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1. CHEMISTRY unchanged if it is even and is increased by 1 if it is
It is the branch of science which deals with the odd. For example: 1.235 = 1.24, 1.225 = 1.22.
substances, their composition and properties, the 5. S.I UNIT
changes which they undergo and the manners by There are seven basic physical quantities. These
which they reacts with each other. are given in the following table along with their
2. SIGNIFICANT FIGURES (S.F.) S:I. unit.
The total number of digits in a number including Sr. No. Physical quantity Unit Symbol
the last digit, whose value is uncertain, is called 1. Length Meter m
number of significant figures. For example: 10.421 2. Mass Kilogram Kg
has five S.F. 3. Time Second s
3. RULES FOR THE CALCULATION OF S.F. 4. Temperature Kelvin K
A. All non-zero digits as well as zeroes between non- 5. Electric current Ampere A
zero digits are significant. For example: 15004 has 6. Luminous Candela Cd
five S.F. intensity
B. Zeroes to the let of first non-zero digit are not S.F. 7. Amount of Mole mol
For example: 0.0028 has two S.F. substance
C. If a number ends in zeroes but these zeroes are to
the right of decimal point, then these are 6. SYMBOLS OF COMMONLY USED PREFIXES
significant. For example: 2.500 has four S.F. IN THE POWER OF TEN
D. If a number ends in zeroes but these zeroes are not
right of decimal point, than these zeroes may or not Table-1
be significant. For example: If 10500 is written as Sr. No. Prefix Symbol Submultiple
1.05 104 , then it has three S.F. However, If it is 1. deci d 101
written as 1.050 104 has four S.F. 2. centi c 102
E. The result of an addition or subtraction should be 3. milli m 103
reported upto same number of decimal places as 4. micro 106
that of the term with least number of decimal 5. nano n 109
places. 6. pico p 1012
For example: Sum of 4.525 + 2.3 + 6.24 = 7. femto f 1015
13.063 will be reported as 13.1. 8. atto a 1018
F. The result of multiplication or division should be
reported upto the same number of S.F. as are
present in least precise number. Table--2
For example : 4.327 2.8 = 12.1156 will be Sr.No. Prefix Symbol Multiple
reported as 12. 1. deca da 101
4. RULES FOR ROUNDING OFF 2. hecto h 102
It implies as follows 3. kilo k 103
A. If the digit just next to the last digit to be retained 4. mega M 106
is less than 5, the last digit is taken as such and all 5. giga G 109
other digits to its right are dropped. For example: 6. tera T 1012
1.234 = 1.23. 7. peta P 1015
B. If the last digit is greater than 5, the digit to be 8. exa E 1018
retained is increased by 1 and other digits on its Check your ability
right are dropped. For example: 1.236 = 1.24. 1. In the final answer of the expression
C. If the digit just next to the last digit to be retained (..)(. )
The number of significant figures is
.
is equal to 5, the last significant figure is left
1
A. 1 B. 2 1. Metals: Metals are generally hard, rigid, good
C.3 D. 4 conductor of heat and electricity, ductile and malleable.
2. The number of significant figures in = However, mercury, is liquid at room temperature. For
. , ., Avogadros number are example: Sodium, potassium, calcium etc.
A. Three B. four
C. five D. can be any of these. 2. Non-metals: These are bad conductor of heat and
3. The prefix is electricity, and are not ductile and non malleable. For
A. giga B. exa example: Hydrogen, oxygen, nitrogen, sulphur etc.
C. kilo D. nano Graphite is an exception , it is good conductor of
4. One Fermi is electricity.
A. 1013 B. 1015 3. Metalloid: These are the elements which behave as
10
C. 10 D. 1012 both metals as well as non-metals. For example:
7. MATTER Arsenic, antimony, bismuth etc.
Anything that occupies space, possesses mass and the
presence of which can be felt by any one or more of our ii. Compound: It is a pure substance containing two or
five senses is called matter. more elements in a fixed ratio by weight. It is always
8. CLASSIFICATION homogeneous. These are of two types:
Matter has been classified into two types: 1. Inorganic compound: These are obtained from non-
A. Physical classification of matter living sources such as rocks and minerals. For example:
B. Chemical classification of matter. common salt, marble, washing soda etc.
A. Physical classification 2. Organic compounds: These are present in plants
This is based upon the physical state of matter: and animals. These are obtained from living-thing. For
There are three states of matter. example: Oil, fats, carbohydrates etc.
i. Solid state ii. Liquid state iii. Mixture: it is a material obtained by the
combination of two or more substances in any ratio. It
iii. Gaseous state. is of two types.
1. Homogeneous mixture: Here, composition is
i. Solid State: A solid has definite shape and definite
uniform throughout the material. For example: Air is a
volume. The magnitude of attractive force is very
homogeneous mixture of oxygen, nitrogen, carbon
strong. For example: Table, chair, sugar etc.
dioxide etc.
ii. Liquid state: A liquid has definite volume but not 2. Heterogeneous mixture: Here, composition is not
definite shape. The liquid has tendency to flow. This is uniform. For example: A mixture of iron pieces and
so because magnitude of attractive forces is weak. For sulphur powder is heterogeneous.
example: Water, milk, ethyl alcohol etc. 9. LAW OF CHEMICAL COMBINATIONS
A. Law of conservation of mass
iii. Gaseous state: A gas has neither definite shape nor It was proposed by A. Lavoisier in 1789. It states that in
definite volume. This is because magnitude of attractive all physical and chemical changes, the total mass of
forces is very weak. For example: Hydrogen, nitrogen, reactants is equal to that of products. It can also be
oxygen etc. stated as, Matter can neither be created nor be
destroyed. A balanced chemical equation is in
B. Chemical classification of matter accordance with this law. E.g.
2 2
This classification is based on chemical composition of 12+ 32 44
matter. These are of three types.
Limitation
i. Element ii. Compound This law does not hold good in nuclear reaction as some
of the mass of reactants is converted into energy
iii. Mixture ( = 2 ). This law, therefore, has been modified to
law of conservation of mass and energy saying that
i. Element: It is a purre substance that contains only total sum of mass and energy during any physical or
one kind of atoms. There are about 112 elements. These chemical change remains constant.
are of three types.
2
B. Law of constant composition e.g. in C2H5OH and CH3 (both C2H6O) ratio of
It was proposed by Joseph Proust in 1799. It states that
a pure chemical compound always consists of the same C:H:O =24:6:16 = 12:3:8 by mass.
elements combined together in definite ratio by weight.
C. Law of Multiple Proportion
e.g., H2O contains H and O in the ratio of 1:8 by mass
irrespective of its source. It was proposed by Dalton in 1803. It states that if two
Limitation elements combine to form two or more compounds, the
i. This law is not applicable if an element exists in weights of one of the elements which combine with a
different isotopes which may be involved in the fixed weight of other, bear a simple number ratio. e.g.
formation of the compound. e.g. 12 2 has C:O in the N and O forms number of oxide as shown in table given
ratio of 12:32 by mass but C14 O2 has C:O in the ratio below.
of 14:32 by mas..
ii. The elements may combine in the same ratio but the
compounds formed may be different.
Thus, Fixing the mass of nitrogen as 14 parts, ratio of masses of oxygen is 8:16:24:32:40 or 1:2:3:4:5, which is a simple
ratio.
A. 2 and 2 B. 3 and 2
15. GRAM ATOMIC MASS (G.A.M)
C. 2 and 2 D. 2 and
7. The law of multiple proportion was proposed by The atomic mass of an element expressed in gram is
A. Lavosier B. Dalton called gram atomic mass. The amount is also known as
C. Proust D. Gay-Lussac one gram atom. G.A.M.=One gram atom
11. AVOGADROS HYPOTHESIS It is the absolute mass in grams of 6.02 1023 atoms
Under similar conditions of T and P, equal volumes of of any element.
all gases contain equal number of molecules.
Applications of Avogadros hypothesis Number of gram atoms
Using Avogadrros hypothesis, it can be concluded that Mass of element in grams
=
Atomic mass of the element in grams
i. Molecular mass = 2 Vapour density
ii. 22.4 L of any gas at S.T.P. weigh equal to molecular 8. 1 a.m.u is equal to
mass in gram. This mass is called Gram molecular
1 1
mass and the volume is known as Gram molecular A. Or 12 B. Of 16
12 14
volume.
C. 1 g of 2 D. 1.66 1023 kg
S.T.P. stands for standard temperature and pressure.
S.T.P condition means 273 K temperature and one 9. Atomic mass of an element is
atmospheric pressure.
(A) the actual mass of one atom of the element
12. ATOMIC MASS UNIT
(B) the relative mass of an atom of the element
1
It is equal to th of the mass of an atom of C-12. It is
12 (C) the average relative mass of different atoms of the
equal to 1.6 1024 g. element
13. ATOMIC MASS (D) much different from the mass number of the
element.
It is the average relative mass of its atoms as compared
with an atom of C-12. It is expressed in a.m.u. 16. MOLECULAR MASS
4
The molecular mass of a molecule expressed in gram 1 = 6.022 1026 .
known as gram molecular mass.
6
28. IMPORTANT FORMULAE AND POINTS
1. Atomic mass specific heat = 6.4
(Duleng and Petit law)
2. Atomic mass = Equivalent wt. Valency
Molecular mass
3. Atomic mass of a gaseous element =
Valency
4. Vapour density of a volatile metal choride
(E+35.5)x
=
2
E = Eq. wt. of metal
X = valency of metal
Gram atomic wt.
5. Wt. of one atom =
N0
Gram molecular wt.
6. Wt. of one molecule =
N0
Gram formula wt.
7. Wt. of formula unit =
N0
Gram ionic wt.
8. Wt. of one ion =
N0