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Among the catalysts screened, Cu-ion exchanged ZSM5 zeolite exhibited the highest NO removal activity, particularly at low
reaction temperatures below 200 C, maintaining a wide operating temperature window. The hydrothermal stability of the
CuZSM5 catalyst can be improved by the optimization of metal content of the catalyst. Through the variation of reactor operating
conditions, NO conversion of better than 90% could be achieved with a minimum NH3 slip. The decomposition of urea was also
examined and a kinetic model for both thermal and catalytic decomposition of urea was developed. Urea-SCR over the CuZSM5
catalyst exhibited that the NO removal activity is competitive to that by NH3-SCR, indicating urea can be eectively utilized in
SCR reactor system as the reducing agent.
KEY WORDS: urea-SCR; decomposition of urea; CuZSM5.
Table 1
Physicochemical properties of the catalysts employed in the present study
V2O5/TiO2 WI 2.0 66
Com Ab 1.6 7.3 60
Pt/Al2O3 WI 1.7 290
CrOx/TiO2 WI 11.9 117
MnOx/TiO2 WI 9.6 190
CuHM IE 2.3 5 31 400
CuHY IE 6.6 3 80
CuUSY IE 3.2 15 100
CuFER IE 1.1 9 24 300
CuZSM5-14-97 IE 2.9 14 97 340
CuZSM5-14-117 IE 3.5 14 117 330
FeZSM5-14-96 IE 2.4 14 96 340
PtZSM5-14-20 IE 0.5 14 20
a
Preparation method, WI: wet impregnation, IE: ion exchange.
b
Commercial catalyst.