Solutions

1
AITS-CRT-II-(Paper-2) PCM(Sol)-JEE(Advanced)/15
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ANSWERS, HINTS & SOLUTIONS

CRT II
(Paper-2)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

A, B A, B, D A, B, C
1.
ALL INDIA TEST SERIES
B, D A, B, D B, C
2.
B, D A, B, D A, B
3.
B, D B, D A, D
4.
B, D A, B, C
5. A,D
A,B,D B, D A, B
6.
A,C,D A, B, C A, B
7.
A A, B, C, D B, C, D
8.
B C B
9.
A D B
10.
A C D
11.
C A B
12.
C D C
13.
C C A
14.
A D B
15.
D B C
16.
A D D
17.
C D C
18.
C B B
19.
B C D
20.
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2
Physics PART I
SECTION A
dU ke2
1. F 4
dr r
mv 2
F
r
ke2 mv 2
4 ... 1
r r
nh
and mvr ... 2
2
ke2 42 m Am
From (1) and (2) r 2
n2 n2 n
2
1 1 ke
T.E. = P.E 3
2 2 Am
3 2
n
6 3
T.E. n , T.E. m
P2
2. constant

P2 nRT
= constant
MP
PT constant
3. In loop ABCDA 2A A i 10 B
10i 2 2 i 0
i0
Potential difference across S 2 i 1 2V 2 -i
D C
1 2V
8. L/R = tan/6 R = 3
tan = 1/CR=1
=/4, leading P.D.
3
Chemistry PART II
SECTION A
1. CrO24
Ba 2
BaCrO 4

2 CrO24
Pb PbCrO 4 Yellow ppt.

CrO24
Sr 2 SrCrO 4

CrO24
2Ag Ag2CrO 4
Re d ppt.
CrO24
Hg22 Hg2CrO 4
2. O OH
H3C C N N C CH3
+
Ni 2
H3C C N N C CH3
HO O
[Ni(dmg)2]
4.

Zn s 2H aq 2
Zn aq H2 ....(1)
Zn2 H2
0.059
E E0cell
log
2
.....(2)
n H

Equilibrium (1) will shift in forward direction and cell potential E will increase.
5. Rate of zero order reactions is independent of the concentration of reaction

In this equation K = AeEa / RT
K = A when Ea = 0
Ea
logK log A
2.303RT
Plot of log K against 1/T is straight line with negative slope.
7. At anode At cathode

2Cl Cl2 2e
Mg2 2e Mg
No. of gm equivalent of Mg at cathode No of gm equivalent of Cl2 at Anode
13 WCl2

24.3 / 2 35.5
WCl2 37.98 gm
or nCl2 0.535
VCl2 = 11.98 lit at NTP
4
9.
O3 H2O Zn O OH O
O (Self Aldol Condensation)
(iodoform reaction in H+) NaIO /
CH3 (i) SOCl2 CH3

(ii) CH2 N2

O O
(iii) H2O / H
CO2
CH2 C OH (Arndt Estert Synthesis) C OH
(1,2-dimethyl
cyclopentene)
10.
O SOCl2 O
O
C OH C Cl
C Cl CH2 N N
H2C N N
O O O
N2 H
C C H C CH N N C CH2 N N
(Carbene)
H2O
CO2
CH C O CH2 COOH
(Unstable) (1,2-dimethyl cyclopentene)
N HO
11. Ba 2
Burning
Ba3N2
2
Ba OH 2 NH3 D
A B
BaCl2 green flame
Hg
+
KI
HgI2 K 2HgI4 3

NH
O NH2 I
12. KOH
Hg
5
13. Reaction of Mn3+ with H2O is spontaneous.
14. Reduction potential of I2 is less than Cl2.
Solution for the Q. No. 15 to 16.

(i) A turns lime water milky so A may be CO2 or SO2
(ii) B condenses into liquid turning anhydrous CuSO4 to blue, so B is H2O.
(iii) Y gives alkaline solution and its solution forms white ppt. Z with BaCl2 and Z on heating with acid
gives CO2 so, Z is BaCO3 and Y is metal carbonate.
(iv) Since, Y and A are formed from X and thus X is metal bicarbonate.
X A B Y
(v)
20.02 g 4.4 g 1.8 g 13.8 g
(vi) The above data reveal that,

2MHCO3 CO2 H2 O M2 CO3
X A B Y
4.4 of CO2 is obtained by 20.02 g of MHCO3
44 g CO2 is obtained by 200.2 g of MHCO3
200.2
Molecular weight of MHCO3 100.1
2
Atomic wt. of M 39.0 g/mole
Thus metal is potassium.
17. BF4 has sp3 hybridisation, CH3 is sp2, F2O is sp3 with two lone pairs on O. Also N2O is linear.
6
Mathematics PART III
SECTION A
(200)! (200)!
1. = = 1.3.5 ........ . 199
2! . 2!. .....2! 100 ! . 2100
(100)!
100 times
(200)! 101 102 200

100
= .......
100 ! . 2 2 2 2
bc a
2. Since, f(1) = 0 the other root is Q
ac b
c
1
Which can be written as a b
c
1
a b
c
Hence, Q
ab
3. a, b, c are in GP
2ab bc
= 12 , =3
ab 2
2a . ar
= 12, ar + ar2 = 6
a ar
ar = 6(1 + r), ar(1 + r) = 6
i.e. 6(1 + r)2 = 6, i.e. (1 + r)2 = 1
1 + r = 1 i.e. r = 0 or r = 2
r = 2
If r = 2, then a = 3
The GP is 3, 6, 12, 24, 48
3 6 12
Clearly no term of the series is square of an integer AM of a, b, c is = =3
3
4. Homogenizing auxiliary circle with normal at P

2 2 a2 (ax sec by cos ec)2
x +y =
(a2 b2 )2
a 4 sec 2 a2b2 cos ec 2
QOR = 90 1 + 1 + =0
(a2 b2 )2 (a2 b2 )2
2 2 2 4 2 2 2 2
2(a b ) = a sec + a b cosec
a4 5a2b2 + 2b4 = a4 tan2 + a2b2 cot2 2a3b.
x 2 5x 3 2x 5 3
2
5. f(x) = 3x x 4 6x 1 9
2
7x 6x 9 14x 6 21
f(x) = 0
f(x) is a constant polynomial and f(0) 0
d0
7
6. (1 + x2)2 (1 + x)n = (1 + 2x2 + x4) (nC0 + nC1 x + nC2 x2 + ......)

= nC0 + nC1 x + (nC2 + 2nC0) x2 + ......
Hence, A0 = 1; A1 = nC1; A2 = nC2 + 2 which are in A.P.

AB P B
7. OP = r = OA A 1
| AB | P

OB OA r

= i j 2k
| OB OA |
4j 3k
= i j 2k O
| 4j 3k |
1
= i j 2k (4j 3k)

5
1 , 1 (5i 9j 13k)

= (5i j 7k)
5 5
8. Put x = 1/t in u or v u = v
Now consider u + v
1/2 1/2
1 1/2 1
9. Px = f(x) dx = 2x dx = x2 =
2 0 4
x 0 0
10. Probability that life of a radio tube is less than or equal to 150 hours
150 150 150
100 100 1 1 1
= f(x) dx = 2
dx = = 100 =
0 100 x x 100 150 100 3
2
Probability that life is greater than 150 hrs =
3
2 2 2 8
Probability that none of these have life less than on equal to 150 hrs = = h
3 3 3 27
11. y = n x has graph here an element in co-domain can have 4 pre-images

y = x2 sin x is zero for infinitely many values of x
y = x3 + 3x + 1 is M.I. and hence one-one function
y = x4 x + 1 has graph
4
y = x x + 1 is two-one
12. From graph it is clear that any horizontal lines cuts the graph at either 1
1 3
one or two points between ,
2 2 1 1 O 1 3 2

2 2
13. At x = 1, y = 0
dy 4 2 2 2
= 2x(x ) (x ) = 2 1 = 1
dx
Equation of tangent y 0 = 1 (x 1), y = x 1
8
x
2
2
14. F(x) = et /2
(1 t ) dt
1
2
x2
F(x) = e 2 (1 x2 )

F(1) = e1/2.0 = 0
15. Let sin x = t; t [1, 1]

1
5 2t 6t 1 0 i.e. t
6
1
So, t ,1
6
1 2 2 1
Now squaring, , , t not possible t ,1
5 2t (6t 1) , t
2 9 9 6
1 1
So, t , sin x sin , x n ( 1)n
2 2 6 6
cos 2x cos 3x sin 2x

16. 2 3
sin2x sin3x cos2x
(2cos 2 x 1) 4 cos3 x 3 cos x 2sin x cos x /4 /4
2 3
2sin x cos x 3 sin x 4 sin3 x 2cos2 x 1
1
Now Let cos2 x = t in above i.e. t 0,1
2
These positions cant be the answer
4t 3 2t(1 t)
Now we have 2t 1 3t
4t 1 2t 1
1
Solving t = 1 but t 0,1
2
So there is no t, so there is no x
17. (P) Form the graph it is clear that x = 5 is the least positive integral value
for which x2 4x > cot1 x. y =
(Q) f(x) = 2ex + aex + 2a + 1 y =
x 2x x
= e (2e + (2a + 1)e + a)
x 2x x
= 2e (e + (a + 1/2)e + a/2)
x x x
= 2e (e + a)(e + 1/2) 0 (4, 0) (5, 0)
For f(x) to be increasing f(x) 0 x R
x
or e + a 0 x R
or a 0
1 f 2 (a x) f (a) 2
lim f (a x) (f (a))2
f 2 (a x) x x 0 xf(a)
lim
(R) lim = e
= e x 0 x = e4
x0
f(a)
k=4
1 2 1
(S) sin (x + 4x 3) = cos (2 |x|)
2
0 x + 4x 3 1 x [1, 3] ..... (1)
Also, 0 2 |x| 1 x [2, 1] [1, 2] ..... (2)
From (1) and (2) x {1, 2}
9
18. (P) Equation of any normal to y2 = 4x is y = tx + 2t + t3

Comparing it with y = 2x + c 4
t = 2 and 2t + t3 = c 4
c = 4 4 8 = 8
c = 8
3y 9
(Q) Equation of the chord whose mid point is (0, 3) is 1= 1
25 25
x2 y2 x2 9 16
i.e. y = 3 it intersects the ellipse + = 1 at 1
16 25 16 25 25
16
x=
5
32
Length of the chord =
5
4k 32
Thus k=8
5 5
(R) The product of the lengths of the perpendiculars from the two focii on any tangent to the hyperbola
x2 y2
= 1 is 3
25 3
3 = k , hence k = 9
(S) Since, x + y = a touches the hyperbola
x2 2y2 = 18
x2 2(a x)2 = 18 has equal roots
i.e., x2 4ax + 18 + 2a2 = 0 has equal roots
16a2 4(18 + 2a2) = 0
8a2 72 = 0 a = 3
|b| = 3
2 A
19. (P) From figure a b
3
2 ab b
2
and a b 2 1
B
a 60
C
ab 3 x
b
x=3
ab
(Q) f(x) = sin x, f(x) + f( x) = 2

f(x) = 2 f( x) = 2 sin ( x) = 2 sin x, where x ,
2
3
f(x) = f(2 x) = 2 sin(2 x), where x , 2
2

sin x , x 0,
2

2 sin x , x ,
2
f x
2 sin x , x , 3

2

3
sin x , x , 2
2

10
/2 3 /2 2
Area = sin xdx 2 sin xdx 2 sin x dx sin x dx
0 /2 3 /2

= 1 2 1 2 1 1 2 sq. units
2 2
(R) Since g = f 1 so fog(x) = x
Therefore f(g(x)) g(x) = 1
f(g(a)) g(a) = 1
1
f(b) 2 = 1 f(b) =
2
(S) Putting x = tan
1 x 2 1 sec 1
tan
x tan 2
1 x2 1 1
This u tan1 tan1 x
x 2 2
2x 1 x2
Putting x = sin , v tan1 2sin1 x
1 2x 2
1 1
du 2 1 x 2 du 1

dv 2 dv x 0 4
1 x2
20. (P) We have to select 3 no. from {1, 2, .....100}

Number division by 6 are 6, 12 ..... 96
16
C 4
Pr ob 100 3
C3 1155
(Q) 22nd century 2200, 2201 ..... 2299
2200 leap year (L), 2201 Non leap year (N)
1 3
In 22nd century: 25 L and 75 N, P(L) P(N)
4 4
366 2
For L: 366 days; 52
7 7
365 1
For N: 365 days; 52
7 7
1 2 3 1 5
Now P(53 Sunday) = P(L) P(53S/L) + P(N)P(53 Sun/N)
4 7 4 7 28
5 0
1 1 1 31
5
(R) P(at least one head) = 1 P (no head) = 1 C5 1
2 2 32 32
3 9 1 3 A B S(12)
(S) P(A B) , P(A B)
4 12 4 12
8 4 5 1 3 5
P(A) ; P(A) , P(A B)
12 12 12
3

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ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

5. Rate of zero order reactions is independent of the concentration of reaction

(iodoform reaction in H+) NaIO /

CH3 (i) SOCl2 CH3

13. Reaction of Mn3+ with H2O is spontaneous.

14. Reduction potential of I2 is less than Cl2.

Solution for the Q. No. 15 to 16.

(vi) The above data reveal that,

Mathematics PART III

(200)! 101 102 200

4. Homogenizing auxiliary circle with normal at P

6. (1 + x2)2 (1 + x)n = (1 + 2x2 + x4) (nC0 + nC1 x + nC2 x2 + ......)

11. y = n x has graph here an element in co-domain can have 4 pre-images

15. Let sin x = t; t [1, 1]

cos 2x cos 3x sin 2x

18. (P) Equation of any normal to y2 = 4x is y = tx + 2t + t3

20. (P) We have to select 3 no. from {1, 2, .....100}

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