Central Board of Secondary Education

Question Paper 2016

[Official]

By

AglaSem
www.schools.aglasem.com
 AglaSem Schools

Series ONS SET-1

·¤æðÇU Ù´.
Code No. 56/1/E
ÚUæðÜ Ù´. ÂÚUèÿææÍèü ·¤æðÇU ·¤æ𠩞æÚU-ÂéçSÌ·¤æ ·ð¤ ×é¹-ÂëcÆU
Roll No. ÂÚU ¥ßàØ çܹð´Ð
Candidates must write the Code on the
title page of the answer-book.

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·ë¤ÂØæ Áæ¡¿ ·¤ÚU Üð´ ç·¤ §â ÂýàÙ-˜æ ×ð´ ×éçÎýÌ ÂëcÆU 15 ãñ´Ð

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·
· ÂýàÙ-˜æ ×ð´ ÎæçãÙð ãæÍ ·¤è ¥æðÚU çΰ »° ·¤æðÇU ِÕÚU ·¤æð ÀUæ˜æ ©žæÚU-ÂéçSÌ·¤æ ·ð¤ ×é¹-ÂëcÆU ÂÚU çܹð´Ð
·ë¤ÂØæ Áæ¡¿ ·¤ÚU Üð´ ç·¤ §â ÂýàÙ-˜æ ×ð´ 26 ÂýàÙ ãñ´Ð

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·
· ·ë¤ÂØæ ÂýàÙ ·¤æ ©žæÚU çܹÙæ àæéM¤ ·¤ÚUÙð âð ÂãÜð, ÂýàÙ ·¤æ ·ý¤×æ´·¤ ¥ßàØ çܹð´Ð

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· §â ÂýàÙ-Â˜æ ·¤æð ÂɸÙð ·ð¤ çÜ° 15 ç×ÙÅU ·¤æ â×Ø çÎØæ »Øæ ãñÐ ÂýàÙ-Â˜æ ·¤æ çßÌÚU‡æ Âêßæüq ×ð´
10.15 ÕÁð ç·¤Øæ Áæ°»æÐ 10.15 ÕÁð âð 10.30 ÕÁð Ì·¤ ÀUæ˜æ ·ð¤ßÜ ÂýàÙ-Â˜æ ·¤æð Âɸð´»ð ¥æñÚU §â
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¥ßçÏ ·ð¤ ÎæñÚUæÙ ß𠩞æÚ-ÂéçSÌ·¤æ ÂÚU ·¤æð§ü ©žæÚU Ùãè´ çܹð´»ðÐ
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· Please check that this question paper contains 15 printed pages.
· Code number given on the right hand side of the question paper should be written
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on the title page of the answer-book by the candidate.

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· Please check that this question paper contains 26 questions.

· Please write down the Serial Number of the question before attempting
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it.
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· 15 minute time has been allotted to read this question paper. The question paper
will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the students will
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read the question paper only and will not write any answer on the answer-book
during this period.
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ÚUâæØÙ çߙææÙ (âñhæç‹Ì·¤)

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CHEMISTRY (Theory)
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çÙÏæüçÚUÌ â×Ø Ñ
3 ƒæ‡ÅðU ¥çÏ·¤Ì× ¥´·¤ Ñ 70
Time allowed : 3 hours Maximum Marks : 70

56/1/E 1 P.T.O.
 AglaSem Schools

âæ×æ‹Ø çÙÎðüàæ Ñ

(i) âÖè ÂýàÙ ¥çÙßæØü ãñ´Ð

(ii) Âýà٠ⴁØæ 1 âð 5 Ì·¤ ¥çÌ Üƒæé-©žæÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýˆØð· ·ð¤ çÜ°¤ 1 ¥´·¤ ãñÐ

(iii) Âýà٠ⴁØæ 6 âð 10 Ì·¤ ܃æé-©žæÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýˆØð·¤ ÂýàÙ ·ð¤ çÜ° 2 ¥´·¤ ãñÐ

(iv) Âýà٠ⴁØæ 11 âð 22 Ì·¤ Öè ܃æé-©žæÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýˆØð·¤ ÂýàÙ ·ð çÜ° 3 ¥´·¤ ãñÐ

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(v) Âýà٠ⴁØæ 23 ×êËØæÏæçÚUÌ ÂýàÙ ãñ ¥æñÚU §â·ð¤ çÜ° 4 ¥´·¤ ãñÐ

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(vi) Âýà٠ⴁØæ 24 âð 26 Ì·¤ Îèƒæü-©žæÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýˆØð·¤ ÂýàÙ ·ð¤ çÜ° 5 ¥´·¤ ãñÐ

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(vii) ØçÎ ¥æßàØ·¤Ìæ ãæð, Ìæð Üæò» ÅðUÕÜæð´ ·¤æ ÂýØæð» ·¤Úð´UÐ ·ñ¤Ë·é¤ÜðÅUÚUæ𴠷𤠩ÂØæð» ·¤è ¥Ùé×çÌ Ùãè´ ãñÐ
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General Instructions :
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(i) All questions are compulsory.

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(ii) Questions number 1 to 5 are very short answer questions and carry 1 mark each.
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(iii) Questions number 6 to 10 are short answer questions and carry 2 marks each.
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(iv) Questions number 11 to 22 are also short answer questions and carry 3 marks each.

(v) Questions number 23 is a value based question and carry 4 marks.

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(vi) Questions number 24 to 26 are long answer questions and carry 5 marks each.
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(vii) Use log tables, if necessary. Use of calculators is not allowed.

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56/1/E 2
 AglaSem Schools

1. çِ٠×ð´ âð ·¤æñÙ ¥çÖç·ý¤Øæ SN1 Âý·¤æÚU ·¤è ãñ?

(i)

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(ii)

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Which of the following reactions is SN1 type ?

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(i)
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(ii)
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2. ·¤æðÜæ§ÇUè âæòËâ ·¤è çSÍÚUÌæ ·ð¤ çÜ° ×éØ ·¤æÚU‡æ çÜç¹°Ð

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Write the main reason for the stability of colloidal sols.

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3. âæ´Îý H2SO4·¤æð ·¤æòÂÚU ¹ÚUæÎÙ ·ð¤ âæÍ »×ü ·¤ÚUÙð ÂÚU °·¤ Ìè¹è »´Ï ßæÜè Ú´U»ãèÙ »ñâ
çÙ·¤ÜÌè ãñ Áæ𠥐ÜèØ KMnO4 çßÜØÙ ·¤æð Ú´U»ãèÙ ·¤ÚU ÎðÌè ãñÐ »ñâ ·¤è Âã¿æÙ ·¤èçÁ°ÐU

On heating Copper turnings with conc. H2SO4, a colourless gas with pungent
smell is evolved which decolourises acidified KMnO4 solution. Identify the gas.

56/1/E 3 P.T.O.
 AglaSem Schools

4. ØçÎ ßñÜð´â Õñ‡ÇU ¥æñÚU ¿æÜ·¤Ìæ Õñ‡ÇU ·ð¤ Õè¿ ·¤æð§ü ª¤Áæü ¥´ÌÚUæÜ Ù ãæð Ìæð ÆUæðâ ·¤è Âý·ë¤çÌ €Øæ
ãæð»è?
What would be the nature of solid if there is no energy gap between valence
band and conduction band ?

5. çÎØð »Øð Øæñç»·¤ ·¤æ ¥æ§ü.Øê.Âè.°.âè. Ùæ× çÜç¹° Ñ

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Write the IUPAC name of the given compound :

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ÚUæ©ËÅU çÙØ× âð ÏÙæˆ×·¤ çß¿ÜÙ ¥æñÚU «¤‡ææˆ×·¤ çß¿ÜÙ çιÜæÙð ßæÜð çßÜØÙæð´ ·ð¤ Õè¿
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6.
Îæð ¥´ÌÚUæð´ ·¤æð çÜç¹°Ð
o
ho

Write two differences between a solution showing positive deviation and a

solution showing negative deviation from Raoult’s law.
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7. çِ٠¥‡æé¥æð´ ·¤è â´ÚU¿Ùæ°¡ çÜç¹° Ñ

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(i) H2S2O8
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(ii) XeF6

Write the structures of the following molecules :

(i) H2S2O8
(ii) XeF6

56/1/E 4
 AglaSem Schools

8. C4H8O ¥‡æéâê˜æ ßæÜæ °·¤ ¥æ»ñüçÙ·¤ Øæñç»·¤ ‘X’ ¥çÖ·¤æÚU·¤ 2,4-DNP ·ð¤ âæÍ ÙæÚ´U»è-ÜæÜ
·¤æ ¥ßÿæð ÎðÌæ ãñÐ Øã ÅUæòÜðÙ ¥çÖ·¤æÚU·¤ ·¤æð ¥Â¿çØÌ Ùãè´ ·¤ÚUÌæ Üðç·¤Ù NaOI ·ð¤ âæÍ
»×ü ·¤ÚUÙð ÂÚU ¥æØÇUæðȤæ×ü ·¤æ ÂèÜæ ¥ßÿæð ÎðÌæ ãñÐ LiAlH4¤·ð¤ âæÍ ¥Â¿çØÌ ãæð·¤ÚU
Øæñç»·¤ X °·¤ Øæñç»·¤ Y ÎðÌæ ãñ Áæð â´æÎý H2SO4 ·ð¤ âæÍ »×ü ·¤ÚUÙð ÂÚU çÙÁüÜè ãæð ÁæÌæ ãñ
¥æñÚU ŽØéÅU-2-§üÙ ÕÙæÌæ ãñÐ X ¥æñÚU Y Øæñç»·¤æð´ ·¤è Âã¿æÙ ·¤èçÁ°Ð

An organic compound ‘X’ having molecular formula C4H8O gives orange-red

ppt. with 2,4-DNP reagent. It does not reduce tollens’ reagent but gives yellow
ppt. of iodoform on heating with NaOI. Compound X on reduction with LiAlH4

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gives compound ‘Y’ which undergoes dehydration reaction on heating with
conc. H2SO4 to form But-2-ene. Identify the compounds X and Y.

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9. ÁÕ °·¤ ©Ââãâ´ØæðÁÙ Øæñç»·¤ PtCl4.6NH3 ·¤æð AgNO3 ·ð¤ âæÍ ç×ÜæØæ ÁæÌæ ãñ ÌÕ
Øæñç»·¤ ·ð¤ ÂýçÌ ×æðÜ ÂÚU AgCl ·ð 4 ×æðÜ ¥ßÿæðçÂÌ ãæðÌð ã´ñÐ çÜç¹° Ñ
as
(i) ·¤æŒÜð€â ·¤è â´ÚU¿Ùæˆ×·¤ âê˜æ
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(ii) ·¤æŒÜð€â ·¤æ ¥æ§ü.Øê.Âè.°.âè. Ùæ×

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When a coordination compound PtCl4.6NH3 is mixed with AgNO3, 4 moles of

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AgCl are precipitated per mole of the compound ? Write :

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(i) Structural formula of the complex

(ii) IUPAC name of the complex

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3
çιÜ槰 ç·¤ °·¤ ÂýÍ× ·¤æðçÅU ·¤è ¥çÖç·ý¤Øæ ·ð¤ ßæ¡ Öæ» Âê‡æü ãæðÙð ×ð´ Áæð â×Ø Ü»Ìæ ãñ
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10.
4
ßã ©â·¤è ¥Ïü-¥æØé ·¤æ Îé»éÙæ ãæðÌæ ãñÐ
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(t½)

¥Íßæ

°·¤ ÁèÚUæð ¥æÇüUÚU ¥çÖç·ý¤Øæ ·ð¤ ÎÚU çSÍÚUæ´·¤ ·ð¤ çÜØð â×æ·¤çÜÌ ÎÚU â×è·¤ÚU‡æ ·¤æð ÃØéˆÂóæ
·¤èçÁ°Ð

56/1/E 5 P.T.O.
 AglaSem Schools

3
Show that the time required for completion of th of reaction of first order is
4
twice that of half-life (t½) of the reaction.
OR
Derive integrated rate equation for rate constant of a zero order reaction.

11. °·¤ Ìˆß b.c.c ÁæÜ·¤ ×ð´ ç·ý¤SÅUçÜÌ ãæðÌæ ãñ çÁâ·ð¤ âðÜ ·¤æ ç·¤ÙæÚUæ 400 pm ãñÐ ØçÎ §â

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Ìˆß ·ð¤ 250 g ×ð´ 2.531024 ÂÚU×æ‡æé ãæð´ Ìæð §â·ð¤ ƒæÙˆß ·¤æ ÂçÚU·¤ÜÙ ·¤èçÁ°Ð

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An element crystallizes in a b.c.c lattice with cell edge of 400 pm. Calculate
the density if 250 g of this element contain 2.531024 atoms ?

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12. ·¤æÚU‡æ ÎèçÁ° Ñ
(i) °ðçËÇUãæ§ÇUæð´ ¥æñÚU ·¤èÅUæðÙæð´ ·ð¤ a-ãæ§ÇþUæðÁÙ ÂÚU×æ‡æé¥æð´ ·¤è Âý·ë¤çÌ ¥ÜèØ ãæðÌè ãñ´Ð
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(ii) °ðçËÇUãæ§ÇUæð´ ·¤æ ©Â¿ØÙ ·¤èÅUæðÙæ𴠷𤠩¿ØÙ âð âÚUÜ ãæðÌæ ãñÐ
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(iii) CH25CH2COOH ¥Âðÿææ·ë¤Ì CH3CH22COOH âð ¥çÏ·¤ ¥ÜèØ ãñÐ

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Give reasons :
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(i) The a-hydrogen atoms of aldehydes and ketones are acidic in nature.
o

(ii) Oxidation of aldehydes is easier than ketones.

ho

(iii) CH25CH2COOH is more acidic than CH3CH22COOH.

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13. ÂýÍ× ·¤æðçÅU ©c×èØ ç߃æÅUÙ ¥çÖç·ý¤Øæ ·ð¤ çÜØð çِ٠¥æ¡·¤Ç¸ð Âýæ# ãé° Ñ
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C2H5Cl(g) ® C2H4(g) 1 HCl(g)

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â×Ø/âð·´¤ÇU ·é¤Ü ÎæÕ/ÂÚU×æ‡æé

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0 0.30
300 0.50

ÎÚU çSÍÚUæ´·¤ ·¤æð ÂçÚU·¤çÜÌ ·¤èçÁ°Ð

(çÎØæ »Øæ Ñ log 250.301, log 350.4771, log 450.6021)

56/1/E 6
 AglaSem Schools

For the first order thermal decomposition reaction, the following data were
obtained :
C2H5Cl(g) ® C2H4(g) 1 HCl(g)
Time / sec Total pressure / atm
0 0.30
300 0.50
Calculate the rate constant.

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(Given : log 250.301 log 350.4771 log 450.6021)

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14. çِ٠ÂÎæð´ ·¤æð ÂçÚUÖæçáÌ ·¤èçÁ° Ñ

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(i) ÂðŒÅUè·¤ÚU‡æ
(ii) ÁèÅUæ çßÖß as
(iii) Õýæ©çÙØÙ ×êß×ð´ÅU
gl
Define the following terms :
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(i) Peptization
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(ii) Zeta potential

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(iii) Brownian movement

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§Ù·¤æð â×ÍüÙ ÎðÙð ßæÜð çâhæ‹Ìæð´ ·¤æð çÜç¹° Ñ

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15.

(i) ßæc ÂýæßSÍæ ÂçÚUc·¤ÚU‡æ

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(ii) ·ý¤æð×ñÅUæð»ýæȤè
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(iii) Ûææ» ŒÜßÙ Âý·ý¤×

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Write the principle behind the following :

(i) Vapour phase refining
(ii) Chromatography
(iii) Froth floatation process

56/1/E 7 P.T.O.
 AglaSem Schools

16. 100 g ÁÜ ×ð´ ÁÕ CaCl2 (M5111 g mol21) ·¤æ 3 g ƒæéÜæ ãæð Ìæð çßÜØÙ ·¤æ çã×æ´·¤
ÂçÚU·¤çÜÌ ·¤èçÁ°, Øã ×æÙ·¤ÚU ¿çÜ° ç·¤ CaCl2 ·¤æ Âê‡æüM¤Â âð ¥æØÙè·¤ÚU‡æ ãæðÌæ ãñÐ
(Kf ÁÜ ·ð¤ çÜ° 5 1.86 K kg mol21)
Calculate the freezing point of a solution when 3 g of CaCl2 (M5111 g mol21)
was dissolved in 100 g of water, assuming CaCl2 undergoes complete ionization.
(Kf for water 5 1.86 K kg mol21)

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17. ·¤æÚU‡æ ÕÌÜ槰 Ñ
âÈð¤Î ȤæòâȤæðÚUâ ·¤è ¥Âðÿææ ÜæÜ È¤æòâȤæðÚUâ ·¤× ç·ý¤ØæàæèÜ ãñÐ

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(i)

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(ii) ¥æ€âèÁÙ ·¤è ¥Âðÿææ âËȤÚU ×ð´ oë´¹ÜÙ ·¤è Âýßëçžæ ¥çÏ·¤ ãñÐ
(iii) ClF3 ÁæÙè ÁæÌè ãñ ÂÚU‹Ìé FCl3 Ùãè´ ÁæÙè ÁæÌè ãñÐ
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Give reasons :
gl
(i) Red phosphorus is less reactive than white phosphorus.
.a

(ii) Sulphur shows greater tendency for catenation than oxygen.

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(iii) ClF3 is known but FCl3 is not known.

o
ho

18. çِ٠¥çÖç·ý¤Øæ¥æð´ ·¤æð Âê‡æü ·¤èçÁ° Ñ

sc

(i) C6 H52COOH
NH3
 
 c‰¼Ë → B 
→ A 
Br2 / KOH
→C
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Fe/HCl NaNO21HCl CuCN

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(ii) C6H5 NO2  → A → B → C

273 - 278K
ht

Complete the following reactions :

NH3 heat Br2 / KOH

(i) C6 H52COOH  → A → B  →C

Fe/HCl NaNO21HCl CuCN

(ii) C6H5 NO2  → A → B → C
273 - 278K

56/1/E 8
 AglaSem Schools

19. çِ٠·ð¤ °·¤Ü·¤æð´ ·¤æ Ùæ× ¥æñÚU ©Ù·¤è â´ÚU¿Ùæ¥æð´ ·¤æð çÜç¹° Ñ
(i) ÕêÙæ-S
(ii) ÅUðÚUèÜèÙ
(iii) ÙæØÜæÙ-6
Write the name of monomers and their structures in the following :

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(i) Buna-S

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(ii) Terylene

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(iii) Nylon-6

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20. (i) Üñ€ÅUæðâ ·ð¤ ÁÜ ¥ÂƒæÅUÙ âð Âýæ# ×æðÙæðâñ·¤ÚUæ§ÇUæð´ ·ð¤ Ùæ× çÜç¹°Ð
as
(ii) a-ãðç܀⠷¤è çSÍÚUÌæ ·ð¤ çÜØð ç·¤â Âý·¤æÚU ·¤æ ¥æÕ‹Ï çÁ×ðÎæÚU ãñ?
gl

(iii) ‹Øêç€Ü¥æðÅUæ§ÇU ¥æñÚU ‹Øêç€Ü¥æâæ§ÇU ·ð¤ Õè¿ ¥´ÌÚU ·¤æð çÜç¹°Ð

.a

(i) Write the name of monosaccharides which are obtained after the
ls

hydrolysis of Lactose.
o

(ii) What type of bonding is responsible for the stability of a-helix ?

ho

(iii) Write the difference between Nucleotide and Nucleoside.

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21. (a) ·¤æŒÜð€â [CoF6]32·ð¤ çÜ° â´·¤ÚU‡æ Âý·¤æÚU, ¿éÕ·¤èØ ÃØßãæÚU ¥æñÚU çSÂÙ ·¤æ SßÖæß
çÜç¹°Ð (Â.â´. Co527)
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·¤æŒÜð€â [Co(en)3]31 €Øæð´ ¥çÏ·¤ SÍæØè ãñ ¥Âðÿææ·ë¤Ì [CoF6]32 ·ð¤

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(b)

(a) For the complex [CoF6]32, write the hybridization type, magnetic
character and spin nature of the complex. (At.number : Co527)

(b) Why is the complex [Co(en) 3 ] 31 more stable than the complex
[CoF6]32 ?

56/1/E 9 P.T.O.
 AglaSem Schools

22. çِ٠·¤æð ¥æ ·ñ¤âð M¤Âæ´ÌçÚUÌ ·¤Úð´U»ð?

(i) €ÜæðÚUæðÕð‹ÁèÙ ·¤æð ÅUæÜé§üÙ ×ð´

(ii) ŽØéÅU-1-§üÙ ·¤æð ŽØéÅU-2-§üÙ ×ð´

(iii) °ÍñÙæòÜ ·¤æð °çÍÜ ¥æØæðÇUæ§ÇU ×ð´

¥Íßæ

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€Øæ ãæðÌæ ãñ ÁÕ Ñ

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(i) °ðË·¤æðãÜè KOH ·ð¤ âæÍ n-ŽØéçÅUÜ €ÜæðÚUæ§ÇU ·¤æð ©Â¿æçÚUÌ ç·¤Øæ ÁæÌæ ãñ?

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(ii) âê¹ð §üÍÚU ·¤è ©ÂçSÍçÌ ×ð´ âæðçÇUØ× ·ð¤ âæÍ 2-€ÜæðÚUæðÂýæðÂðÙ ·¤æð ©Â¿æçÚUÌ ç·¤Øæ ÁæÌæ ãñ?

çÙÁüÜ AlCl3 ·¤è ©ÂçSÍçÌ ×ð´ ·ð¤ âæÍ €ÜæðÚUæðÕð‹ÁèÙ ·¤æð ©Â¿æçÚUÌ ç·¤Øæ ÁæÌæ
(iii) CH3Cl
as
ãñÐ
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©ÂÚUæð€Ì ¥çÖç·ý¤Øæ¥æð´ âð â´Õ´çÏÌ ÚUæâæØçÙ·¤ â×è·¤ÚU‡ææð´ ·¤æð çÜç¹°Ð

.a

How do you convert :

o ls

(i) Chlorobenzene to toluene

ho

(ii) But-1-ene to But-2-ene

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(iii) Ethanol to Ethyl iodide

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OR
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What happens when :

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(i) n-butyl chloride is treated with alcoholic KOH.

(ii) 2-chloropropane is treated with sodium in the presence of dry ether.

(iii) Chlorobenzene is treated with CH3Cl in the presence of anhydrous AlCl3.

Write the chemical equations involved in the above reactions.

56/1/E 10
 AglaSem Schools

23. ¥ˆØ‹Ì ÃØSÌÌæ ·ð¤ ·¤æÚU‡æ ç×. çâ´ã Ùð ÎæðÂãÚU ·ð¤ ¹æÙð ·ð¤ â×Ø âǸæ ãé¥æ ÖæðÁÙ ÜðÙð Ü»ð ¥æñÚU
ÏèÚðU ÏèÚð ¥ÂÙð ÿæð˜æ ×ð´ ©žæ× ·¤æØü ·¤ÚUÙð ×ð´ Âýçâçh ÂýæŒÌ ·¤ÚU ÜèÐ °·¤ çÎÙ ©Ù·¤è ÀUæÌè ×ð´
ÌðÁ ÎÎü ãæðÙð Ü»æ ¥æñÚU ßð ç»ÚU ÂǸðÐ ©Ù·ð¤ çטæ ç×.¹óææ ©‹ãð´ ÇUæò€ÅUÚU ·ð¤ Âæâ Üð »ØðÐ ÇUæò€ÅUÚU
Ùð Áæ¡¿ ·ð¤ ÕæÎ ÂæØæ ç·¤ ß𠥐ÜÌæ âð »ýçâÌ Íð ¥æñÚU ©‹ãð´ ·é¤ÀU Îßæ§Øæ¡ ÜðÙð ·¤è âÜæã Îè
âæÍ ãè ©‹ã𴠃æÚU ·¤æ ÕÙæ ÖæðÁÙ ¹æÙð, Øæð»æâÙ ¥æñÚU ·é¤ÀU àææÚUèçÚU·¤ ÃØæØæ× ·¤ÚUÙð ·¤è âÜæã
ÎèÐ ç×.çâ´ã ¥ÂÙð ç×˜æ ·¤è âÜæã ×æÙ·¤ÚU Îð¹æ ç·¤ ÍæðǸð ãè çÎÙæð´ ×ð´ ßð SßSÍ ×ãâêâ ·¤ÚUÙð
Ü»ðÐ
©ÂÚUæðQ¤ ÂñâðÁ ·¤æð Âɸ·¤ÚU çِ٠·ð¤ ©žæÚU ÎèçÁ° Ñ

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(i) ç×.¹óææ mæÚUæ ÕÌæ° »° ×êËØæð´ (·¤× âð ·¤× 2) ·¤æð çÜç¹°Ð
(ii) °ð‹ÅUæ°ðçâÇU €Øæ ãñ? °·¤ ©ÎæãÚU‡æ ÎèçÁ°Ð

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(iii) €Øæ °ð‹ÅUæ°ðçâÇU ÕãéÌ çÎÙæð´ Ì·¤ ÜðÙæ ÆUè·¤ ãñ? ·¤æÚU‡æ ÎèçÁ°Ð

em
Due to hectic and busy schedule, Mr.Singh started taking junk food in the lunch
break and slowly became habitual of eating food irregularly to excel in his field.
One day during meeting he felt severe chest pain and fell down.
as
Mr. Khanna, a close friend of Mr.Singh, took him to doctor immediately. The
doctor diagnosed that Mr.Singh was suffering from acidity and prescribed some
gl
medicines. Mr.Khanna advised him to eat home made food and change his
lifestyle by doing Yoga, meditation and some physical exercise. Mr.Singh
.a

followed his friend’s advice and after few days he started feeling better.
ls

After reading the above passage, answer the following :

o

(i) What are the values (at least two) displayed by Mr.Khanna ?
ho

(ii) What are antacids ? Give one example.

(iii) Would it be advisable to take antacids for a long period of time ? Give
reason.
sc
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24. (a) 298 K ÂÚU çِ٠¥çÖç·ý¤Øæ ·ð¤ çÜØð DG0 ¥æñÚU log Kc ·¤æ ÂçÚU·¤ÜÙ ·¤èçÁ°Ð
tp

2Al(s)1 3Cu21(aq) → 2Al 31(aq) 1 3Cu(s)

çÎØæ »Øæ E0cell52.02 V
ht

(b) A ¥æñÚU B ·ð¤ E0 ×æÙæð´ ·¤æ ©ÂØæð» ·¤ÚUÌð ãé° Øã ÕÌÜ槰 ç·¤ ¥æØÚUÙ ÂÚU Á´» Ù Ü»ð
§â·ð¤ çÜØð 緤ⷤæ ÜðÂÙ ’ØæÎæ ©ÂØæð»è ãñ ¥æñÚU €Øæð´?
[E0 (Fe21/Fe)520.44 V]
çÎØæ »Øæ5E0(A21/A)522.37 V : E0(B21/B)520.14 V

56/1/E 11 P.T.O.
 AglaSem Schools

¥Íßæ
(a) CH3COOH ·ð¤ 0.001 mol L21 çßÜØÙ ·¤æ ¿æÜ·¤Ìæ 3.90531025 S cm21 ãñÐ
§â·¤è ×æðÜæÚU ¿æÜ·¤Ìæ ¥æñÚU çßØæðÁÙ (a) ·¤è çÇU»ýè ÂçÚU·¤çÜÌ ·¤èçÁ°Ð
çÎØæ »Øæ l0(H1)5349.6 S cm2 mol21 ¥æñÚU
l0(CH3COO2)540.9 S cm2 mol21

(b) ÇþUæ§ü âðÜ ç·¤â Âý·¤æÚU ·¤è ÕñÅUÚUè ãñ? ÇþUæ§ü âðÜ ×ð´ ãæðÙð ßæÜè Âê‡æü ¥çÖç·ý¤Øæ ·¤æð çÜç¹°Ð

/
om
(a) Calculate DG0 and log Kc for the following reaction at 298 K :

.c
2Al(s)1 3Cu21(aq) → 2Al 31(aq) 1 3Cu(s)

em
Given : E0cell 52.02 V

(b) Using the E0 values of A and B, predict which is better for coating the
surface of iron [E0(Fe21/Fe)520.44 V] to prevent corrosion and why ?
as
Given : E0(A21/A)522.37 V : E0(B21/B)520.14 V
gl

OR
.a

(a) The conductivity of 0.001 mol L 21 solution of CH 3 COOH is

ls

3.90531025 S cm21. Calculate its molar conductivity and degree of

dissociation(a).
o

Given l0 (H1)5349.6 S cm2 mol21 and

ho

l0 (CH3COO2)540.9 S cm2 mol21

sc

(b) What type of battery is dry cell ? Write the overall reaction occuring in
dry cell.
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tp

25. (a) çِ٠·ð¤ ·¤æÚU‡æ çÜç¹° Ñ

ht

(i) Mn2O7 ¥ÜèØ ãñ ÁÕç·¤ MnO ÿææÚUèØ ãñÐ

(ii) Zr ¥æñÚU Hf ·ð¤ »é‡æÏü â×æÙ ãñ´Ð
(iii) â´·ý¤×‡æ ÏæÌé°¡ ÕǸè ⴁØæ ×ð´ ·¤æòŒÜð€â Øæñç»·¤ ÕÙæÌè ãñÐ

56/1/E 12
 AglaSem Schools

(b) ÂæØÚUæðÜéâæ§ÅU ¥ØS·¤ (MnO2) âð K2MnO4 ÕÙæÙð ·¤è çßçÏ ·¤æ ߇æüÙ ·¤èçÁ°Ð
KMnO4 ¥æñÚU K2MnO4 ·ð¤ mæÚUæ ç·¤â Âý·¤æÚU ·ð¤ ¿éÕ·¤ˆß çιæØð ÁæÌð ãñ´Ð

¥Íßæ
(a) 3d â´·ý¤×‡æ Ÿæð‡æè ·ð¤ Ìˆß Ùè¿ð çÎØð ÁæÌð ãñ´ Ñ
Sc Ti V Cr Mn Fe Co Ni Cu Zn

çِ٠©žæÚU ÎèçÁ° Ñ

/
om
(i) ·¤æòÂÚU ·¤æ E0(M21/M) ×æÙ ¥ÂýˆØæçàæÌ M¤Â âð ¥çÏ·¤ ÏÙæˆ×·¤ ãñÐ €Øæð´?
(ii) ·¤æñÙ Ìˆß 12 ©Â¿ØÙ ¥ßSÍæ ×ð´ ÂýÕÜ ¥Â¿æØ·¤ ãñ ¥æñÚU €Øæð´?

.c
(iii) Zn21Ü߇æ Ú´U»ãèÙ ãæðÌð ãñÐ €Øæð´?

em
(b) ·ý¤æð×æ§ÅU ¥ØS·¤ (FeCr2O4) âð âæðçÇUØ× ÇU槷ý¤æð×ðÅU ÕÙæÙð ·¤è çßçÏ ·¤æ ߇æüÙ ·¤èçÁ°Ð
as
(a) Account for the following :
gl
(i) Mn2O7 is acidic whereas MnO is basic.
.a

(ii) Zr and Hf exhibit similar properties.

ls

(iii) Transition metals form a large number of complex compounds.

o

(b) Write the preparation of K2MnO4 from pyrolusite ore(MnO2). Write the
ho

type of magnetism shown by KMnO4 and K2MnO4.

OR
sc

(a) The elements of 3d transition series are given as :

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Sc Ti V Cr Mn Fe Co Ni Cu Zn
tp

Answer the following :

ht

(i) Copper has exceptionally positive E0(M21/M) value.Why ?

(ii) Which element is a strong reducing agent in 12 oxidation state and

why ?

(iii) Zn21salts are colourless.Why ?

(b) Write the preparation of sodium dichromate from chromite ore (FeCr2O4).

56/1/E 13 P.T.O.
 AglaSem Schools

26. (a) çِ٠¥çÖç·ý¤Øæ¥æð´ ×ð´ ÂýˆØð·¤ ·ð¤ ©ˆÂæÎ ·¤æð çÜç¹° Ñ
(i)

(ii)

/
Zn dust
(iii) C6 H52OH  →

om
(b) çِ٠¥çÖç·ý¤Øæ¥æð´ ×ð´ ãæðÙð ßæÜð ÚUæâæØçÙ·¤ â×è·¤ÚU‡ææð´ ·¤æð çÜç¹° Ñ

.c
(i) ÚUè×ÚU-ÅUè×Ù ¥çÖç·ý¤Øæ

em
(ii) Èý¤æ§ÇUðÜ-·ñý¤ÅU÷⠷𤠰ÙèâæðÜ ÿææÚU‡æ ¥çÖç·ý¤Øæ
¥Íßæ
as
(a) €Øæ ãæðÌæ ãñ ÁÕ Ñ
(i) ȤèÙæòÜ âæ´Îý HNO3 âð ¥çÖç·ý¤Øæ ·¤ÚUÌæ ãñÐ
gl

(ii) âñçÜçâçÜ·¤ ¥Ü (CH3CO)2O/H1·ð¤ âæÍ ¥çÖç·ý¤Øæ ·¤ÚUÌæ ãñÐ

.a

(iii) °çÍÜ €ÜæðÚUæ§ÇU NaOCH3 ·ð¤ âæÍ ¥çÖç·ý¤Øæ ·¤ÚUÌæ ãñÐ

ls

ª¤ÂÚUæðQ¤ ¥çÖç·ý¤Øæ¥æð´ âð â´Õ´çÏÌ ÚUæâæØçÙ·¤ â×è·¤ÚU‡ææð´ ·¤æð çÜç¹° Ñ

o

(b) çِ٠·ð¤ Õè¿ Âã¿æÙ ·¤èçÁ° Ñ

ho

(i) °ÍñÙæòÜ ¥æñÚU ȤèÙæòÜ

sc

(ii) ÂýæðÂñÙ-2-¥æòÜ ¥æñÚU 2-×èÍæ§ÜÂýæðÂñÙ-2-¥æòÜ

(a) Write the product(s) in each of the following reactions :
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(i)
tp
ht

(ii)

Zn dust
(iii) C6 H52OH  →

56/1/E 14
 AglaSem Schools

(b) Write the chemical equations involved in the following reactions :

(i) Reimer-Tiemann reaction

(ii) Friedal-Crafts alkylation of anisole.

OR

(a) What happens when :

(i) Phenol reacts with conc.HNO3.

/
om
(ii) Salicylic acid reacts with (CH3CO)2O/H1.

(iii) Ethyl chloride reacts with NaOCH3.

.c
Write the chemical equations involved in the above reactions.

em
(b) Distinguish between :

(i) Ethanol and Phenol

as
(ii) Propan-2-ol and 2-methylpropan-2-ol
gl
.a
o ls
ho
sc
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tp
ht

56/1/E 15 P.T.O.