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energy when being fixed into a porous material. Since it loses energy, it is exothermic. Moreover,
the process is reversible and doesnt use mechanical energy but only heat energy. The basic
adsorption cycle for cooling is shown in Fig 1. In the first half of the cycle in AB, the adsorbent
is heated using an external heat source that can be derived from solar power or waste heat until the
pressure reaches a level that permits the desorption of refrigerant (state B). During process BC,
the vapor refrigerant is continuously heated which results in the desorption of vapor refrigerant.
The gaseous refrigerant flows to the condenser at state C and is condensed here when the adsorbent
reaches its maximum temperature. In the second half of the cycle, the temperature starts to
decrease. Meanwhile, the condensed liquid refrigerant flows into the evaporator which then
evaporates and extracts heat from the evaporator (process DA) generating a cooling process
beds, a condenser, and an evaporator. This two-bed configuration makes a continuous adsorption
cycle. The schematic diagram is shown in Fig. 2. One adsorbent bed is heated in desorption
period and the other bed is cooled in adsorption period. One cycle is completed after a full cycle
of both adsorption and desorption. The steps in heating and cooling are reversed when the beds
reached desired upper and lower temperature limits of the adsorption cycle.
Theoretical Framework
Adsorption Equations
concentration (x), adsorbent temperature (T) and adsorption pressure (P). The adsorbate
the surface undergoing adsorption and pressure. It assumes that adsorption is monolayer
and that molecules do not interact with each other. It can be given as (Ng et al., 2001):
x = P * K10 exp (Qst/R0T)
where:
K10 and Qst are the two parameters that can be determined experimentally.
adsorbed by unit mass of solid adsorbent with pressure. It can be given as:
x = x0 (P/Psat) 1/n
where:
given as:
where:
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