulant
Serious eye damage or irritation No conjunctival irritation Causes irritation test results do not accompanied by a short
exposure is permanent corneal injury in rabbits.
Respiratory sensitization Not available
Skin Sensitization human
Carcinogenic
Occupational Safety and Health Act Not available
Employment and Labor Notice Not available
IARC Not available
OSHA Not available
ACGIH A4
NTP Not available
EU CLP Not available
Mutagenicity Voice of the rat dominant lethal test, chromosome aberration test voice, micronucleus
test negative
Reproductive toxicity Appears effects (malformations, delayed ossification, coccyx Tuesday) is a non-toxic
dose to the fetus from the mother animal teratogenicity tests in the mouse continuous
 breeding of rats tested.

Specific target organ toxicity

(single Disability awareness in the people, showing convulsions, stupor state, blood urea
exposure) nitrogen, creatinine and uric acid increased, proteinuria and hematuria, pulmonary
congestion appears.
Specific target organ toxicity (repeated Appear in person lost consciousness, nystagmus, mild headaches and back pain, and
exposure) also the irritation. Appears that inflammatory changes in the lungs and heart in
experimental animals.
Aspiration hazard Not available

12. Impact on the environment

A. Ecotoxicity
Fish LC50 8050 / 96 hr Pimephales promelas
Crustaceans LC50 41100 / 48 hr Daphnia magna
Birds EC50 6500 ~ 13000 / 96 hr Selenastrum capricornutum
B. Persistence and degradability
Persistence log Kow -1.93
Degradability BOD 0.78 /
COD 1.19 /
BOD5/COD 0.66
C. Bioaccumulative
Concentrated Castle BCF 200
Biodegradable 89 (%) 20 day
D. Mobility Not available
E. Other adverse effects Not available

13. DISPOSAL CONSIDERATIONS

A. Methods of disposal If specified in the Waste Management Act Dispose of contents and container in
accordance with the regulations.
B. DISPOSAL CONSIDERATIONS (As specified in the relevant legislation) Dispose of the contents of the container.
C. DISPOSAL CONSIDERATIONS (As specified in the relevant legislation) Dispose of the contents of the container.

14. INFORMATION TRANSPORT D

A. (UN No.) UN No transport hazard class
B. Proper shipping name No
C. Risk rating of Transportation No
D. Packing No
E. Marine pollution Not available
G. Special safety measures regarding the
shipping or transportation needs, or require the
user to know
Emergency measures in case of fire No
Spill contingency measures No

15. Regulatory
. Regulation by the Occupational Safety and Workplace material measured (measurement period: 6 months)
Health Act Managed hazardous materials
Special health examination subject matter (diagnosis period: 12 months)
Exposure limits set material
. Regulated by TCCA No
. Regulated by the Dangerous Goods Safety 4 Motorcycles third petroleum (liquid soluble) 4000
Management Act
. Regulated by the Waste Management Act No
. Regulated by other domestic and foreign
 National regulation
POPs Control Act No
Foreign regulatory
OSHA regulatory No
CERCLA regulatory 2267.995 kg 5000 lb
EPCRA 302 regulatory No
EPCRA 304 regulatory No
EPCRA 313 regulatory Corresponds
Rotterdam Convention on substance No
Stockholm Convention on substance No
Montreal Protocol on Substances No
EU classified information Xn; R22
(Classification)
EU classified information (risk R22
phrases)
EU classified information (safety S2
phrases)

16. Other information

A.Source of data
ICSC(Appearance)
ICSC(Color)
ICSC(Odor)
ICSC(Melting / freezing point)
ICSC(Initial boiling point and boiling range)
ICSC(Flashpoint)
ICSC(Flammable or explosive range of upper / lower)
ICSC(Vapor pressure)
ICSC(Solubility)
ICSC(Vapor density)
ICSC(Gravity)
ICSC(n-Octanol / water partition coefficient)
ICSC(Ignition temperature)
HSDB(Viscosity)
IUCLID(Oral)
IUCLID(Dermal)
IUCLID(Skin Sensitization)
CICADS 45, 2002(reproductive toxicity)
ECOTOX(Fish)
ECOTOX(Crustaceans)
IUCLID(Birds)
ICSC(Persistence)
IUCLID(Degradability)
IUCLID(Concentrated Castle)
IUCLID(Biodegradable)

B. First Date 2017-01-06

C. Revision number and the date of last
revision
Revision number 0
Last Revision Date 0
D. Other
 To see the MSDS provided by the Korea Occupational Safety and Health Agency, edit, modify, and created some of the
Material Safety Data Sheet (MSDS) are
Is available.