Indo Asian Academy PU (Co-Ed) College

KalyanNagar, Bangalore - 560043

II PUC : Model question paper-1 Subject: CHEMISTRY

Time : 3.15 hour Total Marks: 70
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I.ANSWER THE FOLLOWING 10 x1M = 10M
1)Give an example for liquid-liquid solution
2)What are ideal solutions?
3)Define electrode potential
4)Calculate the overall order of a reaction which has the rate expression.
Rate= K [A]1/2 [B]3/2
5)Name the metal that is refined by Van Arkel method.
6)Name the first noble gas compound prepared by Neil Bartlett?
7)Give an example for Heteroleptic complex.
8)Write the general formula of Grignard reagent?
9)Name the product obtained when acetaldehyde reacts with Hydroxyl amine.
10)How many peptide bonds are present in a pentapeptide?

II.ANSWER ANY FIVE OF THE FOLLOWING 5 x2M= 10M

11)Write any two differences between crystalline solids and amorphous solids?
12)Define molar conductivity. How is it related to conductivity?
13)Show that half life of a first order reaction is independent of its initial concentration.
14) i) What is actinide contraction?
ii) Which is the common oxidation state exhibited by actinides?
15)How do you prepare diethyl ether by dehydration of ethanol?
16)How does ketone react with ethylene glycol. Write chemical equation for the reaction.
17)What are analgesics? Give an example for non-narcotic analgesics.
18) What are artificial sweeteners? Give an example.

III.ANSWER ANY FIVE OF THE FOLLOWING 5x 3M = 15M

19)How do you extract aluminium from bauxite ore by Hall-Heroult process?
20)Explain manufacture of nitric acid by Ostwald’s process.

21)a) How is ozonised oxygen prepared?

b) Write the structure of sulphurous acid.
22) What happens when Concentrated chlorine is treated with
i) excess of NH3 ii) Cold & dilute NaOH iii) Hot & ConcNaOH
23) a) 3d Transition metals and their compounds are good catalysts. Give two reasons?
b) Give the formula for the calculation of spin only magnetic moment.
24) Explain the manufacture of Potassium dichromate from chromite ore.
25)(a)Draw geometrical isomers in [Pt(NH3)2Cl2]
(b) Give the IUPAC name for[Co(NH3)5(NO2)]Cl2
26)State the postulates of Werner’s theory of coordination compounds.
IV.ANSWER ANY THREE OF THE FOLLOWING 3 x5M = 15M
27.a) Calculate the packing efficiency in a Face Centered Cubic lattice. 3
b) Calculate the number of particles per unit cell in BCC 2
28. a) 5.8g of a non-volatile solute was dissolved in 100g of carbon disulphide (Molar mass = 76).
TheVapour pressure of the solution was found to be 190mmHg. Calculate the molecular mass
of the solute. The vapour pressure of pure carbon disulphide 195 mm Hg. 3
b) What are azeotropes? Give an example. 2
29. a) The electrical resistance of a column of 0.05M NaOH solution of diameter 1cm and length
50cm is 5.55×103 ohm. Calculate its
(i) resistivity (ii) conductivity (iii) molar conductivity 3
b) Mention two general methods for prevention of corrosion. 2
30.(a)Derive an integrated rate constant of zero order reaction 3
(b) Show that half life of a zero order reaction is directly proportional to initial
concentration of reactant from integrated rate equation. 2
31. a) Write any two differences between lyophilic sols and lyophobic sols 2
b) What are the differences between physisorption and chemisorption 2
c) Give an example for homogeneous catalysis 1

V.ANSWER ANY FOUR OF THE FOLLOWING 4 x5M = 20M

32(a)ExplainSN1 mechanism 3
(b) what is Swarts reaction. 2
33(a)Explain the mechanism of dehydration of alcohols to alkenes. 3
(b) Explain Williamson synthesis with equation. 2
34 a) Which of the following organic compound undergoes Cannizzaro’s reaction?
i) CH3CHO ii) HCHO 2
b) Write the mechanism of addition of HCN to a carbonyl compounds 2
c) Explain the conversion of carboxylic acid into an acid amide. Give the general chemical
equation 1
35a) How do you convert benzene diazonium chloride into chlorobenzene. Name the reaction . 3
b)Explain Hoffmann Bromamide reaction with an example 2
36. a) Write the Haworth structure of maltose 2
b) What are hormones? Give one biological function of insulin 2
c) What are nucleosides? 1
37.a) Give the classification of polymers based on mode of polymerisation. 3
b) What is bio-degradable polymer? Give example 2