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LECTURE 3
HEURISTICS FOR PROCESS SYNTHESIS
Introduction
This lecture deals with the heuristic rules that expedite the
selection and positioning of processing operations as
flowsheets are assembled.
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O OH OH
CH2 - CH2 + H2O CH2 - CH2 (R.2)
Often such processes are designed with two reaction steps, with
storage of the intermediate, to enable continuous production,
even when maintenance problems shut down the first reaction
operation.
So the main issue here is the risk associated with the storage of
hazardous intermediate (ethylene-oxide).
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Alternatives
OH OH
CH2=CH2 + Cl2 + 2NaOH(aq) CH2CH2 + 2NaCl (R.3)
Distribution of Chemicals
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or after reaction...
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Example:
p Manufacture of allyl-chloride
y
-An example of series-parallel reaction
-The desired product is allyl-chloride.
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Kinetic data
HR ko
Reaction E/R (oR)
Btu/lbmole lbmole/(hr ft3atm2)
1 -4,800 206,000 13,600
2 -79,200 11.7 3,430
3 -91,800 4.6 x 108 21,300
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9.60E-04
9.70E-04
9.80E-04
9.90E-04
1.00E-03
1.02E-03
1.01E-03
-0.4
ln(k) -0.8
-1.2
ln(k1)
-1.6 ln(k2)
1/T (980<T<1042 deg R) ln(k3)
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MeOAc
HOAc
Reaction
zone
MeOH
H 2O
MeOH + HOAc MeOAc + H2O
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Separations
Heuristic 9: Separate liquid mixtures using distillation and
stripping towers, liquid-liquid extractors,
crystallization
y and adsorption.
p
Select from
distillation,
Example: enhanced
distillation, stripping
Product from reactor is liquid towers, liquid-liquid
extraction, etc.
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Select from
distillation,
enhanced
distillation stripping
distillation,
towers, liquid-liquid
Attempt to cool
extraction, etc.
reactor products
using cooling
water
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P2
W& = V&dP
P1
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SUMMARY
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.Thank you.
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