C(gr)

OPTIONS: joules

TEMPERATURE SCHEDULE

200.000 298.150 300.000 400.000 500.000 600.000

700.000 800.000 900.000 1000.000 1100.000 1200.000
1300.000 1400.000 1500.000 1600.000 1700.000 1800.000
1900.000 2000.000 2100.000 2200.000 2300.000 2400.000
2500.000 2600.000 2700.000 2800.000 2900.000 3000.000
3100.000 3200.000 3300.000 3400.000 3500.000 3600.000
3700.000 3800.000 3900.000 4000.000 4100.000 4200.000
4300.000 4400.000 4500.000 4600.000 4700.000 4800.000
4900.000 5000.000

NOTE: Thermodynamic properties calculated for temperatures outside the range of

the fitted data may have large errors. This program allows calculations only
for temperatures within 20% above or below the fitted temperature range.

COEFFICIENTS FOR FITTED THERMODYNAMIC FUNCTIONS

C(gr) Graphite. Ref-Elm. TRC(4/83) vc,uc,tc1000-1002.

3 n 4/83 C 1.00 0.00 0.00 0.00 0.00 1 12.01070 0.000
200.000 600.000 7 -2.0 -1.0 0.0 1.0 2.0 3.0 4.0 0.0 1053.500
1.132856760E+05-1.980421677E+03 1.365384188E+01-4.636096440E-02 1.021333011E-04
-1.082893179E-07 4.472258860E-11 0.000000000E+00 8.943859760E+03-7.295824740E+01
600.000 2000.000 7 -2.0 -1.0 0.0 1.0 2.0 3.0 4.0 0.0 1053.500
3.356004410E+05-2.596528368E+03 6.948841910E+00-3.484836090E-03 1.844192445E-06
-5.055205960E-10 5.750639010E-14 0.000000000E+00 1.398412456E+04-4.477183040E+01
2000.000 6000.000 7 -2.0 -1.0 0.0 1.0 2.0 3.0 4.0 0.0 1053.500
2.023105106E+05-1.138235908E+03 3.700279500E+00-1.833807727E-04 6.343683250E-08
-7.068589480E-12 3.335435980E-16 0.000000000E+00 5.848134850E+03-2.350925275E+01
THERMODYNAMIC FUNCTIONS CALCULATED FROM COEFFICIENTS FOR C(gr)

T Cp H-H298 S -(G-H298)/T H delta Hf log K

deg-K J/mol-K kJ/mol J/mol-K J/mol-K kJ/mol kJ/mol

0 0. -1.054 0. INFINITE -1.054 0 INFINITE

200 5.007 -0.665 3.074 6.401 -0.665 0 0
298.15 8.528 0.000 5.734 5.734 0.000 0 0
300 8.592 0.016 5.787 5.734 0.016 0 0
400 11.824 1.040 8.711 6.111 1.040 0 0
500 14.617 2.366 11.659 6.926 2.366 0 0

600 16.835 3.944 14.529 7.956 3.944 0 0

700 18.534 5.716 17.257 9.092 5.716 0 0
800 19.828 7.637 19.820 10.274 7.637 0 0
900 20.826 9.672 22.216 11.470 9.672 0 0
1000 21.612 11.795 24.452 12.657 11.795 0 0

1100 22.243 13.989 26.543 13.826 13.989 0 0

1200 22.762 16.240 28.501 14.968 16.240 0 0
1300 23.198 18.539 30.341 16.080 18.539 0 0
1400 23.572 20.878 32.074 17.161 20.878 0 0
1500 23.897 23.251 33.712 18.211 23.251 0 0

1600 24.185 25.656 35.263 19.228 25.656 0 0

1700 24.443 28.087 36.737 20.215 28.087 0 0
1800 24.676 30.544 38.141 21.173 30.544 0 0
1900 24.890 33.022 39.481 22.101 33.022 0 0
2000 25.089 35.521 40.763 23.002 35.521 0 0

2100 25.275 38.039 41.992 23.878 38.039 0 0

2200 25.449 40.576 43.172 24.728 40.576 0 0
2300 25.615 43.129 44.306 25.555 43.129 0 0
2400 25.773 45.698 45.400 26.359 45.698 0 0
2500 25.924 48.283 46.455 27.142 48.283 0 0
2600 26.070 50.883 47.475 27.904 50.883 0 0
2700 26.211 53.497 48.461 28.648 53.497 0 0
2800 26.347 56.125 49.417 29.372 56.125 0 0
2900 26.480 58.766 50.344 30.080 58.766 0 0
3000 26.609 61.421 51.244 30.770 61.421 0 0

3100 26.736 64.088 52.118 31.445 64.088 0 0

3200 26.860 66.768 52.969 32.104 66.768 0 0
3300 26.982 69.460 53.798 32.749 69.460 0 0
3400 27.102 72.164 54.605 33.380 72.164 0 0
3500 27.220 74.880 55.392 33.998 74.880 0 0

3600 27.337 77.608 56.161 34.603 77.608 0 0

3700 27.453 80.348 56.911 35.196 80.348 0 0
3800 27.568 83.099 57.645 35.777 83.099 0 0
3900 27.681 85.861 58.362 36.347 85.861 0 0
4000 27.794 88.635 59.065 36.906 88.635 0 0

4100 27.906 91.420 59.752 37.455 91.420 0 0

4200 28.017 94.216 60.426 37.994 94.216 0 0
4300 28.128 97.023 61.087 38.523 97.023 0 0
4400 28.238 99.842 61.735 39.043 99.842 0 0
4500 28.347 102.671 62.370 39.555 102.671 0 0

4600 28.456 105.511 62.995 40.057 105.511 0 0

4700 28.565 108.362 63.608 40.552 108.362 0 0
4800 28.674 111.224 64.210 41.039 111.224 0 0
4900 28.782 114.097 64.803 41.518 114.097 0 0
5000 28.890 116.980 65.385 41.989 116.980 0 0