Beruflich Dokumente
Kultur Dokumente
pH
pH
Therefore, when the electrolyte solution makes electrolyte solution Therefore, when the electrolyte solution makes
electrolytes The advantage
some AgClofwill this electrolytes The advantage
PTFE: Polytetrafluoroethylene (PTFE) has of this
hydrophobic properties which
1. Single vs Double Junction
mple, some AgCl will precipitate on the external facecontact with the sample,
result is drifty readings obtained from the sensor of thejunction
junctionisThe
it is result
renewable; asreadings
is drifty
precipitate on the external
the clothobtained from the sensor
face
junction is it is renewable; as the cloth
provide one of the most chemically resistant junctions available. It is
like material is pulled out from its like material is pulled out from its
Electrodes feature either a single
ction system, as the name implies, has two
or position,
Hannas
double
double
junction
the junction
junction
design. Singlename
is renewed
system, as thewith
junction
implies, hascommonly
two usedposition,
in pH electrodes
the junctionfor processwith
is renewed applications.
of which is inelectrodes
contact withserve to put
the sample asthe reference anelectrode
junctions, only onesystem
uncontaminated, of which in contact
is in
fresh contactwith
surface with the
the sampleBEST
as FOR: Samples where greases
an uncontaminated, or surface
fresh oils are present, or in biological
below Undersample. These electrodes
adverse conditions, the sameare less expensive,
shown in the figurehowever,
below Underunder adverse
adverse conditions, the same
solutions containing large amounts of protein.
e ingress is evident However, as the reference tendency of sample ingress is evident However, as the reference
conditions such as high
separated physically from the intermediate
pressure, Open Junction
high temperature, or highly acidic or
electrode system is separated physically from the intermediate
Open Junction
PTFE Sleeve: A sleeve made of polytetrafluoroethylene (PTFE) material
e contaminationalkaline
of thesolutions
electrode is the positive flow
minimized ofThis
thetype
electrolyte electrolyte
area,
of the through
contamination
junction the
is often found junction
of the electrode is minimized This type of junction is often found
ogging of theis surrounds an opening into the reference cell. The hydrophobic properties
often is
junction reversed resulting
also reduced with in theTheingress of sample
likelihood
in referenceof clogging intoofand
half-cells the
theisreference
junction
filled is also reduced with in reference half-cells and is filled
ectrode since the outer reference cell a double junction electrode since
with a special gel which comes into the outer reference of
cell the PTFE sleeve feature a clogging
with a special gel prevention
which comes into system (CPS).
compartment. If this happens, the reference electrode can become
hat is silver-free Since there is no silver uses direct
a fill solution
contactthat isthe
silver-free Since
be there is no silver
with solution to BEST FOR: Solutions with a with
direct contact highthe
solids content
solution to be such as sauces, juices,
contaminated,
precipitate forming to clog theleading
junctionto electrode failure.
present, there
measured
Double
isAn junctionofforming
noadvantage
precipitate electrodes
an open to clog the junction measured An advantage of an open
and wine.
isolate the reference electrode, so even if sample
junction ingress
is low contact were to happen,
resistance junction is low contact resistance
ectrodes usethe
a fillcontamination
solution such as the HI7071
to the referenceSingle
and junction
electrode iselectrodes
low clogging minimized.useAlso
potential a fill solution
the outersuch as the HI7071 and low clogging potential
Fiber Wick (Cloth): A fiber or cloth junction is used with plastic body gel
M KCl + AgCl, while double junction electrodes that contains 3.5M KCl + AgCl, while double junction electrodes
fill solution
082 that contains 3.5M KCl. of a double junction electrode is silver free, which reduces
typically use HI7082 that contains 3.5M KCl. the filled probes. It has the advantage of being renewable. When readings are
risk of silver precipitation clogging the Cone Style
junction. Cone
erratic or unstable, Styleportion (1/8) is pulled out to expose a fresh
a small
This style junction is also renewable new surface ofThis
thestyle junction is also renewable
junction.
Electrolyte Ag/AgCl Inner Tube Electrolyte Ag/AgCl
Containing As the
Housing thesleeve or collar isContaining
moved, fresh As the sleeve or collar is moved, fresh
Reference Wire BEST FOR:
Reference Wire General purpose, environmental, or home use.
electrodes
electrodes
Silver Membrane
fill solution cleans out theSilver
junction with fill solution cleans out the junction with
Sensing Wire
fresh electrolyte This has a Ceramic
higher flow fresh electrolyte This has a higher flow
Inner Ceramic Inner Open: An open junction does not have a frit. The electrode uses an exposed
Junction rate than a ceramic typeJunction
and is often rate than a ceramic type and is often
Ceramic
Silver-Free
specified for ISE measurements
Electrolyte
hard gel as the specified
Ceramic
junction.forThis layer is silver free. The open junction has a
ISE measurements
Outer Ceramic Outer Ceramic
Junction Junction Junction high flow rate making it ideal for semi-solids, emulsions, and other food
Junction
For glass body electrodes, the ceramic junction material is easily fused uses HF resistant glass for aggressive applications that have fluoride
with glass and also has a similar expansion coefficient. Electrodes may ions. Electrodes manufactured with this glass last ten times longer than
contain a single, a double, or a triple ceramic junction. electrodes made with standard pH glass formulations (from 10 to 100
BEST FOR: Any aqueous solution. This is the most common junction found days).The alkaline error is very high for this glass, so it is not suited for pH
in a standard laboratory. measurements above pH 10.
BEST FOR: pH range from 2 to 10 pH and for samples with less than 2 g/L
fluoride.
+ AgCl Electrolyte
Electrolyte
Sensor
Temperature Sensor
Electrolyte
Reference
Abbreviation
Abbreviation
Guide
Guide
Reference
Single Reference
Junction
Junction
Electrolyte
Electrolyte
Amplifier (Bar)
Pressure (Bar)
Junction
Open Junction
Junction
Cloth Junction
Material
Body Material
Temperature
Spherical
Spherical (S) (S) Glass (G)
Glass (G)
Tip Shape
Tip Shape
Viscolene
Viscolene
Refillable
Refillable
Amplifier
ConicalConical
(C) (C) PlasticPlastic
(P) (P)
Pressure
Gel 35M
Ceramic
Ceramic
SMART
SMART
Double
Double
Flat (F)
Flat (F) Metal Metal
(M) (M)
Single
Open
Cloth
Body
Gel
KCl
KCl
Application
Application Recommended
Recommended
Electrodes
Electrodes PagePage
HI1043B/P
HI1043B/P S GS G 01 01287 287
Acids,Acids,
StrongStrong
HI10430*
HI10430* S GS G 01
012101 2101
Alkaline, StrongStrong
Alkaline, HI2111B (half-cell)
HI2111B + HI5311
(half-cell) + HI5311 S P/G
S P/G 01 2104, 2105 2105
01 2104,
Aquariums
Aquariums HI1332B/P
HI1332B/P S PS P 01 01293 293
pH
pH
HI1043B/P
HI1043B/P S GS G 01 01287 287
Bases,Bases,
StrongStrong
HI10430*
HI10430* S GS G 01
012101 2101
HI1131B/P/D
HI1131B/P/D S GS G 01 01288 288
HI11310*
HI11310* S GS G 01
012101 2101
Beer Beer
HI11311*
HI11311* S GS G 01
012101 2101
FC214D
FC214D S M
S M 3 3 296 296
BoilersBoilers
and Cooling Towers
and Cooling HI72911D
Towers HI72911D F MF M PTFE PTFE Polymer
Polymer 3 32100 2100
FC242D
FC242D C MC M 01
01297 297
Cheese
Cheese
FC240B
FC240B C MC M 01 01295 295
Chemicals
Chemicals HI1332B/P/D
HI1332B/P/D S PS P 01 01293 293
HI1053B/P
HI1053B/P C GC G 01 01287 287
Conductivity, Low Low
Conductivity,
HI10530*
HI10530* C GC G 01
012101 2101
HI1043B/P
HI1043B/P S GS G 01 01287 287
Conductivity, High High
Conductivity,
HI10430*
HI10430* S GS G 01
012101 2101
FC210B
FC210B C GC G 01 01294 294
Creams
Creams FC220B
FC220B S GS G 01 01295 295
electrodes
electrodes
FC911B
FC911B S PS P 01
01296 296
HI2031B
HI2031B C GC G 01 01290 290
FC200B/S
FC200B/S C PC P 01 01294 294
FC240B
FC240B C MC M 01 01295 295
Dairy Products
Dairy Products FC201D, FC202D
FC201D, FC202D C PC P 01
01296 296
FC2100*
FC2100* C GC G 01
012102 2102
FC2020*
FC2020* C PC P 01
012102 2102
FC260B (half-cell)
FC260B (half-cell) S GS G 2104 2104
HI1053B/P
HI1053B/P C GC G 01 01287 287
HI10530*
HI10530* C GC G 01
012101 2101
Emulsions
Emulsions HI1612D
HI1612D C GC G 01
01292 292
HI1413B
HI1413B F GF G 01 01298 298
HI1414D
HI1414D F GF G 01
01288 288
HI1053B/P
HI1053B/P C GC G 01 01287 287
Fats and Creams
Fats and Creams
pH Measurement SOP 1.0 8/2017 PRINTED IN USA
HI10530*
HI10530* C GC G 01
012101 2101
FlasksFlasks HI1331B
HI1331B S GS G 01 01289 289
Fluoride, Samples
Fluoride, with with HI1143B
Samples HI1143B S GS G 01 01288 288
Food Industry
Food Industry FC100B
FC100B S PS P 01 01294 294
(General Use) Use)
(General FC911B
FC911B S PS P 01
01296 296
FC201D, FC202D
FC201D, FC202D C PC P 01
01296 296
Food, Food,
Semi-solid
Semi-solid
FC200B/D
FC200B/D C PC P 01 01294 294
*edge specific
*edgeelectrode
specific electrode
Unsure
Unsure
aboutabout
whichwhich
electrode
electrode
to choose?
to choose?
Give your
Givelocal
yourHanna
local Hanna
officeoffice
a call for
a call
assistance.
for assistance. Clean Regularly | Calibrate
www.hannainst.com |
www.hannainst.com | Often | Condition
2.832.83 Always
Getting To Know Your pH Electrode hannainst.com/pH | 877-MY-HANNA | sales@hannainst.com
Getting To Know Your pH Electrode
2 pH Electrode
pH ElectrodeApplication Guide pH Electrode Application Guides
Reference Guides 2
Temperature Sensor
KCl 35M Electrolyte
Double Reference
Single Reference
Ceramic Junction
Gel Electrolyte
Pressure (Bar)
Viscolene Electrolyte
Open Junction
Cloth Junction
Body Material
Spherical (S) Glass (G)
Temperature Sensor
KCl 35M Electrolyte
Double Reference
Conical (C) Plastic (P)
Abbreviation Guide
Tip Shape
Single Reference
Ceramic Junction
Refillable
Amplifier
Flat (F)
Gel Electrolyte
SMART
Pressure (Bar)
Open Junction
Cloth Junction
Body Material
Spherical (S) Glass (G)
Tip Shape
Refillable
Amplifier
Conical (C) Plastic (P)
SMART
Flat (F) Metal (M)
Application Recommended Electrodes Page
FC200B/D C P 01 294
Application Recommended Electrodes Page
Fruits FC230B C P 01 295
HI1043B/P S G 01 287
Acids, Strong FC202D C P 01 296
HI10430* S G 01 2101
FC220B S G 01 295
Fruit Juices,
Alkaline, Organic
Strong HI2111B (half-cell) + HI5311 S P/G 01 2104, 2105
FC911B S P 01 296
Aquariums HI1332B/P S P 01 293
Frozen, Semi FC230B C P 01 295
pH
pH
HI1043B/P S G 01 287
Bases, Strong FC200B/D C P 01 294
HI10430* S G 01 2101
Ham and Sausages FC202D C P 01 296
HI1131B/P/D S G 01 288
FC230B C P 01 295
HI11310* S G 01 2101
Beer HI1053B/P C G 01 287
Horticulture and Nurseries HI11311* S G 01 2101
HI1292D C G 01 288
FC214D S M 3 296
Humidity, High FC911B S P 01 296
Biotechnology (< 100 l) HI1083B/P S G 01 287
HI1043B/P S G 01 287
Boilers and Cooling Towers
Hydrocarbons HI72911D F M PTFE Polymer 3 2100
HI10430* S G 01 2101
FC242D C M 01 297
Cheese HI1131B/P/D S G 01 288
FC240B C M 01 295
HI1230B/D S P 2 289
Chemicals HI1332B/P/D S P 01 293
HI1217D S P 2 291
HI1053B/P C G 01 287
Conductivity, Low HI1610D S G 01 292
HI10530* C G 01 2101
HI1332B/P/D S P 01 293
Laboratory (General Use) HI1043B/P S G 01 287
Conductivity, High HI11310* S G 01 2101
HI10430* S G 01 2101
HI11311* S G 01 2101
FC210B C G 01 294
HI12300* S P 2 2103
Creams FC220B S G 01 295
HI12301* S P 2 2103
electrodes
electrodes
FC911B S P 01 296
HI1291D S P 2 291
HI2031B C G 01 290
HI1413B F G 01 298
Leather FC200B/S C P 01 294
HI1414D F G 01 288
FC240B C M 01 295
FC230B C P 01 295
Dairy Products FC201D, FC202D C P 01 296
FC400B C P 01 295
FC2100* C G 01 2102
Meats FC232D C P 01 297
FC2020* C P 01 2102
FC201D, FC202D C P 01 296
FC260B (half-cell) S G 2104
FC2320* C P 01 2102
HI1053B/P C G 01 287
FC200B/D C P 01 294
HI10530* C G 01 2101
FC100B S P 01 294
Emulsions HI1612D C G 01 292
FC101D S P 01 294
HI1413B F G 01 298
FC210B C G 01 294
Milk and Yogurt HI1414D F G 01 288
pH Measurement SOP 1.0 8/2017 PRINTED IN USA
FC213D C G 01 297
HI1053B/P C G 01 287
Fats and Creams FC201D, FC202D C P 01 296
HI10530* C G 01 2101
FC2100* C G 01 2102
Flasks HI1331B S G 01 289
FC2020* C P 01 2102
Fluoride, Samples with HI1143B S G 01 288
HI1135B S G 3 288
Food Industry FC100B S P 01 294
Monitoring, Continuous
(General Use) HI1611D
FC911B SS GP 201 292
296
NMR Tubes HI1093B
FC201D, FC202D SC GP 01
01 287
296
Food, Semi-solid
Paints HI1043B/P
FC200B/D SC GP 01
01 287
294
Viscolene Electrolyte
Temperature Sensor
Abbreviation Guide
Ceramic Junction
Gel Electrolyte
Spherical (S) Glass (G)
Pressure (Bar)
Open Junction
Cloth Junction
Body Material
Tip Shape
Refillable
Amplifier
Flat (F) Metal (M)
SMART
Viscolene Electrolyte
Temperature Sensor
KCl 35M Electrolyte
Double Reference
Single Reference
Ceramic Junction
Gel Electrolyte
Pressure (Bar)
Open Junction
Cloth Junction
Body Material
Application Recommended Electrodes Tip Shape Page
Refillable
Amplifier
SMART
HI1413B F G 01 298
Paper
HI1414D F G 01 298
pH
Photographic Chemicals HI1230B/D S P 289
Application Recommended Electrodes Page
Plating Baths HI62911D F M PTFE Polymer 3 2100
HI1413B F G 01 298
Paper Quality Control HI1332B/P/D S P 01 293
HI1414D F G 01 298
FC220B S G 01 295
pH
Photographic Chemicals
Sauces HI1230B/D S P 289
FC911B S P 01 296
Plating Baths HI62911D F M PTFE Polymer 3 2100
HI1043B/P S G 01 287
Quality ControlSeawater HI1332B/P/D S P 01 293
HI10430* S G 01 2101
FC220B S G 01 295
Sauces HI1053B/P C G 01 287
FC911B S P 01 296
HI10530* C G 01 2101
HI1043B/P S G 01 287
Seawater HI1612D C G 01 292
HI10430*
Semi-solid Products S G 01 2101
FC200B/D C P 01 294
HI1053B/P C G 01 287
FC201D, FC202D C P 01 296
HI10530* C G 01 2101
HI2031B C G 01 290
HI1612D C G 01 292
Semi-solid Products HI1413B F G 01 298
Skin, Scalp FC200B/D C P 01 294
HI1414D/50 F G 01 298
FC201D, FC202D C P 01 296
Soil, Direct HI1292D C G 01 298
HI2031B C G 01 290
HI1053B/P C G 01 287
HI1413B F G 01 298
Skin, Scalp HI10530* C G 01 2101
Soil Samples HI1414D/50 F G 01 298
HI1230B/D S P 2 289
Soil, Direct HI1292D C G 01 298
electrodes
HI1292D C G 01 288
HI1053B/P C G 01 287
HI1043B/P S G 01 287
Solvents HI10530* C G 01 2101
Soil Samples HI10430* S G 01 2101
HI1230B/D S P 2 289
HI1413B F G 01 298
HI1292D
Surface Measurements C G 01 288 electrodes
HI1414D F G 01 288
HI1043B/P S G 01 287
Solvents Swimming Pools HI1297D C M 3 299
HI10430* S G 01 2101
Titrations, Non Aqueous HI1151 S G 01 288
HI1413B F G 01 298
Surface Measurements HI1043B/P S G 01 287
HI1414D F G 01 288
HI10430* S G 01 2101
Swimming Pools Tris Buffer HI1297D C M 3 299
HI1144B/D S G 01 290
Titrations, Non Aqueous HI1151 S G 01 288
HI1343B S P 01 290
HI1043B/P S G 01 287
Vials and Test Tubes HI1330B/D S G 01 290
HI10430* S G 01 2101
Tris Buffer HI1296D/HI12963 S M 3 299
Wastewater HI1144B/D S G 01 290
HI1297D C M 3 299
HI1343B S P 01 290
Water, High Purity HI1053B/P C G 01 2101
Vials and Test Tubes HI1330B/D S G 01 290
Water, Municipal HI1297D C M 3 299
HI1296D/HI12963 S M 3 299
pH Measurement SOP 1.0 8/2017 PRINTED IN USA
Temperature Sensor
KCl 35M Electrolyte
Abbreviation Guide
Double Reference
Single Reference
Ceramic Junction
Gel Electrolyte
Pressure (Bar)
Open Junction
Cloth Junction
Body Material
Platinum (Pt) Glass (G)
Gold (Au) Plastic (P)
Refillable
Amplifier
SMART
Sensor
Application Recommended Electrodes Page
HI3131B/P Pt G 01 291
HI3618D Pt G 01 291
Laboratory (General Use)
HI36180* Pt G 01 2103
pH
HI36200* Pt P 2 2103
Oxidants HI4430B Au P 2 293
Ozone HI4430B Au P 2 293
Quality Control HI3230B Pt P 2 293
Titrations, ORP HI3131B/P Pt G 01 291
Water, Municipal HI3230B Pt P 2 293
Wine HI3148B Pt G 01 297
*edge specific electrode
Double Reference
Single Reference
Ceramic Junction
Cylindrical (C) Plastic (P)
Pressure (Bar)
Body Material
ORP Half Cell
Platinum (Pt)
pH Half Cell
Reference
Tip Shape
Gold (Au)
electrodes
HI5312 G 01 2106
HI5313 P 01 2106
Titration, Potentiometric HI3133B Pt G 2104
Wide Temperature Range HI5311 G 01 2105
2.86 | www.hannainst.com Unsure about which electrode to choose? Give your local Hanna office a call for assistance.