Beruflich Dokumente
Kultur Dokumente
Electrostatic Precipitation
A Mizuno
Department of Ecological Engineering
Toyohashi University of Technology
Aichi, Japan
ABSTRACT
Electrostatic precipitators have been used widely in industry, and play an important role in
environmental protection. Electrostaticprecipitator (ESP) can be operated with a high collec-
tion efficiency and a low pressure drop. Recently, ESP also has been used for cleaning indoor
air. In this review, principles of electrostatic precipitation, such as particle charging, migra-
tion velocity of charged particles and collection efficiency, are described. Performance of ESP
deteriorates by abnormal phenomena,including back corona for treating high resistivity dust,
abnormal re-entrainment for low resistivity dust, and corona quenching for fine dusts. To cope
with these phenomena, new technologies have been developed. Pulsed energization is a tech-
nique to cope with high resistivity dusts, and this results in lower power consumption. Using
pulsed energization, non-thermal plasma can be generated and chemical reactions can be pro-
moted for treating gaseous pollutants such as NO and volatile organic compounds. Wet ESP
can also remove dusts and gaseous pollutants simultaneously, These new advancements will
widen the field of application of electrostatic precipitation. Some novel applications of ESP,
such as removal of dioxin from incinerators, are also included in this review.
Collecting electrodc
1 INTRODUCTION
2 PRINCIPLE
As shown in Figure 1, an ESP setup contains sharp discharge elec- Figure 1. Schematicdiagram of an electrostatic precipitator.
trodes and smooth collecting electrodes. When HVDC is applied to the
discharge electrode, a corona discharge takes place. Ions and electrons 2.1 CORONA DISCHARGE
are produced at the corona point, and ionic current flows through the The voltage-current characteristicsof a corona discharge [4-51 usu-
space. The ion polarity is either positive or negative. These ions attach ally is expressed as
to suspended solid particles. These charged particles are moved to-
I = AV(V - K) (1)
wards the collecting electrode by a Coulomb force, and are collected on
where A is a constant, V, the corona starting voltage, I the electric
that electrode. When the thickness of the layer of the collected solid par-
current and V the applied voltage. The flashover voltage of negative
ticles reaches a predetermined level, the collecting electrode is rapped
corona at an electrode separation d > 5x1OV2m, is -15d kV, with d
mechanically using a hammer, and the layer falls down into a hopper
in cm, and that of the positive corona is about half that of the negative
located below. These particles are then carried away to outside the ESP.
corona [4]. Usually the negative polarity is used because of the higher
1070-9878/0/$3.0002000 IEEE
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616 Mizuno: Electrostatic Precipitation
=SEO (
mikT 7) (g)
where q* is a charge constant (C), r*the time constant of the diffusion
charging (s),IC the Boltzmann constant c 1 . 3 8 ~ 1 0 J/K,
- ~ ~T the tem-
perature (K), e the electronic charge x 1 . 6 ~ 1 C, 0 Ci
~ ~the~ thermal
velocity of ion (m/s), ni the number density of ions in space (m), mi
the ion mass (kg) and pi is the ion mobility (V m/s2).
In diffusion charging, the particle charge increases logarithmically,
therefore the particle charge at t = 500r*, or 4500 = 6.2q*, can be
regarded as the saturation charge. q* and q500 are independent of E
and J , but proportional to the temperature T.The time constant of the
diffusion charging, r* is in proportion to J-).
2.3 THEORETICAL MIGRATION
VELOCITY OF CHARGED
PARTICLES
The Coulomb force of a suspended charged particle in an electric
field is
F = qE (8)
where F is the Coulomb force (N), q the particle charge (C) and E is
the electric field (Vim). The viscous force on a moving particle is given
by
F, = 37rpdpwe
~
(9)
C,
The particles are moved towards the collecting electrode with a ve-
locity we [lo]
Figure 2. Electrostatic field around a solid particle [l](a) no charge,
@) with charge.
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IEEE Transactions on Dielectrics and Electrical Insulation Vol. 7 N o . 5, October 2000 617
When field charging is applicable, the migration velocity is written hifh. This is an important advantage of ESP which has been used for
as ill CO lection of fine particles such as acid mists. Larger particles are col-
lected effectively,because the migration velocity is proportional to the
. . . ,
diameter of the particle.
The migration velocity is proportional to the particle diameter d, and Concerning the effect of the voltage and the current on the collection
to the square of the field strength E 2 . The migration velocity in the efficiency, the following relationship is often found in many industrial
diffusion charging is [l] ESP,with the value n M 2.
r ) = V"I (18)
Usually a higher collection performance can be obtained when ESP
is operated with the maximum available voltage.
3 CONSTRUCTION OF ESP
2.4 COLLECTION EFFICIENCY
3.1 TYPES OF ESP
The collection efficiency, r ) of ESP is given by Deutsch 1101
There are various types of industrial ESP according to their applica-
r ) = 1 - exp(-w,f)
= 1 - exp -w A (+-) tions, and they are classified as Cylindrical type and plate type (shape
of collecting electrodes);Vertical gas-flow and horizontal gas-flow (di-
rection of gas-flow); One stage and two stage (electrodes geometry);
where we is the migration velocity (m/s), f = A / Q the specific col- and Dry and wet type (with and without using water).
lection area (s/m) , A the area of the collecting electrode (m') and Q
the gas flow rate (m3/s).
Actually, the collection efficiency is affected by many factors, such as
the geometry of the electrodes, the characteristicsof dust particles, etc.,
and there are many reports to amend the theoretical collection efficiency
[11-17]. One example is
17 = 1 - exp (T)
-w,LK
where L is the length of the collecting electrode along the gas stream
(m), w, the gas velocity (m/s), b the separation between the discharge
and the collecting electrode (m), and K a correction factor determined
from actual measurements. Figure 4. Typical construction of plate type electrostatic precipitator
[411.
This detention time toand the gas velocity vo are important factors for Figure 4 shows a plate type ESP consisting of parallel plate elec-
determining the ESP performance. Usually, to and uo are designed to trodes for dust collection. The discharge electrodes are located between
be 10 s, and 0.5 to 2 m/s, respectively.
N the plates. The gas flow is horizontal. This is a dry, one stage ESP. This
g 99.9 type is used commonly in many industrial applications. As shown in
d 99.8 Figure 5, one-stage ESP uses a corona discharge to charge and collect
uh 99.7
I 99 particles at the same time, while two-stage ESP uses corona discharge
2 98 for particle charging and parallel plate electrodes for particle collection.
763 95 One-stage ESP is better to suppress re-entrainment of collected par-
$90 ticles, while in two-stage ESP,the area of the collecting electrode can be
-I increased by reducing the electrode spacing and the size of the ESP can
2 800, be reduced. Two-stage electrodes can be applied for collecting mists
B Pilltick dtamelcr d,>(pm) and adhesive particles.
Figure 3. Fractional collection efhciency [41]. The wet type ESP uses water spray, or running water on the col-
lecting electrode. A higher performance can be obtained because the
Typical fractional collection ESP efficiencies are shown in Figure 3 re-entrainment of collected particles can be eliminated [NI. The back
[l]. For submicrometer particles with 0.1 to 1 p m diameter, the ef- corona also can be suppressed. Gaseous pollutants can be absorbed at
ficiency is smaller. Because the migration velocity is proportional to the same time. These wet type ESP can be used to achieve very low
C,, the collection efficiency of smaller particles 5 0.1 p m becomes emission of particles from flue stacks.
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618 Mizuno: Electrostatic Precipitation
--
%arging zone Collecting zone
1 H.V. I
(a#@ - % d
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IEEE Transactions on Dielectrics and Electrical Insulation Vol. 7 No. 5, October 2000 619
3. Maintenance is easy as the number of moving parts is small. estimate the performance of an ESP. The gas temperature, water con-
4. The collection efficiency is affected by the dust resistivity p d . When
pd<102 Cl m, abnormal dust re-entrainment takes place. When Pd 2
5x10' R m, back corona takes place. For these extremely low or high
value of pd appears at 150 to 200C. -
tent, and the gas composition such as $03,affect Pd. Usually, the peak
ExcClsiYe sparking
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620 Mizuno: Electrostatic Precipitation
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IEEE Transactions on Dielectrics and Electrical Insulation Vol. 7"o. 5, October 2000 621
16.2
3.7
a
VI
W
Table 2. Dust collection efficiency of Mitsubishi dielectric droplet
scrubber (MDDS) [36] Pre-charger PS, charging section (CS), f flow
95 rate, T the gas-water ratio, t the CS retention time, cd the dust collec-
tion efficiency, and e, is the HC1 removal efficiency
90 I I
I
I
ESP
I SCR
I
I
I - - ! - r
I I
I I
!E" H.V. generator
_ _ _ _ _ _ _ r - _- -_ _
--- _ I_
I
Instead of dc, pulsed voltage is applied. The peak voltage of the pulse
can be higher than the dc flashover voltage, and more uniform corona
points can be obtained even with some irregularity of electrode spac-
ing. The ions emitted from the discharge electrode spread due to space
charge, and a more uniform corona current distribution can be ob-
tained. For large scale ESP having large capacitance, durations of ms
or ps can be used. Using semiconductor switching devices, efficient
pulse power supplies can be realized. To apply a pulse voltage, the ESP
capacitance should be charged, and then discharged rapidly As shown
in Figure 12, an LC oscillator circuit is used, and the energy stored in
the ESP capacitance can be recovered effectively As shown in Table 1,
the collection efficiency was improved with a ps pulse energy that con-
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622 Mizuno: Electrostatic Precipitation
Mist separator
as outlet
Parallel plate
electrode (CS)
I,
Gas inlet
Figure 14. Flue gas cleaning system for small scale incinerator [37].
11.75 0.083
PCDF 54.48 0.130
PCDD SPCDF 66.1 0.213 99.7
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IEEE Transactions on Dielectrics and Electrical Insulation Vol. 7 No. 5, October2000 623
Table 4. Dioxin removal by using wet type ESP [37], oxidized. Active charcoal or other catalysts also can be used for simul-
L Dioxin
1,2,3,7,8-PCOD
Test 1
Inlet Outlet
11 5 0 85 19
Test 2 Test 3
taneous removal of dust particles and gaseous pollutants. The exhaust
of ozone should be minimized when an ESP is used for indoor air clean-
ing.
0.68 80 6
1,2,3,4,7,8 HCDD 1 0 13 2 0.066 26 2 6.4 COLLECTION OF FINE
1,2,3,6,7,8-HCDD 1 0 15 2.2 0.065 41 4.3 PARTICLES
1,2,3,7,8,%HCDD 12 0 11 2.2 o , a ~ 32 2.8
1,2,3,4,6,7,8-HCDD 0 3 0.048 n.71 om3 0.8 0 . 0 ~ Particles having <2.5 pm diameter are of concern to human health.
OCDD
2,3,7,8-TCPP
0 018 0.0093
3.6 0 36
- 0.2
3.3
These small particles are generated by clustering or condensation from
the gas phase, and attach heavy metals or absorb volatile organic com-
1,2,3,7,8-TCOF 34 0 31 8.6
2,3,4,7,8-TCDF 26 5 33 60
pounds (VOC) on their surface. The number of these airborne particles
1,2,3,4,7,8-HCDF 62 0 B6 33 is large, and the emission of such particles should be lowered. As de-
1,2,3,6,7,8-HCDF 57 0 83 21 scribed above, there are several methods to increase the partial collec-
1,2,3,7,8,%HCDF 0 55 0 029 0.87 4.3 tion efficiency of such particles [39-401. These are summarized as
2,3,4,6,7,8-HCDF 38 0 65 26
1,2,3,4,6,7,8-HCDF 0.84 0 12 2.6 1. Use of two-stage ESP to increase the area of the collecting electrode, as
1,2,3,4,7,8,9=HCDF 0 088 0 011 0.4 the collection efficiency of fme particles follows the Deutsch equation.
OCDF 0 014 0.0029
2. Use of pre-agglomerationdevice as described above.
Total 73 72
3. Reduce the dust re-entrainmentby wet-type ESP.
4. Reduce the operating temperature to cause condensation of water.
12 mm This increases the diameter of the particles, and reduces the dust re-
t;c H.V. 300 mm
entrainmentby increasingadhesion.
7 CONCLUSIONS
~2t
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