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methyl butane are

(a) 2 (b)3 (c) 4 (d) 1

https://books.google.co.in/books?id=qNuXDQAA The intermediate product formed during the


addition of HCl to propene in presence of
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peroxide is
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Which one of the following has the minimum heat


of hydrogenation per mole?

(a) 1 -butene

(b) trans-2butene

(c) cis-2-butene

(d) 1, 3-butadiene

Isopropyl bromide on Wurtz reaction gives

(a) hexane (b) propane

(c) 2, 3-dimethyl butane (d) neo-hexane (CH3)3CMgCl on reaction with D2O produces

(a) (CH3)3CD (b) (CH3)3OD


The product formed by acid catalysed hydration of
2-phenyl propene is (c) (CD3) 3CD (d) (CD3)3OD

(a) 3-phenyl-2-propanol

(b) I -phcenyl-2-propanol

(c) 2-phenyl-2-propanol
The reaction conditions leading to provide the best
(d) 2-phenyl-1 -propanol yield of C2H5Cl are

The addition of HC1 to 3, 3, 3-trichloropropene


gives

When ethyl bromide and n-propyl bromide is


allowed to react with sodium, in ether, they form

(a) mixture of four alkanes


The number of possible enantiomeric pairs that
can be produced during monochlorination of 2- (b) mixture of three alkanes
(e) mixture of two alkanes

(d) single alkane

Potassium salt of 2, 3-dimethyl maleic acid on


electrolysis gives

(a) ethyene (b) propyne


On the addition of HBr to propene in the absence
of peroxides, the first step involves the addition of (c) 2-butyne (d) 1-butyne

In the reaction sequence (A) will be Reductive ozonolysis of the alkene, CH3
CH=C=CH2will give

(a) only CO2

(b) only CH2O

(e) only CH3CHO

(d) mixture of CH3CHO, HCHO and CO2

Which among the following alkyne will give an


(a) 1 -bromo-2- ethyl cyclopentane aldehyde on hydroboration oxidation reaction?

(b) 1-bromo-! -methyl cyclopentane

(e) I -bromo-5-methyl cyclopentanc

(d) 5-bromo- 1-methyl cyclopentane


When propyne is treated with aqueous H2S04 in
presence of HgSO4 the major product is
Which of the following gives propyne on
hydrolysis? (a) acetone (b) propanol

(a) A14C3 (b) Mg2C3 (c) propanal (d) propyl hydrogen sulphate

(c) B4C (d) La4C3


(a) bromine, CCl4

(b) H2, Lindlar catalyst

(e) dilute H2S04, HgSO4

(d) ammonical cuprous chloride

In the presence of peroxide, and hydrogen


chloride, hydrogen iodide does not undergo anti-
Markovnikovs addition to alkenes because

(a) both are highly ionic


Consider the following reaction, Identify the
structure of the major product X (b) one is oxidizing and other is reducing

(e) one of the steps is endothermic in both the


cases

(d) all the steps are exothcrmic in both the cases

Which is most easily dehydrohalogenated?

Which of the following alkenes will react fastest


with H2 under catalytic condition?

Identify the reagent from the following list which


can easily distinguish between 1-butyne and 2-
butyne?
The product(s) obtained via oxynicrcuration
(HgSO4+ H2S04)of but-1-yne would give

2, 3-dimethyl hexane contains .... tertiary....


secondary and ....primary carbon atoms,
respectively.
The reaction of
(a) 2,4,3 (b) 3,2,4

(c) 43,2 (d) 2,2,4

The reaction of HBr with 2-methyl propene in the


presence of peroxide will give
The heat of hydrogenation of benzene is 50
kcal/mol. The resonance energy of benzene is 36
kcal/mol. The heat of hydrogenation of
cyclohexene is approximately

(a) 9 kcal/mol (b) 19 kcal/mol

(c) 29 kcal/mol (d) 27 kcal/mol

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