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To understand the behaviour of ions in solution and structure of electrode surface. Surface phenomena
including three dimentional concepts of molecules.
10.00
Unit I:
Ions in solution
Debye-Huckel theory of strong electrolysis (ion-ion & ion-solvent interaction), ionic strength,
Debye- Huckel-Onsager conductance equation, activity coefficient , mean ionic activity coefficient,
ionic strength, Debye-Hukel theory of mean ionic activity coefficient, Debye length, The Debye-
Huckel limiting law, qualitative tests of the Debye-Huckel limiting law, Bjerrum model of ion-
association.
8.00
Unit II:
Electrochemistry ? Electrical Double Layer
10.00
Unit III:
Kinetics of Electrode Reactions
9.00
Unit IV:
Surface Phenomena
Prerequisite- Surface tension, pressure difference across curved surface (laplace equation), vapour
pressurebof droplet (calvin equation).
8.00
Unit V:
Collidal Phenomena
Surface active agents, classification, hydrophobic interaction, Micelle formation: the mass action
model and the phase separation model, shape and structure of micelles, micellar aggregation
numbers, critical micelle concentration (CMC), factors affecting CMC, thermodynamics of CMC,
thermodynamics of micellization , micelle temperature range (MTR) or Kraft point, solubilisation,
microemulsion,and reverse micelles.
Essential Readings:
1. Modern Electrochemistry Vol. I & II, Second Edition; J.O.M. Bockris and A.K.N. Reddy; Plenum
Press, New York, 2000.
2. Electrochemistry; S. Glasstone, First Edition; Affiliated East-West press Pvt. Ltd., New Delhi, 1942.
3. Principles of Colloid and Surface Chemistry, Second Edition; Paul C. Heimenz; Marcel Dekkan, New
York, 1986.
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