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ABHISHEK RAJ
2013B2A4224P
OVERVIEW
Background
Experimental
Conclusion
Bibliography
BACKGROUND
Polymer: Large molecule built up by the repetition of small simple chemical
units.
Mechanical Environmental
Strength Stability
APPLICATIONS
Why TPE?
Triphenylethylene derivatives have excellent thermal properties
4methyl Dibromo
Di Methyl TPE TPE aldehyde TPE polymer
benzophenone Methyl TPE
Ylide TPE
Synthesis of 4-methylbenzophenone
Under UV light the dry compound shows Emission but in solution the
emission is not present.
Stability of Product
The impure aldehyde compound was not stable under normal conditions
while doing column chromatography.
It required the use of basified silica using trimethylamine for the
compound to remain stable while doing column chromatography.
1H NMR
singlet
doublet
triplet
13C NMR
Ketone
1H NMR
Doublet
Multiplet Singlet
13C NMR
1H-NMR Spectrum of TPE-(CH2Br)2
Aromatic
Hydrogen
of
Substituted
Ring
Aromatic
Hydrogen (CH2Br )2
1H NMR
Solvent
Aromatic
Peak
H of ring
with
CHO
Aldehyde
H Aromatic
H Aromatic
H of ring
with
CHO
Future Scope of Work
Polymer formation with the monomers prepared.
(b)Y. Liu, Y.H. Tang, N.N. Barashkov, I.S. Irgibaeva, J.W.Y. Lam, R.R. Hu,
D. Birimzhanova, Y.Yu, B.Z. Tang ,J. Am. Chem. Soc., 132 (2010), p. 13951
X.-F. Duan, J. Zeng, J.-W. L, Z.-B. Zhang, J. Org. Chem., 2006, 71, 9873-
9876.
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ACQ
Conventional fluorophores, such as fluorescein, are usually fluorescent when
they are in dilute solution.
In such situation, the excited states often decay via nonradiative decay
pathways, which is known as the aggregation-caused quenching (ACQ) of
light emission.
Mechanism
1 spot 2 spots
SEPARATION
2 spots were obtained which were separated by column chromatography.