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XI (F.Sc.) CHEMISTRY CHAPTER # 1

02-10-2013 10 10 MINUTES

Q.No.1 Choose the best option. 10

(i) In combustion analysis, CO2 produced during the combustion of an organic
compound is absorbed in:
(a) Mg(ClO4)2 (b) Al2O3 (c) 50%KOH (d) H2SO4
(ii) Isotopes of an element differ in:
(a) arrangement of electrons in orbitals (b) chemical properties
(c) electronic configuration (d) properties which depends upon mass
(iii) The number of covalent bonds in 36g of H2O are
(a) 36 x 6.02 x 1023 (b) 2 x 2 x 6.022 x 1023
(c) 6.02/22.414 x 1023 (d) 2 x 6.02 x 1024
(iv) The relative atomic mass of chlorine is 35.5amu. What the mass of 2 moles of
chlorine gas:
(a) 142g (b) 35.5g (c) 71g (d) 18.75g
(v) Which of the following compound has highest %age of oxygen?
(a) H2C2O4 (b) HCHO (c) CH3CH2COOH (d) all have same
(vi) Which of the following process is exothermic?
(a) formation of unipositive ion (b) formation of dipositive ion
(c) formation of uninegative ion (d) formation of dinegative ion
(vii) Molecular ions are generated with high energy?
(a) x-rays (b) -rays (c) beam of electrons (d) all of these
(viii) Which of the following are iso-electronic system:
(a) F-, Cl-, Br- (b) O, O-, O+ (c) F-, Ne, Na+ (d) Be+2, Mg+2, Ca+2
(ix) Efficiency of a reaction can be determined by:
(a) isotropy (b) mass spectrometer(c) isotropy (d) none of these
(x) 27g of Al will react completely with how much mass of O2 to produce Al2O3:
(a) 8g of oxygen (b) 32g of oxygen (c) 16g of oxygen (d) 24g of oxygen

XI (F.Sc.) 30 50 MINUTES

Q.No.2 Give short answers to the following questions. 10x2=20

(i) No individual neon atom in the sample has the mass of 20.18a.m.u.
(ii) Mg atom is twice havier than an atom of carbon.
(iii) Why method of difference is employed to get %age oxygen in combustion analysis.
(iv) Why atomic masses of elements are in fraction?
(v) Calculate mass in grams of 5.136 moles of Ag2CO3.
(vi) Calculate %age of hydrogen and oxygen in H2O.
(vii) How many moles of O2 are required to burn octane (C8H18) present in gasoline?
(viii) Law of conservation of mass has to be obayed during stoichiometric calculations.
(ix) Differentiate between theoretical yield and experimental yield.
(x) A limiting reactant controls amount of product. Justify.
Q.No.3 (A) What is stoichiometry? Give its assumptions and also explain relationships which can
be built on this basis. 05
(B) An unknown metal M reacts with S to form M2S3. If 3.12g of M reacts exactly with
2.88g of sulphar, what are names of metal M & compound M2S3. 05