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ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
2. HAZARDS IDENTIFICATION
GHS Classification
Acute toxicity (Oral) : Category 4
Specific target organ toxicity - : Category 2 (Kidney, Central nervous system, Liver)
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
repeated exposure
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
Chemical name CAS-No. Concentration (% w/w)
ethylene diformate 629-15-2 60 - 100
Ethylene glycol 107-21-1 13 - 30
imidazole 288-32-4 1-3
formic acid 64-18-6 0.1 - 1
In case of skin contact : Wash off immediately with plenty of water for at least 15
minutes.
If skin irritation persists, call a physician.
In case of eye contact : Rinse immediately with plenty of water for at least 15 minutes.
If eye irritation persists, consult a specialist.
Remove contact lenses.
5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Specific hazards during : Do not allow run-off from fire fighting to enter drains or water
firefighting courses.
Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Hand protection
Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Appearance : liquid
Colour : colourless
Odour : characteristic
pH : 5-8
Concentration: 5 %
Solubility(ies)
Water solubility : completely miscible
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Acute toxicity
Acute oral toxicity - Product : Acute toxicity estimate : 1.073 mg/kg
Method: Calculation method
Components:
Ethylene glycol:
Acute dermal toxicity : LD50 (Mouse, male and female): > 3.500 mg/kg
Assessment: The substance or mixture has no acute dermal
toxicity
Skin corrosion/irritation
Product:
Assessment: Irritating to skin.
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
formic acid:
Exposure routes: Skin
Species: Guinea pig
Method: OECD Test Guideline 406
Result: Does not cause skin sensitisation.
Components:
imidazole:
Assessment: Harmful if swallowed., Causes severe skin burns and eye
damage.
Does not cause skin sensitisation.
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Ethylene glycol:
Genotoxicity in vitro : Test Type: reverse mutation assay
Species: Salmonella tryphimurium and E. coli
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: yes
imidazole:
Genotoxicity in vitro : Test Type: unscheduled DNA synthesis assay
Species: rat hepatocytes
Concentration: 0.25, 0.5, 1, 2, 4 mg/ml
Method: OECD Test Guideline 482
Result: negative
GLP: No information available.
formic acid:
Genotoxicity in vitro : Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 473
Result: negative
Components:
Ethylene glycol:
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
imidazole:
Genotoxicity in vivo : Test Type: In vivo micronucleus test
Species: Mouse (male and female)
Cell type: Bone marrow
Application Route: Oral
Dose: 500, 1000, 2000 mg/kg bw
Method: OECD Test Guideline 474
Result: negative
GLP: yes
formic acid:
Genotoxicity in vivo : Method: OECD Test Guideline 477
Result: negative
GLP: no
Components:
imidazole:
Germ cell mutagenicity- : Tests on bacterial or mammalian cell cultures did not show
Assessment mutagenic effects., Animal testing did not show any mutagenic
effects.
Carcinogenicity
Components:
Ethylene glycol:
Species: Rat, (male and female)
Application Route: Oral
Exposure time: 24 month(s)
Dose: 40/200/1000 mg/kg
Frequency of Treatment: 7 d/Weeks daily
NOAEL: 1.000 mg/kg bw/day
Result: negative
Result: negative
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Reproductive toxicity
Components:
ethylene diformate:
Effects on fertility : Test Type: Three-generation study
Species: Rat, male and female
Application Route: Oral
Dose: 40, 200 and 1000 mg/kg bw/day
Fertility: No observed adverse effect level: 1.000 mg/kg body
weight
Early Embryonic Development: No observed adverse effect
level: 1.000 mg/kg body weight
Method: OECD Test Guideline 416
Result: Animal testing did not show any effects on fertility.
GLP: No information available.
Remarks: Information given is based on data obtained from
similar substances.
Ethylene glycol:
Species: Mouse, male and female
Application Route: Oral
Dose: 40/200/1000 milligram per kilogram
Frequency of Treatment: 7 days/week
General Toxicity - Parent: No-observed-effect level: 1.000
mg/kg body weight
General Toxicity F1: No-observed-effect level: 1.000 mg/kg
body weight
formic acid:
Species: Rat, male and female
Application Route: Oral
Method: OECD Test Guideline 416
GLP: yes
Components:
ethylene diformate:
Effects on foetal : Test Type: Embryo-foetal development
development Species: Rabbit
Strain: NZW
Application Route: Oral
Dose: 2000 milligram per kilogram
Duration of Single Treatment: 14 d
Teratogenicity: No observed adverse effect level: > 2.000
mg/kg body weight
Developmental Toxicity: No observed adverse effect level: >
2.000 mg/kg body weight
Method: OECD Test Guideline 414
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Ethylene glycol:
Test Type: Embryo-foetal development
Species: Rat, female
Application Route: Oral
Duration of Single Treatment: 336 h
Frequency of Treatment: 7 days/week
General Toxicity Maternal: No observed adverse effect level:
250 mg/kg body weight
Developmental Toxicity: No observed adverse effect level:
250 mg/kg body weight
Method: No information available.
Result: No teratogenic effects
GLP: yes
imidazole:
Species: Rat, female
Application Route: Oral
Dose: 0, 20, 60, 180 mg/kg bw/d
Frequency of Treatment: 7 days/week
General Toxicity Maternal: No observed adverse effect level:
60 mg/kg body weight
Teratogenicity: No observed adverse effect level: 60 mg/kg
body weight
Embryo-foetal toxicity: No observed adverse effect level: 60
mg/kg body weight
Method: OECD Test Guideline 414
Result: Teratogenic effects
GLP: yes
Components:
imidazole:
Reproductive toxicity - : Clear evidence of adverse effects on development, based on
Assessment animal experiments.
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
imidazole:
Species: Rat, male and female
NOAEL: 60 mg/kg
Application Route: oral (gavage)
Exposure time: 90 day
Number of exposures: daily
Dose: 0, 20, 60, 180 mg/kg
Group: yes
Method: OECD Test Guideline 408
GLP: yes
Target Organs: Liver, Kidney
Components:
imidazole:
Repeated dose toxicity - : Harmful if swallowed., Causes severe skin burns and eye
Assessment damage.
Aspiration toxicity
Components:
ethylene diformate:
May be harmful if swallowed and enters airways.
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Neurological effects
No data available
Further information
Product:
Remarks: No data available
Ecotoxicity
Components:
ethylene diformate:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 42 mg/l
Exposure time: 96 h
Test Type: semi-static test
Method: OECD Test Guideline 203
GLP: yes
Ethylene glycol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 72.860 mg/l
Exposure time: 96 h
Test Type: static test
Test substance: Fresh water
imidazole:
Toxicity to fish : LC50 (Leuciscus idus (Golden orfe)): 283,6 mg/l
Exposure time: 48 h
Test Type: static test
formic acid:
Toxicity to fish : LC50 (Brachydanio rerio (zebrafish)): 130 mg/l
Exposure time: 96 h
Test Type: static test
Test substance: Fresh water
Method: OECD Test Guideline 203
GLP: yes
Components:
ethylene diformate:
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test
Analytical monitoring: yes
Method: OECD Test Guideline 202
GLP: yes
Ethylene glycol:
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test
Test substance: Fresh water
Method: OECD Test Guideline 202
imidazole:
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 341,5 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test
Method: Directive 67/548/EEC, Annex V, C.2.
GLP: no
formic acid:
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 540 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test
Test substance: Fresh water
Method: OECD Test Guideline 202
GLP: yes
Components:
ethylene diformate:
Toxicity to algae : NOEC (Pseudokirchneriella subcapitata (green algae)): 10
mg/l
Exposure time: 72 h
Test Type: static test
Analytical monitoring: yes
Method: OECD Test Guideline 201
GLP: yes
Ethylene glycol:
Toxicity to algae : ErC50 (Pseudokirchneriella subcapitata (algae)): 6.500 -
13.000 mg/l
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Exposure time: 96 h
Test Type: static test
imidazole:
Toxicity to algae : EC50 (Desmodesmus subspicatus (Scenedesmus
subspicatus)): 133 mg/l
Exposure time: 72 h
Test Type: static test
Method: DIN 38412
GLP: no
Components:
Ethylene glycol:
Toxicity to fish (Chronic : NOEC (Pimephales promelas (fathead minnow)): 32.000 mg/l
toxicity) Exposure time: 7 d
Test Type: static test
Test substance: Fresh water
Components:
Ethylene glycol:
Toxicity to daphnia and other : NOEC (Ceriodaphnia dubia (Water flea)): 8.590 mg/l
aquatic invertebrates Exposure time: 7 d
(Chronic toxicity) Test Type: semi-static test
Test substance: Fresh water
Components:
Ethylene glycol:
Toxicity to bacteria : EC20 (activated sludge): > 1.995 mg/l
Exposure time: 30 min
Test Type: static test
Test substance: Fresh water
Method: ISO 8192
imidazole:
Toxicity to bacteria : EC50 (activated sludge): > 1.000 mg/l
Exposure time: 0,5 h
Test Type: static test
Method: OECD Test Guideline 209
GLP: yes
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
organisms
Ecotoxicology Assessment
Components:
imidazole:
Acute aquatic toxicity : This product has no known ecotoxicological effects.
Components:
imidazole:
Chronic aquatic toxicity : This product has no known ecotoxicological effects.
Further information:
No data available
Bioaccumulative potential
Bioaccumulation : No data available
Components:
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Ethylene glycol:
Partition coefficient: n- : log Pow: -1,36
octanol/water
imidazole:
Partition coefficient: n- : log Pow: -0,02 (25 C)
octanol/water Method: OECD Test Guideline 107
formic acid:
Partition coefficient: n- : log Pow: -0,54
octanol/water
Mobility in soil
Mobility : No data available
Components:
Ethylene glycol:
Distribution among : Adsorption/Soil
environmental compartments Medium: Soil
Koc: 0 - 1Method: Calculation method
imidazole:
Distribution among : Koc: 0,988
environmental compartments
Stability in soil : No data available
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
International Regulation
IATA
Not regulated as dangerous goods
IMDG
Not regulated as dangerous goods
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
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SAFETY DATA SHEET
ALBATEX PS-35
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/10/31 400001006667 Date of first issue: 2016/10/31
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA
(USA)
The information and recommendations in this publication are to the best of our knowledge,
information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE
CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.
THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION.
WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE
IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
Hazards, toxicity and behaviour of the products may differ when used with other materials and
are dependent upon the manufacturing circumstances or other processes. Such hazards,
toxicity and behaviour should be determined by the user and made known to handlers,
processors and end users.
The trademarks above are the property of Huntsman Corporation or an affiliate thereof.
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