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Problem #1: 0.2640 g of sodium oxalate is dissolved in a flask and requires 30.74 mL
of potassium permanganate (from a buret) to titrate it and cause it to turn pink (the end
point).
(a) How many moles of sodium oxalate are present in the flask?
(b) How many moles of potassium permanganate have been titrated into the flask to
reach the end point?
(c) What is the molarity of the potassium permanganate?
Solution to (a):
to four sig figs, this would be 0.001970 mol (1970 happens to be the year the
ChemTeam graduated from high school!)
Solution to (b):
From the balanced equation, the oxalate-permanganate molar ratio is five to two.
Solution to (c):
(a) Balance the net ionic equation using the half-reaction method.
(b) Determine the percent iron in the sample.
(c) Is the sample ferrous iodate, ferrous phosphate, or ferrous acetate?
Solution to (a):
The key point is the ferrous ion-dichromate molar ratio, which is six to one.
Solution to (b):
0.000524225 mol times (6 mol Fe(II) / 1 mol dichromate) = 0.00314535 mol Fe(II)
Solution to (c):
Which compound contains 13.76% iron? The only way to determine this is to
calculate the percent composition of the three sbstances.
Ferrous iodate:
Fe(IO3)2
Fe3(PO4)2 = 46.87%
Fe(C2H3O2)2 = 32.11 %
Problem #3: A solution contains both iron(II) and iron(III) ions. A 50.0 mL sample of
the solution is titrated with 35.0 mL of 0.00280 M KMnO4, which oxidizes Fe2+ to
Fe3+. The permangante ion is reduced to manganese(II) ion. Another 50.0 mL sample
of solution is treated with zinc metal, which reduces all the Fe3+ to Fe2+. The resulting
solution is again titrated with 0.00280 M KMnO4, this time 48.0 mL is required. What
are the concentrations of Fe2+ and Fe3+ in the solution?
Solution:
is five to one.
Solution:
1) Balance the equation (in acidic solution, remember the HCl from the problem
statement):
The key point is the bromate to Sb(III) molar ratio, which is one to three.
0.0054625 mol bromate times (3 mol Sb(III) / 1 mol bromate) = 0.0163875 mol
Sb(III)
Problem #5: A rock sample is to be assayed for its tin content by an oxidation-
reduction titration with I3(aq). A 10.00 g sample of the rock is crushed, dissolved in
sulfuric acid, and passed over a reducing agent so that all the tin is in the form Sn2+.
The Sn2+(aq) is completely oxidized by 34.60 mL of a 0.5560 M solution of NaI 3. The
balanced equation for the reaction is
Calculate the amount of tin in the sample and its mass percentage in the rock.
Solution:
the key point is the 1:1 molar ratio between triiodide and the stannous ion
0.0192376 mol times 118.710 g/mol = 2.284 g (to four sig figs)
Problem #6: The amount of I3(aq) in a solution can be determined by titration with a
solution containing a known concentration of S2O32(aq) (thiosulfate ion). The
determination is based on the balanced equation:
from the balanced equation, the molar ratio between triiodide and thiosulfate is:
one to two
therefore:
0.012012 mol of thiosulfate times (1 mol triiodide / 2 mol thiosulfate) = 0.006006 mol
triiodide
3) Determine molarity:
Solution:
3) Determine molarity:
0.00361875 mol / 0.03500 L = 0.1034 M (to four sig figs)
4) Determine milligrams:
Solution:
Comment: the actual reactions are different from the equation presented above. They
can be viewed here.
Please note that four H3AsO4 would be produced from one As4O6. However, to
produce one As4O10 would require four H3AsO4. So the above equation, while not
showing the actual chemical reactions, does accurately represent the ratio (which is
1:4) between As4O6 and triiodide.
Balance this equation and then calculate the concentration of the original MoO42(aq)
solution.
Solution:
the key point is the molar ratio between permanganate and molybdate, which is:
three to five
therefore:
Calculate the amount of iron in the sample and its mass percentage in the ore.
Solution:
the molar ratio for the reaction of permanganate and Fe(II) is:
one to five
therefore:
0.00161792 mol permanganate times (5 mol iron(II) / 1 mol permanganate) =
0.0080896 mol iron(II)
0.0080896 mol iron(II) times 55.845 g/mol = 0.4518 g (to four sig figs)
Solution:
4) Conclusion:
Mn is reduced from +7 to +3
Comment: this is a problem with a fake answer. Under the chemical circumstances
specified, manganese would be reduced to Mn2+. This problem is deliberately set up
to catch a "quickie" answer by the student who knows that, in the real world, the Fe
goes +2 to +3 and the Mn goes from +7 to +2.
Part of the real world underlying this problem is the knowledge that Mn, being at its
highest oxidation state, can only be reduced. Therefore, the Fe must be oxidized and,
based on real world knowledge, it can only go from +2 to +3.
Consequently, we can reason that the Mn goes down 4 in its oxidation number.
Problem #12: A 2.50 g sample of bronze, an alloy of copper and tin, was dissolved in
sulfuric acid. The copper in the alloy reacts with sulfuric acid as shown by the
following balanced reaction:
provides an indirect method for determining the amount of Cu in the original sample.
Calculate the percentage, by mass, of copper in a sample of bronze if 31.50 mL of
1.000 M S2O32 is consumed in the titration.
Solution:
2) S2O32 reacts with triiodide in 2:1 molar ratio. How much triiodide was consumed?
2 is to 0.03150 mol as 1 is to x
x = 0.01575 mol
3) Triiodide is in a 2:1 molar ratio with Cu2+ ion. For every 1 triiodide produced, two
copper ions were consumed. How much Cu2+ was consumed?
1 is to 0.01575 mol as 2 is to x
4) In the reaction between Cu and sulfuric acid, the molar ratio between Cu and
Cu2+ is 1:1. This means 0.03150 mol of Cu was consumed. How many grams of Cu is
this?
0.03150 mol times 63.546 g/mol = 2.00 g (to three sig figs)
6) A slight variation would be to combined chemical equations. Take the last equation
in the question and rearrange it as follows:
I3 ---> 3I + S4O62 - 2S2O32
The thing to notice in the above equation is the 1:1 molar ratio between the S2O32
and the Cu2+. That means that 0.03150 mol of S2O32 reacts with 0.03150 mol of
Cu2+. We can skip the calculation involving the triiodide.
Sometimes what I did can be done. Sometimes, it's too complex, so you suck it up and
just do all the backwards calculations one step at a time.