SDSUS / EN / TSDSUS04

Version: 9.1
Revision Date: 07/07/2015
Initiator: 0001 / PRD
150000093408

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier
Product name: Skydrol 500B-4 Fire Resistant Hydraulic Fluid

Product No.: 34101-00, P3410105, P3410100, P3410101, P3410103, P3410102, P3410104

Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Hydraulic fluid
Uses advised against: None known.

Details of the supplier of the safety data sheet

Manufacturer / Supplier
Eastman Chemical Company
200 South Wilcox Drive
Kingsport, TN 37660-5280 US
+14232292000

Visit our website at www.EASTMAN.com or email emnmsds@eastman.com

Emergency telephone number:

For emergency health, safety, and environmental information, call 1-423-229-4511 or 1-423-229-2000.

For emergency transportation information, in the United States: call CHEMTREC at 800-424-9300 or call
423-229-2000.

SECTION 2: Hazards identification

Hazard Classification:
Health Hazards
Carcinogenicity Category 2

OSHA Specified Hazards: not applicable

Warning label items including precautionary statement:

Pictogram:

Signal Words: Warning

Hazard Statement(s): H351: Suspected of causing cancer.

COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 1/13

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Precautionary Statement:
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and
understood.
P280: Wear protective gloves/protective clothing/eye protection/face
protection.

Response: P308+P313: IF exposed or concerned: Get medical advice/attention.

Storage: P405: Store locked up.

Disposal: P501: Dispose of contents/container to an appropriate treatment and

disposal facility in accordance with applicable laws and regulations, and
product characteristics at time of disposal.

Hazard(s) not otherwise None known.

classified (HNOC):

SECTION 3: Composition/information on ingredients

Substances / Mixtures

General information:

Chemical name Concentration Additional identification Notes

Dibutylphenylphosphate 40 - 70% CAS-No.: 2528-36-1 #
tributyl phosphate 19 - 20% CAS-No.: 126-73-8 #
Butyl diphenyl phosphate 10 - 30% CAS-No.: 2752-95-6
7-Oxabicyclo[4.1.0]heptane-3- <10% CAS-No.: 62256-00-2
carboxylic acid, 2-ethylhexyl ester
butylated hydroxytoluene 0.1 - <1% CAS-No.: 128-37-0 #
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
# This substance has w orkplace exposure limit(s).

SECTION 4: First aid measures

General: Get medical attention if symptoms occur. Show this safety data sheet to the
doctor in attendance. If breathing is difficult, give oxygen. If not breathing,
give artificial respiration. Place unconscious person on the side in the
recovery position and ensure breathing can take place. Ensure that medical
personnel are aware of the material(s) involved and take precautions to
protect themselves.

Description of first aid measures

Inhalation: In case of inhalation of spray mist: Move person into fresh air and keep at
rest. For breathing difficulties, oxygen may be necessary. Consult a
physician for specific advice. Persons who have inhaled vapours or smoke
fumes have to be put under medical observation for at least 48 hours, due
to the delayed appearance of poisoning.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Get medical attention if symptoms occur.

COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 2/13


Skin contact:
Ingestion:
Most important symptoms and
effects, both acute and
delayed:
Indication of any immediate medical attention and special treatment needed
Hazards: No data available.
Treatment:
SECTION 5: Firefighting measures
General Fire Hazards:
Extinguishing media
Suitable extinguishing
media:
Unsuitable extinguishing
media:
Special hazards arising from
the substance or mixture:
Advice for firefighters
Special fire fighting
procedures:
Special protective
equipment for fire-fighters:
SECTION 6: Accidental release measures
COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY
SDSUS / EN / TSDSUS04
Version: 9.1
Revision Date: 07/07/2015
Initiator: 0001 / PRD
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Immediately flush with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. If skin irritation or an allergic
skin reaction develops, get medical attention. Wash contaminated clothing
before reuse. Destroy or thoroughly clean contaminated shoes.
If swallowed, rinse mouth with water (only if the person is conscious). Call a
physician or poison control center immediately. Do not induce vomiting
without advice from poison control center. Never give liquid to an
unconscious person. Provide fresh air, warmth and rest, preferably in
comfortable upright sitting position. Loosen tight clothing such as a collar,
tie, belt or waistband. If vomiting occurs, keep head low so that stomach
content doesn't get into the lungs.
Eye may become red, tear, and become painful. The product contains a
small amount of sensitizing substance which may provoke an allergic
reaction among sensitive individuals. Limited evidence of a carcinogenic
effect.
Treat symptomatically.
Promptly isolate the scene by removing all persons from the vicinity of the
incident if there is a fire. Keep upwind. In case of fire and/or explosion do
not breathe fumes.
Water spray, foam, dry powder or carbon dioxide.
Avoid water in straight hose stream; will scatter and spread fire.
May ignite at high temperature. During fire, gases hazardous to health may
be formed. Risk of chemical pneumonia after aspiration. Hazardous
Combustion Products : carbon dioxide, carbon monoxide , oxides of
phosphorus .
In case of fire: Evacuate area. Move container from fire area if it can be
done without risk. Use water spray to keep fire-exposed containers cool.
Prevent runoff from fire control or dilution from entering streams, sewers, or
drinking water supply. Fire residues and contaminated fire extinguishing
water must be disposed of in accordance with local regulations.
Self-contained breathing apparatus and full protective clothing must be
worn in case of fire.
3/13

Personal precautions,
protective equipment and
emergency procedures:
Environmental Precautions:
Methods and material for
containment and cleaning
up:
Notification Procedures:
SECTION 7: Handling and storage:
Precautions for safe handling:
Conditions for safe storage,
including any
incompatibilities:
Specific end use(s):
COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY
SDSUS / EN / TSDSUS04
Version: 9.1
Revision Date: 07/07/2015
Initiator: 0001 / PRD
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No action shall be taken involving any personal risk or without suitable
training. Keep unauthorized personnel away. Ventilate closed spaces
before entering them. Avoid inhalation of vapors and spray mists. Wear
appropriate personal protective equipment. Caution: Contaminated
surfaces may be slippery. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Reference to other
sections See Section 8 of the SDS for Personal Protective Equipment.
Prevent further leakage or spillage if safe to do so. Clear up spills
immediately and dispose of waste safely. Do not contaminate water
sources or sewer.
Small Liquid Spills: Use a non-combustible material like vermiculite, sand or
earth to soak up the product and place into a container for later disposal.
Large Spillages: Dike for later disposal. Collect spillage in containers, seal
securely and deliver for disposal according to local regulations. Ot herwise,
absorb spill with vermiculite or other inert material, then place in a container
for chemical waste. Clean surface thoroughly to remove residual
contamination. Prevent runoff from entering drains, sewers, or streams.
In the event of a spill or accidental release, notify relevant authorities in
accordance with all applicable regulations.
Do not handle until all safety precautions have been read and understood.
Handle product only in closed system or provide appropriate exhaust
ventilation at machinery. An eye wash bottle must be available at the work
site. Wear appropriate personal protective equipment. See Section 8 of the
SDS for Personal Protective Equipment. Do not taste or swallow. Do not
breathe mist or vapor from heated material. In case of inadequate
ventilation, use respiratory protection. Do not get in eyes and avoid contact
with skin and clothing. Wash promptly with soap and water if skin becomes
contaminated. Remove contaminated clothing and wash it before reuse.
Destroy or thoroughly clean contaminated shoes. Drain or remove
substance from equipment prior to break-in or maintenance. Handle in
accordance with good industrial hygiene and safety practice. See also
Section 8 for additional information on hygiene measures.
Store in a cool, dry place out of direct sunlight. Keep container tightly
closed and in a well-ventilated place. Keep upright. Keep in original
container. Store locked up. Store away from incompatible materials. Keep
away from food, drink and animal feeding stuffs. Store in accordance with
local/regional/national/international regulations.
www.EastmanAviationSolutions.com
4/13

SECTION 8: Exposure controls/personal protection
Control Parameters
Occupational Exposure Limits
Chem ical name
Tributyl phosphate -
Inhalable fraction and vapor.
Tributyl phosphate
Dibutylphenylphosphate
butylated hydroxytoluene,
2,-6-Di-tert-butyl-p-cresol -
Inhalable fraction and vapor.
Exposure controls
Appropriate engineering
controls:
Individual protection measures, such as personal protective equipment
General information:
Eye/face protection:
COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY
SDSUS / EN / TSDSUS04
Version: 9.1
Revision Date: 07/07/2015
Initiator: 0001 / PRD
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Country specific exposure limits have not been established or are not applicable
unless listed below.
type Exposure Lim it Values Source
TWA 5 mg/m3 US. ACGIH Threshold Limit Values (02 2013)
REL 0.2 ppm 2.5 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA 0.2 ppm 2.5 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
TWA 0.3 ppm US. ACGIH Threshold Limit Values (01 2010)
TWA 2 mg/m3 US. ACGIH Threshold Limit Values (01 2010)
Good general ventilation (typically 10 air changes per hour) should be used.
Ventilation rates should be matched to conditions. If applicable, use
process enclosures, local exhaust ventilation, or other engineering controls
to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an
acceptable level.
An eye wash bottle must be available at the work site. Provide access to
washing facilities including soap, skin cleanser and fatty cream.
Safety eyewear complying with an approved standard should be used when
a risk assessment indicates this is necessary to avoid exposure to liquid
splashes, mists, gases or dusts. Recommendations: Wear safety glasses
with side shields (or goggles). Use safety goggles and face shield in case of
splash risk.
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Skin protection
Hand Protection: It is a good industrial hygiene practice to minimize skin contact. If
prolonged or repeated contact is likely, chemical resistant gloves are
recommended. If contact with forearms is likely, wear gauntlet style gloves.
Contact the glove manufacturer for specific advice on glove selection and
breakthrough times for your use conditions. After contamination with
product change the gloves immediately and dispose of them according to
relevant national and local regulations.

Other: Personal protective equipment for the body should be selected based on
the task being performed and the risks involved and should be approved by
a specialist before handling this product. Recommendations: Apron or other
light protective clothing and boots. If prolonged or repeated contact is likely,
chemical resistant clothing is recommended. Promptly remove non-
impervious clothing that becomes wet or contaminated.

Respiratory Protection: If engineering controls do not maintain airborne concentrations below

recommended exposure limits (where applicable) or to an acceptable level
(in countries where exposure limits have not been established), an
approved respirator must be worn. In the United States of America, if
respirators are used, a program should be instituted to assure compliance
with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: Air-
purifying respirator with an appropriate, government approved (where
applicable), air-purifying filter, cartridge or canister. Contact health and
safety professional or manufacturer for specific information.

Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Do
not eat, drink or smoke when using the product. Wash at the end of each
work shift and before eating, smoking and using the toilet. Contaminated
work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reuse. Keep away from food, drink and animal
feeding stuffs.

Environmental Controls: Emissions from ventilation or work process equipment should be checked
to ensure they comply with the requirements of environmental protection
legislation. In some cases, fume scrubbers, filters or engineering
modifications to the process equipment will be necessary to reduce
emissions to acceptable levels. Do not contaminate water sources or
sewer.

SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties

Appearance
Physical state: liquid
Form: liquid oil
Color: purple
Odor: Odorless
Odor Threshold: No data available.
pH: No data available.
Melting Point < -62 C
Boiling Point: No data available.
Flash Point: > 177 C
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Evaporation Rate: No data available.

Flammability (solid, gas): not applicable
Flammability Limit - Upper (%): No data available.
Flammability Limit - Lower (%): No data available.
Vapor pressure: 0.27 hPa (25 C)
Vapor density (air=1): Not available.
Specific Gravity: 1.052 - 1.060 (25 C)
Solubility(ies)
Solubility in Water: No data available.
Solubility (other): No data available.
Partition coefficient (n-octanol/water): Not available.
Autoignition Temperature: 398 C (ASTM D2155)
Decomposition Temperature: No data available.
Dynamic viscosity: No data available.
Kinematic viscosity: < 2,900 mm2/s (-54 C) | 11.4 - 12.4 mm2/s (38 C) | 3.68
- 4 mm2/s (99 C)
Explosive properties: Not classified.
Oxidizing properties: Not classified.

SECTION 10: Stability and reactivity

Reactivity: Material is stable under normal conditions.

Chemical Stability: Material is stable under normal conditions.

Possibility of Hazardous None under normal conditions.

Reactions:

Conditions to Avoid: None known.

Incompatible Materials: Strong oxidizing agents.

Hazardous Decomposition Emits acrid smoke and fumes when heated to decomposition.
Products:

SECTION 11: Toxicological information

Information on likely routes of exposure

Inhalation: None known.

Ingestion: None known.

Skin contact: The product contains a small amount of sensitizing substance which may
provoke an allergic reaction among sensitive individuals in contact with
skin.

Eye contact: Eye may become red, tear, and become painful.

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Information on toxicological effects

Oral
Product: Oral LD-50: (Rat, Male and Female): 2,200 mg/kg (Measured) Target Organ(s): Liver
Not classified.

Dermal
Product: Dermal LD-50: (Rabbit, Male and Female): > 7,940 mg/kg (Measured)
Not classified.

Inhalation
Product: Dusts, mists and fumes: LC50 (Rat, Male and Female, 4 h): 4.5 mg/l (Measured) Not
classified. (highest concentration tested)

Repeated dose toxicity

Product: NOAEL (Rat(Male and Female), Inhalation - dust and mist): 100 mg/m3 (Target
Organ(s): Blood, Liver)

Skin Corrosion/Irritation
Product: Measured (Rabbit, 24 h): Slightly irritating.

Serious Eye Damage/Eye Irritation

Product: Measured (Rabbit, 24 h): Slightly irritating.

Respiratory or Skin Sensitization

Product: Skin Sensitization, Human Repeat Insult Patch Test (Human Repeat Insult Patch
Test): Not a skin sensitizer.

Carcinogenicity
Product: No data available.

Specified substance(s):
Dibutylphenylphosphate IARC Not Listed. NTP Not Listed. OSHA Not Listed.

Specified substance(s):
Tributyl phosphate Rat, Male and Female: Ingestion ; EPA OTS 798.3300Limited evidence of a
carcinogenic effect.
IARC Not Listed. NTP Not Listed. OSHA Not Listed.

Specified substance(s):
Butyl diphenyl phosphate IARC Not Listed. NTP Not Listed. OSHA Not Listed.

Specified substance(s):
2-Ethylhexyl 7- IARC Not Listed. NTP Not Listed. OSHA Not Listed.
oxabicyclo[4.1.0]heptane-3-
carboxylate
Specified substance(s):
butylated hydroxytoluene, IARC Not Listed. NTP Not Listed. OSHA Not Listed.
2,-6-Di-tert-butyl-p-cresol

Toxicity to reproduction
Product: No data available.

Specified substance(s):
Dibutylphenylphosphate (Rat, Male and Female); NOAEL: 5 mg/l; NOAEL: 50 mg/kg; NOAEL: 50
mg/kg; Ingestion; EPA OTS 798.4900

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Specified substance(s):
Tributyl phosphate Two Generation Reproductive Toxicity Study (Rat, Male and Female);
NOAEL: 225 mg/kg; Ingestion; EPA OTS 798.4900

Developmental toxicity
Product: No data available.

Specified substance(s):
Dibutylphenylphosphate Rat; NOAEL: 300 mg/kg; NOAEL: 3 mg/kg; Gavage (Oral)

Specified substance(s):
Tributyl phosphate Rat; NOAEL: 750 mg/kg; Gavage (Oral); EPA OTS 798.4900

Germ Cell Mutagenicity

In vitro
Product: Salmonella typhimurium assay (Ames test) (Bacterial Reverse Mutation Assay):
negative
Mutagenicity - Mammalian (In vitro Mammalian Cell Gene Mutation Test): negative

In vivo
Product: No data available.
Specified substance(s):
Dibutylphenylphosphate Chromosomal aberration intraperitoneal injection (Rat, Male and Female): negative
Specified substance(s):
Tributyl phosphate Chromosomal aberration (Mammalian Bone Marrow Chromosome Aberration Test)
oral: gavage (Rat, Male and Female): negative
Specified substance(s):
2-Ethylhexyl 7- Chromosomal aberration (Mammalian Bone Marrow Chromosome Aberration Test)
oxabicyclo[4.1.0]heptane-3- Intraperitoneal (Rat, Male and Female): equivocal
carboxylate

Specific Target Organ Toxicity - Single Exposure

Product: Inhalation: Not classified.

Specific Target Organ Toxicity - Repeated Exposure

Product: Inhalation: Blood, Liver - Not classified.

Aspiration Hazard
Product: not applicable

Other effects: No data available.

SECTION 12: Ecological information

Ecotoxicity:
Acute hazards to the aquatic environment:
Fish
Product: LC-50 (Rainbow Trout, 96 h): 2.6 mg/l
EC-50 (Fathead Minnow, 96 h): 3.0 mg/l

COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 9/13


Aquatic Invertebrates
Product:
Chronic hazards to the aquatic environment:
Fish
Product:
Specified substance(s):
Dibutylphenylphosphate
Tributyl phosphate
Aquatic Invertebrates
Product:
Specified substance(s):
Dibutylphenylphosphate
Tributyl phosphate
Toxicity to Aquatic Plants
Product:
Persistence and Degradability
Biodegradation
Product:
Specified substance(s):
Dibutylphenylphosphate
Tributyl phosphate
2-Ethylhexyl 7-
oxabicyclo[4.1.0]heptane-3-
carboxylate
BOD/COD Ratio
Product:
Bioaccumulative Potential
Bioconcentration Factor (BCF)
Product:
Specified substance(s):
Dibutylphenylphosphate
Tributyl phosphate
Partition Coefficient n-octanol / water (log Kow)
Product:
COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY
SDSUS / EN / TSDSUS04
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Initiator: 0001 / PRD
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LC-50 (Daphnia magna, 48 h): 6.5 mg/l
No data available.
NOEC (Oncorhynchus mykiss , 60 d): > 0.11 mg/l
NOEC (Oncorhynchus mykiss , 95 d): 0.82 mg/l
LOEC : 1.7 mg/l
No data available.
NOEC (Daphnia magna, 21 d): 0.106 mg/l
NOEC (Daphnia magna, 21 d): 1.3 mg/l
EC-50 (Selenastrum capricornutum, 72 h): 7.8 mg/l
No data available.
Readily biodegradable, failing 10-d window
Not readily degradable.
Readily biodegradable
Readily biodegradable.
No data available.
No data available.
Common Carp, Bioconcentration Factor (BCF): 35 (OECD Guideline Test No. 305:
Bioaccumulation in Fish: Aqueous and Dietary Exposure)
Common Carp, Bioconcentration Factor (BCF): 20 (OECD Guideline Test No. 305:
Bioaccumulation in Fish: Aqueous and Dietary Exposure)
Bioconcentration Factor (BCF): 35
Log Kow: Not available.
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Mobility in Soil: No data available.

Known or predicted distribution to environmental compartments

Tributyl phosphate Log Koc: 3.344

Other Adverse Effects: No data available.

SECTION 13: Disposal considerations

Waste treatment methods

General information: The generation of waste should be avoided or minimized wherever

possible.

Disposal methods:
This product meets the criteria for a synthetic used oil under the U.S. EPA
Standards for the Management of Used Oil (40 CFR 279). Those
standards govern recycling and disposal in lieu of 40 CFR 260 -272 of the
Federal hazardous waste program in states that have adopted these used
oil regulations. Consult your attorney or appropriate regulatory official to be
sure these standards have been adopted in your state. Recycle or burn in
accordance with the applicable standards. Do not discharge into drains,
water courses or onto the ground.

Since emptied containers retain product residue, follow label warnings even
after container is emptied. Empty containers should be taken to an
approved waste handling site for recycling or disposal.

SECTION 14: Transport information

Important Note: Shipping descriptions may vary based on mode of transport, quantities, pack age size,
and/or origin and destination. Consult your company's Hazardous Materials/Dangerous Goods expert for
information specific to your situation.

DOT
Class not regulated

IMDG - International Maritime Dangerous Goods Code

Class not regulated

IATA
Class not regulated

TDG
Class not regulated

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SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture.:

SARA 311-312 Hazard Classification(s):

immediate (acute) health hazard
delayed (chronic) health hazard

US EPCRA (SARA Title III) Section 313 - Toxic Chemical List

NONE

OSHA: hazardous

TSCA (US Toxic Substances Control Act): The intentional components of this product are listed on the
TSCA inventory. Any impurities present in this product are exempt from listing.

DSL (Canadian Domestic Substances List) and CEPA (Canadian Environmenta l Protection Act): All
components of this product are listed on the DSL. Any impurities present in this product are exempt from
listing.

AICS / NICNAS (Australian Inventory of Chemical Substances and National Industrial Chemicals
Notification and Assessment Scheme): All components of this product are listed on AICS or otherwise
comply with NICNAS.

MITI (Japanese Handbook of Existing and New Chemical Substances): All components of this product are
listed in the Handbook or have been approved in Japan by new substance notification.

ECL (Korean Toxic Substances Control Act): One or more components of this product are not listed on the
Korean inventory.

Philippines Inventory (PICCS) : One or more components of this product are not listed on the Philippine
inventory.

Inventory of Existing Chemical Substances in China: All intentional components of this product are listed
on the Inventory of Existing Chemical Substances in China (IECSC).

SECTION 16: Other information

HMIS Hazard Ratings: Health - 2*, Flammability - 1, Chemical Reactivity - 0

HMIS rating involves data interpretations that may vary from company to company. They are intended only for rapid, general
identification of the magnitude of the specific hazard. To deal adequately with the safe handling of this material, all the i nformation
contained in this MSDS must b e considered.

Revision Information: Not relevant.

Key literature references and www.EastmanAviationSolutions.com

sources for data:
Training information: No data available.

Issue Date: 07/07/2015

SDS No.:

COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 12/13

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Disclaimer: This information is provided without warranty. The information is believed to

be correct. This information should be used to make an independent
determination of the methods to safeguard workers and the environment.

COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 13/13