(English+Hindi)

CHEMISTRY U S

1. An ideal gas undergoes isothermal

expansion at constant pressure. During 1. SU U U
the process : U
(1) enthalpy increases but entropy
decreases. (1) U U U
(2) enthalpy remains constant but
entropy increases.
(2) SU U U U
(3) enthalpy decreases but entropy
increases.
(4) Both enthalpy and entropy remain (3) U U U U
constant.
(4) U SU U
2. 50 mL of 0.2 M ammonia solution is
treated with 25 mL of 0.2 M HCl. If pKb
of ammonia solution is 4.75, the pH of the
mixture will be : 2. 0.2 M 50 mL 0.2 M
(1) 3.75 HCl 25 mL
(2) 4.75 pKb 4.75
(3) 8.25 pH
(4) 9.25 (1) 3.75
(2) 4.75
3. The electron in the hydrogen atom (3) 8.25
undergoes transition from higher orbitals (4) 9.25
to orbital of radius 211.6 pm. This
transition is associated with :
(1) Lyman series 3. U U U U U
(2) Balmer series 211.6 pm U U

(3) Paschen series

(4) Brackett series
(1)
(2) U
(3)
(4) U

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4. At 300 K, the density of a certain gaseous 4. 300 K U; 2 U U U

molecule at 2 bar is double to that of
, 4 U U U UU (N2)
dinitrogen (N2) at 4 bar. The molar mass
of gaseous molecule is : U
(1) 28 g mol1
(1) 28 g mol1
(2) 56 g mol1
(2) 56 g mol1
(3) 112 g mol1
(3) 112 g mol1
(4) 224 g mol1
(4) 224 g mol1

5. What quantity (in mL) of a 45% acid

solution of a mono-protic strong acid must 5. U 45% U
be mixed with a 20% solution of the same (mL ) 20%
acid to produce 800 mL of a 29.875% acid
solution ?
29.875%
U 800 mL ?
(1) 320
(2) 325
(1) 320
(3) 316
(2) 325
(4) 330
(3) 316
(4) 330
6. To find the standard potential of M3+/M
electrode, the following cell is constituted :
Pt/M/M 3+ (0.001 mol L 1 )/Ag + (0.01 6. M3+/M UU
mol L1)/Ag

The emf of the cell is found to be 0.421 Pt/M/M 3+ (0.001 mol L 1 )/Ag + (0.01
volt at 298 K. The standard potential of mol L1)/Ag
half reaction M3++3e M at 298 K will
be : ... 298 K ,U 0.421 V
298 K U, M3++3e M, h

(1) 0.38 Volt
)
(2) 0.32 Volt
(3) 1.28 Volt (1) 0.38 V

(4) 0.66 Volt (2) 0.32 V

(3) 1.28 V
(4) 0.66 V

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7. A gas undergoes change from state A to 7. S A S B

state B. In this process, the heat absorbed
, mU c
and work done by the gas is 5 J and 8 J,
respectively. Now gas is brought back to 5 J 8 J U
A by another process during which 3 J of mU A S 3 J c
heat is evolved. In this reverse process of B A U
B to A :
(1) 10 J of the work will be done by the
gas.
(2) 6 J of the work will be done by the (1) mU 10 J
gas.
(3) 10 J of the work will be done by the (2) mU 6 J
surrounding on gas.
(4) 6 J of the work will be done by the (3) U U mU 10 J
surrounding on gas.

(4) U U mU 6 J
8. Adsorption of a gas on a surface follows
Freundlich adsorption isotherm. Plot of
x
log versus log p gives a straight line
m 8. cU U , U
with slope equal to 0.5, then : U U log p
x x
( is the mass of the gas adsorbed per Lh log U U U
m m
gram of adsorbent)
S 0.5 UU ,
(1) Adsorption is independent of x
pressure.
( m , mU
(2) Adsorption is proportional to the )
pressure.
(1) , U
(3) Adsorption is proportional to the
square root of pressure.
(2) ,
(4) Adsorption is proportional to the
square of pressure.
(3) ,

(4) ,

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9. The rate of a reaction quadruples when 9. 300 310 K U

the temperature changes from 300 to
U U
310 K. The activation energy of this
reaction is : :
(Assume activation energy and pre- ( U
exponential factor are independent of UU U U ;
temperature; ln 2=0.693; R=8.314 J
ln 2=0.693; R=8.314 J mol1 K1)
mol1 K1)
(1) 107.2 kJ mol1
(2) 53.6 kJ mol1
(1) 107.2 kJ mol1
(3) 26.8 kJ mol1
(2) 53.6 kJ mol1
(4) 214.4 kJ mol1
(3) 26.8 kJ mol1
(4) 214.4 kJ mol1
10. A solution is prepared by mixing 8.5 g of
CH2Cl2 and 11.95 g of CHCl3. If vapour
pressure of CH2Cl2 and CHCl3 at 298 K 10. 8.5 g CH2Cl2 11.95 g CHCl3 U
are 415 and 200 mmHg respectively, the U 298 K U
mole fraction of CHCl3 in vapour form is :
(Molar mass of Cl=35.5 g mol1) CH2Cl2 CHCl3 c 415
200 mmHg c M S
(1) 0.162 CHCl3

(2) 0.675 (Cl U =35.5 g mol1)

(3) 0.325
(1) 0.162
(4) 0.486
(2) 0.675
(3) 0.325
11. The electronic configuration with the
highest ionization enthalpy is : (4) 0.486
(1) [Ne] 3s2 3p1
(2) [Ne] 3s2 3p2 11. U
(3) [Ne] 3s2 3p3
(4) [Ar] 3d10 4s2 4p3 (1) [Ne] 3s2 3p1
(2) [Ne] 3s2 3p2
(3) [Ne] 3s2 3p3
(4) [Ar] 3d10 4s2 4p3

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12. The following reaction occurs in the Blast 12. ^ (SU U)

Furnace where iron ore is reduced to iron
U S U U
metal :
;
Fe2O3(s)+3 CO(g) 2 Fe(l)+3 CO2(g)
Fe2O3(s)+3 CO(g) 2 Fe(l)+3 CO2(g)
Using the Le Chateliers principle, predict
which one of the following will not disturb - h U
the equilibrium ?
(1) Removal of CO U?
(2) Removal of CO2 (1) CO U U
(3) Addition of CO2
(2) CO2 U U
(4) Addition of Fe2O3
(3) CO2
13. Which one of the following is an oxide ? (4) Fe2O3
(1) KO2
(2) BaO 2 13. , U ?
(3) SiO2 (1) KO2
(4) CsO2 (2) BaO 2
(3) SiO2
14. Which of the following is a set of green (4) CsO2
house gases ?
(1) CH4, O3, N2, SO2
14. ?
(2) O3, N2, CO2, NO2
(3) O3, NO2, SO2, Cl2
(1) CH4, O3, N2, SO2
(4) CO2, CH4, N2O, O3
(2) O3, N2, CO2, NO2
(3) O3, NO2, SO2, Cl2
(4) CO2, CH4, N2O, O3

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15. The group having triangular planar 15. U ,

structures is :
2
(1) BF3, NF3, CO 3 2
(1) BF3, NF3, CO 3
(2) CO 23 , NO
3 , SO3 (2) CO 23 , NO
3 , SO3
(3) NH3, SO3, CO 23
(3) NH3, SO3, CO 23
(4) NCl3, BCl3, SO3
(4) NCl3, BCl3, SO3

16. XeF 6 on partial hydrolysis with water

produces a compound X. The same 16. XeF6, -U U
compound X is formed when XeF6 reacts U, X X
with silica. The compound X is : XeF6 U
(1) XeF2 X
(2) XeF4 (1) XeF2
(3) XeOF4 (2) XeF4
(4) XeO3 (3) XeOF4
(4) XeO3
17. The number of POH bonds and the
oxidation state of phosphorus atom in
pyrophosphoric acid (H 4 P 2 O 7 ) 17. USU U (H4P2O7) POH
respectively are : SU U
(1) four and four U S
(2) five and four
(3) five and five (1) U U
(4) four and five (2) U
(3)
(4) U

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18. Which of the following ions does not 18.

liberate hydrogen gas on reaction with U U U ?
dilute acids ?
(1) Ti2+
(1) Ti2+
(2) V2+
(2) V2+
(3) Cr2+
(3) Cr2+
(4) Mn2+
(4) Mn2+

19. The correct sequence of decreasing number

of -bonds in the structures of H 2SO 3, 19. H2SO3, H2SO4 H2S2O7 U
H2SO4 and H2S2O7 is : - U
(1) H2SO3 > H2SO4 > H2S2O7
(2) H2SO4 > H2S2O7 > H2SO3 (1) H2SO3 > H2SO4 > H2S2O7
(3) H2S2O7 > H2SO4> H2SO3 (2) H2SO4 > H2S2O7 > H2SO3
(4) H2S2O7 > H2SO3 > H2SO4 (3) H2S2O7 > H2SO4> H2SO3
(4) H2S2O7 > H2SO3 > H2SO4
20. [Co2(CO)8] displays :
(1) one CoCo bond, six terminal CO 20. [Co2(CO)8] U
and two bridging CO
(2) one CoCo bond, four terminal CO (1) CoCo , U UU CO
and four bridging CO CO
(3) no CoCo bond, six terminal CO (2) CoCo , U UU CO
and two bridging CO
U CO
(4) no CoCo bond, four terminal CO
and four bridging CO (3) CoCo , U UU CO
CO
(4) CoCo , U UU CO
U CO

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21. A compound of molecular formula 21. C8H8O2 , U

C8H8O2 reacts with acetophenone to form
U S U
a single cross-aldol product in the presence
of base. The same compound on reaction -U
with conc. NaOH forms benzyl alcohol as NaOH U ,
one of the products. The structure of the ,
compound is :
U

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

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22. Which of the following compounds is most 22. , U U

reactive to an aqueous solution of sodium
,
carbonate ?
?

(1)
(1)

(2)
(2)

(3)
(3)

(4)
(4)

23. In the following structure, the double

bonds are marked as I, II, III and IV 23. U , m I, II, III IV
q

Geometrical isomerism is not possible at

site (s) :
S/ S
(1) III
(2) I
(1) III
(3) I and III
(2) I
(4) III and IV
(3) I III

(4) III IV

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24. The major product of the following 24.

reaction is :

(1)
(1)

(2)
(2)

(3)
(3)

(4)
(4)

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25. The incorrect statement among the 25.

following is :
(1) -D-glucose and -D-glucose are
(1) -D- -D- U
anomers.
(2) -D-glucose and -D-glucose are
enantiomers. (2) -D- -D- M
(3) Cellulose is a straight chain
polysaccharide made up of only
-D-glucose units.
(3) o UU
-D-
(4) The penta acetate of glucose does not
react with hydroxyl amine.
(4) U UU, U
26. Which of the following is a biodegradable U
polymer ?

26. ?
(1)

(2) (1)

(2)
(3)

(4) (3)

(4)

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27. The increasing order of the boiling points 27.

for the following compounds is :
C 2 H5 OH C 2 H5Cl C 2 H5CH3
C 2 H5 OH C 2 H5Cl C 2 H5CH3 (I) (II) (III)
(I) (II) (III)
C 2 H5OCH3
C 2 H5OCH3 (IV)
(IV)
(1) (III) < (IV) < (II) < (I)
(1) (III) < (IV) < (II) < (I)
(2) (IV) < (III) < (I) < (II)
(2) (IV) < (III) < (I) < (II)
(3) (II) < (III) < (IV) < (I)
(3) (II) < (III) < (IV) < (I)
(4) (III) < (II) < (I) < (IV)
(4) (III) < (II) < (I) < (IV)

28. Which of the following compounds will

28. m
show highest dipole moment ? ?

(I) (II) (I) (II)

(III) (IV) (III) (IV)

(1) (I) (1) (I)

(2) (II) (2) (II)
(3) (III) (3) (III)
(4) (IV) (4) (IV)

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29. In the following reaction sequence : 29.

The compound I is :
I
(1)
(1)

(2)
(2)

(3)
(3)

(4)
(4)

30. Among the following compounds, the

increasing order of their basic strength is : 30. U

(I) (II)
(I) (II)

(III) (IV)
(III) (IV)
(1) (I) < (II) < (IV) < (III)
(2) (I) < (II) < (III) < (IV) (1) (I) < (II) < (IV) < (III)

(3) (II) < (I) < (IV) < (III) (2) (I) < (II) < (III) < (IV)

(4) (II) < (I) < (III) < (IV) (3) (II) < (I) < (IV) < (III)
(4) (II) < (I) < (III) < (IV)

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